Metal Mobility and Transport from an Oil-Shale Mine, Lake Nõmmejärv, Estonia

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Metal Mobility and Transport from an Oil-Shale Mine, Lake Nõmmejärv, Estonia Metal mobility and transport from an oil-shale mine, Lake Nõmmejärv, Estonia Åsa Ekelund Department of Physical Geography GE6014 Physical Geography, Degree Project 30 hp, NG80 Study Programme in Earth Sciences Spring term 2020 Supervisor: Christian Bronge, Jan Risberg and Lars-Ove Westerberg Preface This Bachelor’s thesis is Åsa Ekelund’s degree project in Physical Geography at the Department of Physical Geography, Stockholm University. The Bachelor’s thesis comprises 30 credits (one term of full-time studies). Supervisors have been Christian Bronge, Jan Risberg and Lars-Ove Westerberg at the Department of Physical Geography, Stockholm University. Examiner has been Stefan Wastegård at the Department of Physical Geography, Stockholm University. The author is responsible for the contents of this thesis. Stockholm, 1 September 2020 Björn Gunnarson Vice Director of studies Metal mobility and transport from an oil-shale mine, Lake Nõmmejärv, Estonia Åsa Ekelund Abstract Mining activities have a large impact on the environment, for example by the release of heavy metals from acid mine drainage and erosion of mine waste. North-eastern Estonia has the largest commercially exploited oil-shale deposit in the world. Waste from the mining processes have led to contamination of groundwater and streams polluted by phenols, oil products, sulphates and heavy metals. This thesis concerns the metal mobility from oil-shale mines in north-eastern Estonia, through water flow in the drainage system directed into Lake Nõmmejärv, which acts as a sedimentation basin for the mining water. A sediment core along with lake bottom surface samples were retrieved and analysed for heavy metals associated with mining. Water samples were collected and analysed for TOC. The sedimentary records show distinctively the change with the high inflow of water. The analysis of heavy metal content does not suggest a high impact on the environment, possibly because of a buffering effect by the limestone bedrock. The contents of heavy metals are somewhat elevated compared to background contents in Swedish lake sediments, but only cadmium and nickel levels are in the range that can be hazardous for the survival of organisms. Keywords: Mine waste, Heavy metals, Oil shale, Lake sediments, Lake Nõmmejärv, Human impact, Kurtna kame field, Estonia. Cover: Lake Nõmmejärv the day of the sampling in October 1994. Photo by Åsa Ekelund Contents 1 Introduction.................................................................................................................. 1 2 Background and study area ........................................................................................ 2 2.1 Study area ............................................................................................................... 2 2.2 Oil shales ................................................................................................................ 6 2.3 Historical background .............................................................................................. 7 2.4 Geochemical background ........................................................................................ 8 2.5 Heavy metals .......................................................................................................... 9 3 Methods .......................................................................................................................10 3.1 Sampling ................................................................................................................11 3.1.1 Water sampling ...............................................................................................11 3.1.2 Sediment sampling ..........................................................................................11 3.2 Analyses ................................................................................................................14 3.2.1 Water analysis.................................................................................................14 3.2.2 Sediment analyses ..........................................................................................14 pH .................................................................................................................................14 Water content (WC), loss on ignition (LOI) & organic carbon content (OC) ...................14 Metal analysis ...............................................................................................................15 Statistical analysis ........................................................................................................16 Presentation of analytical data ......................................................................................16 4 Results and Interpretation .........................................................................................17 4.1 Water samples .......................................................................................................17 4.2 Sediment samples ..................................................................................................18 4.2.1 Composition: WC, LOI550 & OC .......................................................................18 4.2.2 Stratigraphy and pH ........................................................................................18 4.2.3 Metal concentrations in the sediment ..............................................................21 Pb, Cd & Mo .................................................................................................................22 Zn, Cu, Cr, Ni, V ...........................................................................................................22 Fe & Mn ........................................................................................................................23 5 Discussion ..................................................................................................................23 6 Conclusions ................................................................................................................26 7 Acknowledgements ....................................................................................................27 8 References ..................................................................................................................28 Appendix .............................................................................................................................33 Description of analysed metals .........................................................................................33 Table A1, Data, sediment analyses ..................................................................................36 Element compositions and concentrations in the sediment core from Lake Nõmmejärv, also shown in figure 10, here displayed in Excel diagrams: ..............................................37 Appendix References .......................................................................................................43 1 Introduction Oil shale mining has had a large impact on the environment in Estonia (Vallner & Sepp 1993). Power plants using the oil shale have emitted vast amounts of alkaline ash that has affected the soil and water. The pollutants contain sulphur dioxide, nitrogen oxides, heavy metals and organic compounds such as phenols, the latter being a specific pollutant of oil shale processing (Liblik & Rätsep 1994), quite toxic for water organisms. Unused residue is gathered in waste heaps that may self-ignite and cause underground fires that contaminate the water supply with oil and phenols. Apart from the solid waste rock and ash from the production of electricity, there is a hazardous waste called semi-coke that emanates from the production of shale oil. Also, semi-coke contains high concentrations of heavy metals, sulphides and phenols (Gavrilova et al. 2005). During the last 50 years, the most important source of primary energy in Estonia has been oil shale. Between 1970 and 1990, more than 90% of the primary energy came from oil shale (Gavrilova et al. 2005). The extraction of oil shale began in a mercantile perspective in 1918 and peaked in the 1980s when the demand decreased due to the construction of a nuclear power plant in Sosnovyj Bor, Russia. However, still in 2003 more than 80% of the primary energy in Estonia was provided by oil shale (Gavrilova et al. 2005) and the Estonian oil shale industry remains of vital importance to the country. Mines need to be dewatered and when the water is pumped out it contains a large amount of sulphates that lead to acid mine drainage (AMD). Owing to the acidity, heavy metals are released into the surrounding environment and downstream water system (Salomons 1995; Naturvårdsverket & SGU 2017). Heavy metals are naturally occurring elements that have varying definitions such as relatively high densities, atomic weights, or atomic numbers. A common definition is that heavy metals are those metals that have a density of at least 5 times greater than that of water (Tchounwou et al. 2012; Alloway 2013). According to Duffus (2002, p. 794) “there is no authoritative definition to be found in the relevant literature” and some experts find the name meaningless. Still the term “heavy metals” is widely used and recognized and will be used in this paper. Metals are base elements and thus non-degradable. This means that they accumulate in the food chain and can build up to give toxic effects (Brandt & Gröndahl 2000). Still, most metals are essential micronutrients
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