Downloaded from http://sp.lyellcollection.org/ at University of California Berkeley on July 30, 2013 Rock magnetism of remagnetized carbonate rocks: another look MIKE JACKSON* & NICHOLAS L. SWANSON-HYSELL Institute for Rock Magnetism, Winchell School of Earth Sciences, University of Minnesota, Minnesota, US *Corresponding author (e-mail:
[email protected]) Abstract: Authigenic formation of fine-grained magnetite is responsible for widespread chemical remagnetization of many carbonate rocks. Authigenic magnetite grains, dominantly in the super- paramagnetic and stable single-domain size range, also give rise to distinctive rock-magnetic prop- erties, now commonly used as a ‘fingerprint’ of remagnetization. We re-examine the basis of this association in terms of magnetic mineralogy and particle-size distribution in remagnetized carbon- ates having these characteristic rock-magnetic properties, including ‘wasp-waisted’ hysteresis loops, high ratios of anhysteretic remanence to saturation remanence and frequency-dependent susceptibility. New measurements on samples from the Helderberg Group allow us to quantify the proportions of superparamagnetic, stable single-domain and larger grains, and to evaluate the mineralogical composition of the remanence carriers. The dominant magnetic phase is magnetite-like, with sufficient impurity to completely suppress the Verwey transition. Particle sizes are extremely fine: approximately 75% of the total magnetite content is superparamagnetic at room temperature and almost all of the rest is stable single-domain. Although it has been pro- posed that the single-domain magnetite in these remagnetized carbonates lacks shape anisotropy (and is therefore controlled by cubic magnetocrystalline anisotropy), we have found strong exper- imental evidence that cubic anisotropy is not an important underlying factor in the rock-magnetic signature of chemical remagnetization.