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A Novel Route for the Preparation of Hydrotalcite and Synthesis of Intercalated Reversible Dioxygen-Carrying Cobalt (II) Complexes

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A Novel Route for the Preparation of Hydrotalcite and Synthesis of Intercalated Reversible Dioxygen-Carrying Cobalt (II) Complexes A Novel Route for the Preparation of Hydrotalcite and Synthesis of Intercalated Reversible Dioxygen-Carrying Cobalt (II) Complexes M. ZIKMUND, К. PUTYERA, and K. HRNCIAROVÁ Institute of Inorganic Chemistry, Slovak Academy of Sciences, SK-842 36 Bratislava Received 17 May 1996 Reacting a solid MgCC>3-3H20 or Mg5(C03)4(OH)2 • 5H2O (nesquehonite, hydromagnesite, dypingite) with an aqueous solution of sodium aluminate and sodium hydroxide is a novel pro­ cedure to synthesize solid solutions with desired stoichiometric Mg/Al ratios in the hydrotalcite series [Мёз-*А1(ОН)8-2хЫ(СОз)(Н20)4-х] (0 < x < 1). By mixing of an intermediate solid solution of magnesium aluminium oxide obtained by thermal decomposition of hydrotalcite with an aqueous solution of mono- or a, u-dicarboxylates which con­ tain N-donor atom in the presence of ethylene glycol as a swelling agent pillared aminocarboxylate derivatives of hydrotalcite are produced. Nitrogen donor atoms of aminocarboxylate pillars may react with cobalt(II) complexes to form coordinatively unsaturated cobalt(II) chelates. The synthe­ sized model Co(salen) and Co(salophen) complexes immobilized in the interlayer region of anionic clays reversibly bind dioxygen and enjoy high stability in the course of oxygenation-deoxygenation cycles. A relatively scarce natural mineral of the chemi­ tion of divalent cations (e.g. Mn = Mg, Zn, Fe, Co, Ni, 111 cal composition ranged from [Mg6Al2(OH)i6][(C03) Cu) and trivalent cations (e.g. M = AI, Fe, Co, Mn, (H20)4] to [Mg4Al2(OH)12][(C03)(H20)3] occurs in Cr, V) into the brucite-like layers; replacing of anions 71 2 2 two polytype modifications, C03-hydrotalcite-3ič (hy­ (e.g. A " = CO ", CIO", HPO ", carboxylate and drotalcite) and C03-hydrotalcite-2# (manasseite) [1, polyoxopolymetalate anions) and intercalated guest 2]. The typical chemical composition of hydrotal- molecules (e.g. water, polyvalent alcohols, amines) by cites lies in the range [Mg3_xAl(OH)8_2x]2[(C03) other species in the interlayer region. The general for­ (H20)4_x] where (0 < x < 1) and [Mg3_x.Al(OH)8_2x] mula of these synthetic hydrotalcite derivatives may 1 u x+ x is the formula unit of a layer having net charge 1+. be written as [MjL* M x (OR)2) [A2jn] - yL, with The structure of hydrotalcites and their structural 0.25 < x < 0.33. A diverse group of compounds con­ n IH n analogues is derived from that of brucite, Mg(OH)2 taining various combinations of M , M , and A ~ [3—5]. When some of the Mg2+ in the brucite layer ions, as well as molecules and complexes intercalated are isomorphously substituted with Al3+, the mixed into hydrotalcite analogues can be synthesized [5—7]. Mg2+—Al3+ 2-D network bears one unit of positive Properties of hydrotalcite-like compounds depend charge per Al3+, which is compensated by the incor­ on the chemical behaviour and distribution of cations poration of carbonate anions into the interlayers. In incorporated in the brucite-like layers, as well as on addition, some water molecules (about 20 mass %) the chemical composition, electronic structure, stereo­ are located in the interlayer region. chemistry, and distribution of the interlayer anions The interlayer region of hydrotalcite and its deriva­ and of the intercalated guest molecules. The prepa­ tives (anionic clays) behaves as a basic solid sol­ ration, structure, properties, and use of these mate­ vent and provides reactive medium not only for the rials for practical application have been reported in counterions that ensure charge balance of the crystal many research papers [6, 7]. In order to further ex­ structure, but also for a variety of intercalated polar or ploit their potential, alternative processes, satisfactory nonpolar molecules. Several attempts have been made from a technical and economical point of view, are de­ recently for enlargement of the interlayer distance of sirable. hydrotalcite-like compounds by incorporation of large, Anionic clays have been prepared by coprecipita- preferably multiply charged anions into the interlayer tion procedures from mixtures of soluble magnesium space (pillared anionic clays) (Fig. 1). and aluminium salts with different sodium hydroxide The main goals in the development of new syn­ and sodium carbonate solutions [8—13], by simulta­ thetic hydrotalcite-like compounds include: substitu­ neous hydrolysis of magnesium and aluminium alkox- 262 Chem. Papers 50(5)262—270 (1996) INTERCALATED COBALT(II) COMPLEXES + {>J[MI,M|(OH)2]' {-}[AvJ ,УН>° -|ДГ+ Ш[м?.,м*(он)2] Fig. 1. Schematic representation of the layered structure of anion-intercalating hydrotalcite-like compounds. Water molecules situated in the interlayer are omitted for the sake of clarity. ides [14], by reacting an aqueous solution of aluminium extensively [28, 40, 41]. The results obtained sug­ salt with magnesium oxide [15—17], by interaction of gest that charge distribution (arrangement of Al3+) magnesium oxide and alumina gel [18—20], by hete- within the electropositive hydrotalcite layers [42— rocoagulation in mixed suspensions of magnesium hy­ 44] will govern the placing and chain packing den­ droxide and aluminium hydroxycarbonate [21], and by sity of carboxylate anions (free distances between pil­ reacting activated magnesium oxide with an aqueous lars) in the interlayer. The glycinate and isonicotinate sodium aluminate solution [22, 23]. Hydrotalcite can monoanions are twice as numerous as glutamate di- also be prepared (Zikmund et a/. [24]) by simulta­ anions. The geometric orientation and accessibility of neous hydrolysis of aqueous solution of sodium alu­ lone pair orbital which is capable of donating an elec­ minate [29, 30] and solid magnesium carbonate hy­ tron pair from nitrogen atom to a vacant orbital on drates or magnesium carbonate hydroxide hydrates. Co(II) are different. The cr-donor (aliphatic amines) Examples for nesquehonite, MgC03-3H20, hydro- and/or 7T-donor (aromatic amines) effects of the axial magnesite, Mg5(C03)4(OH)2-4H20, and dypingite, N-containing ligand influence changes in 7Г bonding to Mg5(C03)4(OH)2-5H20 [25] are included [24]. an empty p orbital of superoxo anion radical coordi­ This paper describes a method for synthesis of nated to the cobalt atom. Mg—Al—СОз-hydrotalcites. The objectives are the Pillared derivatives of hydrotalcite containing tai­ synthesis and the study of the properties of pillared lored interlayer environment (structure, shape, pack­ monocarboxylate derivatives attached to the internal ing, and orientation of the guests) have been used as surface of hydrotalcite, synthesis of cobalt(II) chelate interactive supports for various reagents. Reactions of complexes connected by donor-acceptor bonds to TV- nitrogen donor atoms from aminocarboxylate pillars donor atom of aminocarboxylate pillars, and the study with labile or coordinatively unsaturated cobalt(II) of the interaction of dioxygen with the coordinatively complexes may be utilized as an anchoring method unsaturated cobalt(II) complexes immobilized in the for synthesis of neutral or charged cobalt(II) com­ interlayer region of hydrotalcite derivatives. plexes (chelates) inside the interlayer [45, 46]. The To make the interlayer region of hydrotalcite exposure of attached cobalt(II) species to vapours of accessible to simple substrates, such as dioxygen chelating ligands (e.g. ethylenediamine, salenH2) af­ or molecules of ligands, pillared aminocarboxylate fords a facile preparative procedure for synthesis of derivatives were synthesized. Carboxylate and various immobilized oxygen carriers. The attachment of pla­ other anionic derivatives of hydrotalcite were prepared nar cobalt(II) chelates containing a neutral didentate 2 by restructuring (reconstitution) reaction [26—28] of (NN')2 or a dianionic tetradentate (N202) ~ donor the mixed metal oxide solid solution formed by the systems and a vacant coordination site (or, at most, a thermal decomposition of C03-hydrotalcite [5, 31— site that is only weakly coordinated to nitrogen atoms) 38]. In the present work, ethylene glycol was used in­ in the structure of aminocarboxylate pillar eliminates stead of glycerol as swelling agent [39]. The interlayer the need for addition of a complementary axial ligand arrangement of carboxylate anions has been studied [47]. Chem. Papers 50(5)262—270 (1996) 263 M. ZIKMUND, K. PUTYERA, К. HRNCIAROVA Fig. 2. Scanning electron micrograph of dypingite (x 20 000). Fig. 3. Scanning electron micrograph of hydrotalcite (X 20 000). EXPERIMENTAL mixture was then filtered, repeatedly washed with hot Magnesium Carbonate Hydrates deionized water until the absence of sodium ions (Na+ content 100—60 ^g of Na per 1 g of sample), and dried Nesquehonite, MgC03-3H20, was prepared by under reduced pressure at 100°C for 24 h. The yield C02-saturation of an aqueous suspension of magne­ was 3000 g (99.3 %). sium hydroxide containing monoethanolamine, The hydrophobing of hydrotalcite was achieved by HO(CH2)2NH2 (about 3 mass %) under continuous surface reaction of sodium stearate or sodium palmi- stirring [48, 49]. Transformation of nesquehonite into tate in aqueous suspension. The wet, freshly prepared dypingite, Mg5(C03)4(OH)2-5H20, was conducted hydrotalcite (before filtration) was added to a dilute by its controlled thermal decomposition using super­ aqueous solution of sodium carboxylate and the reac­ heated water vapour (approx. 200°C, 1 h) [50]. The tion mixture was stirred at 50—90°C for 3 h. The solid morphology of dypingite is shown in Fig. 2. was then filtered, washed with deionized water (Na+ content lower than 30 fig of Na per 1 g of sample) and Hydrotalcites dried at 100°C. The size of the particles ranged from 10 /zm to 50 СОз-hydrotalcite was prepared by reaction of a /xm. The N2 BET surface areas for 80 °C dried ma­ solid magnesium carbonate hydrate with aqueous so­ terial were found to be in the range 15—30 m2 g_1. lution of sodium aluminate. Desired Mg/Al ratios The appearance of a product for application in poly­ may be obtained by suitable choice of stoichiometric mer technology is shown in the SEM picture (Fig.
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