Provenance Study of Jurassic to Early Cretaceous Sandstones from the Palawan Microcontinental Block, Philippines
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῏῍ΐῐῌ (48), pp. 177ῌ199, 2012 ῒ 3 ῎ 28 ῑ Mem. Natl. Mus. Nat. Sci., Tokyo, (48), pp. 177ῌ199, March28, 2012 Provenance Study of Jurassic to Early Cretaceous Sandstones from the Palawan Microcontinental Block, Philippines Kazumi Yokoyama1, ῍, Yukuyasu Tsutsumi1, Tomoki Kase1, Karlo L. Quean˜o 2 and Aguilar Yolanda M.2 1 Department of Geology, National Museum of Nature and Science, Tokyo, 4ῌ1ῌ1 Amakubo, Tsukuba, Ibaraki 305ῌ0005, Japan 2 Mines and Geosciences Bureau, Diliman, Quezon City, Philippines ῍ E-mail: [email protected] Abstract. The Palawan microcontinental block in the Philippines was separated from the southwestern coast of the Asian continent (i.e. southwestern Taiwan) during the opening of the South China Sea in the Oligocene to Miocene times. In this paper, provenances of the detrital grains in the Jurassic to Early Cretaceous sandstones from the Palawan block were studied to determine whether they were derived from the Asian continent. Age distributions of detrital monazites in the sandstones from the Busuanga, Mindoro, and Panay islands are essentially bimodal with peaks at 140ῌ260 Ma and 1800ῌ2000 Ma. Such a pattern is not recognized from the region of assumed origin before the opening of the South China Sea nor from the Indochina Peninsula. A similar bimodal pattern is observed on the Korean Peninsula, in coastal areas of the Shangdong Peninsula, and in Zhejiang Province in China. These areas are located at the marginal East China Sea. Hence, it is concluded that the Jurassic to Early Cretaceous sandstones of the Palawan microcontinent were parentally deposited on the eastern side of present-day Taiwan. Key words: Palawan, monazite, age, sandstone, tectonics. et al., 2003). The Palawan microcontinent con- Introduction sists of Upper Paleozoic to Mesozoic rocks The Palawan microcontinent is a small block (Hashimoto and Sato, 1973: Isozaki et al. consisting mainly of the north terrane of 1987). The constituent rocks belong to oceanic Palawan Island, Busuanga Island, the south- plate stratigraphy or a subduction complex western part of Mindoro Island, and the north- composed mainly of Permian to Upper Jurassic western part of Panay Island (Fig. 1). The chert, Middle Jurassic to Cretaceous clastics, tectonic model of the microcontinent during and limestone blocks of various ages (e.g. the Tertiary has been well illustrated. The Isozaki et al. 1987: Zamoras & Matsuoka, 2001 Palawan microcontinent was located in the &2004; Zamoras et al. 2008). Basaltic blocks western part of Taiwan and separated from the and Cretaceous shallow marine sediments Asian continent at the time of the opening of occur locally on the microcontinent (e.g. the South China Sea (Holloway, 1982). A mag- Zamoras and Matsuoka, 2001: Andal et al., netic anomalies in the South China Sea show 1968). that the spreading started from about 32 Ma In this paper we study the provenances of and ended at 17 Ma (Taylor and Hayes, 1980). the sandstones in the Palawan microcontinent After that time period, the microcontinent to elucidate the location of the deposition or began to collide with the Philippine Mobile subduction at the time of the Jurassic to Early Belt (Hamilton, 1979: Holloway, 1982: Yumul Cretaceous. The conventional approach to pro- 178 Kazumi Yokoyama et al. Fig. 1. Sampling localities of recent sands from Asia and the Palawan microcontinent. Reconstruction of the microcontinent before the opening of the South China Sea is of Zamoras and Matsuoka (2004). Provenance Study of Jurassic to Early Cretaceous Sandstones from the Palawan Microcontinent 179 venance studies of sandstones is based on deter- durated sandstone and shale. Zamoras and mination of chemical compositions of detrital Matsuoka (2001) referred to the BMG (1984) minerals in the sandstones and comparison geological map, but they used the name with data from the Asian continent. The devel- “Guinlo Formation” instead of the King opment of analytical techniques that allow age Ranch Formation and the clastics in the determinations to be made on individual min- Liminangcong Formation were treated as part eral grains has provided a powerful tool in of the “Guinlo Formation”. Except for lime- provenance studies. Many age dating methods stone blocks, Zamoras and Matsuoka (2001 & have been applied to provenance studies of 2004) classified the rocks on the island into zircon, for example the Sensitive High- chert, siliceous mudstone, and terrigenous clas- Resolution Ion Microprobe (SHRIMP) (e.g. tics and divided chert-clastic sequences in the Ireland, 1991; Tsutsumi et al. 2003), fission- Guinlo and Liminangcong formations into track dating (e.g. Garver et al. 1999), in- three belts on the basis of the radiolarian ductively coupled plasma mass spectrometry fossils in the terrigenous clastics: the Northern (ICP-MS) (e.g. Wyck & Norman, 2004; Evans Busuanga (Middle Jurassic), Middle Busuanga et al. 2001), and by monazite data via the (Late Jurassic), and Southern Busuanga electron probe micro-analyzer (EPMA) (e.g. (Early Cretaceous). Zamoras and Matsuoka Suzuki, Adachi & Tanaka, 1991; Fan et al. (2001) described the sandstone in the Guinlo 2004; Yokoyama et al. 2007). Because age data Formation occasionally as arkose sandstones of monazites in the sands from the rivers cut- and have not used the term “tu#aceous” for the ting through the coastal provinces of Eastern clastics. Asia have already been reported (Fig. 1: On the western part of Panay Island, a Yokoyama et al., 2007, 2008, 2010), the bedded chert and clastic sequence occurs. Al- monazite data will be a strong tool for compar- though continuous succession from clastic rock ison between the sandstones on the Palawan to chert has not been confirmed, they are microcontinental block and the sands on the treated as a Jurassic subduction complex con- Asian coastal provinces. sisting of a chert-shale-clastic sequence corre- sponding to the Middle Busuanga belt (Zamoras et al. 2008). The sandstone is ar- Geological setting enitic in composition. In the southwestern part Most of the sandstone samples were collect- of Mindoro Island, Jurassic shallow marine ed from Busuanga Island, north of the Palawan sediments occur. They are composed mainly of block. Geological maps of the island were sandstone and shale with a thin layer of tu#. published by the Bureau of Mines and Geosci- The sediments are rather rich in fossil remains. ences (BMG) in 1984 and radiolarian ages of Late Middle to Early Late Jurassic ammonite, the chert-clastic sequences were later estab- belemnite, and pelecypod were described lished by Zamoras and Matsuoka (2001 & (Andal et al. 1968). Many animal tracks are 2004). According to BMG (1984), the island is also observed in the Jurassic sediments. Some composed of three formations: the King Ranch sandstone layers are frequently intercalated by Formation, the Malajon Limestone, and the black bituminous shale. Liminangcong Formation. The King Ranch Formation is composed predominantly of Sample Description tu#aceous shale and sandstone with inter- calated tu# and minor thinly bedded chert, On Busuanga Island, about twenty sand- whereas the Liminangcong Formation is com- stones were collected from the three belts of posed of bedded chert with interbedded in- Zamoras and Matsuoka (2001 & 2004) as 180 Kazumi Yokoyama et al. Provenance Study of Jurassic to Early Cretaceous Sandstones from the Palawan Microcontinent 181 shown in Fig. 2. Some samples were collected Mindoro and Panay islands are indurated cal- from the same route studied in detail by careous quartzose sandstone and arkose sand- Zamoras and Matsuoka (2001). Sandstones stone, respectively (Fig. 3). were also collected from the shallow marine In addition to the sandstone samples from sediment in the southeastern part of Mindoro the Palawan microcontinent, a few river sands, Island and from a clastic sequence in the west- BA019 and BA020, were collected from the ern part of Panay Island. western part of Busuanga Island (Fig. 2). On Busuanga Island, there are two types of Additionally, five sand samples were newly col- sandstones which correspond to those from the lected from the southern coastal provinces of King Ranch Formation and the Liminangcong the Asian continent (Fig. 1). Characteristics of Formation described in the BMG (1984). The the major river sands from the Asian continent sandstones from the King Ranch Formation (Fig. 1) have been reported by Yokoyama et are poor in quartz and feldspar grains (Fig. 3). al. (2007, 2008, & 2010). The present sand Clay minerals are abundant and loosely samples will also provide indicators of probable packed. And, just as described by the BMG provenance areas on the assumption that the (1984), the clay minerals are identified as being Palawan microcontinent was separated from “tu#aceous”. On the other hand, sandstones the Asian continent. from the Liminangcong Formation are in- They durated samples. are also poor in quartz Analytical Procedures and feldspar fragments (Fig. 3). The di#er- ences between them are simply due to later Procedures for the separation of heavy min- stage metamorphism as described later in this erals and their subsequent identification are the paper. Most of the collected samples from same as have been described by Yokoyama et Busuanga Island are tu#aceous, which is di#er- al. (1990). Carbonate and micaceous minerals ent from the quartzose or arkose sandstones on were not subjected to examination, and mag- Mindoro and Panay islands (Fig. 3). One netic fractions were removed prior to the sepa- sample, BA017, was collected from an outcrop ration of the heavy minerals. Modal propor- along a newly reconstructed road. The outcrop tions of representative heavy minerals are belongs to the Middle Busuanga Belt and con- shown in Table 1. The light minerals are less sists of sandstone and shale. The shale is bitu- source-diagnostic and therefore are not a major minous and locally contains a thin patch of focus in this provenance study. coal (Fig. 3). Sand pipe, a possible trace fossil, Among the heavy minerals, monazite is the is common in the sandstones from both sides of most important for elucidating the provenance.