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Safety Data Sheet SAFETY DATA SHEET Revision Date 20-Nov-2014 Revision Number 3 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identification Product Description: Silver carbonate Cat No. : 176970000; 176970050; 176970250; 176971000 Synonyms None. CAS-No 534-16-7 EC-No. 208-590-3 Molecular Formula C Ag2 O3 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Laboratory chemicals. Uses advised against No Information available 1.3. Details of the supplier of the safety data sheet Company Acros Organics BVBA Janssen Pharmaceuticalaan 3a 2440 Geel, Belgium E-mail address [email protected] 1.4. Emergency telephone number For information US call: 001-800-ACROS-01 / Europe call: +32 14 57 52 11 Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99 CHEMTREC Tel. No.US:001-800-424-9300 / Europe:001-703-527-3887 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture CLP Classification - Regulation (EC) No 1272/2008 Physical hazards Based on available data, the classification criteria are not met Health hazards Serious Eye Damage/Eye Irritation Category 1 Environmental hazards Acute aquatic toxicity Category 1 Chronic aquatic toxicity Category 1 Classification according to EU Directives 67/548/EEC or 1999/45/EC Symbol(s) Xi - Irritant N - Dangerous for the environment R-phrase(s) R41 - Risk of serious damage to eyes R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment ______________________________________________________________________________________________ ACR17697 Page 1 / 9 SAFETY DATA SHEET Silver carbonate Revision Date 20-Nov-2014 ______________________________________________________________________________________________ For the full text of the R-phrases and H-Statements mentioned in this Section, see Section 16. 2.2. Label elements Signal Word Danger Hazard Statements H318 - Causes serious eye damage H410 - Very toxic to aquatic life with long lasting effects Precautionary Statements P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P280 - Wear protective gloves/ protective clothing/ eye protection/ face protection P261 - Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray P273 - Avoid release to the environment 2.3. Other hazards No information available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Component CAS-No EC-No. Weight % CLP Classification - DSD Classification - Regulation (EC) No 67/548/EEC 1272/2008 Carbonic acid, disilver(1+) salt 534-16-7 EEC No. 208-590-3 >95 Eye Dam. 1 (H318) N; R50/53 Aquatic Acute 1 (H400) Xi; R41 Aquatic Chronic 1 (H410) For the full text of the R-phrases and H-Statements mentioned in this Section, see Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures General Advice If symptoms persist, call a physician. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention. Skin Contact Obtain medical attention. Wash off immediately with plenty of water for at least 15 minutes. Ingestion Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur. Inhalation Move to fresh air. If breathing is difficult, give oxygen. Obtain medical attention. Protection of First-aiders Use personal protective equipment. ______________________________________________________________________________________________ ACR17697 Page 2 / 9 SAFETY DATA SHEET Silver carbonate Revision Date 20-Nov-2014 ______________________________________________________________________________________________ 4.2. Most important symptoms and effects, both acute and delayed None reasonably foreseeable. Causes eye burns. 4.3. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Suitable Extinguishing Media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Extinguishing media which must not be used for safety reasons No information available. 5.2. Special hazards arising from the substance or mixture Do not allow run-off from fire fighting to enter drains or water courses. Hazardous Combustion Products Carbon monoxide (CO), Carbon dioxide (CO2). 5.3. Advice for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Ensure adequate ventilation. Avoid dust formation. 6.2. Environmental precautions Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained. See Section 12 for additional ecological information. Avoid release to the environment. Collect spillage. 6.3. Methods and material for containment and cleaning up Sweep up or vacuum up spillage and collect in suitable container for disposal. Keep in suitable, closed containers for disposal. 6.4. Reference to other sections Refer to protective measures listed in Sections 8 and 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Wear personal protective equipment. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Avoid dust formation. 7.2. Conditions for safe storage, including any incompatibilities Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from light. ______________________________________________________________________________________________ ACR17697 Page 3 / 9 SAFETY DATA SHEET Silver carbonate Revision Date 20-Nov-2014 ______________________________________________________________________________________________ 7.3. Specific end use(s) Use in laboratories SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Exposure limits List source(s): Component Italy Germany Portugal The Netherlands Finland Carbonic acid, TWA: 0.01 mg/m3 (8 disilver(1+) salt Stunden). AGW - exposure factor 2 TWA: 0.01 mg/m3 (8 Stunden). MAK Höhepunkt: 0.02 mg/m3 Component Austria Denmark Switzerland Poland Norway Carbonic acid, STEL: 0.02 mg/m3 15 disilver(1+) salt Minuten TWA: 0.01 mg/m3 8 Stunden Biological limit values This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific regulatory bodies. Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust Derived No Effect Level (DNEL) No information available Route of exposure Acute effects (local) Acute effects Chronic effects Chronic effects (systemic) (local) (systemic) Oral Dermal Inhalation Predicted No Effect Concentration No information available. (PNEC) 8.2. Exposure controls Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source ______________________________________________________________________________________________ ACR17697 Page 4 / 9 SAFETY DATA SHEET Silver carbonate Revision Date 20-Nov-2014 ______________________________________________________________________________________________ Personal protective equipment Eye Protection Goggles (European standard - EN 166) Hand Protection Protective gloves Glove material Breakthrough time Glove thickness EU standard Glove comments Nitrile rubber See manufacturers - EN 374 (minimum requirement) Neoprene recommendations Natural rubber PVC Skin and body protection Long sleeved clothing Inspect gloves before use. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) Ensure gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. Remove gloves with care avoiding skin contamination. Respiratory Protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly Large scale/emergency use Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced Recommended Filter type: Particulates filter conforming to EN 143 Small scale/Laboratory use Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposure
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