minerals Article Major, Trace, and Rare-Earth Element Geochemistry of Nb-V Rich Andradite-Schorlomite-Morimotoite Garnet from Ambadungar-Saidivasan Alkaline Carbonatite Complex, India: Implication for the Role of Hydrothermal Fluid-Induced Metasomatism Amiya K. Samal 1 , Rajesh K. Srivastava 1,* and Dewashish Upadhyay 2 1 Centre of Advanced Study in Geology, Banaras Hindu University, Varanasi 221005, India;
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[email protected] Abstract: In situ major, trace and rare-earth element composition of Ti-rich garnets from Ambadungar- Saidivasan alkaline carbonatite complex (ASACC) are presented to constrain its likely genesis. The garnets are characterized by high andradite (42.7–57.3), schorolomite (22.0–31.0), and morimotoite (15.6–26.5) end members. No distinct chemical zonation is noticed except for minor variations in Ti content. The garnets are enriched in LREE (average 731 ppm) and relatively depleted in HREE Citation: Samal, A.K.; Srivastava, (average 186 ppm) and show an M-type first tetrad that leads to a convex upward pattern between R.K.; Upadhyay, D. Major, Trace, and Ce and Gd. Mildly positive to no Eu anomalies are observed (Eu/Eu* = 1.06–1.17). The REE patterns Rare-Earth Element Geochemistry of (LaN/YbN = 1.11–2.11) are similar to those of garnets from skarn deposits. The presence of tetrad Nb-V Rich Andradite-Schorlomite- effect in the LREE pattern suggests an active role of metasomatic processes involving hydrothermal Morimotoite Garnet from fluids during the growth of the garnets.