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This Is the Author Version Published As: QUT Digital Repository
QUT Digital Repository: http://eprints.qut.edu.au/ This is the author version published as: Frost, Ray L. and Bahfenne, Silmarilly (2010) A Review of the Vibrational Spectroscopic Studies of Arsenite, Antimonite, and Antimonate Minerals. Applied Spectroscopy Reviews: an international journal of principles, methods, and applications, 45(2). pp. 101-129. Copyright Taylor & Francis 1 A Review of the Vibrational Spectroscopic Studies of Arsenite, Antimonite, and 2 Antimonate Minerals 3 4 Silmarilly Bahfenne and Ray L. Frost 5 6 Inorganic Materials Research program, School of Physical and Chemical Sciences, Queensland 7 University of Technology, GPO Box 2434, Brisbane Queensland 4001, Australia 8 9 Abstract 10 11 This review focuses on the vibrational spectroscopy of the compounds and minerals 12 containing the arsenite, antimonite and antimonate anions. The review collects and 13 correlates the published data. 14 15 Key words: Arsenite, antimonite, antimonate, infrared spectroscopy, Raman 16 spectroscopy 17 18 1 19 Arsenite, Antimonite and Antimonate Minerals 20 21 Introduction 22 23 Arsenic and antimony are found throughout the earth’s crust as a variety of minerals, although 24 not particularly abundant. It has been estimated that there are 2 grams of arsenic and 0.2 grams 25 of antimony in every tonne of crustal rocks [1]. Many arsenic-bearing minerals associated with 26 sulphides have been identified, such as arsenopyrite FeAsS, orpiment As2S3, and realgar α- 27 As4S4. When these ores are oxidised, As2O3 is obtained as a by-product. Antimony also 28 occurs with sulphur, Sb2S3 being the principal source. Many oxides have also been identified; 3+ 5+ 29 valentinite Sb2O3 and cervantite Sb Sb O4. -
GRAESERITE, Featisasol3(OH), a NEW MINERAL SPECIES of the DERBYLITE GROUP from the MONTE LEONE NAPPE, BINNTAL REGION, WESTERN AL
1083 The Canadian Mineralogist Vol.36, pp. 1083-1088(1998) GRAESERITE,FeaTisAsOl3(OH), A NEWMINERAL SPECIES OF THE DERBYLITE GROUP FROM THE MONTELEONE NAPPE, BINNTAL REGION, WESTERN ALPS, SWITZERLAND MICHAEL S. KRZEMNICKII Mineralagisch-Petrographischzs Instint, Universitiit Ba$eI, Bemoullistr. 30, CH-4056 Basel, Switzerl.and ERIC REUSSERI Iwtitut fiir Mincralogie und Petrographie, ETH-7zntram, Sonneggstr. 5, CH-8092 Zurich SwitzerLanl AssrRAcr Graeserite, ideally Fe4t3AsOl3(OH), is a new mineral species of the derbylite gloup, which includes derbylite, tomichite, a"ndhemloite. It is found in needle-shapedcrystals, elongate along the c axis. Graeserils i5 6sn6alinig, spacegtoup AXm, with the cell paramelersa 7 .184(2), b 14.289(6),c 5.006(2) A, p 105.17(2)",V 495.9(2) At, z=2, D,a.. =!.56 g/cm3.The VHNxgis_52L (Mohs hardness -595). The strongest five lines of the X-ray powder-diffraction pattern [d in An)(hkD] are: 2.681(100)@31), 2.846(80X131), 1.583(50X351), 3.117 (30)(220), nd 2.029(30)(122). Graeserite is black and metallic, with a black streak; it displays a conchoidal fracture. Pleochroism, bireflectance a"ndinternal reflections were not observed. The measured values of reflecrance in air are compared with those of other members of the derbylite group. Electron-microprobe analyses gave TiO2 40.89, Fe2O333.64, FeO"6" 3.94, PbO 5.00, As2O3 13.51,Sb2O3 1.43, and H2O"a" 1.30, loral 99.80 wt.7o. The empirical formula, based on 13 atoms of oxygen and one hydroxyl group, is (Fe3*z.qrFe2*o.gsTlos+Pbo.rs)>r.grTi3(As3*s.9aSb3*e.m)>r.orOrg(OH). -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
A New Mineral from Mn Ores of the Ushkatyn-III Deposit, 3 Central Kazakhstan and Metamorphic Rocks of the Wanni Glacier, Switzerland 4 5 Oleg S
1 Revision 1 2 Gasparite-(La), La(AsO4), a new mineral from Mn ores of the Ushkatyn-III deposit, 3 Central Kazakhstan and metamorphic rocks of the Wanni glacier, Switzerland 4 5 Oleg S. Vereshchagin*1, Sergey N. Britvin1,6, Elena N. Perova1, Aleksey I. Brusnitsyn1, 6 Yury S. Polekhovsky1, Vladimir V. Shilovskikh2, Vladimir N. Bocharov2, 7 Ate van der Burgt3, Stéphane Cuchet4, and Nicolas Meisser5 8 1Institute of Earth Sciences, St. Petersburg State University, University Emb. 7/9, 199034 St. 9 Petersburg, Russia 10 2Geomodel Centre, St. Petersburg State University, Uliyanovskaya St. 1, 198504 St. 11 Petersburg, Russia 12 3Geertjesweg 39, NL-6706EB Wageningen, The Netherlands 13 4ch. des Bruyeres 14, CH-1007 Lausanne, Switzerland 14 5Musée cantonal de géologie, Université de Lausanne, Anthropole, 1015 Lausanne, 15 Switzerland 16 6Kola Science Center, Russian Academy of Sciences, Fersman Str. 14, 184209 Apatity, 17 Murmansk Region, Russia 18 *E-mail: [email protected] 19 1 20 Abstract 21 Gasparite-(La), La(AsO4), is a new mineral (IMA 2018-079) from Mn ores of the Ushkatyn- 22 III deposit, Central Kazakhstan (type locality) and from alpine fissures in metamorphic rocks 23 of the Wanni glacier, Binn Valley, Switzerland (co-type locality). Gasparite-(La) is named 24 for its dominant lanthanide, according to current nomenclature of rare-earth minerals. 25 Occurrence and parageneses in both localities is distinct: minute isometric grains up to 15 µm 26 in size, associated with fridelite, jacobsite, pennantite, manganhumite series minerals 27 (alleghanyite, sonolite), sarkinite, tilasite and retzian-(La) are typically embedded into 28 calcite-rhodochrosite veinlets (Ushkatyn-III deposit), versus elongated crystals up to 2 mm in 29 size in classical alpine fissures in two-mica gneiss without indicative associated minerals 30 (Wanni glacier). -
Cation Ordering and Pseudosymmetry in Layer Silicates'
I A merican M ineralogist, Volume60. pages175-187, 1975 Cation Ordering and Pseudosymmetryin Layer Silicates' S. W. BerI-nv Departmentof Geologyand Geophysics,Uniuersity of Wisconsin-Madison Madison, Wisconsin5 3706 Abstract The particular sequenceof sheetsand layers present in the structure of a layer silicate createsan ideal symmetry that is usually basedon the assumptionsof trioctahedralcompositions, no significantdistor- tion, and no cation ordering.Ordering oftetrahedral cations,asjudged by mean l-O bond lengths,has been found within the constraints of the ideal spacegroup for specimensof muscovite-3I, phengile-2M2, la-4 Cr-chlorite, and vermiculite of the 2-layer s type. Many ideal spacegroups do not allow ordering of tetrahedralcations because all tetrahedramust be equivalentby symmetry.This includesthe common lM micasand chlorites.Ordering oftetrahedral cations within subgroupsymmetries has not beensought very often, but has been reported for anandite-2Or, llb-2prochlorite, and Ia-2 donbassite. Ordering ofoctahedral cations within the ideal spacegroups is more common and has been found for muscovite-37, lepidolite-2M", clintonite-lM, fluoropolylithionite-lM,la-4 Cr-chlorite, lb-odd ripidolite, and vermiculite. Ordering in subgroup symmetries has been reported l-oranandite-2or, IIb-2 prochlorite, and llb-4 corundophilite. Ordering in local out-of-step domains has been documented by study of diffuse non-Bragg scattering for the octahedral catlons in polylithionite according to a two-dimensional pattern and for the interlayer cations in vermiculite over a three-cellsuperlattice. All dioctahedral layer silicates have ordered vacant octahedral sites, and the locations of the vacancies change the symmetry from that of the ideal spacegroup in kaolinite, dickite, nacrite, and la-2 donbassite Four new structural determinations are reported for margarite-2M,, amesile-2Hr,cronstedtite-2H", and a two-layercookeite. -
New Data on Cafarsite: Reinvestigation of Its Crystal Structure and Chemical Composition
Eur. J. Mineral. 2018, 30, 859–868 Published online 9 May 2018 New data on cafarsite: reinvestigation of its crystal structure and chemical composition 1,* 2 1 1 GEORGIA CAMETTI ,MARIKO NAGASHIMA ,MARTIN FISCH and THOMAS ARMBRUSTER 1 Mineralogical Crystallography, Institute of Geological Sciences, University of Bern, Baltzerstr. 1þ3, 3012 Bern, Switzerland *Corresponding author, e-mail: [email protected] 2 Graduate School of Science and Engineering, Yamaguchi University, Yamaguchi 753-8512, Japan Abstract: The crystal structure of cafarsite from Wanni glacier, Monte Cervandone, was re-investigated by single-crystal X-ray diffraction (space group Pn3, R1 = 0.022) and new electron-microprobe analyses. The REE (mainly Ce and Y) were found to substitute Ca. A new anion site, four-coordinated by Ca, was located by difference Fourier analysis and refined with F scattering factors. Two octahedral sites (Ti1 and Fe2) are occupied by mainly Ti and Fe3þ, replacing each other whereas the octahedral site Mn1 hosts Mn2þ and Fe2þ. The new structure refinements and chemical analyses lead to the simplified chemical formula 3þ 2þ 2þ (Ca7.8Na0.8Mn0.5REE0.4)S9.5(Ti3.9Fe 2.1Fe 0.9Mn 0.1)S7(AsO3)14F0.5. According to our findings, there is no evidence for either H2O or OH in the structure. In contrast to the original study of 1977, the structure has no significant cation vacancies and is based on 14 AsO3 groups per formula unit, not on 12 AsO3 as previously suggested. Key-words: cafarsite; crystal structure; electron-microprobe analyses; calcium titanium arsenite; new formula; REE. 1. Introduction This study was initiated to clarify this contradiction and to determine whether H2O is actually present in cafarsite. -
Arsenic-Rich Fergusonite-Beta-(Y) from Mount Cervandone (Western Alps, Italy): Crystal Structure and Genetic Implications
American Mineralogist, Volume 95, pages 487–494, 2010 Arsenic-rich fergusonite-beta-(Y) from Mount Cervandone (Western Alps, Italy): Crystal structure and genetic implications ALESS A NDRO GU A STONI ,1 FERN A NDO CÁM A R A ,2 A ND FA BRIZIO NESTOL A 1,3,* 1Department of Geoscience, University of Padova, via Giotto 1, 35137 Padova, Italy 2CNR-Institute of Geosciences and Georesources, U.O.S. Pavia, via Ferrata 1, 27100 Pavia, Italy 3CNR-Institute of Geosciences and Georesources, U.O.S. Padova, via Giotto 1, 35137 Padova, Italy ABSTR AC T An As-rich variety of fergusonite-beta-(Y) occurs as greenish yellow pseudo-bipyramidal crystals up to 1 mm in length in centimeter-sized secondary cavities within sub-horizontal pegmatite dikes at Mount Cervandone (Western Alps, Italy). The mineral is associated with quartz, biotite, potassium feldspar, and orange-yellow barrel-shaped hexagonal crystals of synchysite-(Ce) up to 2 mm in length. Fergusonite-beta-(Y) crystallized during the Alpine metamorphism under amphibolite-facies conditions, as a result of interaction between As-enriched hydrothermal fluids, circulating through the pegmatite dikes, and precursor accessory minerals in the pegmatites enriched in high-field-strength elements. These pegmatites are of NYF (niobium-yttrium-fluorine) geochemical type and served as the principal source of Be, Y, Nb, Ta, and rare-earth elements (REE) that were liberated and redeposited as rare Be-As-Y-REE minerals, including the As-rich fergusonite-beta-(Y). The latter mineral crystallizes with monoclinic symmetry [a = 5.1794(14), b = 11.089(3), c = 5.1176(14) Å, β = 91.282(8)°, V = 3 293.87(14) Å , space group I2/a] and has the empirical formula (Y0.70Dy0.07Er0.05Ca0.05Gd0.02U0.02Yb0.01 5+ Tb0.01Th0.01Nd0.01)Σ0.95(Nb0.68As0.27W0.06Ta0.01Si0.01)Σ1.03O4. -
Single Crystal Raman Spectroscopy of Selected Arsenite, Antimonite and Hydroxyantimonate Minerals
SINGLE CRYSTAL RAMAN SPECTROSCOPY OF SELECTED ARSENITE, ANTIMONITE AND HYDROXYANTIMONATE MINERALS Silmarilly Bahfenne B.App.Sci (Chem.) Chemistry Discipline This thesis is submitted as part of the assessment requirements of Master of Applied Science Degree at QUT February 2011 KEYWORDS Raman, infrared, IR, spectroscopy, synthesis, synthetic, natural, X-ray diffraction, XRD, scanning electron microscopy, SEM, arsenite, antimonate, hydroxyantimonate, hydrated antimonate, minerals, crystal, point group, factor group, symmetry, leiteite, schafarzikite, apuanite, trippkeite, paulmooreite, finnemanite. i ii ABSTRACT This thesis concentrates on the characterisation of selected arsenite, antimonite, and hydroxyantimonate minerals based on their vibrational spectra. A number of natural arsenite and antimonite minerals were studied by single crystal Raman spectroscopy in order to determine the contribution of bridging and terminal oxygen atoms to the vibrational spectra. A series of natural hydrated antimonate minerals was also compared and contrasted using single crystal Raman spectroscopy to determine the contribution of the isolated antimonate ion. The single crystal data allows each band in the spectrum to be assigned to a symmetry species. The contribution of bridging and terminal oxygen atoms in the case of the arsenite and antimonite minerals was determined by factor group analysis, the results of which are correlated with the observed symmetry species. In certain cases, synthetic analogues of a mineral and/or synthetic compounds isostructural or related to the mineral of interest were also prepared. These synthetic compounds are studied by non-oriented Raman spectroscopy to further aid band assignments of the minerals of interest. Other characterisation techniques include IR spectroscopy, SEM and XRD. From the single crystal data, it was found that good separation between different symmetry species is observed for the minerals studied. -
29 Devitoite, a New Heterophyllosilicate
29 The Canadian Mineralogist Vol. 48, pp. 29-40 (2010) DOl: 1O.3749/canmin.48.1.29 DEVITOITE, A NEW HETEROPHYLLOSILICATE MINERAL WITH ASTROPHYLLITE-LiKE LAYERS FROM EASTERN FRESNO COUNTY, CALIFORNIA ANTHONY R. KAMPP§ Mineral Sciences Department, Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, California 90007, USA. GEORGE R. ROSSMAN Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125-2500, USA. IAN M. STEELE AND JOSEPH J. PLUTH Department of the Geophysical Sciences, The University of Chicago, 5734 S. Ellis Avenue, Chicago, Illinois 60637, U.S.A. GAIL E. DUNNING 773 Durshire Way, Sunnyvale, California 94087, U.S.A. ROBERT E. WALSTROM P. O. Box 1978, Silver City, New Mexico 88062, USA. ABSTRACT Devitoite, [Ba6(P04MC03)] [Fe2+7Fe3+2(Si4012h02(OH)4], is a new mineral species from the Esquire #8 claim along Big Creek in eastern Fresno County, California, U.SA. It is also found at the nearby Esquire #7 claim and at Trumbull Peak in Mariposa County. The mineral is named for Alfred (Fred) DeVito (1937-2004). Devitoite crystallized very late in a sequence of minerals resulting from fluids interacting with a quartz-sanbornite vein along its margin with the country rock. The mineral occurs in subparallel intergrowths of very thin brown blades, flattened on {001} and elongate and striated parallel to [100]. The mineral has a cream to pale brown streak, a silky luster, a Mohs hardness of approximately 4, and two cleavages: {OO!} perfect and {01O} good. The calculated density is 4.044 g/cm '. It is optically biaxial (+), Cl 1.730(3), 13 1.735(6), 'Y 1.755(3); 2Vcalc = 53.6°; orientation: X = b, Y = c, Z = a; pleochroism: brown, Y»> X> Z. -
Contact Zone Mineralogy and Geochemistry of the Mt. Mica Pegmatite, Oxford County, Maine
University of New Orleans ScholarWorks@UNO University of New Orleans Theses and Dissertations Dissertations and Theses Spring 5-16-2014 Contact Zone Mineralogy and Geochemistry of the Mt. Mica Pegmatite, Oxford County, Maine Kimberly T. Clark University of New Orleans, [email protected] Follow this and additional works at: https://scholarworks.uno.edu/td Part of the Geochemistry Commons, and the Geology Commons Recommended Citation Clark, Kimberly T., "Contact Zone Mineralogy and Geochemistry of the Mt. Mica Pegmatite, Oxford County, Maine" (2014). University of New Orleans Theses and Dissertations. 1786. https://scholarworks.uno.edu/td/1786 This Thesis is protected by copyright and/or related rights. It has been brought to you by ScholarWorks@UNO with permission from the rights-holder(s). You are free to use this Thesis in any way that is permitted by the copyright and related rights legislation that applies to your use. For other uses you need to obtain permission from the rights- holder(s) directly, unless additional rights are indicated by a Creative Commons license in the record and/or on the work itself. This Thesis has been accepted for inclusion in University of New Orleans Theses and Dissertations by an authorized administrator of ScholarWorks@UNO. For more information, please contact [email protected]. Contact Zone Mineralogy and Geochemistry of the Mt. Mica Pegmatite, Oxford County, Maine A Thesis Submitted to the Graduate Faculty of the University of New Orleans in partial fulfillment of the requirements for the degree of Master of Science In Earth and Environmental Science By Kimberly T. Clark B.S. -
Mineralogy and Crystal Structures of Barium Silicate Minerals
MINERALOGY AND CRYSTAL STRUCTURES OF BARIUM SILICATE MINERALS FROM FRESNO COUNTY, CALIFORNIA by LAUREL CHRISTINE BASCIANO B.Sc. Honours, SSP (Geology), Queen's University, 1998 A THESIS SUBMITTED IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF MASTER OF SCIENCE in THE FACULTY OF GRADUATE STUDIES (Department of Earth and Ocean Sciences) We accept this thesis as conforming to the required standard THE UNIVERSITY OF BRITISH COLUMBIA December 1999 © Laurel Christine Basciano, 1999 In presenting this thesis in partial fulfilment of the requirements for an advanced degree at the University of British Columbia, I agree that the Library shall make it freely available for reference and study. I further agree that permission for extensive copying of this thesis for scholarly purposes may be granted by the head of my department or by his or her representatives. It is understood that copying or publication of this thesis for financial gain shall not be allowed without my written permission. Department of !PcX,rU\ a^/icJ OreO-^ Scf&PW The University of British Columbia Vancouver, Canada Date OeC S/79 DE-6 (2/88) Abstract The sanbornite deposits at Big Creek and Rush Creek, Fresno County, California are host to many rare barium silicates, including bigcreekite, UK6, walstromite and verplanckite. As part of this study I described the physical properties and solved the crystal structures of bigcreekite and UK6. In addition, I refined the crystal structures of walstromite and verplanckite. Bigcreekite, ideally BaSi205-4H20, is a newly identified mineral species that occurs along very thin transverse fractures in fairly well laminated quartz-rich sanbornite portions of the rock. -
STRONG and WEAK INTERLAYER INTERACTIONS of TWO-DIMENSIONAL MATERIALS and THEIR ASSEMBLIES Tyler William Farnsworth a Dissertati
STRONG AND WEAK INTERLAYER INTERACTIONS OF TWO-DIMENSIONAL MATERIALS AND THEIR ASSEMBLIES Tyler William Farnsworth A dissertation submitted to the faculty at the University of North Carolina at Chapel Hill in partial fulfillment of the requirements for the degree of Doctor of Philosophy in the Department of Chemistry. Chapel Hill 2018 Approved by: Scott C. Warren James F. Cahoon Wei You Joanna M. Atkin Matthew K. Brennaman © 2018 Tyler William Farnsworth ALL RIGHTS RESERVED ii ABSTRACT Tyler William Farnsworth: Strong and weak interlayer interactions of two-dimensional materials and their assemblies (Under the direction of Scott C. Warren) The ability to control the properties of a macroscopic material through systematic modification of its component parts is a central theme in materials science. This concept is exemplified by the assembly of quantum dots into 3D solids, but the application of similar design principles to other quantum-confined systems, namely 2D materials, remains largely unexplored. Here I demonstrate that solution-processed 2D semiconductors retain their quantum-confined properties even when assembled into electrically conductive, thick films. Structural investigations show how this behavior is caused by turbostratic disorder and interlayer adsorbates, which weaken interlayer interactions and allow access to a quantum- confined but electronically coupled state. I generalize these findings to use a variety of 2D building blocks to create electrically conductive 3D solids with virtually any band gap. I next introduce a strategy for discovering new 2D materials. Previous efforts to identify novel 2D materials were limited to van der Waals layered materials, but I demonstrate that layered crystals with strong interlayer interactions can be exfoliated into few-layer or monolayer materials.