A Continuous Coordinate System for the Plane by Triangular Symmetry
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Molecular Symmetry
Molecular Symmetry Symmetry helps us understand molecular structure, some chemical properties, and characteristics of physical properties (spectroscopy) – used with group theory to predict vibrational spectra for the identification of molecular shape, and as a tool for understanding electronic structure and bonding. Symmetrical : implies the species possesses a number of indistinguishable configurations. 1 Group Theory : mathematical treatment of symmetry. symmetry operation – an operation performed on an object which leaves it in a configuration that is indistinguishable from, and superimposable on, the original configuration. symmetry elements – the points, lines, or planes to which a symmetry operation is carried out. Element Operation Symbol Identity Identity E Symmetry plane Reflection in the plane σ Inversion center Inversion of a point x,y,z to -x,-y,-z i Proper axis Rotation by (360/n)° Cn 1. Rotation by (360/n)° Improper axis S 2. Reflection in plane perpendicular to rotation axis n Proper axes of rotation (C n) Rotation with respect to a line (axis of rotation). •Cn is a rotation of (360/n)°. •C2 = 180° rotation, C 3 = 120° rotation, C 4 = 90° rotation, C 5 = 72° rotation, C 6 = 60° rotation… •Each rotation brings you to an indistinguishable state from the original. However, rotation by 90° about the same axis does not give back the identical molecule. XeF 4 is square planar. Therefore H 2O does NOT possess It has four different C 2 axes. a C 4 symmetry axis. A C 4 axis out of the page is called the principle axis because it has the largest n . By convention, the principle axis is in the z-direction 2 3 Reflection through a planes of symmetry (mirror plane) If reflection of all parts of a molecule through a plane produced an indistinguishable configuration, the symmetry element is called a mirror plane or plane of symmetry . -
ICES REPORT 14-22 Characterization, Enumeration and Construction Of
ICES REPORT 14-22 August 2014 Characterization, Enumeration and Construction of Almost-regular Polyhedra by Muhibur Rasheed and Chandrajit Bajaj The Institute for Computational Engineering and Sciences The University of Texas at Austin Austin, Texas 78712 Reference: Muhibur Rasheed and Chandrajit Bajaj, "Characterization, Enumeration and Construction of Almost-regular Polyhedra," ICES REPORT 14-22, The Institute for Computational Engineering and Sciences, The University of Texas at Austin, August 2014. Characterization, Enumeration and Construction of Almost-regular Polyhedra Muhibur Rasheed and Chandrajit Bajaj Center for Computational Visualization Institute of Computational Engineering and Sciences The University of Texas at Austin Austin, Texas, USA Abstract The symmetries and properties of the 5 known regular polyhedra are well studied. These polyhedra have the highest order of 3D symmetries, making them exceptionally attractive tem- plates for (self)-assembly using minimal types of building blocks, from nanocages and virus capsids to large scale constructions like glass domes. However, the 5 polyhedra only represent a small number of possible spherical layouts which can serve as templates for symmetric assembly. In this paper, we formalize the notion of symmetric assembly, specifically for the case when only one type of building block is used, and characterize the properties of the corresponding layouts. We show that such layouts can be generated by extending the 5 regular polyhedra in a sym- metry preserving way. The resulting family remains isotoxal and isohedral, but not isogonal; hence creating a new class outside of the well-studied regular, semi-regular and quasi-regular classes and their duals Catalan solids and Johnson solids. We also show that this new family, dubbed almost-regular polyhedra, can be parameterized using only two variables and constructed efficiently. -
Chapter 1 – Symmetry of Molecules – P. 1
Chapter 1 – Symmetry of Molecules – p. 1 - 1. Symmetry of Molecules 1.1 Symmetry Elements · Symmetry operation: Operation that transforms a molecule to an equivalent position and orientation, i.e. after the operation every point of the molecule is coincident with an equivalent point. · Symmetry element: Geometrical entity (line, plane or point) which respect to which one or more symmetry operations can be carried out. In molecules there are only four types of symmetry elements or operations: · Mirror planes: reflection with respect to plane; notation: s · Center of inversion: inversion of all atom positions with respect to inversion center, notation i · Proper axis: Rotation by 2p/n with respect to the axis, notation Cn · Improper axis: Rotation by 2p/n with respect to the axis, followed by reflection with respect to plane, perpendicular to axis, notation Sn Formally, this classification can be further simplified by expressing the inversion i as an improper rotation S2 and the reflection s as an improper rotation S1. Thus, the only symmetry elements in molecules are Cn and Sn. Important: Successive execution of two symmetry operation corresponds to another symmetry operation of the molecule. In order to make this statement a general rule, we require one more symmetry operation, the identity E. (1.1: Symmetry elements in CH4, successive execution of symmetry operations) 1.2. Systematic classification by symmetry groups According to their inherent symmetry elements, molecules can be classified systematically in so called symmetry groups. We use the so-called Schönfliess notation to name the groups, Chapter 1 – Symmetry of Molecules – p. 2 - which is the usual notation for molecules. -
Symmetry of Graphs. Circles
Symmetry of graphs. Circles Symmetry of graphs. Circles 1 / 10 Today we will be interested in reflection across the x-axis, reflection across the y-axis and reflection across the origin. Reflection across y reflection across x reflection across (0; 0) Sends (x,y) to (-x,y) Sends (x,y) to (x,-y) Sends (x,y) to (-x,-y) Examples with Symmetry What is Symmetry? Take some geometrical object. It is called symmetric if some geometric move preserves it Symmetry of graphs. Circles 2 / 10 Reflection across y reflection across x reflection across (0; 0) Sends (x,y) to (-x,y) Sends (x,y) to (x,-y) Sends (x,y) to (-x,-y) Examples with Symmetry What is Symmetry? Take some geometrical object. It is called symmetric if some geometric move preserves it Today we will be interested in reflection across the x-axis, reflection across the y-axis and reflection across the origin. Symmetry of graphs. Circles 2 / 10 Sends (x,y) to (-x,y) Sends (x,y) to (x,-y) Sends (x,y) to (-x,-y) Examples with Symmetry What is Symmetry? Take some geometrical object. It is called symmetric if some geometric move preserves it Today we will be interested in reflection across the x-axis, reflection across the y-axis and reflection across the origin. Reflection across y reflection across x reflection across (0; 0) Symmetry of graphs. Circles 2 / 10 Sends (x,y) to (-x,y) Sends (x,y) to (x,-y) Sends (x,y) to (-x,-y) Examples with Symmetry What is Symmetry? Take some geometrical object. -
Omputational Design and Fabrication with Auxetic Materials
Beyond Developable: Computational Design and Fabrication with Auxetic Materials Mina Konakovic´ Keenan Crane Bailin Deng Sofien Bouaziz Daniel Piker Mark Pauly EPFL CMU University of Hull EPFL EPFL Figure 1: Introducing a regular pattern of slits turns inextensible, but flexible sheet material into an auxetic material that can locally expand in an approximately uniform way. This modified deformation behavior allows the material to assume complex double-curved shapes. The shoe model has been fabricated from a single piece of metallic material using a new interactive rationalization method based on conformal geometry and global, non-linear optimization. Thanks to our global approach, the 2D layout of the material can be computed such that no discontinuities occur at the seam. The center zoom shows the region of the seam, where one row of triangles is doubled to allow for easy gluing along the boundaries. The base is 3D printed. Abstract 1 Introduction We present a computational method for interactive 3D design and Recent advances in material science and digital fabrication provide rationalization of surfaces via auxetic materials, i.e., flat flexible promising opportunities for industrial and product design, engi- material that can stretch uniformly up to a certain extent. A key neering, architecture, art and science [Caneparo 2014; Gibson et al. motivation for studying such material is that one can approximate 2015]. To bring these innovations to fruition, effective computational doubly-curved surfaces (such as the sphere) using only flat pieces, tools are needed that link creative design exploration to material making it attractive for fabrication. We physically realize surfaces realization. A versatile approach is to abstract material and fabrica- by introducing cuts into approximately inextensible material such tion constraints into suitable geometric representations which are as sheet metal, plastic, or leather. -
Geometry Topics
GEOMETRY TOPICS Transformations Rotation Turn! Reflection Flip! Translation Slide! After any of these transformations (turn, flip or slide), the shape still has the same size so the shapes are congruent. Rotations Rotation means turning around a center. The distance from the center to any point on the shape stays the same. The rotation has the same size as the original shape. Here a triangle is rotated around the point marked with a "+" Translations In Geometry, "Translation" simply means Moving. The translation has the same size of the original shape. To Translate a shape: Every point of the shape must move: the same distance in the same direction. Reflections A reflection is a flip over a line. In a Reflection every point is the same distance from a central line. The reflection has the same size as the original image. The central line is called the Mirror Line ... Mirror Lines can be in any direction. Reflection Symmetry Reflection Symmetry (sometimes called Line Symmetry or Mirror Symmetry) is easy to see, because one half is the reflection of the other half. Here my dog "Flame" has her face made perfectly symmetrical with a bit of photo magic. The white line down the center is the Line of Symmetry (also called the "Mirror Line") The reflection in this lake also has symmetry, but in this case: -The Line of Symmetry runs left-to-right (horizontally) -It is not perfect symmetry, because of the lake surface. Line of Symmetry The Line of Symmetry (also called the Mirror Line) can be in any direction. But there are four common directions, and they are named for the line they make on the standard XY graph. -
Symmetry in Chemistry - Group Theory
Symmetry in Chemistry - Group Theory Group Theory is one of the most powerful mathematical tools used in Quantum Chemistry and Spectroscopy. It allows the user to predict, interpret, rationalize, and often simplify complex theory and data. At its heart is the fact that the Set of Operations associated with the Symmetry Elements of a molecule constitute a mathematical set called a Group. This allows the application of the mathematical theorems associated with such groups to the Symmetry Operations. All Symmetry Operations associated with isolated molecules can be characterized as Rotations: k (a) Proper Rotations: Cn ; k = 1,......, n k When k = n, Cn = E, the Identity Operation n indicates a rotation of 360/n where n = 1,.... k (b) Improper Rotations: Sn , k = 1,....., n k When k = 1, n = 1 Sn = , Reflection Operation k When k = 1, n = 2 Sn = i , Inversion Operation In general practice we distinguish Five types of operation: (i) E, Identity Operation k (ii) Cn , Proper Rotation about an axis (iii) , Reflection through a plane (iv) i, Inversion through a center k (v) Sn , Rotation about an an axis followed by reflection through a plane perpendicular to that axis. Each of these Symmetry Operations is associated with a Symmetry Element which is a point, a line, or a plane about which the operation is performed such that the molecule's orientation and position before and after the operation are indistinguishable. The Symmetry Elements associated with a molecule are: (i) A Proper Axis of Rotation: Cn where n = 1,.... This implies n-fold rotational symmetry about the axis. -
Generating Apparently-Random Colour Patterns
Computational Aesthetics in Graphics, Visualization, and Imaging (2012) D. Cunningham and D. House (Editors) Random Discrete Colour Sampling Henrik Lieng Christian Richardt Neil A. Dodgson Generating apparently-randomUniversity of Cambridge colour patterns Used with permission of the authors Figure 1: We present an algorithm that distributes colours randomly using a human-centric definition of randomness. Left: Colours distributed using Matlab’s random-number generator. Middle: Result of our algorithm. Notice that our algorithm does not produce any distinctive patterns. Right: An image similar to one of Damien Hirst’s spot paintings. Abstract Apparently-random distributions of colours in a discrete setting have been used by many artists and craftsmen in the past century. Manual colourisation is a tedious and difficult process. Automatic colourisation, on the other hand, tends not to not look ‘random’ to a human, as randomly-generated clusters and patterns stimulate human perception and break the appearance of randomness. We propose an algorithm that minimises these apparent patterns, making the distribution of colours look as if they have been distributed randomly by a human. We show that our approach is superior to current solutions, especially for small numbers of colours. Our algorithm is easily extendible to non-regular patterns in any coordinate system. Categories and Subject Descriptors (according to ACM CCS): I.3.8 [Computer Graphics]: Applications; I.3.m [Com- puter Graphics]: Miscellaneous—Visual Arts; J.5 [Arts and Humanities]: Fine Arts. 1. Introduction Random colour sampling in the spatially discrete space was used in the early twentieth-century by numerous artists such as Jean Arp, Sophie Tauber and Vilmos Huszár. -
Eindhoven University of Technology MASTER Lateral Stiffness Of
Eindhoven University of Technology MASTER Lateral stiffness of hexagrid structures de Meijer, J.H.M. Award date: 2012 Link to publication Disclaimer This document contains a student thesis (bachelor's or master's), as authored by a student at Eindhoven University of Technology. Student theses are made available in the TU/e repository upon obtaining the required degree. The grade received is not published on the document as presented in the repository. The required complexity or quality of research of student theses may vary by program, and the required minimum study period may vary in duration. General rights Copyright and moral rights for the publications made accessible in the public portal are retained by the authors and/or other copyright owners and it is a condition of accessing publications that users recognise and abide by the legal requirements associated with these rights. • Users may download and print one copy of any publication from the public portal for the purpose of private study or research. • You may not further distribute the material or use it for any profit-making activity or commercial gain ‘Lateral Stiffness of Hexagrid Structures’ - Master’s thesis – - Main report – - A 2012.03 – - O 2012.03 – J.H.M. de Meijer 0590897 July, 2012 Graduation committee: Prof. ir. H.H. Snijder (supervisor) ir. A.P.H.W. Habraken dr.ir. H. Hofmeyer Eindhoven University of Technology Department of the Built Environment Structural Design Preface This research forms the main part of my graduation thesis on the lateral stiffness of hexagrids. It explores the opportunities of a structural stability system that has been researched insufficiently. -
Symmetry Groups
Symmetry Groups Symmetry plays an essential role in particle theory. If a theory is invariant under transformations by a symmetry group one obtains a conservation law and quantum numbers. For example, invariance under rotation in space leads to angular momentum conservation and to the quantum numbers j, mj for the total angular momentum. Gauge symmetries: These are local symmetries that act differently at each space-time point xµ = (t,x) . They create particularly stringent constraints on the structure of a theory. For example, gauge symmetry automatically determines the interaction between particles by introducing bosons that mediate the interaction. All current models of elementary particles incorporate gauge symmetry. (Details on p. 4) Groups: A group G consists of elements a , inverse elements a−1, a unit element 1, and a multiplication rule “ ⋅ ” with the properties: 1. If a,b are in G, then c = a ⋅ b is in G. 2. a ⋅ (b ⋅ c) = (a ⋅ b) ⋅ c 3. a ⋅ 1 = 1 ⋅ a = a 4. a ⋅ a−1 = a−1 ⋅ a = 1 The group is called Abelian if it obeys the additional commutation law: 5. a ⋅ b = b ⋅ a Product of Groups: The product group G×H of two groups G, H is defined by pairs of elements with the multiplication rule (g1,h1) ⋅ (g2,h2) = (g1 ⋅ g2 , h1 ⋅ h2) . A group is called simple if it cannot be decomposed into a product of two other groups. (Compare a prime number as analog.) If a group is not simple, consider the factor groups. Examples: n×n matrices of complex numbers with matrix multiplication. -
Symmetry in 2D
Symmetry in 2D 4/24/2013 L. Viciu| AC II | Symmetry in 2D 1 Outlook • Symmetry: definitions, unit cell choice • Symmetry operations in 2D • Symmetry combinations • Plane Point groups • Plane (space) groups • Finding the plane group: examples 4/24/2013 L. Viciu| AC II | Symmetry in 2D 2 Symmetry Symmetry is the preservation of form and configuration across a point, a line, or a plane. The techniques that are used to "take a shape and match it exactly to another” are called transformations Inorganic crystals usually have the shape which reflects their internal symmetry 4/24/2013 L. Viciu| AC II | Symmetry in 2D 3 Lattice = an array of points repeating periodically in space (2D or 3D). Motif/Basis = the repeating unit of a pattern (ex. an atom, a group of atoms, a molecule etc.) Unit cell = The smallest repetitive volume of the crystal, which when stacked together with replication reproduces the whole crystal 4/24/2013 L. Viciu| AC II | Symmetry in 2D 4 Unit cell convention By convention the unit cell is chosen so that it is as small as possible while reflecting the full symmetry of the lattice (b) to (e) correct unit cell: choice of origin is arbitrary but the cells should be identical; (f) incorrect unit cell: not permissible to isolate unit cells from each other (1 and 2 are not identical)4/24/2013 L. Viciu| AC II | Symmetry in 2D 5 A. West: Solid state chemistry and its applications Some Definitions • Symmetry element: An imaginary geometric entity (line, point, plane) about which a symmetry operation takes place • Symmetry Operation: a permutation of atoms such that an object (molecule or crystal) is transformed into a state indistinguishable from the starting state • Invariant point: point that maps onto itself • Asymmetric unit: The minimum unit from which the structure can be generated by symmetry operations 4/24/2013 L. -
39 Symmetry of Plane Figures
39 Symmetry of Plane Figures In this section, we are interested in the symmetric properties of plane figures. By a symmetry of a plane figure we mean a motion of the plane that moves the figure so that it falls back on itself. The two types of symmetry that we discuss are Reflection Symmetry: A plane figure is symmetric about a line if it is its own image when flipped across the line. We call the reflection line the line of symmetry. In other words, a figure has a line symmetry if it can be folded along the line so that one half of the figure matches the other half. Reflection symmetry is also known as mirror symmetry, since the line of symmetry acts like a double-sided mirror. Points on each side are reflected to the opposite side. Many plane figures have several line symmetries. Figure 39.1 shows some of the plane figures with their line symmetries shown dashed. Figure 39.1 Remark 39.1 Using reflection symmetry we can establish properties for some plane figures. For example, since an isosceles triangle has one line of symmetry then the 1 base angles, i.e. angles opposed the congruent sides, are congruent. A similar property holds for isosceles trapezoids. Rotational Symmetry: A plane figure has rotational symmetry if and only if it can be rotated more than 0◦ and less than or equal to 360◦ about a fixed point called the center of rotation so that its image coincides with its original position. Figure 39.2 shows the four different rotations of a square.