Individually Listed EPCRA Section 313 Chemicals with CAS Numbers Are Arranged Alphabetically Starting on Page II-3
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2,4-Dichlorophenoxyacetic Acid
2,4-Dichlorophenoxyacetic acid 2,4-Dichlorophenoxyacetic acid IUPAC (2,4-dichlorophenoxy)acetic acid name 2,4-D Other hedonal names trinoxol Identifiers CAS [94-75-7] number SMILES OC(COC1=CC=C(Cl)C=C1Cl)=O ChemSpider 1441 ID Properties Molecular C H Cl O formula 8 6 2 3 Molar mass 221.04 g mol−1 Appearance white to yellow powder Melting point 140.5 °C (413.5 K) Boiling 160 °C (0.4 mm Hg) point Solubility in 900 mg/L (25 °C) water Related compounds Related 2,4,5-T, Dichlorprop compounds Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) 2,4-Dichlorophenoxyacetic acid (2,4-D) is a common systemic herbicide used in the control of broadleaf weeds. It is the most widely used herbicide in the world, and the third most commonly used in North America.[1] 2,4-D is also an important synthetic auxin, often used in laboratories for plant research and as a supplement in plant cell culture media such as MS medium. History 2,4-D was developed during World War II by a British team at Rothamsted Experimental Station, under the leadership of Judah Hirsch Quastel, aiming to increase crop yields for a nation at war.[citation needed] When it was commercially released in 1946, it became the first successful selective herbicide and allowed for greatly enhanced weed control in wheat, maize (corn), rice, and similar cereal grass crop, because it only kills dicots, leaving behind monocots. Mechanism of herbicide action 2,4-D is a synthetic auxin, which is a class of plant growth regulators. -
USDA, Forest Service Forest Health Protection GSA Contract No
SERA TR 02-43-13-03b Triclopyr - Revised Human Health and Ecological Risk Assessments Final Report Prepared for: USDA, Forest Service Forest Health Protection GSA Contract No. GS-10F-0082F USDA Forest Service BPA: WO-01-3187-0150 USDA Purchase Order No.: 43-1387-2-0245 Task No. 13 Submitted to: Dave Thomas, COTR Forest Health Protection Staff USDA Forest Service Rosslyn Plaza Building C, Room 7129C 1601 North Kent Street Arlington, VA 22209 Submitted by: Patrick R. Durkin Syracuse Environmental Research Associates, Inc. 5100 Highbridge St., 42C Fayetteville, New York 13066-0950 Telephone: (315) 637-9560 Fax: (315) 637-0445 E-Mail: [email protected] Home Page: www.sera-inc.com March 15, 2003 TABLE OF CONTENTS LIST OF APPENDICES ...................................................... iv LIST OF WORKSHEETS ...................................................... v LIST OF ATTACHMENTS .................................................... v LIST OF TABLES ............................................................ v LIST OF FIGURES ......................................................... viii ACRONYMS, ABBREVIATIONS, AND SYMBOLS .............................. ix COMMON UNIT CONVERSIONS AND ABBREVIATIONS ......................... xi CONVERSION OF SCIENTIFIC NOTATION .................................... xii EXECUTIVE SUMMARY ................................................... xiii 1. INTRODUCTION ........................................................ 1-1 2. PROGRAM DESCRIPTION ................................................ 2-1 2.1. OVERVIEW -
Common and Chemical Names of Herbicides Approved by the WSSA
Weed Science 2010 58:511–518 Common and Chemical Names of Herbicides Approved by the Weed Science Society of America Below is the complete list of all common and chemical of herbicides as approved by the International Organization names of herbicides approved by the Weed Science Society of for Standardization (ISO). A sponsor may submit a proposal America (WSSA) and updated as of September 1, 2010. for a common name directly to the WSSA Terminology Beginning in 1996, it has been published yearly in the last Committee. issue of Weed Science with Directions for Contributors to A herbicide common name is not synonymous with Weed Science. This list is published in lieu of the selections a commercial formulation of the same herbicide, and in printed previously on the back cover of Weed Science. Only many instances, is not synonymous with the active ingredient common and chemical names included in this complete of a commercial formulation as identified on the product list should be used in WSSA publications. In the absence of label. If the herbicide is a salt or simple ester of a parent a WSSA-approved common name, the industry code number compound, the WSSA common name applies to the parent as compiled by the Chemical Abstracts Service (CAS) with compound only. CAS systematic chemical name or the systematic chemical The chemical name used in this list is that preferred by the name alone may be used. The current approved list is also Chemical Abstracts Service (CAS) according to their system of available at our web site (www.wssa.net). -
Transport of Dangerous Goods
ST/SG/AC.10/1/Rev.16 (Vol.I) Recommendations on the TRANSPORT OF DANGEROUS GOODS Model Regulations Volume I Sixteenth revised edition UNITED NATIONS New York and Geneva, 2009 NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ST/SG/AC.10/1/Rev.16 (Vol.I) Copyright © United Nations, 2009 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS Sales No. E.09.VIII.2 ISBN 978-92-1-139136-7 (complete set of two volumes) ISSN 1014-5753 Volumes I and II not to be sold separately FOREWORD The Recommendations on the Transport of Dangerous Goods are addressed to governments and to the international organizations concerned with safety in the transport of dangerous goods. The first version, prepared by the United Nations Economic and Social Council's Committee of Experts on the Transport of Dangerous Goods, was published in 1956 (ST/ECA/43-E/CN.2/170). In response to developments in technology and the changing needs of users, they have been regularly amended and updated at succeeding sessions of the Committee of Experts pursuant to Resolution 645 G (XXIII) of 26 April 1957 of the Economic and Social Council and subsequent resolutions. -
Problématiques Environnementales Et Du Développement Durable
Université Paris EST Ecole Doctorale Sciences, Ingénierie et Environnement THESE DE DOCTORAT Présentée par: SEYDINA IBRAHIMA KEBE Pour obtenir le grade de Docteur de l’Université Paris EST Spécialité : Chimie et Sciences des Matériaux Sujet de Thèse : Synthèse de matériaux monolithiques pour la séparation et la catalyse en phase liquide: Problématiques environnementales et du développement durable Soutenance le 9 décembre 2016 Devant la commission d’examen formée de : K. Faure : Chargée de recherche, CNRS Rapporteur T. Tran-Maignan : Maître de conférences Rapporteur F. Le Derf : Professeur Examinateur A. Elaissari : Directeur de recherche, CNRS Examinateur A. Bressy : Chargée de recherche, CNRS Membre invité M. Guerrouache : Ingénieur de recherche Membre invité B. Carbonnier : Professeur Directeur de thèse Thèse réalisée au sein de l’équipe Systèmes Polymères Complexes, ICMPE, CNRS, Thiais France Remerciements Je tiens à profiter de ce rapport pour exprimer mes plus grands et chaleureux remerciements envers tous ceux qui ont, en leur manière, contribué à la réussite de cette thèse Cette thèse a pu être réalisée grâce à l'accueil Madame Valérie LANGLOIS adjointe directrice de l’ICMPE, directrice du SPC professeur et chercheuse à l’Université Paris Est Créteil (UPEC). Je lui témoigne ma reconnaissance. Je n’aurais jamais commencé sans exprimer tout particulièrement mes plus grands remerciements et à témoigner toute ma reconnaissance à Benjamin CARBONNIER mon directeur de thèse, professeur des universités à l’UPEC pour l’expérience enrichissante qu’il m’a fait vivre. De simples mots, ne sauraient décrire ma satisfaction à son égard. Je tiens à remercier Mohamed GUERROUACHE, ingénieur, pour son temps consacré à me donner des explications et à me guider. -
Herbicide Mode of Action Table High Resistance Risk
Herbicide Mode of Action Table High resistance risk Chemical family Active constituent (first registered trade name) GROUP 1 Inhibition of acetyl co-enzyme A carboxylase (ACC’ase inhibitors) clodinafop (Topik®), cyhalofop (Agixa®*, Barnstorm®), diclofop (Cheetah® Gold* Decision®*, Hoegrass®), Aryloxyphenoxy- fenoxaprop (Cheetah®, Gold*, Wildcat®), fluazifop propionates (FOPs) (Fusilade®), haloxyfop (Verdict®), propaquizafop (Shogun®), quizalofop (Targa®) Cyclohexanediones (DIMs) butroxydim (Factor®*), clethodim (Select®), profoxydim (Aura®), sethoxydim (Cheetah® Gold*, Decision®*), tralkoxydim (Achieve®) Phenylpyrazoles (DENs) pinoxaden (Axial®) GROUP 2 Inhibition of acetolactate synthase (ALS inhibitors), acetohydroxyacid synthase (AHAS) Imidazolinones (IMIs) imazamox (Intervix®*, Raptor®), imazapic (Bobcat I-Maxx®*, Flame®, Midas®*, OnDuty®*), imazapyr (Arsenal Xpress®*, Intervix®*, Lightning®*, Midas®* OnDuty®*), imazethapyr (Lightning®*, Spinnaker®) Pyrimidinyl–thio- bispyribac (Nominee®), pyrithiobac (Staple®) benzoates Sulfonylureas (SUs) azimsulfuron (Gulliver®), bensulfuron (Londax®), chlorsulfuron (Glean®), ethoxysulfuron (Hero®), foramsulfuron (Tribute®), halosulfuron (Sempra®), iodosulfuron (Hussar®), mesosulfuron (Atlantis®), metsulfuron (Ally®, Harmony®* M, Stinger®*, Trounce®*, Ultimate Brushweed®* Herbicide), prosulfuron (Casper®*), rimsulfuron (Titus®), sulfometuron (Oust®, Eucmix Pre Plant®*, Trimac Plus®*), sulfosulfuron (Monza®), thifensulfuron (Harmony®* M), triasulfuron (Logran®, Logran® B-Power®*), tribenuron (Express®), -
Exposure to Herbicides in House Dust and Risk of Childhood Acute Lymphoblastic Leukemia
Journal of Exposure Science and Environmental Epidemiology (2013) 23, 363–370 & 2013 Nature America, Inc. All rights reserved 1559-0631/13 www.nature.com/jes ORIGINAL ARTICLE Exposure to herbicides in house dust and risk of childhood acute lymphoblastic leukemia Catherine Metayer1, Joanne S. Colt2, Patricia A. Buffler1, Helen D. Reed3, Steve Selvin1, Vonda Crouse4 and Mary H. Ward2 We examine the association between exposure to herbicides and childhood acute lymphoblastic leukemia (ALL). Dust samples were collected from homes of 269 ALL cases and 333 healthy controls (o8 years of age at diagnosis/reference date and residing in same home since diagnosis/reference date) in California, using a high-volume surface sampler or household vacuum bags. Amounts of agricultural or professional herbicides (alachlor, metolachlor, bromoxynil, bromoxynil octanoate, pebulate, butylate, prometryn, simazine, ethalfluralin, and pendimethalin) and residential herbicides (cyanazine, trifluralin, 2-methyl-4- chlorophenoxyacetic acid (MCPA), mecoprop, 2,4-dichlorophenoxyacetic acid (2,4-D), chlorthal, and dicamba) were measured. Odds ratios (OR) and 95% confidence intervals (CI) were estimated by logistic regression. Models included the herbicide of interest, age, sex, race/ethnicity, household income, year and season of dust sampling, neighborhood type, and residence type. The risk of childhood ALL was associated with dust levels of chlorthal; compared to homes with no detections, ORs for the first, second, and third tertiles were 1.49 (95% CI: 0.82–2.72), 1.49 (95% CI: 0.83–2.67), and 1.57 (95% CI: 0.90–2.73), respectively (P-value for linear trend ¼ 0.05). The magnitude of this association appeared to be higher in the presence of alachlor. -
Agricultural Biotechnology: Benefits of Transgenic Soybeans
AGRICULTURAL BIOTECHNOLOGY: BENEFITS OF TRANSGENIC SOYBEANS Leonard P. Gianessi Janet E. Carpenter April 2000 National Center for Food and Agricultural Policy 1616 P Street, NW, First Floor Washington, DC 20036 Tel: 202-328-5048 Fax: 202-328-5133 [email protected] Preparation of this report was supported financially with a grant from the Rockefeller Foundation TABLE OF CONTENTS 1. Introduction 2. U.S. Soybean Production 3. Soybean Products 4. Soybean Physiology 5. Soybeans – Agronomic Factors 6. Soybean Genetic Improvements A. Introduction B. Reproductive Process C. Artificial Cross Breeding D. Mutation Breeding E. Transgenic Plants 7. Weed Competition – Soybeans 8. Weed Control in Soybeans: 1940’s – 1950’s 9. Herbicides – An Overview 10. Herbicide Use in Soybeans: 1960’s – 1995 A. Introduction B. Historical Overview 1. The Early 1960’s 2. Soil Applied Herbicides 3. Postemergence Herbicides 4. Sulfonylurea/Imidazolinone Herbicides 5. Burndown Herbicides C. Summary of Usage: 1995 11. Transgenic Herbicide Tolerant Soybeans A. Glyphosate – An Overview B. Performance of Roundup Ready Soybeans C. Herbicide Ratings D. Adoption Impacts: 1995 – 1998 1. Herbicide Costs 2. Soybean Yields 3. Returns 4. Other Aggregate Studies 5. Herbicide Treatments 6. Herbicide Use Amounts 7. Other Impacts 12. Summary and Conclusions 13. References Appendix 1: Soybean Processing – A Description 1. Introduction Soybeans and other crops have been improved genetically for many decades through traditional crop breeding – a technique that requires that species be sexually compatible. With the development of biotechnology methods, scientists have the ability to transfer single genes from one living organism into another, regardless of species or sexual compatibility. Varieties that are developed through the transfer of genes between species that are not sexually compatible are referred to as “transgenic.” Transgenic soybean plants have been developed with a gene from a soil bacteria that allows the use of an herbicide that would normally kill soybeans. -
FSC-TPL-01-002 Application for a Derogation to Use a Highly Hazardous Pesticide
FSC-TPL-01-002 Application for a derogation to use a highly hazardous pesticide. 2,4-D, 2-ethylhexyl ester Name and contact details of SCS certification body requesting Dave Wager derogation: [email protected] 510 251-7049 To be completed at the national level Active ingredient for which derogation requested: Geographical scope of All states of USA requested derogation: Is there an accredited or preliminarily accredited FSC FSC US standard Forest Stewardship Standard applicable to the territory concerned? Requested time period for derogation: 5 years (nb Derogations shall normally be issued for a five-year period. There will be a presumption against renewal of a derogation after the expiry of the five-year period). 1. Demonstrated need Need may be demonstrated where: - The pesticide is used for protecting native species and forests against damage caused by introduced species or for protecting human health against dangerous diseases, OR - Use of the pesticide is obligatory under national laws or regulations, OR - Use of the pesticide is the only economically, environmentally, socially and technically feasible way of controlling specific organisms which are causing severe damage in natural forests or plantations in the specified country (as indicated by consideration, assessments and preferably field-trials of alternative non- chemical or less toxic pest-management methods) Explain how the proposed use complies with the specified criteria for need, including the consideration of alternatives which do not require the use of pesticides on the FSC list of ‘highly hazardous pesticides’: Overview 2,4-D ester is a selective herbicide used to control broad leaved plants such as woody species and forbs. -
Special Report 354 April 1972 Agricultural Experiment Station
ORTMAL DO ;10T REMOVE 7.9 m FILE Special Report 354 April 1972 Agricultural Experiment Station Oregon State University, Corvallis I FIELD APPLICATION OF HERBICIDES--AVOIDING DANGER TO FISH Erland T. Juntunen Department of Fisheries and Wildlife Oregon State University Corvallis, Oregon and Logan A. Norris Pacific Northwest Forestry Sciences Laboratory and Range Experiment Station Forest Service, U. S. Department of Agriculture Corvallis, Oregon April, 1972 Trade names are used in this publication solely to provide specific information. No endorsement of products is intended nor is criticism implieLl to products mentioned or omitted. Recommendations are not made concerning safe use of products nor is any guarantee or warranty of results or effects of the products intended or implied. ii Chemical weed and brush control with herbicides is an important land management practice in modern agriculture and forestry. In some cases, herbicides are applied directly to bodies of water for aquatic weed control. More commonly, herbicides are applied to lands adjacent to waterways for general weed and brush control. The responsible applicator will avoid damage to fishery resources by being fully aware of a particular herbicides potential hazard to fish. Herbicide applications should be considered hazardous to fish when there is the probability fish will be exposed to herbicide concen- trations which are harmful. This bulletin offers information that will aid in selecting the particular herbicides and formulations of least hazard to fish considering the toxicity of the herbicide and the poten- tial for its entry into streams, lakes, or ponds. Entry of Herbicides into the Aquatic Environment In aquatic weed control, the effective concentration of herbicide in the water depends on the rate of application, the rate of the spread of the chemical, the size and chemical composition of the body of water, the rate of degradation or adsorption of the chemical on sediments, and the rate of mixing of treated water with untreated water. -
Five Tyrosines and Two Serines in Human Albumin Are Labeled by the Organophosphorus Agent FP-Biotin
View metadata, citation and similar papers at core.ac.uk brought to you by CORE Chem. Res. Toxicol. 2008, 21, 1787–1794 1787 provided by PubMed Central Five Tyrosines and Two Serines in Human Albumin Are Labeled by the Organophosphorus Agent FP-Biotin Shi-Jian Ding,† John Carr,† James E. Carlson,‡ Larry Tong,§ Weihua Xue,§ Yifeng Li,† Lawrence M. Schopfer,§ Bin Li,§ Florian Nachon,| Oluwatoyin Asojo,† Charles M. Thompson,⊥ Steven H. Hinrichs,† Patrick Masson,| and Oksana Lockridge*,§ Department of Pathology and Microbiology, UniVersity of Nebraska Medical Center, Omaha, Nebraska 68198, Applied Biosystems, Framingham, Massachusetts 01701, Eppley Institute, UniVersity of Nebraska Medical Center, Omaha, Nebraska 68198, Centre de Recherches d SerVice de Sante´ des Arme´es, Unite´ d’Enzymologie, BP87, 38702 La Tronche Cedex, France, and Department of Biomedical and Pharmaceutical Sciences, UniVersity of Montana, Missoula, Montana 59812 ReceiVed April 23, 2008 Tyrosine 411 of human albumin is an established site for covalent attachment of 10-fluoroethoxyphosphinyl- N-biotinamidopentyldecanamide (FP-biotin), diisopropylfluorophosphate, chlorpyrifos oxon, soman, sarin, and dichlorvos. This work investigated the hypothesis that other residues in albumin could be modified by organophosphorus agents (OP). Human plasma was aggressively treated with FP-biotin; plasma proteins were separated into high and low abundant portions using a proteome partitioning antibody kit, and the proteins were digested with trypsin. The FP-biotinylated tryptic peptides were isolated by binding to monomeric avidin beads. The major sites of covalent attachment identified by mass spectrometry were Y138, Y148, Y401, Y411, Y452, S232, and S287 of human albumin. Prolonged treatment of pure human albumin with chlorpyrifos oxon labeled Y138, Y150, Y161, Y401, Y411, and Y452. -
ACTION: Original DATE: 08/20/2020 9:51 AM
ACTION: Original DATE: 08/20/2020 9:51 AM TO BE RESCINDED 3745-100-10 Applicable chemicals and chemical categories. [Comment: For dates of non-regulatory government publications, publications of recognized organizations and associations, federal rules, and federal statutory provisions referenced in this rule, see paragraph (FF) of rule 3745-100-01 of the Administrative Code titled "Referenced materials."] The requirements of this chapter apply to the following chemicals and chemical categories. This rule contains three listings. Paragraph (A) of this rule is an alphabetical order listing of those chemicals that have an associated "Chemical Abstracts Service (CAS)" registry number. Paragraph (B) of this rule contains a CAS registry number order list of the same chemicals listed in paragraph (A) of this rule. Paragraph (C) of this rule contains the chemical categories for which reporting is required. These chemical categories are listed in alphabetical order and do not have CAS registry numbers. (A) Alphabetical listing: Chemical Name CAS Number abamectin (avermectin B1) 71751-41-2 acephate (acetylphosphoramidothioic acid o,s-dimethyl ester) 30560-19-1 acetaldehyde 75-07-0 acetamide 60-35-5 acetonitrile 75-05-8 acetophenone 98-86-2 2-acetylaminofluorene 53-96-3 acifluorfen, sodium salt [5-(2-chloro-4-(trifluoromethyl)phenoxy)-2- 62476-59-9 nitrobenzoic acid, sodium salt] acrolein 107-02-8 acrylamide 79-06-1 acrylic acid 79-10-7 acrylonitrile 107-13-1 [ stylesheet: rule.xsl 2.14, authoring tool: RAS XMetaL R2_0F1, (dv: 0, p: 185720, pa: