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(12) United States Patent (10) Patent No.: US 8,333,944 B2 Constantz Et Al

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(12) United States Patent (10) Patent No.: US 8,333,944 B2 Constantz Et Al USOO833394.4B2 (12) United States Patent (10) Patent No.: US 8,333,944 B2 Constantz et al. (45) Date of Patent: *Dec. 18, 2012 (54) METHODS OF SEQUESTERING CO2 61/073,319, filed on Jun. 17, 2008, provisional application No. 61/082,766, filed on Jul. 22, 2008, (75) Inventors: Brent R. Constantz, Portola Valley, CA provisional application No. 61/088,340, filed on Aug. (US); Andrew Youngs, Antelope, CA 12, 2008, provisional application No. 61/088,347, (US); Philip Brian Tuet, Milpitas, CA filed on Aug. 13, 2008, provisional application No. (US); Sidney Omelon, Willowdale (CA): 61/101,626, filed on Sep. 30, 2008, provisional Kasra Farsad, San Jose, CA (US); application No. 61/121,872, filed on Dec. 11, 2008. Ryan J. Gilliam, San Jose, CA (US); Valentin Decker, San Jose, CA (US); (51) Int. C. Donald W. Kirk, Caledon (CA); J. BOID 53/62 (2006.01) Douglas Way, Boulder, CO (US); Allen BOID 53/78 (2006.01) J. Bard, Austin, TX (US); Robert (52) U.S. C. ......... 423/225; 423/220; 423/230; 423/234 Danziger, Carmel, CA (US); Miguel (58) Field of Classification Search .................. 423/210, Fernandez, San Jose, CA (US); Cecily 423/220, 225, 230, 234 Ryan, San Jose, CA (US) See application file for complete search history. (73) Assignee: Calera Corporation, Los Gatos, CA (56) References Cited (US) U.S. PATENT DOCUMENTS (*) Notice: Subject to any disclaimer, the term of this 1,169,766 A 2f1916 Brassert patent is extended or adjusted under 35 (Continued) U.S.C. 154(b) by 40 days. FOREIGN PATENT DOCUMENTS This patent is Subject to a terminal dis claimer. AU 2001213118 B2 12/2001 (Continued) (21) Appl. No.: 12/942,558 OTHER PUBLICATIONS (22) Filed: Nov. 9, 2010 Various authors, "Calcium Carbonate: From the Cretaceous Period into the 21 Century.” Birkhauser Verlag (2001), pp. 1-54. http:// (65) Prior Publication Data books.google.com/books?id=pbkKGa19k5QC&Ipg=PA15 US 2011 FOO590OO A1 Mar. 10, 2011 &ots=gUUiWmGIR&dq=vaterite%20limestone &pg=PA54#v=two page&q&f=true—viewed Jul. 14, 2011.* Related U.S. Application Data (Continued) (63) Continuation of application No. 12/344,019, filed on Dec. 24, 2008, now Pat. No. 7,887,694, and a Primary Examiner — Daniel C McCracken continuation-in-part of application No. Assistant Examiner — Daniel Berns PCT/US2008/088242, filed on Dec. 23, 2008, and a (74) Attorney, Agent, or Firm — Calera Corporation continuation-in-part of application No. PCT/US2008/088246, filed on Dec. 23, 2008. (57) ABSTRACT (60) Provisional application No. 61/017.405, filed on Dec. Methods of sequestering carbon dioxide (CO) are provided. 28, 2007, provisional application No. 61/057,173, Aspects of the methods include precipitating a storage stable filed on May 29, 2008, provisional application No. carbon dioxide sequestering product from an alkaline-earth 52 gas r --- 50 -- - - West cals: idesalinatedyeleaks 20 sity AO weake 60 overy US 8,333,944 B2 Page 2 metal-containing water and then disposing of the product, provided are systems for practicing methods of the invention. e.g., by placing the product in a disposal location or using the product as a component of a manufactured composition. Also 12 Claims, 19 Drawing Sheets US 8,333,944 B2 Page 3 U.S. PATENT DOCUMENTS 4,036,749 7, 1977 Anderson 4,045,524 8, 1977 Bornert 1,172,930 2, 1916 Brassert et al. 4,069,063 1, 1978 Ball 1,176,747 3, 1916 Ferguson 4,080,270 3, 1978 O'Leary et al. 1493,579 5, 1924 Walter 4,106,296 8, 1978 Leonard, Jr. et al. 1,543,942 6, 1925 Mathesius 4,107,022 8, 1978 Strempel et al. 1,655,171 1, 1928 Wagner 4,117,060 9, 1978 Murray 1,678,345 7, 1928 Mattison 4,128,462 12, 1978 Ghiringhelli et al. 1,759,361 5, 1930 Miller 4,140,510 2, 1979 Scholze et al. 1,785,365 12, 1930 Seil 4,147,599 4, 1979 O'Leary et al. 1,823,269 9, 1931 Grilli 4,157.250 6, 1979 Regehr et al. 1,865,833 7, 1932 Chesny 4,164,537 8, 1979 Drostholm et al. 1897,725 2, 1933 Gaus et al. 4,188,291 2, 1980 Anderson 1924,503 8, 1933 Lambert 4,217, 186 8, 1980 McRae 1986,736 1, 1935 Mauthe et al. 4,219,396 8, 1980 Gancy et al. 2,006,295 6, 1935 Chewning et al. 4,242,185 12, 1980 McRae 2,054,315 9, 1936 Ebner et al. 4,246,075 1, 1981 Hilbertz 2,082,101 6, 1937 Dougherty 4,253,922 3, 1981 Welch 2,204,771 6, 1940 Rice et al. 4,263,021 4, 1981 Downs et al. 2,227.465 1, 1941 Roche, Jr. et al. 4.264,367 4, 1981 Schutz 2,241,674 5, 1941 Mohr, Jr. et al. 4,303,549 12, 1981 Boylan 2,242.294 5, 1941 Fox et al. 4,307,066 12, 1981 Davidson 2,273.795 2, 1942 Heise et al. 4,308.298 12, 1981 Chen 2,304,391 12, 1942 Zimmerman 4,312.646 1, 1982 Fattinger et al. 2,329,940 9, 1943 Ponzer 4,315,872 2, 1982 Senjo et al. 2,383,674 8, 1945 Osborne 4,335,788 6, 1982 Murphey et al. 2.458,039 1, 1949 Wait 4,337,230 6, 1982 Ellestad et al. 2,606,839 8, 1952 Evans 4,340,572 7, 1982 Ben-Shmuel et al. 2,810,450 10, 1957 Hartmann 4,361475 11, 1982 Moeglich 2.934,419 4, 1960 Cook 4,363,667 12, 1982 Birchall 2,967,807 1, 1961 Osborne et al. 4,370,307 1, 1983 Judd 3,046,152 T. 1962 Tsuneyoshi 4,376,101 3, 1983 Sartori et al. 3,120,426 2, 1964 Crawford, Jr. 4,377,554 3, 1983 Johnson 3,165,460 1, 1965 Zang et al. 10, 1983 Loutfy et al. 3,179,579 4, 1965 Gustave et al. 4.410,606 4,432,175 2, 1984 Smith . 52.223.6 3, 196092 7, 1965 Beer 4.450,009 5, 1984 Childs et al. 3,202,522 8, 1965 Chi-Sun Yang et al. 4,477,573 10, 1984 Taufen 3,222,267 12, 1965 Tirrell et al. 4,508,545 4, 1985 DeLoach 3,262,865 T. 1966 Waters, Jr. 4,561,945 12, 1985 Coker et al. 3,264,125 8, 1966 Bourlin et al. 4,588.443 5, 1986 Bache 3,322,574 5, 1967 Justi et al. 4,620,969 11, 1986 Wilkinson 3,340,003 9, 1967 Judd 4,634,533 1, 1987 Somerville et al. 3,350,292 10, 1967 Weinberger et al. 4,670,234 6, 1987 Holter et al. 3,374,164 3, 1968 Baleet al. 4,716,027 12, 1987 Morrison 3.420,775 1, 1969 Cadwallader 4,738,695 4, 1988 Carr et al. 3,463,814 8, 1969 Blanco et al. 4,804,449 2, 1989 Sweeney 3,466,169 9, 1969 Nowak et al. 4,818,367 4, 1989 Winkler 3.47 1999 10, 1969 Schon 4,838,941 6, 1989 Hill 3,511,595 5, 1970 Fuchs 4,852,344 8, 1989 Warner 3,511,712 5, 1970 Giner 4,880.447 11, 1989 Bloch 3,525,675 8, 1970 Gaudin 4,899,544 2, 1990 Boyd 3,558,769 1, 1971 Globus 4.915,877 4, 1990 Shepherd 3,574,530 4, 1971 Suriani et al. 4.915,914 4, 1990 Morrison 3,627,479 12, 1971 Yee 4,931,264 6, 1990 Rochelle et al. 3,627,480 12, 1971 Birchall 5,037,286 8, 1991 Roberts 3,630,762 12, 1971 Olton et al. 5,100,633 3, 1992 Morrison 3,663,379 5, 1972 Kendall 5,127,765 7, 1992 Millgard et al. 3,686,372 8, 1972 Hiatt et al. 5,141,620 8, 1992 Molter 3,721,621 3, 1973 Hough 5,230,734 7, 1993 Kumasaka et al. 3,725,267 4, 1973 Gelblum 5,244,304 9, 1993 Weill et al. 3,733,788 5, 1973 Crowley 5,246,551 9, 1993 Pletcher et al. 3,816,592 6, 1974 Rinaldi et al. 5,275,794 1, 1994 Luna 3,834,129 9, 1974 Darlinger et al. 5,282,935 2, 1994 Cawlfield et al. 3,847,632 11, 1974 Blengsli 5,318,758 6, 1994 Fujii et al. 3,861,928 1/1975 Slater et al. 5,348,712 9, 1994 Marquis et al. 3,864,236 2, 1975 Lindstrom 5,362,688 11, 1994 Porta et al. 3,904,496 9, 1975 Harke et al. 5,364,611 11, 1994 Iijima et al. 3,907,526 9, 1975 Saleem et al. 5,366,513 11, 1994 Goldmann et al. 3,912,801 10, 1975 Stephens 5,376,343 12, 1994 Fouche 3,917,795 11, 1975 Pelczarski et al. 1/1995 Conroy 3,925,534 12, 1975 Singleton et al. 5,378,279 3,953,568 4, 1976 Seko et al. 5,388,456 2, 1995 Kettel 3,959,419 5, 1976 Kitterman 5,427,608 6, 1995 Auer et al. 3,963,592 6, 1976 Lindstrom 5.439,509 8, 1995 Spink et al. 3,970,528 7, 1976 Zirngieblet al. 5,455,013 10, 1995 Shibata et al. 3,975,503 8, 1976 Hauschild et al. 5,470,671 11, 1995 Fletcher et al. 3,997,303 12, 1976 Newton 5,520,898 5, 1996 Pinnavaia et al.
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