Sludge Stabil: Hanford Site, Zation at the Plutonium Finish

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Sludge Stabil: Hanford Site, Zation at the Plutonium Finish DOE~A-0978 . Sludge Stabil:zation at the Plutonium Finish: ng Plant, -, Hanford Site, Mchland, Washington U.S. Dep-ent of Energ NcMand, Wash@on October 1994 _—_— DOE~A-0978 I I ( I —....— .—.. U,S. Deparment of Energy Glossary Glossary Acronp md Abbreviation ARF airborne release fraction ASIL Acceptable Source Impact Level D&D dmontamination and decommissioning DOE U.S. Department of Energy EA Environment Assessment Ecology State of Washington Department of Ecology EDE effective dose equivalent EIS Environment Impact Statement EPA U.S. Environment Protection Agency FFTF Fmt Flux Test Facflity HEPA High-Efficiency Partictiate Air LFL lower flammability limit LCF latent cancer fatrdity NESHAP Natioti Emission S~dards for H=dous Air Pollutants PFP Plutonium Finishing Plant PRF Plutonium Reclamation Factiity PUREX Plutonium-Uranium Extraction RCW Resource Conservationand Recove~ A~ of 1976 rem Roentgen Equivalent Man RMC ~ remote mechanical “C” TBP tributyl phosphate TLV-STEL Threshold Limit Value - Short Term Exposure Limit TLV-TWA Threshold Limit Value - Time Weighted Average Tri-Party Agreement Hanford Federal Facilip Agreement and Consent Order TRUS@ Transuranic Waste Storage and Assay Factiity WAC WmhingtonAdministr~.ve Code WIPP Waste Isolation Ptiot Plant Definition of Selected Tem Effective Dose Eauivdent. A value used for estimating the toti risk of potential health effects from radiation exposure. This estimate is the sum of the committed effective dose equivalent from interti deposition of radionuclidm in the body and the effective dose equivalent from exterti radiation received during a year. Latent cancer fatalitv: The excess mcer fatiities h a population due to exposure to a carcinogen. DOEEA-0978 October 1994 — -—— — U.S. Department of Energy Glossary Defiition of Seleded Terms (cont.) Maximdlv exuosed individud. A hypothetical member of tie public residing near the Hanford Site who, by virtue of location and living habits, could receive the highest possible radiation dose from radioactive effluents released from the Hanford Site. Person-rem. A population dose based on the number of persons multiplied by the radiation dose. Plutonium Finishing Plant. The Plutonium Finishing Plant, a complex of many butidings, mostiy atiched, that functioned to provide plutonium in various forms for defense purposes. In the past, the plant has dso been referred to as the “Z Plant. ” roent~en eauivdent man (rem). A special unit of dose equivalent that indicates the potential for impact on human cells.The dose equivalent in reins is numericrdly equal to the absorbed dose in rads multiplied by the quality factor, the distribution factor, and any other necessary modifying factors. Remote mechanical “C”. Remote mechanical “C” line, historically the third planned meti processing line at the Plutonium Ftishing Plant. x. A muddY Or SIUShYm~s, deposit, Or sedfient SUCh= a PreciPi~ted solid matter or a precipitate or setiing in liquid (such as a mixture of impurities and acid). Transuranic waste. Without regard to source or form, radioactive waste that at the end of institutioti control periods is con-ted with alpha-emitting radionuclides of atomic numbers greater than 92 with hrdf-lives greater than 20 years and concentrations greater than 100 nCi/g. Scientific Notation Conversion Chart Mdtipfier I Eqnivdent Mdtipfier Equivalent 10’ I 1,000,000 ~ol 0.1 10’ / 100,000 102 .01 104 I 10,000 103 .001 103 I 1,000 II 104 I .0001 lV I 100 II 10’ I .OOOO1 ’101 I 10 II lo~ I .000001 loo 11 II 10-7 I .0000001 I II 108 I .00000001 I DOE~A-0978 G-2 October 1994 ..-. .—. —. , .1 >. .>,. .>,.’ —--T ... — U.S. Department of Energy Glossary ( Metric Conversion Chart Mdtiply n you how To get E you how MdtipIy by To get by Length centimeters 0.393 inches Mometers 0.62 ties meters 3.2808 feet cubic meters 35.34 cubic feet Area square 0.39 square ties square 0.1550003 square kilometers centimeters inch Mass (wei@t) grams 0.0022 pounds grams 0.035 ounces Mlograrns 2.2046 pounds Volume liters 0.26 gtions cubic meters 35.3147 cubic feet Temperature Celsius mdtiply by 9/5ths, then add 32 Fahrenheit I Source: ~C Ha@ook of Oem ad P@tia, Robert C. W-t, Ph.D., 70th Ed., 1989-1990, CRC Press, he., Boca Raton, Morida. I DOE~A-0978 G-3 October 1994 ,- . ... I U.S. Depwtient of Energy Executive -W I I Executive S~ary ‘1I This Environment Assessment evaluates the proposed action to operate two laboratory-size muffle furnaces in glovebox HC-21C, lomted in the Plutonium Finishing I Plant (PFP), Hanford Site, Rictiand, Washington. A muffle furnace is a type of small electric radiant oven. The cavity is surrounded by fue brick to separate the material being dried from the heating elements. The muffle furnaces would be used to stabflize chemically reactive sludges that contain approximately 25 tiograms (55 pounds) of plutonium by 1 heating to approximately 500 to 1000 ‘C (900 to 1800 ‘F). The resulting stable powder, 1I mostly plutonium oxide with impurities, would be stored in the PFP vad~. I The presence of chemic~y reactive plutonium-bearing sludges in the process gloveboxes poses a risk to workers from radiation exposure and limib the avaflabtiity of storage space for future plant cleanup. Therefore, there is a need to stabflizethe material . into a form suitable for long-term storage. This proposed action would be an interim action, which would tie place prior to completion of an Environment Impact Statement for the PFP which would evaluate stabdization of dl plutonium-bearing materials and cleanout of the factiity. However, ody 10 percent of the toti quantity of plutonium in reactive materials is in the sludges, so this action wtil not limit the choice of reasonable alternatives or prejudice the Record of Decision of the Plutonium Finishing Plant Environment Impact Statement. The sludge stabdization process would consist of relocating sludge containers from the Plutonium Reclamation Facflity to Room 230A and into glovebox HC-21C, pouring the material into a boat (crucible) for heating, and weighing tie fu~ boat. After weighing the DOE~A-0978 m-l October 1994 -.. U.S. Depar~ent of Energy Executive Sununary boat, it would be placed into one of the tinaces, and the furnace temperature controller would be programmed to slowly heat the sludges. The heating cycle would vary depending on the composition of the sludges. During the heating process, plutonium compounds would be converted to plutonium oxide, and any excess moisture would be driven off. After heating, the furnace would be allowed to cool, then the stabtiized material would be removed from the furnace, transferred to another glovebox, sieved, and dyzed for stabtiity. Other routine operations may be performed on the material, such as hand grinding the residues in order to prepare the material for storage. If acceptable, the material would be repackaged and removed from the glovebox for storage. Material that does not meet storage acceptance criteria would be recycled through the stabflintion process. Completion of sludge stabtiization would require about 400 to 600 batches. The uncertainty is due to the assumed recycle rate and other factors. It is estimated that the process would average two batches, per furnace, per day. Each batch would be limited to less than 500 grams (1. 1 pounds) of material per batch, and less than 2 percent organic composition. The stable, impure plutonium oxide would be packaged in approximately 150 l-liter (0.264-gdlon) containers, and stored in the PFP storage vaults awaiting future disposition. There is sufficient capacity in the vaults to accept this material. The No-Action alternative to the proposed action would be to not process the sludges. The sludges would continue to be stored in the gloveboxes. This would not accomplish the I purpose for this proposed action. DOE~A-0978 Es-2 October 1994 I -- —., 1 ,:’. ,, . .—.. — U.S. Depmment of Energy Executive -SY Another alternative to the proposed action would be to discard the sludges as waste, rdthough this alternative is not permitted under current rules. The sludges would be combined with a cement-like material which would be packaged in waste drums. Approximately 250 208-liter (55 gallon) drums of contact-handed transuranic waste would be i generated from the sludges. The drums would be stored in Hanford Site waste facfiities, untfl a fii repository was avaflable. Another alternative considered several processing alternatives that would stabflize the sludges. These processing operations include operating the Plutonium Reclamation Facflity (PRF) or vitrifying the sludges. These alternatives are viable; however, tie PRF process is simtiar to historical defense production proctises; in some instances (i.e., vitri@ing), make the processed material incompatible for future disposition and would expose the operating staff to substantially higher doses of radiation. Operation of the furnaces under the proposed action would produce low levels of radiological air emissions due to the furnace offgas. The offgas would be faltered twice prior I to exiting the plant stack. After passing through the fdtration, the to~ plant emissions would not be measurably increased above current levels. The estimated health effect to the public from toti plant emissions has historically averaged about 0.00005 latent cancer fatality (LCF) per year (O.1 Roentgen Equivalent Man [rem] per year) for the population within 80 Uometers (50 mfles) of the PFP. No fati mcers are expected to be attributable to this exposure. DOEkA-0978 Es-3 October 1994 U.S. Depa~ent of Energy Executive SununWy The process would generate small amounts of gaseous butene, nitrogen oxides, carbon dioxide and water. The resulting maximum onsite and offsite concentrations from continuous emission of these chemicals out the plant stack would be a factor of 1~ or lower than any applicable health standards.
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