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Tantaline® Surface Alloy Treatment Services

Tantaline® Surface Alloy Treatment Services

Solutions for Conquering Corrosion.

Tantaline® Surface Alloy Treatment Services

www.tantaline.com Tantaline® Technology

Tantaline® treatment is a diffusion bonded protective desired deposit. CVD technology has proven itself to layer of tantalum formed by chemical vapor deposition be robust, economical, and scalable over many years (CVD) on the surface of common materials. The of service in semiconductor and other industries. resulting surface has the same properties of pure tantalum because it is tantalum. Tantalum is the most corrosion resistant metal commercially available due Tantaline CVD to its very dense surface oxide layer. Compatibility with Our proprietary process creates a dense tantalum concentrated high temperature acidic environments surface with all of the beneficial properties of pure has been well established in industrial applications. tantalum metal. The Tantaline® process is conducted Tantaline® treatment enables the highest level of in a sealed reaction chamber under highly controlled corrosion resistance for components used in a wide conditions. This CVD process is geometry independent range of aggressive atmospheres at a competitive which enables both internal and external surfaces of price. This treatment can be applied to stock parts as a complex shapes to be treated at the same time. direct substitute for specialty metals. The list includes Parts typically treated include valves, fittings, solid tantalum, tantalum cladding, titanium, zirconium autoclaves, process chambers, flow reactors, and nickel alloys like Hastelloy®*, Inconel® ** and Alloy fasteners, mixers, flowmeters, and medical devices. 20. Treatment of stock parts fabricated from common Specialty items can be evaluated for treatment upon base metals can significantly reduce the overall lead request. Base metal is typically standard grades of time for otherwise difficult to obtain special order stainless steel, but the treatment process has been items. successfully applied to many substrate materials. Years of service have proven the reliability of Chemical Vapor Deposition Tantaline® treatment across a broad range of industries including chemical processing, oil & gas, mining, pharmaceutical, and medical. The list of Chemical Vapor Deposition (CVD) is the precisely successful applications continues to grow along with controlled decomposition of gases used to deposit a our technical capabilities and manufacturing capacity. high quality, high performance material onto a surface. CVD requires multidisciplinary engineering including chamber design, temperature control, gas and vapor flow, pressure control, and automation to achieve the

This is a 316 stainless steel washer that has been treated in the Tantaline® process. As a result, this washer has a pure tantalum metal surface and all of the corrosion resistant properties of pure tantalum metal. Call for your test coupon today to test it in your corrosive medium.

*Hastelloy® is a trademark of Haynes International | **Inconel® is a trademark of Special Metals Wiggin Limited www.tantaline.com | +1 88 TANTALUM | +1 631-981-7081 Key Benefits of Tantaline®

Unmatched Performance Taking advantage of tantalum metal’s extraordinary corrosion resistance and the robust diffusion bonded layer, Tantaline® treated parts have continuously exceeded the service life of specialty metal components in the most aggressive acidic environments.

High Value Solution Tantaline® technology is the ideal solution to obtain the corrosion resistance of tantalum at cost effective pricing.

Rapid Turn-Around Stainless Steel Customers benefit from the ready availability of Tantaline® Alloy Zone Tantalum etal Surface standard stainless steel parts that can then be Tantaline® treated and shipped in as little as two weeks. The Tantaline® surface Custom Solutions Technical experts in deposition technologies, alloy is diffusion bonded materials science and engineering are available to evaluate unique challenges in exceedingly demanding and inseparable to the applications to offer high value added solutions. substrate.

“When other alloys don't stand a chance in the environment, the Tantaline® Dr. Brian Chambers surface treatment performs beautifully.” Engineering Team Leader Excerpt from testimonial video October 10, 2013

The secret to the Tantaline® solution is its long service life, rapid turn-around, and cost-effective pricing.

Call us at +1 631-981-7081 to discuss an application solution for your project. We can also be reached at [email protected] or visit www.tantaline.com.

Solutions for Conquering Corrosion. Typical Tantaline® Treatable Applications and Solutions

Bellows Tantaline® treated bellows and expansion joints are the most corrosion resistant components commercially available for use in aggressive hot acids offering an ideal solution for long service life.

Valves Tantaline® treatment has successfully applied to a wide range of valve components and styles including Ball, Plug, Check, Needle and Butterfly. Re-assembly and testing services are available for end uses.

Flowmeters Tantaline® treatment can be applied to Vortex, Coriolis, Magnetic, Ultrasonic, and other style flowmeters used in aggressive applications such as sour gas (H2S) processing.

Autoclaves Tantaline continues to work directly with world class OEMs to provide a unique turn-key solution to end users in the Pharmaceutical and Chemical Process industries.

*Hastelloy® is a trademark of Haynes International www.tantaline.com | +1 88 TANTALUM | +1 631-981-7081 The items shown here are only a selection of the types of parts and services that can be provided. Contact us at www.tantaline.com to learn more about treatment possibilities.

Tube Fittings Tantaline® treated tube fittings can be provided directly to OEMs and end users in a wide range of styles and sizes. Rapid treatment of readily available stock hardware provides added benefit

Rupture Discs Holders The Tantaline® treatment is commonly applied to a wide range of standard and custom pressure safety devices. These devices have provided many years of industrially proven reliability.

Fasteners Tantaline® treated stud-bolts, bolts, nuts, and washers combine superior corrosion resistance with advantageous mechanical properties compared to cp-tantalum, and are thus the ideal solution in acidic environments. Rapid treatment of readily available stock hardware provides added benefit.

Custom Treatment Services Experienced scientists and engineers are available to help develop unique solutions for enhancing the corrosion resistance of custom parts for existing and new applications.

Solutions for Conquering Corrosion. Corrosion Charts

These charts show the corrosion rate of various metals in sulfuric and hydrochloric acids in relation to concentration and temperature. Tantalum by far outperforms other specialty metals and alloys.

₂SO₄ Corrosion Resistance my (mmy)

2 Tantalum 2 Zirconium astelloy

Temerature (C) Temerature ioium astelloy C astelloy 2 Titanium 2 4

₂SO₄ Concentration (wt%)

C Corrosion Resistance my (mmy) 2

Tantalum 2 ioium Zirconium

Temerature (C) Temerature

astelloy 2 astelloy C22 2 2 4 HCI Concentration (%)

www.tantaline.com | +1 88 TANTALUM | +1 631-981-7081 Applications Media where Tantaline® shows immunity — the immunity is valid up to at Agitators least 150°C (302°F), unless otherwise noted:

Autoclaves Acetic acid, CH3COOH Fatty acids, R-COOH H3PO4 Acetic anhydride, (CH CO)2-O Ferric chloride, FeCl Phosphorus, <700°C (1290°F), P Bellows 3 3 Acetone, CH3COCH3 Ferric sulfate, Fe2(SO4)3 Phosphorus chlorides, PCl3

Burst Disc Holders Air, <300°C (570°F) Ferrous sulfate, FeSO4 Phosphorus oxychloride, POCl3 Alcohols, R-OH Food stuffs Phthalic anhydride, C H C O Couplings 6 4 2 3 Aldehydes, R-CHO Formaldehyde, HCHO Pickling acids, except HNO3-HF

Diaphragm Seals Aluminum chloride, AlCl3 Formic acid, HCOOH bromide, KBr Aluminum nitrate, Al(NO ) Fruits , KCl Expansion Joints 3 3 Aluminum sulfate, Al4(SO4)3 Glycerine, CH2OHCHOHCH2OH Potassium dichromate, K2Cr2O7

Fasteners Amines, R-NH3 Graphite, <1000°C, C Potassium ferricyanide, Ammonium bicarbonate, NH CO Hydroiodic acid, HI K Fe(CN) Fittings 4 3 3 6 Ammonium carbonate (NH4)2CO3 Hydrobromic acid, HBr , KI

Flanges Ammonium chloride, NH4Cl Hydrocarbons, HxCy Potassium nitrate, KNO3 Ammonium nitrate, NH NO Hydrochloric acid, HCl Potassium permanganate, KMnO Flow Meters 4 3 4 Ammonium acid fosfate, NH4H2PO4 Hydrogen bromide, <400°C, HBr Potassium sulfate, K2SO4

Flow Reactors Ammonium fosfate, (NH4)3PO4 Hydrogen chloride, <350°C, HCl Potassium thiosulfate, K2S2O3 Ammonium sulfate, (NH ) SO Hydrogen iodide, HI Propionic acid, C H COOH Glass Repair Kits 4 2 4 2 5 Amyl acetate, C7H14O2 Hydrogen peroxide, H2O2 Refrigerants

Grounding Rings Amyl chloride, C5H11Cl Hydrogen sulfide, 2H S Sea water Aniline hydrochloride C H NH .HCl Hydroxyacetic acid, CH Silver nitrate, AgNO Heat Exchangers 6 5 2 2 3 Aqua regia, HCl-HNO3 mixture OHCOOH Sodium acetate, NaCH3COO

Instrumentation Barium carbonate, BaCO3 Hypochlorus acid, HClO Sodium aluminate, NaAlO4 Barium chloride, BaCl Iodine, <300°C (570°F), I Sodium bisulfate, solution, NaHSO Laboratory Reactors 2 2 4 Barium hydroxide, Ba(OH)2 Ketones, R-CO-R Sodium bromide, NaBr

Mixers Barium nitrate, Ba(NO3)2 Lactic acid, CH3CH(OH)CO2H Sodium chlorate, NaClO3 Benzoic acid, C H COOH Lead salts Sodium chloride, NaCl Orifice Plates 6 5 Body fluids Magnesium chloride, MgCl2 Sodium citrate, Na3CH(COO)3

Patch Kits Boric acid, H3BO4 Magnesium hydroxide, Mg(OH)2 Sodium cyanide, NaCN Bromine, dry, <300°C (570°F), Br Magnesium sulfate, MgSO Sodium dichromate, Na Cr O Pumps 2 4 2 2 7 Bromine, wet, Br2 Maleic acid, C4H4O4 Sodium hypochlorite, NaClO

Rupture Disc Holders Butyric acid, C3H7COOH Manganous chloride, MnCl2 Sodium nitrate, NaNO3 Calcium bicarbonate, Ca(HCO ) Methyl alcohol, CH OH Sodium nitrite, NaNO Seals 3 2 3 2 Calcium bisulfates, Ca(HSO4)2 Methylsulfuric acid, (CH3)HSO4 Sodium fosfate, Na3PO4

Static Mixers Calcium bisulfites, Ca(HSO3)2 Milk Sodium silicate, Na4SiO4 Calcium carbonate, CaCO Mineral oils Sodium sulfate, Na SO Stirrers 3 2 4 Calcium chloride, CaCl2 Mixed acids (sulfuric-nitric), Sodium sulfide, Na2S

Temperature Sensors Calcium hydroxide, Ca(OH)2 H2SO4-HNO3 Sodium sulfite, NaSO3 Calcium hypochlorite, CaOCl Motor fuels Sodium thiosulfate, Na S O Thermowells 2 2 3 Carbolic acids, R-COOH Nickel salts Stearic acid, c17H35CO2H

Valves Carbon dioxide, CO2 Nitric acid, HNO3 Succinic acid, C4H6O4 Chloric acid, HClO Nitric acid, fuming, HNO Sugar Vessels 3 3 Chlorinated brine Nitric oxide, NO2 Sulfamic acid, H3NSO3

Custom Parts Chlorine, dry, <250°C (480°F) Cl2 Nitrogen, <300°C (570°F), N2 Sulfur, <500°C (930°F), S

Chlorine, wet, <350°C (662°F), Cl2 Nitrous acid, HNO2 Sulfur chlorides, SxCl2

Chlorine oxides Nitrosyl chloride, NOCl Sulfur dioxide, SO2

Industries Chloroacetic acid, CH2ClCOOH Organic chlorides, R-Cl Sulfuric acid, to 175°C (350°F), H2SO4 Chromic acid, H Cr O Organic acids, R-COOH Sulfurous acid, H SO Agricultural 2 2 7 2 3 Chrome plating solutions Organic esters, R-COO-R’ Sulfuryl chloride, SO2Cl2

Bioethanol (Hydrolysis) Citric acid, C6H8O7 Organic salts Tannic acid C76H52O46 Cleaning solutions Oxalic acid, (COOH) Tartaric acid, C H O Chemical Processing 2 4 6 6 Copper salts, Oxygen, <300°C (570°F), O2 Thoinyl chloride, SOCl2

Engineering Dichloroacetic acid, CHCl2COOH Perchloric acid, HClO4 Tin salts Dimethyl formamide, (CH ) CNH Petroleum products Zinc chloride, ZnCl Food 3 2 2 2 Ethylene dibromide, C2H2Br2 Phenol, C6H5OH Zinc sulfate, ZnSO4

Flow Batteries Ethyl sulfate, C2H6O4S Phosphoric acid, <4ppmF,<180°C, Fuel Cells Laboratories Tantaline® shows limited resistance in the following media:

Medical Devices Air,>300°C (570°F) (+ free SO3“>100% H2SO4”) Sodium carbonate, Na2CO3 Ammonia (aqueous or gas), NH Potassium carbonate, K CO Sodium hydroxide, dilute, NaOH Mining 3 2 3 Fluoride salts , dilute, KOH Sodium hydroxide, conc., NaOH New Energy Hydrofluoric acid, HF (aqueous) Potassium hydroxide, conc., KOH , molten,

Oil & Gas Hydrogen, >300°C (570°F), H2 Potassium pyrosulfate, molten, Na2S2O7 Hydrogen fluoride, HF K S O , SO Pharmaceutical 2 2 7 3 Oleum (fuming sulfuric acid), Sodium bisulfate, molten, Sulfuric acid, >175°C (350°F), Precious Metals H2SO4 NaHSO4 H2SO4

Solutions for Conquering Corrosion. AMERICAS EUROPE Tantaline CVD Tantaline CVD ApS 355 South Technology Drive Nordborgvej 81, L3-V108 Central Islip, NY 11722 DK-6430 Nordborg VISIT OUR Tantaline® is a brand and United States Denmark Tel: +1 631-981-7081 Tel: +45 70 200 679 WEBSITE TO registered trademark of CVD Fax: +1 631-981-7095 Fax: +45 70 200 689 Materials Corporation E-mail: [email protected] E-mail: [email protected] LEARN MORE www.tantaline.com Solutions for Conquering Corrosion. © 2017 CVD Equipment Corporation | All rights reserved.