Summaries of Physical Research in the Geosciences
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DOE/ER-0292 Dist. Category: UC-11 & 70 Summaries of Physical Research in the Geosciences Published: September 1986 DE86 015659 US. Department of Energy Office of Energy Research Division of Engineering, Mathematics & Geosciences Washington, D.C. 20545 DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency Thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof. DISCLAIMER Portions of this document may be illegible in electronic image products. Images are produced from the best available original document. 4.-E i * .. CONTENTS FOREWORD . ...... INTRODUCTION TO THE GEOSCIENCES RESEARCH PROGRAM OF THE OFFICE OF BASIC ENERGY SCIENCES .......... ...... 1 PART1. ON+SITE rn . ...... ARGONNE NATIONAL LABORATORY ..................... 2 Geochemistry .................... ...... 2 A . Trace Element Migration in the Earth's Crust . ...... 2 B . Migration of Heavy Element Chemical Species in Geologic Media ..................... 4 C . Thermochemistry of Geothermal Materials ......... 5 LAWRENCE BERKELEY LABORATORY ..................... 7 I Geology. Geophysics. and Earth Dynamics ............ 7 I A . Deep Electromagnetic Sounding of the Crust ........ 7 B . Fast ASP Development ................... 7 C . Center for Computational Seismology ........... 9 D . Test of an MHD Source for Crustal Electromagnet Sounding . 10 E . Effect of Fracture Characteristics upon Acoustic Wave Propagation in Boreholes ................ 11 F . Microcrack Growth in Crystalline Rock .......... 11 G . Advanced Research Concepts ................ 13 Geochemistry .......................... 14 A . Thermodynamics of High Temperature Brines ........ 14 B . Thermodynamic Properties of Silicate Materials ...... 15 C . Generation of Petroleum and its Precursor Compounds ... 15 D . Studies of the Interactions Between Mineral Surfaces and Ions in Solution .................. 16 E . Abiogenic Methane Production from Igneous and Metamorphic Rocks ......................... 16 F . Wonisothermal Reservoir Dynamics ............. 17 G . Chemical Transport in Natural Systems .......... 17 H . Impacts and Mass Extinctions ............... 19 Energy Resource Recognition. Evaluation. and Utilization .... 21 A . Hydrothermal Chemistry ...................21 B . PrecDrilling Data Review for the Long Valley Caldera. California ........................ 22 C . Reflection Profiling at the Salton Sea Deep Hole ..... 23 D . Geophysical Measurements Facility ............ 23 E . Geomechanical Laboratory Studies ............. 24 F . Continental Scientific Drilling Review Group ....... 24 G . Aqueous Solutions*Database ................ 25 H . Fundamental Studies of Fluid Flow in Fractured Rock Masses under Stress .................. 25 I . Transport Properties of RockGFluid Systems at Elevated Temperatures and Pressures ............... 26 iii \ LAWRENCE LIVERMORE NATIONAL LABORATORY ................ 28 Geology. Geophysics. and Earth Dynamics ............ 28 1 . Rock Mechanics ...................... 28 B . Diffusion in Silicate Materials ............. 30 C . Electrical Conductivity and Temperature in Upper Mantle ......................... 32 D . Attenuation and Dispersion in Partially Saturated Rocks ......................... 33 E . Surface Wave Method for Determining Earthquake Mechanisms with Applications to Regional Stress Fieldstudies ..................... 33 F . Advanced Concepts .................... 34 Geochemistry .......................... 35 A . Thermodynamics. Kinetics. and Transport in Aqueous Electrolyte Solutions ................. 35 B . Kinetic and Compositional Model of High Pressure Kerogen Pyrolysis ................... 36 Energy Resource Recognition. Evaluation. and Utilization .... 38 A . Continental Drilling Program Information and Data Management Unit .................... 38 B . Viscosity and Electrical Conductivity of Rock Melts: Continental Scientific Drilling Program ........ 39 C . Seismic Studies of Possible Magma Injection and Magma Chambers in the Long Valley Region ........... 40 I D . Shallow Hole Investigations of Long Valley. Valles. and Salton Sea Thermal Regimes ............. 41 E . Salton Sea Scientific Drilling Program Science Management Activities ................. 43 F . SSSDP: Constraints from Borehole Gravity on Geothermal System Models and Resource Definition for the Salton Sea Geothermal Field .................. 43 G . SSSDP: Physical and Chemical Laboratory Studies of Cores from the Salton Sea Scientific Drilling Project . 43 H . Underground Imaging ................... 43 LOS ALAMOS NATIONAL LABORATORY .................... 45 Geology. Geophysics. and Earth Dynamics ............ 45 A . Electrical Conductivity. Temperature. and Radiative Transport in the Earth ................. 45 B . Nonlinear Generation of Acoustic Beams .......... 46 C . Creep Deformation of Rock ................ 46 D . Pore"Size Distribution from NMR Measurements ....... 47 E . Advanced Geoscience Concepts Research .......... 47 Geochemistry .......................... 49 A . Coal Maturation: Occurrence. Form. and Distribution of Sulfur and Mineral Matter in Peat .......... 49 B . Rock-Water Interactions and Element Migration in the Jemez Hydrothermal System ............... 50 C . Thermodynamic Properties of Aqueous Solutions at High Temperatures and Pressures ............... 51 iv I. .. 1. ._ b* D. The Geochemistry of Technetium and'Ruthenium and Geochemical 'Controls ori the Redistribution of Multivalent Elements in the Lithosphere . :. 51 E. Trace Element Geochemistry of V'olcanic Gases from Basaltic Volcanoes of Oceanic Hotspots . '. , 52 F. RAMAN,Spebtroscopy of Aqueous Solution Species . , . 53 Energy Resource R Evaluation, and Utilization'. 55 A. Field and Geochemical Studies of the Polvadera Group, Jemez Volcanic Field, *New Mexico.. i . 55 B. The Bandelier Pluton . ; . 56 C. Valles Caldera Drilling Pfogramr Core hole VC-1 . 57 D. Valles Caldera Drilling Program: Core hole VC-2a . 58 E. Development and Initiation of Sample Management Policy Procedures and dSDP .'. 58 60 Solar-Terrestrial'Atmospheric'Interactions . b . , . A. Energy Transport in Space Plasma . 60 B. Electrodynamical Aspects of the Solar Wind- Magnetosphere Interaction . ; . 61 C. Energetic Particle Acceleration and Transport .a in,the Terrestrial Magnetosphere . 62 OAK RIDGE NATIONAL LABORATORY . .-; .'.... 64 , Geochemistry'. b. , . .' , , . 64 A. Geochemistry of 'Crustal Processes to. High Temperatures and Presiures,:. .. 64 B. Oxygen and Hydrogen Isotope Systematics In Geothermal and Magma/ otherma1 Regimes .I .. 71 PACIFIC NORTHWEST LABORATORY . ................ 72 Geochemistry . * '. ., . .. **@.*..*......*. 72 A. Chemical Migration by Contact Metamorphism Between . e'. , 72 d Utilization . 74 A. Remote Sensing: Geoscience Data Analysis and Integratiom . Solar -Terrestr ial- Atmosph ,* .:e 7 77 A. DOE Insolation/Aeronomy Studies + . 0,. ..... 77 .( SANDIA NATIONAL LABORATORIES . 0, .,. ,,. 81 Geology, Geophysics, Earth Dynamics . , . ** ' 81 A. Crustal Strain . , , . 81 B. Time'Depen t, Deformation aud Fracture of Brittle Rock. ............. 82 C, Creep Mechanisms and Microstructure in Rock Salt . ; . 82 D. Acoustic Emissions and'Damage in Geomaterials . , . 83 E. Advanced Concepts . ,, . , , b .. , , . 84 .I V 1 -Y Geochemistry ......................... 86 A . Magmatic Volatiles .................... 86 . B . Clay .H20 Interactions ................ 88 C . Chemical Diffusion Processes in Silicate Minerals .... 88 Energy Resource Recognition. Evlation. and Utilization . 0 90 A . CSDP .High Temperature CeophysiCal Research Techniques . 90 B . Magmatic Emplacement .................. 91 'C. CSDP Long Valley .Mono Craters Site Assessment .... 92 D . Inyo Domes Research Drilling Program .......... 93 E . Geoscience Research Drilling Office .......... 0 94 PART11. OFF-SITE .......................... 95 UNIVERSITY OF ALASKA ......................... 96 Magnetic Field Annihilation in the Magnetosphere and its A s ....................... 96 ARIZONA STATE UNIVERSITY ....................... 98 illfng Investigation of a Young Magmatic Intrusion Beneath the Inyo Domes; Long Valley. California: Structural and Emplacement Studies .............. 98 UNIVERSITY OF ARIZONA ........................ 101 Solar Variability: Changes in Figure and Mean Diameter ....101 BROW UNIVERSITY ........................... 104 Thermal Regimes of Major Volcanic Centers: Magnetotelluric .Constraints on the Coupling of Deep-seated Magma Genesis to High&Level Geothermal Reservoirs ........ .. ......104 CALIFORNIA INSTITUTE OF TECHNOLOGY ..................107 .-In Situ Stress in Deep Boreholes ................107 Infrared Spectroscopy and Hydrogen Isotope Geochemistry of Hydrous Sllicate Glasses ................... 109 UNIVERSITY OF CALIFORNIA ....................... 111 AdvectivePDiffusive/Dispersive