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Professor Dr Fakultät für Chemie und Pharmazie ForschungsberichtForschungsbericht 2010-20112006-2007 BandBand 119 Forschungsbericht der Fakultät für Chemie und Pharmazie für die Jahre 2010–2011 Band 11 Ludwig-Maximilians-Universität München II Herausgeber: Fakultät für Chemie und Pharmazie der Ludwig-Maximilians-Universität München München, 2012 Für den Inhalt der Beiträge sind die Autoren verantwortlich Sekretariat: Gertrud Adelmann Dekanat der Fakultät für Chemie und Pharmazie der Ludwig-Maximilians-Universität München Butanandtstr. 5–13 (Haus F), 81377 München Druck und Binden: UNI-Druck, Herbert Novotny, München Vorwort "Die Universitäten dienen vornehmlich der Forschung und Lehre und verbinden diese zu einer vorwiegend wissenschaftsbezogenen Ausbildung". Mit dem vorliegenden Forschungsbericht legt die Fakultät für Chemie und Pharmazie der LMU Rechenschaft darüber ab, wie sie in den Jahren 2010 und 2011 den ersten Teil ihrer in §2, Satz 4, des Bayerischen Hochschulgesetzes definierten Aufgaben erfüllt hat. Die große Zahl an Veröffentlichungen in international erstklassigen Publikationsorganen belegt, dass die Wissenschaftlerinnen und Wissenschaftler der Fakultät die staatlichen Fördermittel und eingeworbenen Drittmittel effizient genutzt haben: Durch die erfolgreich abgeschlossenen Forschungsprojekte wurde die Wissensbasis verbreitert, auf der ein Großteil des materiellen Wohlstands unserer Gesellschaft beruht, und gleichzeitig die daran beteiligten Doktorandinnen und Doktoranden in die Methodik wissenschaftlichen Arbeitens eingeführt und auf ihre spätere berufliche Tätigkeit vorbereitet. Die hohe Forschungsaktivität der Fakultät führte zu einer weiteren Steigerung der Drittmittelförderung in Einzelprojekten, Graduiertenkollegs, Sonderforschungsberei- chen und Exzellenzclustern, wodurch es auch möglich wurde, aktuelle Forschungsrich- tungen zu verstärken. So wurde im Berichtszeitraum durch die Neueinrichtung eines Lehrstuhls der zunehmenden Bedeutung der Theoretischen Chemie Rechnung getragen. Das Bayerische Forschungszentrums für Molekulare Biosysteme, Teil des Programms „Aufbruch Bayern―, befindet sich derzeit im Aufbau. Als Anerkennung hoher Forschungskompetenz darf auch gewertet werden, dass zu den früher bereits eingeworbenen drei Grants des European Research Councils im Berichtszeitraum vier weitere Bewilligungen hinzukamen. Berufungen von sieben Nachwuchswissenschaftlern unserer Fakultät auf Professuren an andere Universitäten dokumentieren die erfolgreiche Nachwuchsförderung. Umgekehrt haben zwei junge Wissenschaftlerinnen und zwei Wissenschaftler Rufe an unsere Fakultät angenommen. Diesem Forschungsbericht nicht zu entnehmen sind die großen Anstrengungen zur Verbesserung der Lehre bei stark gestiegenen Studierendenzahlen (doppelter Abitur- Jahrgang), die in enger Abstimmung mit unseren Studierenden erfolgte. Der Einsatz von Studiengebühren für die Finanzierung von Tutoren, Modernisierung der Praktika und Unterstützung von Auslandsaufenthalten für Studierende spielte hierbei eine wichtige Rolle. Allen Mitarbeiterinnen und Mitarbeitern der Fakultät danke ich sehr herzlich für ihr Engagement in Forschung und Lehre. Es macht Freude, mit ihnen zu arbeiten! Professor Dr. Herbert Mayr Dekan der Fakultät für Chemie und Pharmazie IV Zur Fakultät für Chemie und Pharmazie gehören das Department Biochemie, das Department Chemie und das Department Pharmazie. Die aktuellen Adessen lauten: Department Biochemie Feodor-Lynen-Straße 25, Haus A 81377 München, Tel. 089/2180-0 Department Chemie Butenandtstraße 5–13 (Haus D, E und F), 81377 München, Tel. 089/2180-0 Lehrbereich Anorganische Chemie: Haus D Lehrbereich Organische Chemie: Haus F Lehrbereich Physikalische Chemie: Haus E Butenandtstr. 5-13 81377 München Department Pharmazie – Zentrum für Pharmaforschung – Butenandtstr. 5–13 (Haus B und C, teilweise Haus D), 81377 München, Tel. 089/2180-0 Lehrbereich Pharmazeutische Chemie: Haus C Lehrbereich Pharmazeutische Biologie und Biotechnologie: Haus B und Haus D Lehrbereich Pharmazeutische Technologie und Biopharmazie: Haus B Lehrbereich Pharmakologie für Naturwissenschaften: Haus C V Lehrbereich Anorganische Chemie Seiten Beck, Wolfgang 1–3 Boehm, Hanns-Peter 4 Böttcher Hans-Christian 5–6 Herres-Pawlis, Sonja 7–11 Johrendt, Dirk 12–15 Karaghiosoff, Konstantin 16–18 Klapötke, Thomas 19–29 Klüfers, Peter 30–36 Kornath, Andreas 37–38 Lorenz, Ingo-Peter 39–40 Lotsch, Bettina 41–44 Nöth, Heinrich 45–47 Oeckler, Oliver 48–51 Schmedt auf der Günne, Jörn 52–53 Schnick, Wolfgang 54–59 Sünkel, Karlheinz 60–61 Lehrbereich Biochemie Beckmann, Roland 62–65 Conti, Elena 66–68 Cramer, Patrick 69–75 Fässler, Reinhold 76–79 Förstemann, Klaus 80–81 Gaul, Ulrike 82–83 Grininger, Martin 84–86 Halic, Mario 87 Hartl, F. Ulrich 88–93 Hopfner, Karl-Peter 94–98 Mann, Matthias 99–108 Martin, Dietmar 109 Niessing, Dierk 110–111 Schäffner, Anton 112–114 Söding, Johannes 115–118 Sträßer, Katja 119–121 Tresch, Achim 122–124 Turck, Christoph 125–129 Wendler, Petra 130–131 Wilson, Daniel 132–134 Wolf, Eva 135–137 VI Lehrbereich Organische Chemie Carell, Thomas 138–144 Dube, Henry 145–146 Heuschmann, Manfred 147 Hoffmann-Röder, Anja 148–150 Huisgen, Rolf 151 Knochel, Paul 152–161 Koszinowski, Konrad 162–163 Langhals, Heinz 164–168 Mayr, Herbert 169–174 Ofial, Armin 175–176 Steglich, Wolfgang 177 Trauner, Dirk 178–184 Zipse, Hendrik 185–188 Lehrbereich Physikalische Chemie Bein, Thomas 189–196 Bräuchle, Christoph 197–203 Ebert, Hubertus 204–210 Fattakhova-Rohlfing, Dina 211–214 Hartschuh, Achim 215–217 Ködderitzsch, Diemo 218–220 Lamb, Don C. 221–224 Minar, Jan 225–227 Ochsenfeld, Christian 228–231 Scheu, Christina 232–235 deVivie-Riedle, Regina 236–239 Wintterlin, Joost 240–241 VII Lehrbereich Pharmazeutische Chemie Bracher, Franz 242–245 Wanner, Klaus 246–248 Lehrbereich Pharmazeutische Biologie und Biotechnologie Fürst, Robert 249–251 Günther, Michael 252 Ogris, Manfred 253–258 Vollmar, Angelika 259–264 Wagner, Ernst 265–271 Wagner, Hildebert 272–273 Zahler, Stefan 274–276 Lehrbereich Pharmazeutische Technologie und Biopharmazie Besheer, Ahmed 277–278 Frieß, Wolfgang 279–282 Myschik, Julia 283–284 Winter, Gerhard 285–290 Lehrbereich Pharmakologie für Naturwissenschaften Biel, Martin 291–294 Michalakis, Stylianos 295–297 Wahl-Schott, Christian 298–299 Index Fachgebiete/Autoren 300–313 Alphabetisches Namensverzeichnis 314–315 1 Lehrbereich Anorganische Chemie Univ.-Prof. Dr. rer. nat. Dr. h.c. Wolfgang Beck, em. geb. 1932 in München, Chemiestudium Technische Hochschule München, Promotion bei Prof. W. Hieber (1960) und Habilitation (1963) an der TH München, seit 1968 o. Professor und Vorstand des Instituts für Anorganische Chemie, 1973/74 Dekan der Fa- kultät für Chemie und Pharmazie, 1977 Gastprofessor an der University of Wisconsin, Madison, 1990/92 Mitglied des Senats und der Versammlung, Fachgutachter der Deut- schen Forschungsgemeinschaft (1981- 1992); seit 2000 Emeritus. Mitgliedschaften GDCh, American Chemical Society, The Royal Society of Chemistry Ehrungen 2011 Ehrendoktor der Technischen Universität München Forschungsprojekte Metallorganische und Komplex-Chemie: Metallkomplexe mit biologisch wichtigen Lig- anden (vor allem -Aminosäuren, Peptide), metallvermittelte Synthese von Peptiden und Cyclopeptiden. Nitrosyl-Metallkomplexe. Publikationen Reactions of Metal Carbonyls with the Azide Ion and – vice versa – Reactions of Azido Complexes with Carbon Monoxide: Isocyanato Complexes. + – Analogous Reactions in NO /N3 Transition Metal Chemistry Wolfgang Beck and Wolf Peter Fehlhammer Z. Anorg. Allg. Chem. 2010, 636, 157-162. Coordination of the Ester Group – Hydrido-Rhodium(III) and Iridium(III) Complexes of Orthometallated Diphenylmethylene Glycine Esters Bernhard Schreiner and Wolfgang Beck Z. Anorg. Allg. Chem. 2010, 636, 499-505. 2 Reactions of ―in-Situ‖ Generated Cr(CO)5CN-C(Cl)-PR3 (R = Ph, NMe2) with Potential Dipolarophiles. New Examples of [3+2] Cycloadditions with Concomi- tant Interligand CC Bond Formation Samyoung Ahn, Volker Langenhahn, Wilfried Sperber, Wolfgang Beck, and Wolf Peter Fehlhammer Z. Anorg. Allg. Chem. 2010, 636, 492-498. Metal Complexes of Biologically Important Ligands, CLXXIV Palladium(II) and Platinum(II) Complexes with Schiff Bases from 2-(Diphenylphosphino)benzaldehyde and α-Amino Acid Esters Bernhard Schreiner, Christian Robl, Barbara Wagner-Schuh, and Wolfgang Beck Z. Naturforsch. 2010, 65b, 503-510. [3+2] Cycloadditions of Metallo Nitrile Ylides and Metallo Nitrile Imines with Metal Carbonyl, Thiocarbonyl, and Isocyanide Complexes: Heterodimetallic Systems with Bridging Heterocycles Friedrich Schoder, Ulrike Plaia, Robert Metzner, Wilfried Sperber, Wolfgang Beck and Wolf Peter Fehlhammer Z. Anorg. Allg. Chem. 2010, 636, 700-709. Metal Complexes of Biologically Important Ligands, CLXXV Pentamethylcyclopentadienyl Halfsandwich Complexes of Rhodium(III) and Iridium(III) with Schiff Bases from 2-(Diphenylphosphino)- benzaldehyde and α-Amino Acid Esters Bernhard Schreiner, Barbara Wagner-Schuh, and Wolfgang Beck Z. Naturforsch. 2010, 65b, 679-686. Die Strukturen von δ-PdCl2 und γ-PdCl2: Phasen mit negativer thermischer Aus- dehnung in einer Richtung Jürgen Evers, Wolfgang Beck, Michael Göbel, Stefanie Jakob, Peter Mayer, Gilbert Oehlinger, Marianne Rotter und Thomas M. Klapötke Angew. Chem. 2010, 122, 5812-5817. The Structures of δ-PdCl2 and γ-PdCl2: Phases with Negative Thermal Expansion in One Direction Jürgen Evers, Wolfgang Beck, Michael Göbel, Stefanie Jakob, Peter Mayer, Gilbert Oehlinger, Marianne Rotter, and Thomas M. Klapötke
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