Observations of OH and HO2 Radicals in Coastal Antarctica
Atmos. Chem. Phys., 7, 4171–4185, 2007 www.atmos-chem-phys.net/7/4171/2007/ Atmospheric © Author(s) 2007. This work is licensed Chemistry under a Creative Commons License. and Physics Observations of OH and HO2 radicals in coastal Antarctica W. J. Bloss1,*, J. D. Lee1,**, D. E. Heard1, R. A. Salmon2, S. J.-B. Bauguitte2, H. K. Roscoe2, and A. E. Jones2 1School of Chemistry, University of Leeds, Woodhouse Lane, Leeds, LS2 9JT, UK 2British Antarctic Survey, Madingley Road, Cambridge, CB3 0ET, UK *now at: School of Geography, Earth & Environmental Sciences, University of Birmingham, Edgbaston, Birmingham, B15 2TT, UK **now at: Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK Received: 18 January 2007 – Published in Atmos. Chem. Phys. Discuss.: 23 February 2007 Revised: 27 July 2007 – Accepted: 10 August 2007 – Published: 16 August 2007 Abstract. OH and HO2 radical concentrations have been Field measurement campaigns, in which coordinated mea- measured in the boundary layer of coastal Antarctica for a surements of radical species such as OH, HO2, NO etc. have six-week period during the austral summer of 2005. The been performed, provide a means to test and refine our un- measurements were performed at the British Antarctic Sur- derstanding of fast radical photochemistry. Measurements ◦ 0 ◦ 0 vey’s Halley Research Station (75 35 S, 26 19 W), using of OH and HO2 radicals have been performed in a range the technique of on-resonance laser-induced fluorescence to of marine and continental, polluted and clean environments detect OH, with HO2 measured following chemical conver- (e.g.
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