Mafic-Ultramafic Igneous Rocks and Associated Carbonatites of the Gem Park Complex, Custer and Fremont Counties, Colorado

Total Page:16

File Type:pdf, Size:1020Kb

Mafic-Ultramafic Igneous Rocks and Associated Carbonatites of the Gem Park Complex, Custer and Fremont Counties, Colorado Mafic-Ultramafic Igneous Rocks And Associated Carbonatites of the Gem Park Complex, Custer and Fremont Counties, Colorado GEOLOGICAL SURVEY PROFESSIONAL PAPER 649 MAFIG-ULTRAMAFIC IGNEOUS ROCKS AND ASSOCIATED CARBONATITES OF THE GEM PARK COMPLEX, CUSTER AND FREMONT COUNTIES, COLORADO S a wa tc h C r i s t o Range S a n g r e d a Range rh p I e x * '*w 5 tp" *,. ' j^.*f\ A- j*s'j»- ' ^«K*£ DEMOB R^TjC MQ^NTAIN. \3 1 /T* :S>- * >." " '"' _J^ ^: '-V*^ Bdj^|*°C,j^B^*' * X* -H'c;"",.,,,,'*^ ,,' -aCr* Gem Park, Colo. View northwestward from Democratic Mounta GEM MOUNTAIN Sawatch Range ark -Cbtrfplex -« "*» +** 4ifa. ving pyroxenite and gabbro of the Gem Park Complex. Mafic-Ultramafic Igneous Rocks And Associated Carbonatites of the Gem Park Complex, Custer and Fremont Counties, Colorado By RAYMOND L. PARKER and WILLIAM N. SHARP GEOLOGICAL SURVEY PROFESSIONAL PAPER 649 The Gem Park Complex its geology and mineralogy, and its niobium distribution UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON: 1970 UNITED STATES DEPARTMENT OF THE INTERIOR WALTER J. HIGKEL, Secretary GEOLOGICAL SURVEY William T. Pecora, Director Library of Congress catalog-card No. 79-608291 For sale by the Superintendent of Documents, U.S. Government Printing Office, Washington, B.C. 20402 (Paper cover) CONTENTS Pag-e Abstract __ _-_---__---__-_--..---__-_____-_______-____ Gem Park Complex Continued Introduction __________________________________________ 1 Carbonatite dikes_--______---------_--__-__-___-__- 7 General geology-______________________________________ 1 Attitude, orientation, and distribution of dikes.___ 7 Precambrian rocks.________________________________ 3 Composition of dikes.-______..______..__-_____-__ P Cambrian rocks.__________________________________ 3 Carbonatite in rocks that enclose the complex. _ _ _ _ P Tertiary volcanic rocks and gravel ___________________ 3 Fenite ----_--_--------_-----_------------------_ 10 Quaternary alluvium and colluvium._________________ 3 Mineralogy.___-_____-_-____.---_-_______-___-_-__--__ 11 Structure _________________________________________ 4 Carbonatites ______________________________________ 11 Gem Park Complex._------_-_--____--___._____________ 4 Fenites ____-_-____-_____-_----_.--_-_-_---------__ 14 Pyroxenite. _______________________________________ 4 Geochemistry. ________________________________________ 1? Gabbro and associated rocks._______________________ 5 Summary and conclusions--..__-.-_______--______----_-- 22 Nepheline syenite pegmatite._______________________ 6 Economic geology____________________________________ 2? Lamprophyre and syenite porphyry dikes.____________ 7 References.______________.-_--_-_____---_________-_-__ 2? ILLUSTRATIONS Page FRONTISPIECE. Gem Park, Colo., view northwestward from Democratic Mountain. PLATE 1. Geologic map of Gem Park______________________________________________________________________ _In pod et 2. Map of fenitized rocks at the Vermiculite mine, showing sample localities and radioactivity anomaly, Gem Park, Colo. _____---_---_--_----____-_____-______-_______-_____-______________-_____________ _______ _In pocHt FIGURE 1. Map showing location and geologic setting of the mafic-ultramafic Gem Park Complex and the McClure Mountain Complex.______________________________________________________________________________________ 2 2-5. Photomicrographs of: 2. Pyroxenite__ - -__--__--__-__--___---__-_-____-__--__----___-__-___--____---_-___--__-__-___ 5 3. Gabbro___-___________-_-________-___________-______--______-_-________________________-___ 6 4. Plagioclase-rich rock.________________________________________________________________________ 6 5. Lamprophyre.______________________________________________________________________________ 7 6, 7. Photomicrographs of deformed dolomite-blue amphibole-pyrochlore Carbonatite _____________________________ P. 9 8. Photomicrograph of finely crystalline apatite clot in carbonatite_____-__--_--_-___-__-__------_------___--_ 12 9. Photomicrograph of monazite rosette in carbonatite-_____________________________________________________ 13 10-17. Photographs of: 10. Black lustrous lueshite crystals.._____________________________________________________________ 15 11. Cut section of lavender-gray lueshite twin cluster.-_____________________________________________ 15 12. Fersmite after lueshite in dolomite__________________________________________________________ 15 13. Fersmite in thin section.____________________________________________________________________ 16 14. Natroniobite and columbite replacing lueshite__________________________________________________ 16 15. Fragments of natroniobite and columbite._____________________________________________________ 17 16. Grains of fibrous monazite___________________________________________________________________ 17 17. Thorianite crystals.---_--_-_____-___________________--_____--_--____-_----____-_--_-___---- 18 VII VIII CONTENTS TABLES Page TABLE 1. Chemical analyses and norms of some rocks from the Gem Park Complex-_________________________________ 4 2. Modes of mafic and ultramafic rocks from the Gem Park Complex.-____--________________-_____-__-_-_--_- 5 3. Minerals in carbonatites from the Gem Park Complex_ -______________--_-__________--__-_-_-._-__-------- 12 4. Semiquantitative spectrographic analysis of green rare-earth apatite from the Gem Park Complex _____________ 13 5. Chemical composition of light-amber pyrochlore from the Gem Park Complex.-_________-___--___-_-__-__-_- 13 6. Semiquantitative spectrographic analysis of columbite from the Gem Park Complex___.-_-_____-_______-_-__ 14 7. Minerals in fenitized gabbro and pyroxenite from the Gem Park Complex-___--_-__-__--___--____-_-_--_--_ 14 8. Semiquantitative spectrographic analysis of lueshite from the Gem Park Complex___________________________ 16 9. Semiquantitative spectrographic analysis of fersmite from the Gem Park Complex.,_____-______-_--__---___- 16 10. X-ray diffraction data for natroniobite.__-____-_________-__,___________-____-_-_----_--------__-__-_--- 17 11. Analyses of carbonatites from Gem Park.__________________-___________-_-_-________--.-__-__-_-_-__--- 19 12. Analyses of rocks from fenite area, Gem Park Complex-___________-____-______-___---_--------_---_--_- 21 MAFIC-ULTRAMAFIC IGNEOUS ROCKS AND ASSOCIATED CARBONATITES OF THE GEM PARK COMPLEX, CUSTER AND FREMONT COUNTIES, COLORADO By RAYMOND L. PAEKER and WILLIAM N. SHARP ABSTRACT the geologic relationships in the region. With the discov­ The Gem Park Complex (a new name in this report), which ery of the McClure Mountain Complex the senior author lies about 11 miles northwest of Westcliffe, Colo., is a small instigated the study reported here. funnel-shaped composite body related to the McClure Mountain Gem Park has been the site of limited mining sin°.e Complex a few miles to the northeast. The Gem Park Complex the 1880's. The Gem mine, which consists of a group of consists mostly of pyroxenite and gabbro with minor dikes and bodies of lamprophyre, syenite porphyry, and nepheline syenite shallow workings at the north edge of Gem Park, pro­ pegmatite, and abundant dikes and irregular bodies of carbona- duced an unknown but small quantity of nickel-silver tite, all of Cambrian age. A mass of fenite lies near the center ore prior to 1885. The old vermiculite mine in the central of the complex. The whole complex lies discordantly in Precam- part of the complex (called the Vermiculite mine in this brian gneissic terrane and is overlain by Tertiary volcanic rocks. report) and the Niles mine at the west edge of the com­ Large areas in the complex are covered by Quaternary alluvium and colluvium. plex produced a combined total of somewhat less than Some carbonatite dikes and fenite contain concentrations of 3,000 tons of vermiculite during and just prior to World niobium, rare-earth elements, thorium, phosphorus, some other War II (A. L. Bush, oral commun., 1968). A minor ton­ elements, and vermiculite. nage of magnetite ore was scraped from the surface at the The arrangement of carbonatite dikes, the position of the fenite, south border of the complex but the amount recovered and other features suggest that a large carbonatite body lies beneath the surface near the center of the complex. and other data pertaining to that activity are not known. We thank Mr. D. W. Fieldman, of the Congdon and INTRODUCTION Carey Co., and the Cleavenger Land and Cattle Co. for allowing access to properties in the Gem Park area, and The complex of mafic and ultramafic igneous rocks Prof. A. G. Bulakh, of Leningrad University, who gener­ and associated carbonatites, herein formally designated ously furnished information on natroniobite and oth^r the Gem Park Complex, underlies an area of about 2 square miles at Gem Park, a small oval valley in the rare minerals from the Kola Peninsula, U.S.S.R. We also northern Wet Mountains, Fremont and Ouster Counties, thank U.S. Geological Survey colleagues F. A. Hild?- Colo., about 21 miles southwest of Canon City and about brand, who conducted both field and laboratory work 11 miles northwest of Westcliffe which is designated as early in the study, R. B. Taylor, who made some of tH the type area. The complex is similar in composition to photomicrographs used in the report, and J. W. Adams, part of the mafic and ultramafic rock complex at Iron who advised on problems in mineralogy and in the prep­ Mountain, about 9 miles to the northeast in the McClure aration of the manuscript. Mountain Complex (Shawe and Parker, 1967). (See
Recommended publications
  • Volume Lateral Magma Transport from the Mull Volcano: 10.1002/2016GC006712 an Insight to Magma Chamber Processes
    PUBLICATIONS Geochemistry, Geophysics, Geosystems RESEARCH ARTICLE Large-volume lateral magma transport from the Mull volcano: 10.1002/2016GC006712 An insight to magma chamber processes Key Points: Osamu Ishizuka1,2 , Rex N. Taylor3, Nobuo Geshi1, and Nobutatsu Mochizuki4 The magma flow direction within dikes from the Mull volcano gradually 1Research Institute of Earthquake and Volcano Geology, Geological Survey of Japan, AIST, Tsukuba, Japan, 2Japan Agency changed from near vertical to for Marine-Earth Science and Technology, Yokosuka, Japan, 3Ocean and Earth Science, University of Southampton, horizontal within 30 km of its center National Oceanography Centre, European Way, Southampton, 4Priority Organization for Innovation and Excellence, Magma assimilating lower crust only forms proximal dikes and feeds Kumamoto University, Kumamoto, Japan overlying upper crustal reservoir which forms proximal or distal dikes Magma volumes from basaltic lower Abstract Long-distance lateral magma transport within the crust has been inferred for various magmatic and felsic upper crustal reservoirs systems including oceanic island volcanoes, mid-oceanic ridges, and large igneous provinces. However, were combined to generate andesitic long-distance dikes studying the physical and chemical properties of active fissure systems is difficult. Hence, this study investi- gates the movement of magma away from the Mull volcano in the North Atlantic Igneous Province, where Supporting Information: erosion has exposed its upper crustal dike networks. Magmatic lineations within dikes indicate that the Supporting Information S1 magma flow in the Mull dike suite changed from near vertical to horizontal within 30 km of the volcanic Table S1 center. This implies that distal dikes were fed by lateral magma transport from Mull.
    [Show full text]
  • Bedrock Geology Glossary from the Roadside Geology of Minnesota, Richard W
    Minnesota Bedrock Geology Glossary From the Roadside Geology of Minnesota, Richard W. Ojakangas Sedimentary Rock Types in Minnesota Rocks that formed from the consolidation of loose sediment Conglomerate: A coarse-grained sedimentary rock composed of pebbles, cobbles, or boul- ders set in a fine-grained matrix of silt and sand. Dolostone: A sedimentary rock composed of the mineral dolomite, a calcium magnesium car- bonate. Graywacke: A sedimentary rock made primarily of mud and sand, often deposited by turbidi- ty currents. Iron-formation: A thinly bedded sedimentary rock containing more than 15 percent iron. Limestone: A sedimentary rock composed of calcium carbonate. Mudstone: A sedimentary rock composed of mud. Sandstone: A sedimentary rock made primarily of sand. Shale: A deposit of clay, silt, or mud solidified into more or less a solid rock. Siltstone: A sedimentary rock made primarily of sand. Igneous and Volcanic Rock Types in Minnesota Rocks that solidified from cooling of molten magma Basalt: A black or dark grey volcanic rock that consists mainly of microscopic crystals of pla- gioclase feldspar, pyroxene, and perhaps olivine. Diorite: A plutonic igneous rock intermediate in composition between granite and gabbro. Gabbro: A dark igneous rock consisting mainly of plagioclase and pyroxene in crystals large enough to see with a simple magnifier. Gabbro has the same composition as basalt but contains much larger mineral grains because it cooled at depth over a longer period of time. Granite: An igneous rock composed mostly of orthoclase feldspar and quartz in grains large enough to see without using a magnifier. Most granites also contain mica and amphibole Rhyolite: A felsic (light-colored) volcanic rock, the extrusive equivalent of granite.
    [Show full text]
  • The Geology, Petrography and Geochemistry of Gabbroic Rocks Of
    The Geology, Petrography and Geochemistry of Gabbroic Rocks of the Pants Lake Intrusive Suite on the Donner/Teck South Voisey's Bay Property, North-Central Labrador, Canada Heather E. MacDonald A thesis submitted in conformity with the requirements for the degree of Mastet's of Science Graduate Department of the Department of Geology University of Toronto O Copyright by Heather E. MacDonald, 1999 National Library Bibliothèque nationale 1*1 of Canada du Canada Acquisitions and Acquisitions et Bibliographie Services services bibliographiques 395 Wellingtori Street 395. rue Wellington OttawaON K1A ON4 OnawaON KlAONQ Canada Canada The author has granted a non- L'auteur a accordé une licence non exclusive licence allowing the exclusive permettant à la National Library of Canada to Bibliothèque nationale du Canada de reproduce, loan, distribute or seii reproduire, prêter, distribuer ou copies of this thesis in microform, vendre des copies de cette thèse sous paper or electronic formats. la forme de rnicrofiche/film, de reproduction sur papier ou sur format électronique. The author retains ownership of the L'auteur consewe la propriété du copyright in this thesis. Neither the droit d'auteur qui protège cette thèse. thesis nor substantiai extracts fiom it Ni la thèse ni des extraits substantiels may be printed or otherwise de celle-ci ne doivent être imprimés reproduced without the author's ou autrement reproduits sans son permission. autorisation. The Geology, Petrography and Ceochernistry of Gabbroic Rocks of the Pants Lake Intrusive Suite on the Donner/Teck South Voisey's Bay Property, North-Central Labrador, Canada Heather E. MacDonald Master's of Science, 1999 Department of Geology University of Toronto Abstract The South Voisey's Bay property held by Donner Minerals Limited in North-Central Labrador hosts Ni-Cu-Co mineralization within gabbroic rocks of the Pants Lake Intrusive Suite (PLIS).
    [Show full text]
  • Module 7 Igneous Rocks IGNEOUS ROCKS
    Module 7 Igneous Rocks IGNEOUS ROCKS ▪ Igneous Rocks form by crystallization of molten rock material IGNEOUS ROCKS ▪ Igneous Rocks form by crystallization of molten rock material ▪ Molten rock material below Earth’s surface is called magma ▪ Molten rock material erupted above Earth’s surface is called lava ▪ The name changes because the composition of the molten material changes as it is erupted due to escape of volatile gases Rocks Cycle Consolidation Crystallization Rock Forming Minerals 1200ºC Olivine High Ca-rich Pyroxene Ca-Na-rich Amphibole Intermediate Na-Ca-rich Continuous branch Continuous Discontinuous branch Discontinuous Biotite Na-rich Plagioclase feldspar of liquid increases liquid of 2 Temperature decreases Temperature SiO Low K-feldspar Muscovite Quartz 700ºC BOWEN’S REACTION SERIES Rock Forming Minerals Olivine Ca-rich Pyroxene Ca-Na-rich Amphibole Na-Ca-rich Continuous branch Continuous Discontinuous branch Discontinuous Biotite Na-rich Plagioclase feldspar K-feldspar Muscovite Quartz BOWEN’S REACTION SERIES Rock Forming Minerals High Temperature Mineral Suite Olivine • Isolated Tetrahedra Structure • Iron, magnesium, silicon, oxygen • Bowen’s Discontinuous Series Augite • Single Chain Structure (Pyroxene) • Iron, magnesium, calcium, silicon, aluminium, oxygen • Bowen’s Discontinuos Series Calcium Feldspar • Framework Silicate Structure (Plagioclase) • Calcium, silicon, aluminium, oxygen • Bowen’s Continuous Series Rock Forming Minerals Intermediate Temperature Mineral Suite Hornblende • Double Chain Structure (Amphibole)
    [Show full text]
  • Characteristics of Cr-Spinel and Whole Rock Geochemistry of the Nuasahi Igneous Complex, Orissa, India
    Characteristics of Cr-Spinel and Whole Rock Geochemistry of the Nuasahi Igneous Complex, Orissa, India Sisir K. Mondal1, Michael D. Glascock2 and Edward. M. Ripley1 1Department of Geological Sciences, Indiana University, Bloomington, Indiana 47405 2Research Reactor Center, University of Missouri, Columbia, Missouri 65211 e-mail: [email protected], ripley@indiana@edu, [email protected] The Precambrian Nuasahi Igneous and contain minor interstitial phases such as Complex (NIC) is located in the southern part of serpentine, chlorite, talc, magnesite and sulfides. the Singhbhum North Orissa Province in Eastern Disseminated Cr-spinels occur as both cumulus and India and contains one of the largest and richest intercumulus phase in ultramafic cumulates and are chromite deposits in India. The NIC occurs in a commonly altered to ferritchromite/magnetite, terrain of the Archaean Iron Ore Group (IOG) of particularly in highly serpentinized rocks. The rocks of 3.1-3.3Ga age. The NIC consists of three ferrianchromite grains are irregularly distributed in principal components (1) chromiferous ultramfic the sulfide-rich assemblages of the breccia zone and rocks with four chromitite lodes; (2) massive in the matrix of the breccia. gabbroic rocks with titaniferous magnetite bands; (3) later intrusives of diabases and pyroxenite Chemical Composition (Fig.1). The field relations of these three The composition of olivine from both components define the following stratigraphic dunite and olivine-orthopyroxenite/harzburgite sequence: units is similar, with Fo and NiO contents ranging from 92 to 94 and 0.21 to 0.40wt%, respectively. Laterite The composition of orthopyroxene from enstatitite (3) Dykes and sills of diabase and pyroxenite and olivine-orthopyroxenite/harzburgite is En ~91- (2) Gabbroic rocks with titaniferous Ultramafic- magnetite bands 94 and from orthopyroxenite in the middle part of mafic (1) Chromiferous ultramafic rocks – the ultramafic sequence the composition is En ~84- complex interlayered sequence of enstatitite, olivine- 91.
    [Show full text]
  • Reflectance Spectral Features and Significant Minerals in Kaishantun
    minerals Article Reflectance Spectral Features and Significant Minerals in Kaishantun Ophiolite Suite, Jilin Province, NE China Chenglong Shi 1 ID , Xiaozhong Ding 1,*, Yanxue Liu 1 and Xiaodong Zhou 2 1 Institute of Geology, Chinese Academy of Geological Sciences, No. 26 Baiwanzhuang Street, Beijing 100037, China; [email protected] (C.S.); [email protected] (Y.L.) 2 Survey of Regional Geological and Mineral Resource of Jilin Province, No.4177 Chaoda Road, Changchun 130022, China; [email protected] * Correspondence: [email protected]; Tel.: +86-10-6899-9675 Received: 28 January 2018; Accepted: 28 February 2018; Published: 5 March 2018 Abstract: This study used spectrometry to determine the spectral absorption of five types of mafic-ultramafic rocks from the Kaishantun ophiolite suite in Northeast China. Absorption peak wavelengths were determined for peridotite, diabase, basalt, pyroxenite, and gabbro. Glaucophane, actinolite, zoisite, and epidote absorption peaks were also measured, and these were used to distinguish such minerals from other associated minerals in ophiolite suite samples. Combined with their chemical compositions, the blueschist facies (glaucophane + epidote + chlorite) and greenschist facies (actinolite + epidote + chlorite) mineral assemblage was distinct based on its spectral signature. Based on the regional tectonic setting, the Kaishantun ophiolite suite probably experienced the blueschist facies metamorphic peak during subduction and greenschist facies retrograde metamorphism during later slab rollback. Keywords: reflectance spectrum; ophiolite suite; mineral classification; Kaishantun; NE China 1. Introduction Ophiolites are segments of oceanic crust that have been residually accreted in convergent boundaries [1–3]. The principal focus of recent studies related to ophiolites has been on the spatial and temporal patterns of felsic to mafic-ultramafic rock suites.
    [Show full text]
  • Mineralogy and Geochemistry of Ocelli in the Damtjernite Dykes and Sills, Chadobets Uplift, Siberian Craton: Evidence of the Fluid–Lamprophyric Magma Interaction
    minerals Article Mineralogy and Geochemistry of Ocelli in the Damtjernite Dykes and Sills, Chadobets Uplift, Siberian Craton: Evidence of the Fluid–Lamprophyric Magma Interaction Anna A. Nosova 1,*, Ludmila V. Sazonova 1,2, Alexey V. Kargin 1 , Elena O. Dubinina 1 and Elena A. Minervina 1 1 Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry, Russian Academy of Sciences (IGEM RAS), 119017 Moscow, Russia; [email protected] (L.V.S.); [email protected] (A.V.K.); [email protected] (E.O.D.); [email protected] (E.A.M.) 2 Geology Department, Lomonosov Moscow State University, 119991 Moscow, Russia * Correspondence: [email protected]; Tel.:+7-499-230-8414 Abstract: The study reports petrography, mineralogy and carbonate geochemistry and stable iso- topy of various types of ocelli (silicate-carbonate globules) observed in the lamprophyres from the Chadobets Uplift, southwestern Siberian craton. The Chadobets lamprophyres are related to the REE-bearing Chuktukon carbonatites. On the basis of their morphology, mineralogy and relation with the surrounding groundmass, we distinguish three types of ocelli: carbonate-silicate, containing carbonate, scapolite, sodalite, potassium feldspar, albite, apatite and minor quartz ocelli (K-Na-CSO); carbonate–silicate ocelli, containing natrolite and sodalite (Na-CSO); and silicate-carbonate, con- taining potassium feldspar and phlogopite (K-SCO). The K-Na-CSO present in the most evolved Citation: Nosova, A.A.; Sazonova, damtjernite with irregular and polygonal patches was distributed within the groundmass; the patches L.V.; Kargin, A.V.; Dubinina, E.O.; consist of minerals identical to minerals in ocelli. Carbonate in the K-Na-CSO are calcite, Fe-dolomite Minervina, E.A.
    [Show full text]
  • A Geochemical Study of the Riddle Peaks Gabbro, North Cascades: Evidence for Amphibole Accumulation in the Mid-Crust of an Arc
    Western Washington University Western CEDAR WWU Graduate School Collection WWU Graduate and Undergraduate Scholarship 2014 A geochemical study of the Riddle Peaks gabbro, North Cascades: evidence for amphibole accumulation in the mid-crust of an arc Angela C. Cota Western Washington University Follow this and additional works at: https://cedar.wwu.edu/wwuet Part of the Geology Commons Recommended Citation Cota, Angela C., "A geochemical study of the Riddle Peaks gabbro, North Cascades: evidence for amphibole accumulation in the mid-crust of an arc" (2014). WWU Graduate School Collection. 362. https://cedar.wwu.edu/wwuet/362 This Masters Thesis is brought to you for free and open access by the WWU Graduate and Undergraduate Scholarship at Western CEDAR. It has been accepted for inclusion in WWU Graduate School Collection by an authorized administrator of Western CEDAR. For more information, please contact [email protected]. A GEOCHEMICAL STUDY OF THE RIDDLE PEAKS GABBRO, NORTH CASCADES: EVIDENCE FOR AMPHIBOLE ACCUMULATION IN THE MID CRUST OF AN ARC By Angela C. Cota Submitted for Partial Completion Of the Requirements for the Degree Master of Science Kathleen L. Kitto, Dean of the Graduate School ADVISORY COMMITTEE Chair, Dr. Susan DeBari Dr. Elizabeth Schermer Dr. Robert Miller MASTER’S THESIS In presenting this thesis in partial fulfillment of the requirements for a master’s degree at Western Washington University, I grant to Western Washington University the nonexclusive royalty‐free right to archive, reproduce, distribute, and display the thesis in any and all forms, including electronic format, via any digital library mechanisms maintained by WWU. I represent and warrant this is my original work, and does not infringe or violate any rights of others.
    [Show full text]
  • Melt-PX, a Melting Parameterization for Mantle Pyroxenites Between 0.9
    PUBLICATIONS Journal of Geophysical Research: Solid Earth RESEARCH ARTICLE The role of pyroxenite in basalt genesis: Melt-PX, a melting 10.1002/2015JB012762 parameterization for mantle pyroxenites between Key Points: 0.9 and 5GPa • Melt-PX predicts the melting behavior of pyroxenites as a function of P, T, Sarah Lambart1,2, Michael B. Baker1, and Edward M. Stolper1 and X • > At P ~3.5 GPa, a large fraction 1Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California, USA, 2Department (>20%) of natural pyroxenites have near-solidus temperatures greater of Earth and Planetary Sciences, University of California, Davis, California, USA than those of fertile peridotite • Crustal thickness depends on the mass fraction and composition of Abstract Geochemical and isotopic data suggest that the source regions of oceanic basalts may contain pyroxenite in the mantle as well as pyroxenite in addition to peridotite. In order to incorporate the wide range of compositions and melting mantle potential temperature behaviors of pyroxenites into mantle melting models, we have developed a new parameterization, Melt-PX, which predicts near-solidus temperatures and extents of melting as a function of temperature and pressure Supporting Information: for mantle pyroxenites. We used 183 high-pressure experiments (25 compositions; 0.9–5 GPa; 1150–1675°C) • Supporting Information S1 • Table S1 to constrain a model of melt fraction versus temperature from 5% melting up to the disappearance of • Melt-PX spreadsheet clinopyroxene for pyroxenites as a function of pressure, temperature, and bulk composition. When applied to the global set of experimental data, our model reproduces the experimental F values with a standard error of Correspondence to: estimate of 13% absolute; temperatures at which the pyroxenite is 5% molten are reproduced with a S.
    [Show full text]
  • Ree‐ Minerals in Carbonatite, Alkaline and Hydrothermal Rocks, Northern and Central Finland
    ERES2014: 1st European Rare Earth Resources Conference|Milos|04‐07/09/2014 REE‐ MINERALS IN CARBONATITE, ALKALINE AND HYDROTHERMAL ROCKS, NORTHERN AND CENTRAL FINLAND Thair AL‐ANI1* and Olli SARAPAA2 1 Geological Survey of Finland, P.O. Box 96, FI‐02151 Espoo, Finland 2 Geological Survey of Finland, P.O. Box 77, FI‐96101 Rovaniemi, Finland Email: [email protected], [email protected] Abstract REE‐rich minerals were identified and analyzed by electron microprobe from different targets located in the northern and central Finland. Both primary and hydrothermal minerals were found namely: phosphates (monazite‐Ce), fluor‐carbonates (bastnaesite‐Ce), hydrated carbonates (ancylite‐Ce), hydrated aluminium silicates, (allanite), oxides (fergusonite) and U‐Pb rich minerals. Sokli Jammi‐ Kaulus carbonatite veins are enriched in LREE, P, F, Sr and Ba hosting in ancylite, bastnaesite, apatite and monazite. Allanite‐(Ce) and fergusonite (Y) are abundant in alkaline gneiss of the Katajakangas REE‐occurrence. The Korsnäs Pb‐REE deposit includes apatite with monazite inclusions, calcio‐ancylite and bastnasite. The Mäkärä‐ Vaulo REE‐prospect in arkosic gneisses is dominated by monazite, allanite and xenotime. Albitites at Enontekiö contain bastnaesite, monazite, allanite, xenotime and U‐rich minerals includes davidite, masuyite and sayrite. The Honkilehto Au‐Co‐S‐mineralization at Kuusamo is characterized by U‐rich minerals with bastnaesite and allanite. The results obtained provide vital insights into the mineralizing processes associated with REE‐prospects in northern and central Finland. Introduction Economic REE deposits are not known in Finland. However, REEs were extracted in the 1960’s century as a by‐product in the fertilizer production from the apatite concentrates of the Kola Peninsula and the Korsnäs Pb mine in western Finland (1).
    [Show full text]
  • Geochemistry of an Ultramafic-Rodingite Rock Association in the Paleoproterozoic Dixcove Greenstone Belt, Southwestern Ghana
    Journal of African Earth Sciences 45 (2006) 333–346 www.elsevier.com/locate/jafrearsci Geochemistry of an ultramafic-rodingite rock association in the Paleoproterozoic Dixcove greenstone belt, southwestern Ghana Kodjopa Attoh a,*, Matthew J. Evans a,1, M.E. Bickford b a Department of Earth and Atmospheric Sciences, Cornell University, Snee Hall, Ithaca, NY 14853, USA b Department of Earth Sciences, Syracuse University, Syracuse, NY 13244, USA Received 11 January 2005; received in revised form 20 February 2006; accepted 2 March 2006 Available online 18 May 2006 Abstract Rodingite occurs in ultramafic rocks within the Paleoproterozoic (Birimian) Dixcove greenstone belt in southwestern Ghana. U–Pb analyses of zircons from granitoids intrusive into the greenstone belt constrain the age of the rodingite-ultramafic association to be older than 2159 Ma. The ultramafic complex consists of variably serpentinized dunite and harzburgite overlain by gabbroic rocks, which together show petrographic and geochemical characteristics consistent with their formation by fractional crystallization involving olivine and plagioclase cumulates. Major and trace element concentrations and patterns in the ultramafic–mafic cumulate rocks and associated plagiogranite are similar to rocks in ophiolitic suites. The rodingites, which occur as irregular pods and lenses, and as veins and blocks in the serpentinized zones, are characterized by high Al2O3 and CaO contents, which together with petrographic evidence indicate their formation from plagioclase-rich protoliths. The peridotites are highly depleted in REE and display flat, chondrite-normalized REE pat- terns with variable, but mostly small, positive Eu anomalies whereas the rodingites, which are also highly depleted, with overall REE contents from 0.04 to 1.2 times chondrite values, display distinct large positive Eu anomalies.
    [Show full text]
  • Petrogenesis of Natrocarbonatite at Oldoinyo Lengai, East Africa— Evidence from Fe and U Isotope Variations
    PETROGENESIS OF NATROCARBONATITE AT OLDOINYO LENGAI, EAST AFRICA— EVIDENCE FROM FE AND U ISOTOPE VARIATIONS BY ZHENHAO ZHOU THESIS Submitted in partial fulfillment of the requirements for the degree of Master of Science in Geology in the Graduate College of the University of Illinois at Urbana-Champaign, 2017 Urbana, Illinois Adviser: Professor Craig C. Lundstrom Abstract Ol Doinyo Lengai (ODL), Tanzania, is the only active carbonatite volcano on earth. Cyclical activity that consists of quiescent natrocarbonatite lava flow, explosive silicate eruption and dormancy has been observed throughout the 20th century at ODL. From 2007 to 2008, ODL explosively erupted coexisting natrocarbonatites and nephelinites. Numerous studies have been aimed at understanding how ODL natrocarbonatite forms. Liquid immiscibility is a favored hypothesis although condensate fluid separation is an alternative model. However, the exact mechanism that forms the ODL natrocarbonatite remains unresolved. We carried out Fe and U isotope analyses among a variety of ODL samples. Our sample set includes natrocarbonatite that erupted in 2005, 2 comingled tephras (mixture of natrocarbonatite and nephelinite) and a sequence of 8 nephelinite tephras that erupted in 2007- 2008; as well as magnetites separated from 2005 natrocarbontite; Ti-andradites and clinopyroxenes that were separated from one of the nephelinite tephras. Our results show a lighter Fe isotope composition of natrocarbonatite (!56Fe of -0.08‰ relative to IRMM-14) compared to nephelinite tephras (-0.06 to 0.20 ‰ relative to IRMM-14). Magnetites yield heavier Fe isotope composition (0.03‰) than natrocarbonatite; Ti-andradite has the heaviest Fe isotope composition among all analyzed samples due to its enrichment in Fe3+.
    [Show full text]