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779 Part 770—Interpretations
Pt. 770 15 CFR Ch. VII (1–1–21 Edition) in the item that qualitatively affect the per- roller bearings and parts). This applies formance of the U.S. and foreign items; to separate shipments of anti-friction (vi) Evidence of the interchangeability of bearings or bearing systems and anti- U.S. and foreign items; friction bearings or bearing systems (vii) Patent descriptions for the U.S. and foreign items; shipped with machinery or equipment (viii) Evidence that the U.S. and foreign for which they are intended to be used items meet a published industry, national, or as spares or replacement parts. international standard; (2) An anti-friction bearing or bear- (ix) A report or eyewitness account, by ing system physically incorporated in a deposition or otherwise, of the foreign item’s segment of a machine or in a complete operation; machine prior to shipment loses its (x) Evidence concerning the foreign manu- identity as a bearing. In this scenario, facturers’ corporate reputation; (xi) Comparison of the U.S. and foreign end the machine or segment of machinery item(s) made from a specific commodity, containing the bearing is the item sub- tool(s), device(s), or technical data; or ject to export control requirements. (xii) Evidence of the reputation of the for- (3) An anti-friction bearing or bear- eign item including, if possible, information ing system not incorporated in a seg- on maintenance, repair, performance, and ment of a machine prior to shipment, other pertinent factors. but shipped as a component of a com- plete unassembled (knocked-down) ma- SUPPLEMENT NO. -
Supporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is © The Royal Society of Chemistry 2017 Supporting Information Colorimetric Sensor Array for Amines based on Responsive Lanthanide Complex Entrapment Peng Li, Zhiqiang Li, Decui Yao, and Huanrong Li* School of Chemical Engineering and Technology, Hebei University of Technology, Guang Rong Dao 8, Hongqiao District, Tianjin 300130, P. R. China. *E-mail: [email protected] 1 Figure S1 Molecular structure of HFA. Figure S2 XRD pattern of zeolite Y (ZY) Figure S3 SEM images of zeolite Y (ZY) 2 Figure S4 a) Emission spectra of Eu1Tb9(HFA)n@ZY after treatment with various amine vapors using an excitation wavelength of 302 nm. (Eu1Tb9(HFA)n@ZY (red line), aniline (green line), Benzylamine (blue line), Propylamine (cyan line), 1,3-Propanediamine (magenta line), Ethylenediamine (yellow line), Triethylamine (dark yellow line), Cyclohexylamine (navy line), Methylamine (purple line), N- Methylaniline (wine line), Butylamine (olive line), ammonia (dark cyan line), Tert-butylamine (royal line), Ethylamine (orange line)) b) The relative emission intensity at 612 nm and at 544 nm (IEu/ITb) of Eu1Tb9(HFA)n@ZY excitated at 302 nm upon treatment with various amine solvent vapors. (a: Eu1Tb9(HFA)n@ZY, b: Aniline, c: Benzylamine, d: Propylamine, e: 1,3-Propanediamine, f: Ethylenediamine, g: Triethylamine, h: Cyclohexylamine, i: Methylamine, j: N- Methylaniline , k: Butylamine, l: Ammonia, m: Tert-butylamine and n: Ethylamine) 3 Figure S5 a) Emission spectra of Eu0.5Tb9.5(HFA)n@ZY -
Neighboring Hetero-Atom Assistance of Sacrificial Amines to Hydrogen Evolution Using Pt-Loaded Tio2-Photocatalyst
Catalysts 2014, 4, 162-173; doi:10.3390/catal4020162 OPEN ACCESS catalysts ISSN 2073-4344 www.mdpi.com/journal/catalysts Article Neighboring Hetero-Atom Assistance of Sacrificial Amines to Hydrogen Evolution Using Pt-Loaded TiO2-Photocatalyst Masahide Yasuda 1,*, Takayuki Tomo 1, Shoichi Hirata 1, Tsutomu Shiragami 1 and Tomoko Matsumoto 2 1 Department of Applied Chemistry, Faculty of Engineering, University of Miyazaki, Gakuen-Kibanadai Nishi, Miyazaki 889-2192, Japan; E-Mails: [email protected] (T.T.); [email protected] (S.H.); [email protected] (T.S.) 2 Center for Collaborative Research and Community Cooperation, University of Miyazaki, Gakuen-Kibanadai Nishi, Miyazaki 889-2192, Japan; E-Mail: [email protected] * Author to whom correspondence should be addressed; E-Mail: [email protected]; Tel.:+81-985-7314. Received: 27 February 2014; in revised form: 12 May 2014 / Accepted: 13 May 2014 / Published: 26 May 2014 Abstract: Photocatalytic H2 evolution was examined using Pt-loaded TiO2-photocatalyst in the presence of amines as sacrificial agents. In the case of amines with all of the carbon attached to the hetero-atom such as 2-aminoethanol, 1,2-diamonoethane, 2-amino-1,3-propanediol, and 3-amino-1,2-propanediol, they were completely decomposed into CO2 and water to quantitatively evolve H2. On the other hand, the amines with both hetero-atoms and one methyl group at the β-positions (neighboring carbons) of amino group such as 2-amino-1-propanol and 1,2-diaminopropane were partially decomposed. Also, the photocatalytic H2 evolution using amines without the hetero-atoms at the β-positions such as ethylamine, propylamine, 1-butylamine, 1,3-diaminopropane, 2-propylamine, and 2-butylamine was inefficient. -
Interagency Committee on Chemical Management
DECEMBER 14, 2018 INTERAGENCY COMMITTEE ON CHEMICAL MANAGEMENT EXECUTIVE ORDER NO. 13-17 REPORT TO THE GOVERNOR WALKE, PETER Table of Contents Executive Summary ...................................................................................................................... 2 I. Introduction .......................................................................................................................... 3 II. Recommended Statutory Amendments or Regulatory Changes to Existing Recordkeeping and Reporting Requirements that are Required to Facilitate Assessment of Risks to Human Health and the Environment Posed by Chemical Use in the State ............................................................................................................................ 5 III. Summary of Chemical Use in the State Based on Reported Chemical Inventories....... 8 IV. Summary of Identified Risks to Human Health and the Environment from Reported Chemical Inventories ........................................................................................................... 9 V. Summary of any change under Federal Statute or Rule affecting the Regulation of Chemicals in the State ....................................................................................................... 12 VI. Recommended Legislative or Regulatory Action to Reduce Risks to Human Health and the Environment from Regulated and Unregulated Chemicals of Emerging Concern .............................................................................................................................. -
Chemical Compatibility Storage Group
CHEMICAL SEGREGATION Chemicals are to be segregated into 11 different categories depending on the compatibility of that chemical with other chemicals The Storage Groups are as follows: Group A – Compatible Organic Acids Group B – Compatible Pyrophoric & Water Reactive Materials Group C – Compatible Inorganic Bases Group D – Compatible Organic Acids Group E – Compatible Oxidizers including Peroxides Group F– Compatible Inorganic Acids not including Oxidizers or Combustible Group G – Not Intrinsically Reactive or Flammable or Combustible Group J* – Poison Compressed Gases Group K* – Compatible Explosive or other highly Unstable Material Group L – Non-Reactive Flammable and Combustible, including solvents Group X* – Incompatible with ALL other storage groups The following is a list of chemicals and their compatibility storage codes. This is not a complete list of chemicals, but is provided to give examples of each storage group: Storage Group A 94‐75‐7 2,4‐D (2,4‐Dichlorophenoxyacetic acid) 94‐82‐6 2,4‐DB 609-99-4 3,5-Dinitrosalicylic acid 64‐19‐7 Acetic acid (Flammable liquid @ 102°F avoid alcohols, Amines, ox agents see SDS) 631-61-8 Acetic acid, Ammonium salt (Ammonium acetate) 108-24-7 Acetic anhydride (Flammable liquid @102°F avoid alcohols see SDS) 79‐10‐7 Acrylic acid Peroxide Former 65‐85‐0 Benzoic acid 98‐07‐7 Benzotrichloride 98‐88‐4 Benzoyl chloride 107-92-6 Butyric Acid 115‐28‐6 Chlorendic acid 79‐11‐8 Chloroacetic acid 627‐11‐2 Chloroethyl chloroformate 77‐92‐9 Citric acid 5949-29-1 Citric acid monohydrate 57-00-1 Creatine 20624-25-3 -
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United States Patent (19) [11] 3,772,046 Knapp Et Al
United States Patent (19) [11] 3,772,046 Knapp et al. (45) Nov. 13, 1973 (54) TIO, SLURRIES HAVING A HIGH SOLIDS 3,674,528 7|1972 Bronson.............................. 106.1300 CONTENT 3,510,334 5/1970 Goodspeed.............. ... 106/300 3,506,466 4/1970 Bramekamp et al..... ... 106/300 75 Inventors: Donald Edward Knapp, Savannah, 2,933,408 4/1960 Dempster et al..... ... 106/300 Ga.; Lindo Paul Nageroni, Bound 3,702,773 1 1/1972 Hall et al............................ 1061300 Brook, N.J. (73) Assignee: American Chemical Company, Primary Examiner-Delbert E. Gantz Stamford, Conn. Assistant Examiner-James W. Hellwege 22 Filed: Jan. 17, 1972 Attorney-Roland A. Dexter (21) Appl. No.: 218,453 Related U.S. Application Data 57 ABSTRACT 63 Continuation-in-part of Ser. No. 55,286, July 15, Pigment slurries of 70% by weight solids contents are 1970, abandoned. shown to have long term stability even when exposed to typical paper making chemicals such as calcium (52) U.S. Cl................................................. 106.1300 carbonate. The aqueous slurries are formulated with (51 Int. Cl............................................... C09c 1/62 pigment containing a small but effective admixed 58) Field of Search..................................... 106/300 amount of polyhydric alcohol and an alkanolamine, and with water which contains a small but effective 56) References Cited amount of a second alkanol-amine which provides a UNITED STATES PATENTS slurry pH of at least 9. 3,649,323 3/1972 Roe et al............................ 106/300 5 Claims, No Drawings 3,772,046 2 TIO, SLURRIES HAVING A HIGH SOLIDS bonate which is frequently encountered in the produc CONTENT tion of paper. -
European Union
EUROPEAN PARLIAMENT 2004 2009 Consolidated legislative document 3.9.2008 EP-PE_TC1-COD(2007)0121(PAR12) ***I POSITION OF THE EUROPEAN PARLIAMENT adopted at first reading on 3 September 2008 with a view to the adoption of Regulation (EC) No .../2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 (EP-PE_TC1-COD(2007)0121(PAR12)) PE 411.696 EN EN ANNEX VI Table 3.2 The list of harmonised classification and labelling of hazardous substances from Annex I to Directive 67/548/EEC Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes 001-001-00-9 hydrogen 215-605-7 1333-74-0 F+; R12 F+ R: 12 S: (2-)9-16-33 001-002-00-4 aluminium lithium hydride 240-877-9 16853-85-3 F; R15 F R: 15 S: (2-)7/8-24/25-43 001-003-00-X sodium hydride 231-587-3 7646-69-7 F; R15 F R: 15 S: (2-)7/8-24/25-43 001-004-00-5 calcium hydride 232-189-2 7789-78-8 F; R15 F R: 15 S: (2-)7/8-24/25-43 003-001-00-4 lithium 231-102-5 7439-93-2 F; R15 F; C R14 R: 14/15-34 C; R34 S: (1/2-)8-43-45 1 Index No International Chemical Identification EC No CAS No Classification Labelling Concentration Limits Notes 003-002-00-X n-hexyllithium 404-950-0 21369-64-2 F; R15-17 F; C R14 R: 14/15-17-35 C; R35 S: (1/2-)6-16-26-30- 36/37/39-43-45 004-001-00-7 beryllium 231-150-7 7440-41-7 Carc. -
University of Groningen Vapor Pressures of Several Commercially
University of Groningen Vapor Pressures of Several Commercially Used Alkanolamines Klepacova, Katarina; Huttenhuis, Patrick J. G.; Derks, Peter W. J.; Versteeg, Geert F.; Klepáčová, Katarína Published in: Journal of Chemical and Engineering Data DOI: 10.1021/je101259r IMPORTANT NOTE: You are advised to consult the publisher's version (publisher's PDF) if you wish to cite from it. Please check the document version below. Document Version Publisher's PDF, also known as Version of record Publication date: 2011 Link to publication in University of Groningen/UMCG research database Citation for published version (APA): Klepacova, K., Huttenhuis, P. J. G., Derks, P. W. J., Versteeg, G. F., & Klepáčová, K. (2011). Vapor Pressures of Several Commercially Used Alkanolamines. Journal of Chemical and Engineering Data, 56(5), 2242-2248. https://doi.org/10.1021/je101259r Copyright Other than for strictly personal use, it is not permitted to download or to forward/distribute the text or part of it without the consent of the author(s) and/or copyright holder(s), unless the work is under an open content license (like Creative Commons). The publication may also be distributed here under the terms of Article 25fa of the Dutch Copyright Act, indicated by the “Taverne” license. More information can be found on the University of Groningen website: https://www.rug.nl/library/open-access/self-archiving-pure/taverne- amendment. Take-down policy If you believe that this document breaches copyright please contact us providing details, and we will remove access to the work immediately and investigate your claim. Downloaded from the University of Groningen/UMCG research database (Pure): http://www.rug.nl/research/portal. -
2-Diethylaminoethanol Cas N°:100-37-8
OECD SIDS 2-DIETHYLAMINOETHANOL FOREWORD INTRODUCTION 2-DIETHYLAMINOETHANOL CAS N°:100-37-8 UNEP PUBLICATIONS 1 OECD SIDS 2-DIETHYLAMINOETHANOL SIDS Initial Assessment Report For SIAM 15 Boston, USA; 22-25 October 2002 1. Chemical Name: 2-Diethylaminoethanol 2. CAS Number: 100-37-8 3. Sponsor Country: Germany Contact Point: BMU (Bundesministerium für Umwelt, Naturschutz und Reaktorsicherheit) Prof. Dr. Ulrich Schlottmann Postfach 12 06 29 D- 53048 Bonn-Bad Godesberg 4. Shared Partnership with: BASF AG, Germany; Air Products and Chemicals Inc., USA; Atofina Chemicals Inc., USA; DOW Chemicals Company, USA; The Amines HPV Panel of the American Chemistry Council, USA 5. Roles/Responsibilities of the Partners: · Name of industry sponsor BASF AG, Germany /consortium Contact person: Dr. Hubert Lendle GUP/CL - Z570 D-67056 Ludwigshafen · Process used see next page 6. Sponsorship History · How was the chemical or by ICCA-Initiative category brought into the HPV Chemicals Programme? 7. Review Process Prior to last literature search (update): the SIAM: 16 May 2002 (Human Health): databases medline, toxline; search profile CAS-No. and special search terms 04 January 2002 (Ecotoxicology): databases CA, biosis; search profile CAS-No. and special search terms 8. Quality check process: As basis for the SIDS-Dossier the IUCLID was used. All data have been checked and validated by BUA 9. Date of Submission: 13 August 2002 10. Comments: 2 UNEP PUBLICATIONS OECD SIDS 2-DIETHYLAMINOETHANOL OECD/ICCA - The BUA* Peer Review Process Qualified BUA personnel (toxicologists, -
448 Part 770—Interpretations
§ 770.1 15 CFR Ch. VII (1±1±97 Edition) (vii) Evidence that the parts and compo- SUPPLEMENT NO. 2 TO PART 768ÐITEMS nents of the item are of foreign origin or are ELIGIBLE FOR EXPEDITED LICENSING exempt from U.S. licensing requirements by PROCEDURES [RESERVED] the parts and components provision § 732.4 of the EAR. (3) Sufficient quantity: PART 770ÐINTERPRETATIONS (i) Evidence that foreign sources have the item in serial production; Sec. (ii) Evidence that the item or its product is 770.1 Introduction. used in civilian applications in foreign coun- 770.2 Commodity interpretations. tries; 770.3 Interpretations related to exports of (iii) Evidence that a foreign country is technology and software to destinations marketing in the specific country an item of in Country Group D:1. its indigenous manufacture; 770.4 Interpretations related to chemical (iv) Evidence of foreign inventories of the mixturesÐde minimis exceptions exam- item; ples. (v) Evidence of excess capacity in a foreign AUTHORITY: 50 U.S.C. app. 2401 et seq.; 50 country's production facility; U.S.C. 1701 et seq.; E.O. 12924, 3 CFR, 1994 (vi) Evidence that foreign countries have Comp., p. 917; Notice of August 15, 1995 (60 FR not targeted the item or are not seeking to 42767, August 17, 1995). purchase it in the West; SOURCE: 61 FR 12920, Mar. 25, 19 unless oth- (vii) An estimate by a knowledgeable erwise noted. source of the foreign country's needs; or (viii) An authoritative analysis of the § 770.1 Introduction. worldwide market (i.e., demand, production rate for the item for various manufacturers, In this part, references to the EAR plant capacities, installed tooling, monthly are references to 15 CFR chapter VII, production rates, orders, sales and cumu- subchapter C. -
DEGRADATION of DIETHANOLAMINE SOLUTIONS by MALCOLM L. KENNARD B.Sc, University of Nottingham, England, 1974 M.A.Sc., University
DEGRADATION OF DIETHANOLAMINE SOLUTIONS by MALCOLM L. KENNARD B.Sc, University of Nottingham, England, 1974 M.A.Sc., University of British Columbia, 1978 A THESIS SUBMITTED IN PARTIAL FULFILMENT OF THE REQUIREMENTS FOR THE DEGREE OF DOCTOR OF PHILOSOPHY in THE FACULTY OF GRADUATE STUDIES Department of Chemical Engineering We accept this thesis as conforming to the required standard THE UNIVERSITY OF BRITISH COLUMBIA January 1983 © Malcolm L. Kennard, 1983 In presenting this thesis in partial fulfilment of the requirements for an advanced degree at the University of British Columbia, I agree that the Library shall make it freely available for reference and study. I further agree that permission for extensive copying of this thesis for scholarly purposes may be granted by the head of my department or by his or her representatives. It is understood that copying or publication of this thesis for financial gain shall not be allowed without my written permission. Department of The University of British Columbia 1956 Main Mall Vancouver, Canada V6T 1Y3 Date DE-6 (.3/81) ABSTRACT Raw natural gas contains acid gases such as H2S and C02 which must be removed before the gas can be sold. The removal of these gases is called "sweetening" and the use of Diethanolamine (DEA) as a solvent has become widely accepted by industry. The process is simply based on the absorption and desorption of the acid gases in aqueous DEA. Side reactions can occur when DEA reacts with the C02 to produce degradation compounds. This degradation causes a loss in valuable DEA and an increase in plant operating costs. -
BASF Intermediates for Coatings Industry
Intermediates Intermediates for the coatings industry BASF – The Chemical Company BASF is the world’s leading chemical company: The Chemical Company. Its portfolio ranges from chemicals, plastics, performance products and crop protection products to oil and gas. We combine economic success with environmental protection and social responsibility. Through science and innovation, we enable our customers in nearly every industry to meet the current and future needs of society. Our products and solutions contri- bute to conserving resources, ensuring nutrition and improving quality of life. We have summed up this contribution in our corporate purpose: We create chemistry for a sustainable future. Top intermediates supplier The BASF Group’s Intermediates division develops, produces and markets a comprehensive portfolio of more than 600 intermediates around the world. The most important of the division’s product groups include amines, diols, polyalcohols, acids and specialties. Among other applications, intermediates are used as starting materials for coatings, plastics, pharma- ceuticals, textile fibers, detergents and crop protectants. Innovative intermediates from BASF help to improve the properties of final products and the efficiency of production processes. The ISO 9001 certified Intermediates division operates plants at production sites in Europe, Asia and the Americas. 2 Listening makes the difference! We have supplied the coatings industry for many years with a Focusing on coatings industry needs, we wide range of high-quality intermediates for the production of organize professional innovation workshops, modern coatings. Binders, crosslinking agents and reactive develop new products in joint projects and diluents as well as solvents and additives form part of our offer technical support.