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South North West East West East West East West East Eastern Central West Eastern and Central Western and Central Western and Central Age from: Repetski and others (2008) Stratigraphy from: Ryder and others (2008, 2009) Stratigraphy from: Ryder and others (2008, 2009, 2010) Stratigraphy from: Berg and others (1983); Ryder and others (2010) Stratigraphy from: Repetski and others (2008) Era System Series (Ma) Valley Valley Rome Trough Rome Trough Rome Trough and Ridge Bedford and Ridge

Cleveland Member Venango Group 359.2 Upper strata, undivided Ohio Three Lick Bed equivalent rocks Chagrin Shale Bradford Group Perrysburg Formation Shale Dunkirk Shale Member Huron Member of Ohio Shale Huron Member Elk Group Scherr Formation Upper Dunkirk Shale Angola Shale Member (upper) Java Formation Java Formation Angola Shale Member West Falls West Falls West Falls Angola Shale Member Formation Member Rhinestreet Shale Member of the Formation Rhinestreet Shale Member Formation Rhinestreet Shale Member Upper Devonian strata, undivided 385.3 Sonyea and Genesee Formations, undivided Sonyea and Genesee Formations, undivided Sonyea and Genesee Formations, undivided Tully Tully Limestone Tully Limestone Mahantango Formation Moscow, Ludlowville, and Skaneateles , undivided Hamilton Olentangy Shale (lower) Hamilton Hamilton Middle Group Group Group Tioga Bentonite Marcellus Shale Marcellus Shale Tioga Bentonite Marcellus Shale Marcellus Shale Boyle Dolomite Onondaga Limestone Huntersville and Onondaga Limestone Needmore Onondaga Limestone Devonian Shale 397.5 Oriskany Oriskany Sandstone

Bois Blanc Formation Oriskany Oriskany Sandstone Lower Sandstone Shriver Formation and Helderberg Limestone Helderberg Licking Creek Limestone, Limestone undivided Mandata Shale Mandata Shale Helderberg Limestone 416.0 Keyser Limestone (upper) Corriganville and New Creek , undivided Bass Islands Dolomite Bass Islands Dolomite Keyser Limestone (lower) Big Mountain Shale Bass Islands Dolomite Akron Dolomite Pridoli Camillus Shale Camillus Formation Salina Group Salina Salina Group Tonoloway Limestone Salina Group Salina Group Syracuse Formation Syracuse Formation Group 418.7 Vernon Formation Vernon Formation ? “Newburg zone” of drillers ?

“Corniferous ” carbonate formations Tymochtee and Upper Newburg sandstone Wills Creek Formation Paleozoic Ludlow Greenfield Limestones, McKenzie Eramosa Dolomite McKenzie Limestone undivided Lockport Dolomite Lockport Dolomite 422.9 Member Lockport Group

Formation Rochester Member of Berg Mifflintown and others (1983) Keefer Sandstone of Ohio and (Ryder, 2004) Wenlock of Pennsylvania (Ryder, 2004) Keefer Sandstone Keefer Sandstone of Ohio 428.2 (Big Six sandstone) and West Virginia (Ryder, 2004) Keefer Formation of Rochester Shale Pennsylvania (Ryder, 2004) Alger Shale Lower Silurian carbonates Rose Hill Formation

Rose Hill Lower Silurian carbonates and shales, undivided Formation and shales, undivided Lower

Llandovery Group Drowning Castanea Member Clinch Crab Orchard Undivided members “Clinton” sandstone, Cabot Head Shale, and Medina Sandstone Creek Cabot Head Shale Medina Group Formation Medina sandstone, undivided Group Tuscarora Formation 443.7 Brassfield Member Brassfield Limestone Queenston Shale through Clays Ferry Formation, undivided Juniata Formation Queenston Shale Queenston Shale Reedsville Shale group (informal usage) Reedsville Shale Oswego Sandstone Utica Shale Utica Shale Antes Shale Utica Shale Upper Trenton Limestone Trenton Group Millbrig Bentonite Bed Millbrig Bentonite Bed Trenton Limestone Millbrig Bentonite Bed Millbrig Bentonite Bed Trenton Limestone

Deicke Bentonite Bed Deicke Bentonite Bed Deicke Bentonite Bed Deicke Bentonite Bed Black River Group High Bridge Group Black River Limestone Black River Group

460.9 Loysburg Formation Wells Creek dolomite (informal usage) Unnamed anhydritic dolomite (informal usage)

Middle St. Peter Sandstone Unnamed sandstone (St. Peter Sandstone 471.8 equivalent)

EXPLANATION Major lithology Sample locations Sandstone Limestone with chert From Salina Group, Bass Islands Dolomite, Keyser Limestone Figure 2. Correlation chart of Middle Ordovician through Upper Devonian rocks in Kentucky, New York, Ohio, Pennsylvania, and West Virginia showing intervals sampled for total organic carbon (TOC) and (or Formation), Wills Creek Formation, or Tonoloway Limestone Gray shale Dolomite Rock-Eval analysis. Geologic time scale from Gradstein and others (2004). Black shale Dolomite with dark-gray to black shale From Lockport Dolomite (or Group), Eramosa Dolomite, or McKenzie Limestone (or Member) U.S. Geological Survey Professional Paper 1708–G.11 Red shale Dolomite with evaporite beds From Cabot Head Shale, Rose Hill Formation, Rochester Shale, Limestone Bentonite bed—Dashed where or other Lower Silurian strata approximate