New Mineral Names*
Total Page:16
File Type:pdf, Size:1020Kb
American Mineralogist, Volume 75, pages 1209-1216, 1990 NEW MINERAL NAMES* JOHN L. JAMBOR CANMET, 555 Booth Street, Ottawa, Ontario KIA OG1, Canada JACEK PuZIEWICZ Institute of Geological Sciences, University of Wroclaw, Cybulskiego 30, 50-205 Wroclaw, Poland Arupite* partly corroded and striated; {100}, {012}, {210} prom- V.F. Buchwald. (1990) A new mineral, arupite, NilP04)2. inent, {201}, {101}, and {010} subordinate. No cleavage, 8H20, the nIckel analogue of vivianite. Neues Jahrb. sub-conchoidal to uneven fracture, H = 2, red streak, Mineral. Mon., 76-80. Dmeas= 4.5(1), Deale= 4.11 g/cm3 with Z = 4. Maximum and minimum reflectance values at 589 nm for a single Electron-microprobe analysis gave NiO 40.18, CoO grain in arbitrary orientation range from 23.8 to 24.7% 0.39, FeO 4.53, P20S 27.60, H20 (by difference) 27.30, in air, and 10.2 to 11.6% in oil. X-ray study indicated sum 100 wt%, corresponding to (Ni2.7sFeo.33Coo.03)~3.14-monoclinic symmetry, space group P2';c, a = 15.647(4), (P04)2.0100.12.7 .84H20, ideally Ni3(P04)2. 8H20, which is b = 8.038(3), c = 10.750(3) A, (3 = 91.27(3)°. Strongest the nickel analogue of vivianite. The mineral occurs as lines of the calculated powder-diffraction pattern earthy aggregates up to 2 mm in diameter; sky-blue to are 4.46( 65,012), 4.28(74,112), 4.09(61,31 I), turqoise-blue color, earthy luster, translucent, H = 1.5- 3.78(6_3,021,302),3.72(55,302),3.42(54,312),3.07- 2, nonfluorescent, Deale= 2.85 g/cm3 with Z = 2. Indi- (65,321), 3.06(100,321), and 2.68(59,004,023). vidual grains are short prisms, 2-5 ~m long. Optically The mineral occurs in the well-known, late Tertiary, biaxial, 1.632(5), ,,/' 1.680(5), X = blue, Z = col- a' = = thallium-mineral-bearing Allchar deposit in southern orless. By analogy to vivianite, monoclinic, space group Macedonia, Yugoslavia. The new name is for J.H. Ber- 121m, a = 9.889(15), b = 13.225(11), c = 4.645(4) A, {3 nard of the Geological Survey of Czechoslovakia, who = 102.41 (11 )0. Strongest lines of the X-ray powder pat- first recognized the mineral. Type material is at the Na- tern, which is similar to those of vivianite and synthetic rodni Museum in Prague, Czechoslovakia, at the Natur- Ni3(P04)2.8H20, are 7.878(36,110), 6.624(100,020), historisches Museum in Vienna, Austria, and at the In- 4.818(61,200), 3.805(50,101), 2.922(72,301), and stitut flir Mineralogie und Kristallographie der Universitat 2.672(46,321). Vienna, Austria. J .L.J. The mineral occurs in the Santa Catharina Ni-rich Fe meteorite, which was severely weathered when found in 1875 on the coast of southern Brazil. Associated second- Florensovite* ary Ni minerals are honessite and reevesite. The new name is for Hans Arup (1928-), Director of the Danish Cor- L.Z. Reznitskii, E.V. Sklyarov, L.F. Piskunova, Z.F. Ush- rosion Center. Type material is in the Division of Me- chapovskay~ (1989) Florensovite Cu(Crl.sSbo.s)S4-A new sulfosplnel from Pribaikalya. Zapiski Vsese Mine- teorites, Smithsonian Institution, Washington, D.C. J.L.J. ralog. Obsch., 118(1), 57-65 (in Russian). Microprobe analysis (39 given) gave: Cu 18.80, Zn 0.75, Bernardite* Cr 24.24, Sb 19.17, V 0.02, S 38.45, sum 100.43 wt% J. Pasava, F. Pertlik, E.F. Stumpfl, J. Zemann (1989) Ber- corresponding to CUO.972ZnO.038Crl.S31Sbo.S17VO.001S3.940.B; nardite, a new thallium arsenic sulphosalt from All- analogy with synthetic compounds it is suggested that char, Macedonia, with a determination of the crystal copper is monovalent, chromium is trivalent, and anti- structure. Mineral. Mag., 53, 531-538. mony is pentavalent. The mineral forms a continuous solid solultion with kalininite (ZnCr 2S4),with the Cu:Sb Six electon-microprobe analyses of a grain gave TI 22.0- ratio constant at 2: 1. Grains are typically 50-60 ~m in 23.4, As 35.2-43.7, Sb 0.1-10.4, S 29.8-32.6, corre- diameter, and the maximum size is 150 x 200 ~m. Con- sponding to Tl(As1-xSbx)sSs and TI(As1-x)sS9, with 0.0 ~ tacts between Cu-rich kalininite and Cu-poor florensovite x ~ 0.15; the ideal formula is TIAssSs, based on X-ray are gradational; there are also sharp contacts between ka- crystal-structural study. The mineral occurs with realgar lininite containing 0.7 atoms of Zn per formula unit (pfu) and orpiment as black, thick-tabular crystals that are typ- and florensovite containing 0.7-0.8 atoms Cu pfu. Color ically ~ 1 mm, but up to 4 x 3 x 1.5 mm; faces are dull, black, adamantine to metallic luster, strongly magnetic, H = 477-541 kglmm2, average 511 (Mohs 5) with a 50-g load for grains of composition CUo.so-SSZnO.lS-0.20;Deatc = * Before publication, minerals marked with an asterisk were approved by the Commission on New Minerals and Mineral 4.28 g/cm3 with Z = 8. Insoluble in dilute and concen- Names, International Mineralogical Association. trated HCl. Optically pale creamy in reflected light, iso- 0003-004X/90/0910-1209$02.00 1209 1210 JAMBOR AND PUZIEWICZ: NEW MINERAL NAMES tropic, no internal reflections. Reflectance measurements A combination of flame photometry, atomic-absorp- for a grain with CUo.8SZnO.15(nm, R %): 440,23.2; 460,24.5; tion spectroscopy, and volume-weight analyses gave CuO 480,25.7; 500,26.4; 520,26.5; 540,26.5; 560,26.8; 48.62, PbO 0.17, ZnO 0.62, Na20 0.20, K20 10.48, Cl 580,27.0; 600,27.4; 620,27.5; 640,27.1; 660,26.6; 6.20, S03 33.96, H20- 1.75, H20+ 0.00, insoluble residue 680,26.3; 700,26.2. X-ray powder-diffraction study 0.20, 0 == CI 1.40, sum 100.80 wt°jo. The H20 was as- showed the mineral to be cubic, space group Fd3m (by sumed to be absorbed, and the deficiency of anions rel- analogy with synthetic CuCr2S4), a = 10.005(6) A; strong- ative to cations (2; A = 1.02, 2; K = 1.47) was assumed est lines (20 given) are: 3.01(100,311), 2.50(80,400), to be due to additional 0 anions by analogy with melano- 1.923(80,511,333), 1.768(100,440), 1.021 (80,844). thallite and piypite. Calculated 0 = 3.56 wt°jo, and the The mineral was found in Cr- and V-rich metasedi- formula is (K1.06Nao.03)2:1.09(Cu2.92Zno.04)2:2.9601.04Clo.84- mentary rocks of the Slyudyanka granulite complex, south (S04)2.03. Soluble in H20 and in weak acid (1:20) solu- of Lake Baikal, Siberia, USSR, associated with diopside, tions. Decomposes in air in a few weeks because of hy- calcite, quartz (main rock-forming minerals), tremolite, dration. Crystals are rodlike, greenish-yellowish brown, uvarovite-goldmanite gamet, karelianite-eskolaite, py- elongate [001] and up to 3 mm long, rectangular or rhom- rite, ilmenite, pyrrhotite, magnesiochromite, chalcopy- bic (angle 74.70, calc. 74.30) in cross section, up to 0.5 rite, franklinite, barite, apatite, zircon, and other miner- mm wide; well-developed {II O} and {I OO}, poor {II O} als. Sulfospinels occur as irregular inclusions, up to 0.8 and {DOl}. Luster vitreous, streak yellow, H = 3.5, per- mm in size, in pyroxene and gamet, or as overgrowths fect {Oil} and {I DO}cleavages, Dmeas= 3.48, Deale= 3.58 on eskolaite-karelianite. Aggregates of the sulfospinels are g/cm3 with Z = 4. In transmitted light, transparent, yel- slaglike, brittle, and crumble under a needle. The new low, biaxial positive, a = 1.695, (3 = 1.718, l' = 1.759 name is for Nikolai Aleksandrovich Florensov, organizer (:to.002), 2 ~ale = 75°; elongation negative, extinction of geological academic studies in Siberia. Type material straight relative to elongation, X = c, Y = a, Z = b. No is at the Central Siberian Geological Museum, Novosi- pleochroism, no dispersion. X-ray single-crystal and birsk, USSR. J.P. powder study showed the mineral to be orthorhombic, space group Pnam or Pna21, a = 9.741(5), b = 12.858(6), c = 7.001(3) A. The strongest lines in the powder pattern Ilbaite are 7.76(100,110), 3.501(65,002), 3.217(30,040), A. Motiu, L. Suciu (1987) Geochemical and structural 2.682(30,240), and 2.591(41,330). study of the pulverulent white masses that occur in the The mineral was found in the area of the Great Tol- ore body of the Ilba lode. Studia Univ. Babes-Bolyai, bachik Fissure Eruption, Kamchatka Peninsula, USSR, Geol.-Geog., 32(2), 95-97 (in English). where it occurs as a fumarolic product intergrown with copper, potassium, and sodium sulfates, and associated A highly fractured zone in the Ilba mine, 30 km from Baia-Mare, Marumres County, northwestern Rumania, with ponomarevite, hematite, and klyuchevskite. Speci- contains white pulverulent masses for which wet-chemi- mens were collected from sublimates that formed at 120- cal analysis gave Si02 45.80, A1203 28.86, Ti02 0.14, Fe203 240°C. The new name is for the locality. Type material 0.62, CaO 1.29, MgO 0.32, Na20 0.01, K20 0.09, H20 is at the Mining Museum of the Leningrad Mining Insti- 22.64 wt°jo [sum 99.77].