Prairie L. Carbonatite Complex
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Summary of the Mineral Information Package for the Khanneshin Carbonatite Area of Interest
Chapter 21A. Summary of the Mineral Information Package for the Khanneshin Carbonatite Area of Interest Contribution by Robert D. Tucker, Harvey E. Belkin, Klaus J. Schulz, Stephen G. Peters, and Kim P. Buttleman Abstract The Khanneshin carbonatite is a deeply dissected igneous complex of Quaternary age that rises approximately 700 meters above the flat-lying Neogene sediments of the Registan Desert, Helmand Province, Afghanistan. The complex consists almost exclusively of carbonate-rich intrusive and extrusive igneous rocks, crudely circular in outline, with only three small hypabyssal plugs of leucite phonolite and leucitite outcropping in the southeastern part of the complex. The complex is broadly divisible into a central intrusive vent (or massif), approximately 4 kilometers in diameter, consisting of coarse-grained sövite and brecciated and agglomeratic barite-ankerite alvikite; a thin marginal zone (less than 1 kilometer wide) of outwardly dipping (5°–45°). Neogene sedimentary strata; and a peripheral apron of volcanic and volcaniclastic strata extending another 3–5 kilometers away from the central intrusive massif. Small satellitic intrusions of biotite-calcite carbonatite, no larger than 400 meters in diameter, crop out on the southern and southeastern margin of the central intrusive massif. In the 1970s several teams of Soviet geologists identified prospective areas of interest for uranium, phosphorus, and light rare earth element (LREE) mineralization in four regions of the carbonatite complex. High uranium concentrations are reported in two regions; the greatest concentrations are confined to silicified shear zones in sandy clay approximately 1.1 kilometers southwest of the peripheral part of the central vent. An area of phosphorus enrichment, primarily occurring in apatite, is present in coarse-grained agglomeratic alvikite, with abundant fenite xenoliths, approximately 750 meters south of the periphery of the central vent. -
Mineralogy and Geochemistry of Ocelli in the Damtjernite Dykes and Sills, Chadobets Uplift, Siberian Craton: Evidence of the Fluid–Lamprophyric Magma Interaction
minerals Article Mineralogy and Geochemistry of Ocelli in the Damtjernite Dykes and Sills, Chadobets Uplift, Siberian Craton: Evidence of the Fluid–Lamprophyric Magma Interaction Anna A. Nosova 1,*, Ludmila V. Sazonova 1,2, Alexey V. Kargin 1 , Elena O. Dubinina 1 and Elena A. Minervina 1 1 Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry, Russian Academy of Sciences (IGEM RAS), 119017 Moscow, Russia; [email protected] (L.V.S.); [email protected] (A.V.K.); [email protected] (E.O.D.); [email protected] (E.A.M.) 2 Geology Department, Lomonosov Moscow State University, 119991 Moscow, Russia * Correspondence: [email protected]; Tel.:+7-499-230-8414 Abstract: The study reports petrography, mineralogy and carbonate geochemistry and stable iso- topy of various types of ocelli (silicate-carbonate globules) observed in the lamprophyres from the Chadobets Uplift, southwestern Siberian craton. The Chadobets lamprophyres are related to the REE-bearing Chuktukon carbonatites. On the basis of their morphology, mineralogy and relation with the surrounding groundmass, we distinguish three types of ocelli: carbonate-silicate, containing carbonate, scapolite, sodalite, potassium feldspar, albite, apatite and minor quartz ocelli (K-Na-CSO); carbonate–silicate ocelli, containing natrolite and sodalite (Na-CSO); and silicate-carbonate, con- taining potassium feldspar and phlogopite (K-SCO). The K-Na-CSO present in the most evolved Citation: Nosova, A.A.; Sazonova, damtjernite with irregular and polygonal patches was distributed within the groundmass; the patches L.V.; Kargin, A.V.; Dubinina, E.O.; consist of minerals identical to minerals in ocelli. Carbonate in the K-Na-CSO are calcite, Fe-dolomite Minervina, E.A. -
Ree‐ Minerals in Carbonatite, Alkaline and Hydrothermal Rocks, Northern and Central Finland
ERES2014: 1st European Rare Earth Resources Conference|Milos|04‐07/09/2014 REE‐ MINERALS IN CARBONATITE, ALKALINE AND HYDROTHERMAL ROCKS, NORTHERN AND CENTRAL FINLAND Thair AL‐ANI1* and Olli SARAPAA2 1 Geological Survey of Finland, P.O. Box 96, FI‐02151 Espoo, Finland 2 Geological Survey of Finland, P.O. Box 77, FI‐96101 Rovaniemi, Finland Email: [email protected], [email protected] Abstract REE‐rich minerals were identified and analyzed by electron microprobe from different targets located in the northern and central Finland. Both primary and hydrothermal minerals were found namely: phosphates (monazite‐Ce), fluor‐carbonates (bastnaesite‐Ce), hydrated carbonates (ancylite‐Ce), hydrated aluminium silicates, (allanite), oxides (fergusonite) and U‐Pb rich minerals. Sokli Jammi‐ Kaulus carbonatite veins are enriched in LREE, P, F, Sr and Ba hosting in ancylite, bastnaesite, apatite and monazite. Allanite‐(Ce) and fergusonite (Y) are abundant in alkaline gneiss of the Katajakangas REE‐occurrence. The Korsnäs Pb‐REE deposit includes apatite with monazite inclusions, calcio‐ancylite and bastnasite. The Mäkärä‐ Vaulo REE‐prospect in arkosic gneisses is dominated by monazite, allanite and xenotime. Albitites at Enontekiö contain bastnaesite, monazite, allanite, xenotime and U‐rich minerals includes davidite, masuyite and sayrite. The Honkilehto Au‐Co‐S‐mineralization at Kuusamo is characterized by U‐rich minerals with bastnaesite and allanite. The results obtained provide vital insights into the mineralizing processes associated with REE‐prospects in northern and central Finland. Introduction Economic REE deposits are not known in Finland. However, REEs were extracted in the 1960’s century as a by‐product in the fertilizer production from the apatite concentrates of the Kola Peninsula and the Korsnäs Pb mine in western Finland (1). -
Nd, Pb and Sr Isotopic Data from the Napak Carbonatite-Nephelinite Centre, Eastern Uganda: an Example of Open-System Crystal Fractionation
Contrib Mineral Petrol (1994) 115:356-366 Contributions tO Mineralogy and Petrology Springer-Verlag 1994 Nd, Pb and Sr isotopic data from the Napak carbonatite-nephelinite centre, eastern Uganda: an example of open-system crystal fractionation Antonio Simonetti and Keith Bell Ottawa-Carleton Geoscience Centre, Department of Earth Sciences, Carleton University, Ottawa, Ontario K1S 5B6, Canada Received June 30, 1992 / Accepted May 25, 1993 Abstract. Nd, Pb and Sr isotopic data from nephelinite magmas cannot be in equilibrium with a lherzolitic mantle lavas from the Tertiary nephelinite-carbonatite complex source (Bultitude and Green 1968, 1971; Allen et al. 1975; of Napak, eastern Uganda, show large isotopic variations Merrill and Wyllie 1975), but are probably the products of that can only be attributed to open-system behaviour. small ( < 5%) degrees of partial melting of a carbonated Possible explanations of the data include mixing between (high C02/H20 ratio) peridotite or pyrolite at high pres- nephelinitic melts derived from an isotopically heterogen- sures (Brey and Green 1977; Brey 1978; Olafsson and eous mantle, or interaction between a HIMU melt and Eggler 1983; Wallace and Green 1988). Experimental re- mafic granulites. In both models crystal fractionation, sults are consistent with derivation of a primary involving olivine and clinopyroxene, played an important nephelinitic liquid from an amphibole peridotite at pres- role. Major element chemistry, textural evidence and iso- sures of 20 to 25 kbar (Olafsson and Eggler 1983; Eggler topic data from clinopyroxene phenocrysts from the ol- 1989). ivine-bearing nephelinites, suggest that the pyroxenes did The eastern branch of the East African Rift Valley not crystallize from their host liquids. -
Petrogenesis of Natrocarbonatite at Oldoinyo Lengai, East Africa— Evidence from Fe and U Isotope Variations
PETROGENESIS OF NATROCARBONATITE AT OLDOINYO LENGAI, EAST AFRICA— EVIDENCE FROM FE AND U ISOTOPE VARIATIONS BY ZHENHAO ZHOU THESIS Submitted in partial fulfillment of the requirements for the degree of Master of Science in Geology in the Graduate College of the University of Illinois at Urbana-Champaign, 2017 Urbana, Illinois Adviser: Professor Craig C. Lundstrom Abstract Ol Doinyo Lengai (ODL), Tanzania, is the only active carbonatite volcano on earth. Cyclical activity that consists of quiescent natrocarbonatite lava flow, explosive silicate eruption and dormancy has been observed throughout the 20th century at ODL. From 2007 to 2008, ODL explosively erupted coexisting natrocarbonatites and nephelinites. Numerous studies have been aimed at understanding how ODL natrocarbonatite forms. Liquid immiscibility is a favored hypothesis although condensate fluid separation is an alternative model. However, the exact mechanism that forms the ODL natrocarbonatite remains unresolved. We carried out Fe and U isotope analyses among a variety of ODL samples. Our sample set includes natrocarbonatite that erupted in 2005, 2 comingled tephras (mixture of natrocarbonatite and nephelinite) and a sequence of 8 nephelinite tephras that erupted in 2007- 2008; as well as magnetites separated from 2005 natrocarbontite; Ti-andradites and clinopyroxenes that were separated from one of the nephelinite tephras. Our results show a lighter Fe isotope composition of natrocarbonatite (!56Fe of -0.08‰ relative to IRMM-14) compared to nephelinite tephras (-0.06 to 0.20 ‰ relative to IRMM-14). Magnetites yield heavier Fe isotope composition (0.03‰) than natrocarbonatite; Ti-andradite has the heaviest Fe isotope composition among all analyzed samples due to its enrichment in Fe3+. -
Compositionally Stratified Lithosphere and Carbonatite Metasomatism
Lithos 116 (2010) 111–128 Contents lists available at ScienceDirect Lithos journal homepage: www.elsevier.com/locate/lithos Compositionally stratified lithosphere and carbonatite metasomatism recorded in mantle xenoliths from the Western Qinling (Central China) Ben-Xun Su a,b,c,⁎, Hong-Fu Zhang a, Patrick Asamoah Sakyi d, Ji-Feng Ying a, Yan-Jie Tang a, Yue-Heng Yang a, Ke-Zhang Qin b, Yan Xiao a, Xin-Miao Zhao a a State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, P.O. Box 9825, Beijing 100029, China b Key Laboratory of Mineral Resources, Institute of Geology and Geophysics, Chinese Academy of Sciences, P.O. Box 9825, Beijing 100029, China c Graduate University of Chinese Academy of Sciences, Beijing 100049, China d Department of Geology, University of Ghana, P.O. Box LG 58, Legon-Accra, Ghana article info abstract Article history: In Central China, long-distance effects from collision between the North China and Yangtze cratons, uplift of Received 4 May 2009 the Tibetan Plateau and subduction of the Pacific Ocean are believed to converge in the Western Qinling. Accepted 8 January 2010 Mantle xenoliths from Baiguan and Haoti kamafugites in the Western Qinling were investigated to Available online 15 January 2010 understand the lithospheric structure and mantle metasomatism beneath the orogenic belt. The Western Qinling lithosphere with depths of at least 120 km is geothermally hot and compositionally stratified, Keywords: companied by a step-wise decrease in fertility with depth. The shallower portion of the lithospheric mantle is Carbonatite metasomatism represented by type 2 xenoliths which lack alteration and deformation, and have fertile characteristics in Mantle peridotite Stratified lithospheric mantle compositions. -
Mineralogy, Geochemistry and Petrology of a Pyrochlore-Bearing Carbonatite at Seabrook Lake, Ontario
Mineralogy, Geochemistry and Petrology of a Pyrochlore-bearing Carbonatite at Seabrook Lake, Ontario by Myron John Osateriko B.Sc, University of British Columbia, 1965 A Thesis Submitted in Partial Fulfilment ' of the Requirements for the Degree of MASTER OF SCIENCE in the Department of GEOLOGY We accept this thesis as conforming to the required standard THE UNIVERSITY OF BRITISH COLUMBIA April, 1967 In presenting this thesis in partial fulfilment of the requirements for an advanced degree at the University of British Columbia, I agree that th3 Library shall make it freely available for reference and study. I further agree that permission for extensive copying of this thesis for scholarly purposes may be granted by the Head of my Department or by his representatives. It is understood that copying or publication of this thesis for financial gain shall not be allowed without my written permission. Depa rtment The University of British Columbia Vancouver 8, Canada i ABSTRACT The Seabrook Lake carbonatite complex is one of the smallest of nine known carbonatite complexes in central Ontario. The complex, which is one-half square mile in area and pear- shaped in plan, consists of fenitized granite and breccia, mafic breccia, ijolite and related breccia, and carbonatite. The bulbous northern part of the complex consists of a plug-like core of carbonatite surrounded by mafic breccia and carbonatite dykes. The narrow southern part consists of ijolite and related breccia. Enveloping all of these rocks.is a fenitized aureole which grades outward to unaltered granite that underlies much of the surrounding area. The carbonatite is composed of calcite with the following minor mineral, in decreasing order of abundance: goethite, microcline, magnesioriebeckite-riebeckite, magnetite-ulvospinel, apatite, hematite, pyrite, albite, biotite, chlorite, pyrochlore, brookite, sphene, ferroan dolomite (ankerite?), aegirine, chalcopyrite, wollastonite and quartz. -
Geology of the Cluggerfluorite Deposit
Revista Brasileira de Geociências 17(3): 288-294, setembro de 1987 GEOLOGY OF THE CLUGGE RFLUORITE DEPOSIT. MATO PRETO. PARANÁ. BRAZIL ROBERT E. JENK INS n- ABSTRACT The Mato Preto fluorite deposite are located in the Ribeira River valley 80 km NNE from Curitiba, Paraná, Brazil. They consist of three known orebodies and numerous minar occurrences wi thin an area of about 15 km ê. Clugger, the largest dcposit, is a hydrothermnl replacemcnt and fracture-fil ling type in a brecciated and sheared contact zone among carbonatitc, nephellne syenitc, phonolite, and tin guaite of the Cretaceous-Paleocene age Mato Preto Igneous Complex. Fluorite occurs LS four subparallel but coalescing ore lenses which forro envelopes about dikes of phonolite-tinguaite and have strlke lengths of 250 m, aggregate thickness up to 80 m, and extend to at least 120 m in depth . Dikes and Ienses strike N50-55E and dip steeply to the northwest. Fluorite forms matrix replacemcnts and crosscutting veins in premineral and intermineral breccias adjacent to dikes. Fluorite mineralizatioo has been introduced in at least two pulses and is associated with barite-celestlre, apatite, rare earth minerais, and sulfides. Late explosive venting of the system has formed pipes of volcanic breccia with crackle breccia in ore adjacent. Fluorite along breakage planes is recrystallized into monomineralic veinlets. Mineralization is associated with fracture controlled epidote aJteration, but major silicification apparently predates ore. The c1ugger deposit was probably fonne d at low pressures and temperatures, possibly within a vent of a now-eroded Mato Preto volcano. RESUMO Os depósitos de Iluorita de Mato Preto situam-se no vale do Rio Ribeira, 80 km a NNE de Curitiba,Paraná. -
Carbonatite Dikes of the Chupadera Mountains, Socorro County, New
Garbonatitedikes of the Chupadera Mountains, SocorroGounty, New Mexico byBruce R. VanAllen and David L. Emmons,Tenneco Minerals Company, P.0. Box 27F, Lakewood, C0 80227 and TheodoreP. Paster, Consulting Geologist, 11425 E. Cimmanon Dr., Englewood, C080111 Introduction Bureauof Mines and Mineral Resourcesin- depths of t2-15 km, and metamorphosed at Calcitic carbonatites and thorium-bearing dependentlyidentified the carbonatites(Kent, temperaturesof 500-550"C.The exposed quartz deposits have been identified in the 1.982;Mclemore, 1983). stratigraphic thickness of metasedimentary southern Chupadera Mountains in Socorro rocks may exceed 3,000 ft. Schistosity ap- Counfy.The dikes and quartz veins arehosted profmates original bedding and is indica. by Precambrianmetamorphic rocks, whereas Geologic setting tive of two or more periods of folding before jasperoidoccurs in Paleozoiccarbonate rocks. The Chupadera Mountains are within a carbonatiteemplacement. There aPPearsto The depositsoccur in protractedsections 20, north-trending, west-tilted horst along the be at least one early west-northwest-trend- 21,28, and29,T5S, R1W on the northeastern western margin of the Rio Grande rift. Car- ing episode of isoclinal folding followed by portion of the Pedro Armendaris Spanish bonatitescrop out in a 2 mi'exposure of Pre- a'period of northeast-trendingopen folding Land Grant No. 34 and on the western edge cambrian rocks (Fig. 2), which has been (Bowring et al., 1983). of the Bosque del Apache National Wildlife mappedand describedby Kottlowski (1960), Narrow bodies of biotite schist and am- Refuge.The approimate location of these Condie and Budding (1979), Kent (1982), phibolite within the metasedimentary units depositsand the locationsand agesof other Bowring et al. -
Evidence for a Carbonatite-Influenced Source Assemblage for Intraplate
minerals Article Evidence for a Carbonatite-Influenced Source Assemblage for Intraplate Basalts from the Buckland Volcanic Province, Queensland, Australia Joshua J. Shea * and Stephen F. Foley Department Earth and Planetary Sciences and ARC Centre of Excellence for Core to Crust Fluid Systems, Macquarie University, North Ryde 2109, New South Wales, Australia * Correspondence: [email protected] Received: 20 June 2019; Accepted: 7 September 2019; Published: 10 September 2019 Abstract: Eastern Australia contains a widespread suite of primitive (MgO 7.5 wt.%) intraplate ≥ basaltic provinces, including those sited along the longest continental hotspot track on Earth ( 2000 km), the Cosgrove track. The Buckland volcanic province is the most southerly basaltic ≈ province on the Cosgrove track before a >1600 km stretch that contains only sparse leucitite volcanism. Buckland is also situated just northeast of the edge of thick cratonic lithosphere where it transitions to a thinner continental lithosphere (<110 km) to the east, which may influence the production of plume-derived melts. Here, analysis of minor and trace elements in olivines in alkali basalts and basanites from the Buckland Province are combined with whole-rock compositions to elucidate the mantle source assemblages, and to calibrate minor and trace element indicators in olivine for application to source mineralogy. Olivine xenocrysts show element concentration ranges typical for peridotites; Mn and Al concentrations indicate that the ambient mantle is spinel, rather than garnet, peridotite. High modal pyroxene content is indicated by high Ni, Zn/Fe, and Fe/Mn in olivines, while high Ti/Sc is consistent with amphibole in the source. Residual phlogopite in the source of the basanites is indicated by low K/Nb in whole rocks, while apatite contains high P2O5 and low Rb/Sr ( 0.015) and Sr/La ( 13). -
Petrography and Engineering Properties of Igneous Rocks
ENGINEERil~G MONOGRAPHS No. I United States Department of the Interior BUREAU OF RECLAMATION PETROGRAPIIY AND ENGINEERING· PROPER11ES OF IGNEOUS ROCKS hy Rit~bard C. 1\lielenz Denver, Colorado October 1948 95 cents (R.evised September 1961) United States Department of the Interior STEWART L. UDALL, Secretacy Bureau of Reclamation FLOYD E. DOMINY, Commissioner G~T BLOODGOOD, Assistant Commissioner and Chief Engineer Engineering Monograph No. 1 PETROGRAPHY AND ENGINEERING PROPERTIRES ·OF IGNEOUS RO<;:KS by Richard C. Mielenz Revised 1959. by William Y. Holland Head. Petrographic Laboratory Section Chemical Engineering Laboratory Branch Commissioner's Office. Denver Technical Infortnation Branch Denver Federal Center Denver, Colorado ENGINEERING MONOGRAPHS are published in limited editions for the technical staff of the Bureau of Reclamation and interested technical circles in Government and private agencies. Their purpose is to record devel opments, innovations, .and progress in the engineering and scientific techniques and practices that are employed in the planning, design, construction, and operation of Rec lamation structures and equipment. Copies 'may be obtained from the Bureau of Recla- · mation, Denver Federal Center, Denver, Colon.do, and Washington, D. C. Excavation and concreting of altered zones in rhyolite dike in the spillway foundation. Davis Damsite. Arizona-Nevada. Fl'ontispiece CONTENTS Page Introduction . 1 General Basis of Classification of Rocks . 1 Relation of the Petrographic Character to the Engineering Properties of Rocks . 3 Engineering J?roperties of Igneous Rocks ................................ :. 4 Plutonic Rocks . 4 Hypabyssal Rocks . 6 Volcanic Rocks..... 7 Application of Petrography to Engineering Problems of the Bureau of Reclamation . 8 A Mineralogic and Textural Classification of Igneous Rocks . -
Evidence for the Alkaline Nature of Parental Carbonatite Melts at Oka Complex in Canada
ARTICLE Received 22 Apr 2013 | Accepted 30 Sep 2013 | Published 30 Oct 2013 DOI: 10.1038/ncomms3687 Evidence for the alkaline nature of parental carbonatite melts at Oka complex in Canada Wei Chen1, Vadim S. Kamenetsky2 & Antonio Simonetti1 The Earth’s sole active carbonatite volcano, Oldoinyo Lengai (Tanzania), is presently erupting unique natrocarbonatite lavas that are characterized by Na- and K-bearing magmatic car- bonates of nyerereite [Na2Ca(CO3)2] and gregoryite [(Na2,K2,Ca)CO3]. Contrarily, the vast majority of older, plutonic carbonatite occurrences worldwide are dominated by Ca-(calcite) or Mg-(dolomite)-rich magmatic carbonates. Consequently, this leads to the conundrum as to the composition of primary, mantle-derived carbonatite liquids. Here we report a detailed chemical investigation of melt inclusions associated with intrusive (plutonic) calcite-rich carbonatites from the B120 Ma carbonatite complex of Oka (Canada). Melt inclusions are hosted by magnetite (Fe3O4), which crystallizes through a significant period of carbonatite melt solidification. Our results indicate mineral assemblages within the melt inclusions that are consistent with those documented in natrocarbonatite lavas. We propose therefore that derivation of alkali-enriched parental carbonatite melts has been more prevalent than that preserved in the geological record. 1 Department of Civil and Environmental Engineering and Earth Sciences, University of Notre Dame, 156 Fitzpatrick Hall, Notre Dame, Indiana 46556, USA. 2 ARC Centre of Excellence in Ore Deposits and School of Earth Sciences, University of Tasmania, Hobart, Tasmania 7001, Australia. Correspondence and requests for materials should be addressed to W.C. (email: [email protected]). NATURE COMMUNICATIONS | 4:2687 | DOI: 10.1038/ncomms3687 | www.nature.com/naturecommunications 1 & 2013 Macmillan Publishers Limited.