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RHODACAL DS 4 SECTION 1: Identification of the Substance

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RHODACAL DS 4 SECTION 1: Identification of the Substance SAFETY DATA SHEET RHODACAL DS 4 Revision Date 11/01/2018 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier - Trade name RHODACAL DS 4 1.2 Relevant identified uses of the substance or mixture and uses advised against Uses of the Substance / Mixture - Surfactants for various applications 1.3 Details of the supplier of the safety data sheet Company Solvay USA Inc., NOVECARE 504 Carnegie Center Princeton, NJ, 08540, US Telephone Number: 800-973-7873 1.4 Emergency telephone FOR EMERGENCIES INVOLVING A SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT, CONTACT CHEMTREC (24-Hour Number): 800-424-9300 within the United States and Canada, or 703-527-3887 for international collect calls. SECTION 2: Hazards identification Although OSHA has not adopted the environmental portion of the GHS regulations, this document may include information on environmental effects. 2.1 Classification of the substance or mixture HCS 2012 (29 CFR 1910.1200) Skin irritation, Category 2 H315: Causes skin irritation. Serious eye damage, Category 1 H318: Causes serious eye damage. 2.2 Label elements HCS 2012 (29 CFR 1910.1200) Pictogram Signal Word - Danger Hazard Statements - H315 Causes skin irritation. - H318 Causes serious eye damage. Precautionary Statements Prevention PRCO90002067 Version : 1.04 / US ( Z8 ) www.solvay.com 1 / 18 SAFETY DATA SHEET RHODACAL DS 4 Revision Date 11/01/2018 - P264 Wash skin thoroughly after handling. - P280 Wear protective gloves/ eye protection/ face protection. Response - P302 + P352 IF ON SKIN: Wash with plenty of soap and water. - P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. - P332 + P313 If skin irritation occurs: Get medical advice/ attention. - P362 Take off contaminated clothing and wash before reuse. 2.3 Other hazards which do not result in classification - H401: Toxic to aquatic life. - H412: Harmful to aquatic life with long lasting effects. - Does NOT present any particular fire hazard. - On combustion, toxic gases are released. - (following evaporation of water) - Hazardous reactions may occur on contact with certain chemicals. (Refer to the list of incompatible materials section 10: "Stability-Reactivity"). SECTION 3: Composition/information on ingredients 3.1 Substance - Not applicable, this product is a mixture. 3.2 Mixture - Chemical nature Aqueous solution of sodium dodecylbenzenesulfonate Hazardous Ingredients and Impurities Identification number Chemical name Concentration [%] CAS-No. Benzenesulfonic acid, dodecyl-, branched, sodium salt 69227-09-4 >= 20 - < 25 The specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. Non Hazardous Ingredients and Impurities Identification number Chemical name Concentration [%] CAS-No. Water/Inerts ***** 75- 80 SECTION 4: First aid measures 4.1 Description of first-aid measures General advice - Show this material safety data sheet to the doctor in attendance. - First responder needs to protect himself. - Place affected apparel in a sealed bag for subsequent decontamination. In case of inhalation PRCO90002067 Version : 1.04 / US ( Z8 ) www.solvay.com 2 / 18 SAFETY DATA SHEET RHODACAL DS 4 Revision Date 11/01/2018 - If breathed in, move person into fresh air. - If breathing is difficult, give oxygen. - If victim has stopped breathing: - administer CPR (cardio-pulmonary resuscitation) - Get immediate medical advice/ attention. In case of skin contact - Wash off immediately with plenty of water for at least 15 minutes. - If a person feels unwell or symptoms of skin irritation appear, consult a physician. - Remove contaminated clothing and shoes. - Wash contaminated clothing before re-use. - In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. - Seek medical advice. - Wash contaminated clothing before re-use. In case of eye contact - Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. - If eye irritation persists, consult a physician. - Get immediate medical advice/ attention. In case of ingestion - If victim is conscious: - Rinse mouth with water. - Keep at rest. - Do not induce vomiting without medical advice. - Do not leave the victim unattended. - Vomiting may occur spontaneously - Risk of product entering the lungs on vomiting after ingestion. - Lay victim on side. - Seek medical advice. - Do not give anything to drink. 4.2 Most important symptoms and effects, both acute and delayed Effects - Skin contact may aggravate existing skin disease - Inhalation of product may aggravate existing chronic respiratory problems such as asthma, emphysema or bronchitis 4.3 Indication of any immediate medical attention and special treatment needed Notes to physician - Treat symptomatically. - There is no specific antidote available. - All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. SECTION 5: Firefighting measures PRCO90002067 Version : 1.04 / US ( Z8 ) www.solvay.com 3 / 18 SAFETY DATA SHEET RHODACAL DS 4 Revision Date 11/01/2018 Flash point > 200 °F (> 93 °C) Pensky-Martens closed cup Flammability class: Will burn Autoignition temperature No data available Flammability / Explosive limit No data available 5.1 Extinguishing media Suitable extinguishing media - Water spray - Foam - Carbon dioxide (CO2) - Multipurpose powders Unsuitable extinguishing media - High volume water jet - (frothing possible) 5.2 Special hazards arising from the substance or mixture Specific hazards during fire fighting - Harmful or toxic vapors are released. - Under fire conditions: - Will burn - Corrosive or suffocating vapors are released. - (following evaporation of water) Hazardous combustion products: - On combustion or on thermal decomposition (pyrolysis), releases: - Carbon oxides - Nitrogen oxides (NOx) - Hydrogen sulfide - Sulfur oxides 5.3 Advice for firefighters Special protective equipment for fire-fighters - Firefighters should wear NIOSH/MSHA approved self-contained breathing apparatus and full protective clothing. Specific fire fighting methods - Do not use a solid water stream as it may scatter and spread fire. - Fight fire remotely due to the risk of explosion. - Cool containers/tanks with water spray. Further information - Standard procedure for chemical fires. - Collect contaminated fire extinguishing water separately. This must not be discharged into drains. - Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. PRCO90002067 Version : 1.04 / US ( Z8 ) www.solvay.com 4 / 18 SAFETY DATA SHEET RHODACAL DS 4 Revision Date 11/01/2018 SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures - Avoid contact with eyes, skin, and respiratory system. - Wear suitable protective equipment. - For personal protection see section 8. - Stop the leak and if possible, avoid any contact with skin and apparel. 6.2 Environmental precautions - Take all necessary measures to avoid accidental discharge of products into drains and waterways due to the rupture of containers or transfer systems. - Do not flush into surface water or sanitary sewer system. - Spills may be reportable to the National Response Center (800-424-8802) and to state and/or local agencies 6.3 Methods and materials for containment and cleaning up Methods for containment - Stop the leak. Turn leaking containers leak-side up to prevent the escape of liquid. - Dam up with sand or inert earth (do not use combustible materials). - Keep in properly labeled containers. - Keep in suitable, closed containers for disposal. Recovery - Sweep up or vacuum up spillage and collect in suitable container for disposal. - Never return spills in original containers for re-use. Decontamination / cleaning - Wash nonrecoverable remainder with large amounts of water. - Clean contaminated surface thoroughly. - Recover the cleaning water for subsequent disposal. - Wash with plenty of water and detergent. - Decontaminate tools, equipment and personal protective equipment in a segregated area. Disposal - Dispose of in accordance with local regulations. Additional advice - Material can create slippery conditions. 6.4 Reference to other sections - 7. HANDLING AND STORAGE - 8. EXPOSURE CONTROLS/PERSONAL PROTECTION - 13. DISPOSAL CONSIDERATIONS SECTION 7: Handling and storage 7.1 Precautions for safe handling - Freezing will affect the physical condition but will not damage the material. Thaw and mix before using. PRCO90002067 Version : 1.04 / US ( Z8 ) www.solvay.com 5 / 18 SAFETY DATA SHEET RHODACAL DS 4 Revision Date 11/01/2018 - Avoid localized overheating. - Vent drums while heating - Mix thoroughly before use. - Does not require any specific or particular measures. - Handle in accordance with good industrial hygiene and safety practice. - Comply with instructions for use. - Avoid splashes. - Avoid inhalation, ingestion and contact with skin and eyes. Hygiene measures - Use clean, well maintained personal protection equipment. - Personal hygiene is an important work practice exposure control measure and the following general measures should be taken when working with or handling this materials: - 1) Do not store, use, and/or
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