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The Calcium Arsenates
Station RuIletin 131. June, 1918 Oregon Agricultural College Experiment Station AGRICULTURAL CHEMISTRY DEPARTMENT The Calcium Arsenates By R. H. ROBINSON Acting Chemist, Oregon Agricultural Experiment Station. CORVALLIS, OREGON The regular huIlejne of the Station are sent free to the residents of Oregon who request them. THE CALCIUM ARSENATES By R. H. ROBINSON Acting Chemist, Oregon Agricultural Experiment Station INTRODUCTION Chemical investigations on the calcium arsenates relative to their economfic value and practicability as insecticides have been carried on by the department of Agricultural Chemistry of this Station during the past two years.The results obtained from these investigations are presented in this bulletin.The work was supported by the annual funds provided by the Adams Act of the United States Government.. Commercial calcium arsenate is an arsenical now being produced by reliable manufacturers of spray material and offered for sale as a sub- stitute for the arsenates of lead.The value of the latter as a stomachic insecticide has been demonstrated, and itis now used extensively for the successful controlof the codling moth, the destructionof the cotton boll worm., the tobacco worm, and the Colorado potato beetle. Previous inveatigations on the toxic values and killing power of calcium arsenate and lead arsenate indicate equal efficiency. A consideration of a few figures will show the economic advantages which might be gained if calcium arsenate could be substituted for lead arsenate.A conservative estimate of the quantity of lead arsenate used annually in the United States, as stated by one of the largest manufac- turers of spray materials, is probably more than 30,000,000 pounds. -
FENIX OUTDOOR Chemical Guideline and Restricted Substances
Management Guideline Number: SU-POL-FE-01-V04-2018-EN Version: 2.1 Pages: 1 of 82 Valid from: 2018-08-08 Chemical Guideline and Restricted Created by: var. au. /AB Substances List Approved by: Aiko Bode/Swerea FENIX OUTDOOR Chemical Guideline and Restricted Substances List (RSL) 1 Number: SU-POL-FE-01-V04-2018-EN Management Version: 2.1 Guideline Page: 2 of 82 Content 1. General Considerations ......................................................................................................... 4 2. Purpose ................................................................................................................................... 4 3. Scope of Application .............................................................................................................. 5 4. Additional Valid Instructions and Reference Documents ................................................... 5 5. Definition of Terms ................................................................................................................. 5 6. Duties and Responsibilities ................................................................................................... 7 7. Content – The Chemicals List ............................................................................................... 8 7.1 Process and Packaging-related Chemicals 8 7.1.1 Alkylphenol ethoxylates (APEO) and derivatives .......................................................................................... 8 7.1.2 Aliphatic organic solvents ............................................................................................................................. -
EWG VERIFIED™ Products Cannot Contain Any of the Ingredients Outlined in This Document
EWG’S UNACCEPTABLE LIST: Baby Diapers EWG VERIFIED™ products cannot contain any of the ingredients outlined in this document. Appendix A. Substances prohibited inEWG VERIFIED diapers based on GHS hazard classifications. A = aquatic toxicity, C = carcinogenicity, D = reproductive toxicity (development), F = reproductive toxicity (fertility), L = reproductive toxicity (lactation [breast-feeding children]), M = mutagenic, Sr = sensitization (respiratory), Ss =sensitization (skin) Chemical name(s) EC Number(s) CAS Number(s) Hazards ((4-phenylbutyl)hydroxyphosphoryl)acetic acid 412-170-7 83623-61-4 Ss (-)(3S,4R)-4-(4-fluorophenyl)-3-(3,4-methylenedioxy-phenoxymethyl)-N-benzylpiperidine hydrochloride 432-360-3 105813-13-6 SsA (+)-(1S,2S,3S,5R)-2,6,6-trimethylbicyclo[3.1.1]heptane-3-spiro-1'-(cyclohex-2'-en-4'-one) 430-460-1 133636-82-5 SsA (+/-)-(R*,R*)-6-fluoro-3,4-dihydro-2-oxiranyl-2H-1-benzopyran; 6-fluoro-2-(2-oxiranyl)chromane 419-620-1 - Ss (±) trans-3,3-dimethyl-5-(2,2,3-trimethyl-cyclopent-3-en-1-yl)-pent-4-en-2-ol 411-580-3 107898-54-4 A (±)-[(R*,R*) and (R*,S*)]-6-fluoro-3,4-dihydro-2-oxiranyl-2H-1-benzopyran 419-600-2 99199-90-3 Ss (±)-4-(3-chlorophenyl)-6-[(4-chlorophenyl)hydroxy(1-methyl-1H-imidazol-5-yl)methyl]-1-methyl-2(1H)-quinolin 430-730-9 - A (±)-4-[2-[[3-(4-hydroxyphenyl)-1-methylpropyl]amino]-1-hydroxyethyl]phenol hydrochloride 415-170-5 90274-24-1 Ss (±)-α-[(2-acetyl-5-methylphenyl)-amino]-2,6-dichlorobenzene-aceto-nitrile 419-290-9 Ss (1,3,4,5,6,7-hexahydro-1,3-di-oxo-2H-isoindol-2-yl)methyl (1R-trans)-2,2-dimethyl-3-(2-methylprop-1- -
Chemicals of High Concern List (Sorted Alphabetically), July 2010
Minnesota Department of Health, Chemicals of High Concern list, July 1, 2010 Persistent, Bioaccumulative, Toxic or very CAS Persistent, very HPV (2006 and 3 of 4 Number Chemical Name Health endpoint(s) Bioaccumulative Source(s) Use example(s) or class years) (S)-4-hydroxy-3-(3-oxo-1-phenylbutyl)-2- Maine (EU Reproductive 5543-57-7 benzopyrone Reproduction Toxicant) Sunscreen Maine (CA Prop 65; IARC; EU Carcinogen; NTP 11th ROC; OSPAR Chemicals of High Concern); WA Appen1; 91-94-1 [1,1'-biphenyl]-4,4'-diamine, 3,3'-dichloro-Cancer x Minnesota HRL Dye, curing agent Maine (OSPAR Chemicals of [1,1'-biphenyl]-4,4'-diamine, N,N'-bis(2,4- Concern; Canada PBiT); WA 29398-96-7 dinitrophenyl)-3,3'-dimethoxy- x Appen1 Colorant [1,1'-Biphenyl]-4-ol, 3,4',5-tris(1,1- Maine (Canada PBiT); WA 6257-39-2 dimethylethyl)- x Appen1 [1,1'-Biphenyl]-4-ol, 3,4'-bis(1,1- Maine (Canada PBiT); WA 42479-88-9 dimethylethyl)- x Appen1 Chemical intermediate [1,1'-biphenyl]-4-ol, 3,5-bis(1,1- Maine (OSPAR Chemicals of 2668-47-5 dimethylethyl)- x Concern); WA Appen1 [2,6'-Bibenzothiazole]-7-sulfonic acid, 2'- (4-aminophenyl)-6-methyl-, diazotized, coupled with diazotized 4- aminobenzenesulfonic acid and Maine (Canada PBiT); WA 91696-90-1 resorcinol, sodium salts x Appen1 1(2H)-Quinolineethanol, 6-[(2-chloro-4,6- dinitrophenyl) azo]-3,4-dihydro-2,2,4,7- Maine (Canada PBiT); WA 63133-84-6 tetramethyl- x Appen1 1(2H)-Quinolinepropanamide, 6-(2,2- dicyanoethenyl)-3, 4-dihydro-2,2,4,7- Maine (Canada PBiT); WA 63467-15-2 tetramethyl-N-phenyl- x Appen1 1,1,1,2-Tetrachloro-2,2-bis(4- -
Alfa Laval Black and Grey List, Rev 14.Pdf 2021-02-17 1678 Kb
Alfa Laval Group Black and Grey List M-0710-075E (Revision 14) Black and Grey list – Chemical substances which are subject to restrictions First edition date. 2007-10-29 Revision date 2021-02-10 1. Introduction The Alfa Laval Black and Grey List is divided into three different categories: Banned, Restricted and Substances of Concern. It provides information about restrictions on the use of Chemical substances in Alfa Laval Group’s production processes, materials and parts of our products as well as packaging. Unless stated otherwise, the restrictions on a substance in this list affect the use of the substance in pure form, mixtures and purchased articles. - Banned substances are substances which are prohibited1. - Restricted substances are prohibited in certain applications relevant to the Alfa Laval group. A restricted substance may be used if the application is unmistakably outside the scope of the legislation in question. - Substances of Concern are substances of which the use shall be monitored. This includes substances currently being evaluated for regulations applicable to the Banned or Restricted categories, or substances with legal demands for monitoring. Product owners shall be aware of the risks associated with the continued use of a Substance of Concern. 2. Legislation in the Black and Grey List Alfa Laval Group’s Black and Grey list is based on EU legislations and global agreements. The black and grey list does not correspond to national laws. For more information about chemical regulation please visit: • REACH Candidate list, Substances of Very High Concern (SVHC) • REACH Authorisation list, SVHCs subject to authorization • Protocol on persistent organic pollutants (POPs) o Aarhus protocol o Stockholm convention • Euratom • IMO adopted 2015 GUIDELINES FOR THE DEVELOPMENT OF THE INVENTORY OF HAZARDOUS MATERIALS” (MEPC 269 (68)) • The Hong Kong Convention • Conflict minerals: Dodd-Frank Act 1 Prohibited to use, or put on the market, regardless of application. -
The Synthesis and Characterization of Novel Pentafluorosulfanyl-Containing Heterocycles and Pentafluorosulfanyldifluoromethane
Clemson University TigerPrints All Dissertations Dissertations May 2019 The yS nthesis and Characterization of Novel Pentafluorosulfanyl-Containing Heterocycles and Pentafluorosulfanyldifluoromethane Steven Paul Belina Clemson University, [email protected] Follow this and additional works at: https://tigerprints.clemson.edu/all_dissertations Recommended Citation Belina, Steven Paul, "The yS nthesis and Characterization of Novel Pentafluorosulfanyl-Containing Heterocycles and Pentafluorosulfanyldifluoromethane" (2019). All Dissertations. 2373. https://tigerprints.clemson.edu/all_dissertations/2373 This Dissertation is brought to you for free and open access by the Dissertations at TigerPrints. It has been accepted for inclusion in All Dissertations by an authorized administrator of TigerPrints. For more information, please contact [email protected]. THE SYNTHESIS AND CHARACTERIZATION OF NOVEL PENTAFLUOROSULFANYL-CONTAINING HETEROCYCLES AND PENTAFLUOROSULFANYLDIFLUOROMETHANE A Dissertation Presented to the Graduate School of Clemson University In Partial Fulfillment of the Requirements for the Degree Doctor of Philosophy Chemistry by Steven Paul Belina May 2019 Accepted by Joseph S. Thrasher, Ph.D., Committee Chair Julia L. Brumaghim, Ph.D. R. Karl Dieter, Ph.D. Joseph W. Kolis, Ph.D. Title Page ABSTRACT Beginning in the early 1960s, scientists began to experiment with the pentafluorosulfanyl moiety. The unique properties of the functional group has attracted interest among fluorine chemists and more recently even organic chemists. These properties include high group electronegativity, high steric bulk, high lipophilicity, a highly electron withdrawing nature, and a square pyramidal geometry. However, the development and deployment of the pentafluorosulfanyl functional group has been significantly slowed. The main cause for the slow development is a lack of easily available reagents to synthesize pentafluorosulfanyl-containing compounds. Historically, the primary reagents used for synthesizing pentafluorosulfanyl-containing compounds were SF5Cl and SF5Br. -
The East African Sub-Regional Project
UNEPIUNDP/DUTCH Joint Project on Environmental Law UNEP and Institutions in Africa THE EAST AFRICAN SUB-REGIONAL PROJECT DEVELOPMENT AND HARMONISATION OF ENVIRONMENTAL LAWS VOLUME 4 DECEMBER 1999 ,44 UNEP/UNDP/DUTCH Joint Project on Environmental Law and Institutions in Africa UNEP UWD TILE EAST AFRICAN SUB-REGIONAL PROJECT DEVELOPMENT AND HARMONISATION OF ENVIRONMENTAL LAWS VOLUME 4 REPORT ON THE DEVELOPMENT AND HARMONISATION OF LAWS ON HAZARDOUS AND NON-HAZARDOUS WASTES 7$ ? 4 + December 1999 ISBN: 92-807-1887-8 PREFACE Environmental law is an essential tool for the governance East African countries are focused on issues which are and management of the environment and natural resources. essentially of sub-regional character. The management of the It is the foundation of national and regional policies and Joint Project is based at UNEP within its environmental law actions to ensure that the use of natural resources is done activities and is directed by a Task Manager, who works under equitably and sustainably. guidance of a Steering Committee. Members of the Steering Committee are UNEP, UNDP, FAO, The World Bank, IUCN In the East African sub-regional countries of Kenya, Tanzania Environmental Law Centre and The Dutch Government. and Uganda have, since 1995, been developing and harmoning various environmental laws in selected sectors THE PROCESS FOR DEVELOPMENT AND within their region. The process of developing and HARMONiZATION OF THE LAWS harmonizing environmental laws is intended to lead to the enactment or amendment of the internal legislative, regulatory Representatives of the three governments met in February and administrative framework of each country. Such change 1995 to work out general principles and modalities for their has been harmonized at a sub-regional level where the three cooperation. -
2019 Minnesota Chemicals of High Concern List
Minnesota Department of Health, Chemicals of High Concern List, 2019 Persistent, Bioaccumulative, Toxic (PBT) or very Persistent, very High Production CAS Bioaccumulative Use Example(s) and/or Volume (HPV) Number Chemical Name Health Endpoint(s) (vPvB) Source(s) Chemical Class Chemical1 Maine (CA Prop 65; IARC; IRIS; NTP Wood and textiles finishes, Cancer, Respiratory 11th ROC); WA Appen1; WA CHCC; disinfection, tissue 50-00-0 Formaldehyde x system, Eye irritant Minnesota HRV; Minnesota RAA preservative Gastrointestinal Minnesota HRL Contaminant 50-00-0 Formaldehyde (in water) system EU Category 1 Endocrine disruptor pesticide 50-29-3 DDT, technical, p,p'DDT Endocrine system Maine (CA Prop 65; IARC; IRIS; NTP PAH (chem-class) 11th ROC; OSPAR Chemicals of Concern; EuC Endocrine Disruptor Cancer, Endocrine Priority List; EPA Final PBT Rule for 50-32-8 Benzo(a)pyrene x x system TRI; EPA Priority PBT); Oregon P3 List; WA Appen1; Minnesota HRV WA Appen1; Minnesota HRL Dyes and diaminophenol mfg, wood preservation, 51-28-5 2,4-Dinitrophenol Eyes pesticide, pharmaceutical Maine (CA Prop 65; IARC; NTP 11th Preparation of amino resins, 51-79-6 Urethane (Ethyl carbamate) Cancer, Development ROC); WA Appen1 solubilizer, chemical intermediate Maine (CA Prop 65; IARC; IRIS; NTP Research; PAH (chem-class) 11th ROC; EPA Final PBT Rule for 53-70-3 Dibenzo(a,h)anthracene Cancer x TRI; WA PBT List; OSPAR Chemicals of Concern); WA Appen1; Oregon P3 List Maine (CA Prop 65; NTP 11th ROC); Research 53-96-3 2-Acetylaminofluorene Cancer WA Appen1 Maine (CA Prop 65; IARC; IRIS; NTP Lubricant, antioxidant, 55-18-5 N-Nitrosodiethylamine Cancer 11th ROC); WA Appen1 plastics stabilizer Maine (CA Prop 65; IRIS; NTP 11th Pesticide (EPA reg. -
Open MYO THEIN-Phd Dissertation
The Pennsylvania State University The Graduate School Department of Engineering Science and Mechanics BIOCHIPS EMPLOYING MICROELECTRODES AND MICROTRANSDUCERS FOR CHARACTERIZATION AND PERMEABILIZATION OF CELL MEMBRANE AT THE WHOLE–CELL AND CELLULAR LEVEL A Dissertation in Engineering Science and Mechanics by Myo Min Thein © 2010 Myo Min Thein Submitted in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy December 2010 The dissertation of Myo Min Thein was reviewed and approved* by the following: Jian Xu Associate Professor of Engineering Science and Mechanics and Adjunct Professor of Electrical Engineering Thesis Advisor and Chair of Committee Bernhard R. Tittmann Schell Professor of Engineering Science and Mechanics Yinong Yang Associate Professor of Plant Pathology Sulin Zhang Assistant Professor of Engineering Science and Mechanics Judith A. Todd P. B. Breneman Department Head Chair Head of the Department of Engineering Science and Mechanics * Signatures are on file in the Graduate School. ii Abstract In this study, two types of biochips, Integrated Microelectrode Array (IMA) chip and Ultrasonic Micro–Transducer Array (UMTA) biochip, were designed and micro– fabricated. The IMA chip employs cell–size microelectrode array architecture in order to electrically characterize cellular components, especially the properties of cell membrane, at the single–cell level. The UMTA biochip consists of arrays of high–aspect–ratio piezoelectric micro–transducers that are employed to efficiently permeabilize the cell membrane -
United States Patent As Fice Patiented Sept
s 2,904,403 United States Patent As fice Patiented Sept. 15, 1959 1 2 are agitated during this period by any suitable means. The vessel is then cooled, opened and iodine penta 2,904,403 fluoride collected and purified by conventional procedures such as distillation. When alkali or alkaline earth metal PREPARATION OF BF iodates are used in the process, the iodine pentafluoride William Channing Smith, Wilmington, Del, assignor to may be isolated in the form of a solid complex compound E. H. du Pont de Nemours and Company, Wilmington, with alkali or alkaline earth metal fluorides. Dei, a corporation of Delaware in a continuous process gaseous sulfur tetrafluoride is No Drawing. Application June 7, 1957 passed through a tube containing the iodine compound, Serial No. 664,162 0 preferably heated to a temperature high enough to vola tilize the iodine pentafluoride as it is formed. The 5 Claims. (C. 23-205) iodine pentafluoride is separated from the gas effluent by cooling in traps and the unreacted sulfur tetrafluoride is recycled through the reaction tube. This invention relates to iodine fluorides and has as 5 The following examples illustrate the process of the its primary object provision of a novel method of prepar invention. ing such fluorides, iodine pentafluoride in particular. Iodine pentafluoride is a versatile and well-known Example 1 fluorinating agent which can be used to prepare fluorine (A) A bomb, lined with stainless steel and of 145 mi. bearing compounds that are not readily accessible by 20 capacity, was charged with 33.4 g. (0.10 mode) of iodine other routes. -
Hazardous Waste Classification
HAZARDOUS WASTE CLASSIFICATION: REVIEW OF WORST CASE TO LESS WORST CASE METAL SPECIES WITH A WORKED EXAMPLE FOR A CONTAMINATED SOIL Ian Bishop 1,* and Pierre Hennebert 2 1 One Touch Data Ltd, Suite 4, Third Floor, Nicholsons House, Nicholsons Walk, Maidenhead SL6 1LD, United Kingdom 2 INERIS (National Institute for Industrial Environment and Risks), BP 2, F-60550 Verneuil-en-Halatte, France Article Info: ABSTRACT Received: The classification of waste as either hazardous or non-hazardous, especially for mix- 28 October 2020 Revised: tures such as contaminated soils, ashes, filter cakes and sludges, is not straight for- 17 February 2021 ward. In particular, as the laboratories can only measure total metal concentrations, Accepted: both the European and the UK technical guidance state that if the classifier doesn’t 25 February 2021 know exactly which metal species is in their waste, then they should start from a Available online: worst case species and use lines of evidence to work towards a more reasonable 31 March 2021 (less hazardous) species. However, the guidance doesn’t define or list worst case Keywords: nor less worst case species. While some authors have documented worst case spe- Hazardous properties cies, this is only in relation to documenting the concentrations at which each hazard Worst case Metal species property is triggered for a given worst case species. This paper addresses this gap. It documents how to define both the worst case species and more importantly, lists less worst case species for 32 elements and 204 metal species; species based on those listed in the European legislation but also supplemented by species that hav- en’t (yet) been included in this legislation but are significant nevertheless. -
31.12.2008 EN Official Journal of the European Union L 353/923
31.12.2008 Table 3.2 The list of harmonised classification and labelling of hazardous substances from Annex I to Directive 67/548/EEC Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes 001-001-00-9 hydrogen 215-605-7 1333-74-0 F+; R12 F+ EN R: 12 S: (2-)9-16-33 001-002-00-4 aluminium lithium hydride 240-877-9 16853-85-3 F; R15 F R: 15 S: (2-)7/8-24/25-43 Official Journal of the European Union L 353/923 001-003-00-X sodium hydride 231-587-3 7646-69-7 F; R15 F R: 15 S: (2-)7/8-24/25-43 001-004-00-5 calcium hydride 232-189-2 7789-78-8 F; R15 F R: 15 S: (2-)7/8-24/25-43 003-001-00-4 lithium 231-102-5 7439-93-2 F; R15 F; C R14 R: 14/15-34 C; R34 S: (1/2-)8-43-45 003-002-00-X n-hexyllithium 404-950-0 21369-64-2 F; R15-17 F; C R14 R: 14/15-17-35 C; R35 S: (1/2-)6-16-26-30- 36/37/39-43-45 004-001-00-7 beryllium 231-150-7 7440-41-7 Carc. Cat. 2; T+ E R49 R: 49-25-26-36/37/ T+; R26 38-43-48/23 T; R25-48/23 S: 53-45 Xi; R36/37/ 38 R43 L 353/924 Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes 004-002-00-2 beryllium compounds with the exception of aluminium —— Carc.