Es-1 Doe Has More Than 7,000 Surplus Contaminated
Total Page:16
File Type:pdf, Size:1020Kb
Load more
Recommended publications
-
Prohibited and Restricted Chemical List
School Emergency Response Plan and Management Guide Prohibited and Restricted Chemical List PROHIBITED AND RESTRICTED CHEMICAL LIST Introduction After incidents of laboratory chemical contamination at several schools, DCPS, The American Association for the Advancement of Science (AAAS) and DC Fire and Emergency Management Services developed an aggressive program for chemical control to eliminate student and staff exposure to potential hazardous chemicals. Based upon this program, all principals are required to conduct a complete yearly inventory of all chemicals located at each school building to identify for the removal and disposal of any prohibited/banned chemicals. Prohibited chemicals are those that pose an inherent, immediate, and potentially life- threatening risk, injury, or impairment due to toxicity or other chemical properties to students, staff, or other occupants of the school. These chemicals are prohibited from use and/or storage at the school, and the school is prohibited from purchasing or accepting donations of such chemicals. Restricted chemicals are chemicals that are restricted by use and/or quantities. If restricted chemicals are present at the school, each storage location must be addressed in the school's written emergency plan. Also, plan maps must clearly denote the storage locations of these chemicals. Restricted chemicals—demonstration use only are a subclass in the Restricted chemicals list that are limited to instructor demonstration. Students may not participate in handling or preparation of restricted chemicals as part of a demonstration. If Restricted chemicals—demonstration use only are present at the school, each storage location must be addressed in the school's written emergency plan. Section 7: Appendices – October 2009 37 School Emergency Response Plan and Management Guide Prohibited and Restricted Chemical List Following is a table of chemicals that are Prohibited—banned, Restricted—academic curriculum use, and Restricted—demonstration use only. -
Basic Description for Ground and Air Hazardous
BASIC DESCRIPTION FOR GROUND AND AIR GROUND AND AIR HAZARDOUS MATERIALS SHIPMENTS GROUND SHIPMENTS AIR SHIPMENTS SHIPMENTS HAZARD DOT DOT CLASS OR MAXIMUM EXEMPTION, GROUND EXEMPTION, HAZARDOUS MATERIALS DESCRIPTIONS DIVISION I.D. NUMBER LABEL(S) REQUIRED OR QUANTITY PER SPECIAL SERVICE TO LABEL(S) REQUIRED OR MAXIMUM NET CARGO SPECIAL NON-BULK AND PROPER SHIPPING NAME (Subsidiary if (ALSO MARK PACKING EXEMPTION, SPECIAL PERMIT INNER PERMIT CANADA EXEMPTION, SPECIAL PERMIT QUANTITY PER AIRCRAFT PERMIT SPECIAL EXCEPTIONS PACKAGING (ALSO MARK ON PACKAGE) applicable) ON PACKAGE) GROUP OR EXCEPTION RECEPTACLE OR 173.13 PERMITTED OR EXCEPTION PACKAGE** QUANTITY OR 173.13 PROVISIONS §173.*** §173.*** (1) (2) (3) (4) (5) (6) (7) (8) (9) (10) (11) (12) (13) (14) (15) Accellerene, see p-Nitrosodimethylaniline Accumulators, electric, see Batteries, wet etc Accumulators, pressurized, pneumatic or hydraulic (containing non-flammable gas), see Articles pressurized, pneumatic or hydraulic (containing non-flammable gas) FLAMMABLE FLAMMABLE Acetal 3 UN1088 II LIQUID * YES LIQUID * 5 L 150 202 FLAMMABLE Acetaldehyde 3 UN1089 I LIQUID YES Forbidden None 201 May not be regulated when shipped via UPS Acetaldehyde ammonia 9 UN1841 III ground YES CLASS 9 * 30 kg 30 kg 155 204 FLAMMABLE FLAMMABLE Acetaldehyde oxime 3 UN2332 III LIQUID * YES LIQUID * 25 L 150 203 CORROSIVE, CORROSIVE, Acetic acid, glacial or Acetic acid solution, FLAMMABLE FLAMMABLE A3, A6, with more than 80 percent acid, by mass 8 (3) UN2789 II LIQUID * YES LIQUID * 1 L A7, A10 154 202 Acetic -
150 Subpart A—General Subpart B—Table of Hazardous Materials
§ 172.1 49 CFR Ch. I (10–1–19 Edition) APPENDIX B TO PART 172—TREFOIL SYMBOL shipping name. In addition, the Table APPENDIX C TO PART 172—DIMENSIONAL SPEC- specifies or references requirements in IFICATIONS FOR RECOMMENDED PLACARD this subchapter pertaining to labeling, HOLDER packaging, quantity limits aboard air- APPENDIX D TO PART 172—RAIL RISK ANAL- YSIS FACTORS craft and stowage of hazardous mate- rials aboard vessels. AUTHORITY: 49 U.S.C. 5101–5128, 44701; 49 CFR 1.81, 1.96 and 1.97. (b) Column 1: Symbols. Column 1 of the Table contains six symbols (‘‘ + ’’, ‘‘A’’, SOURCE: Amdt. 172–29, 41 FR 15996, Apr. 15, ‘‘D’’, ‘‘G’’, ‘‘I’’ and ‘‘W’’) as follows: 1976, unless otherwise noted. (1) The plus (+) sign fixes the proper shipping name, hazard class and pack- Subpart A—General ing group for that entry without regard to whether the material meets the defi- § 172.1 Purpose and scope. nition of that class, packing group or This part lists and classifies those any other hazard class definition. When materials which the Department has the plus sign is assigned to a proper designated as hazardous materials for shipping name in Column (1) of the purposes of transportation and pre- § 172.101 Table, it means that the mate- scribes the requirements for shipping rial is known to pose a risk to humans. papers, package marking, labeling, and When a plus sign is assigned to mix- transport vehicle placarding applicable tures or solutions containing a mate- to the shipment and transportation of rial where the hazard to humans is sig- those hazardous materials. -
Chemical Compatibility Storage Group
CHEMICAL SEGREGATION Chemicals are to be segregated into 11 different categories depending on the compatibility of that chemical with other chemicals The Storage Groups are as follows: Group A – Compatible Organic Acids Group B – Compatible Pyrophoric & Water Reactive Materials Group C – Compatible Inorganic Bases Group D – Compatible Organic Acids Group E – Compatible Oxidizers including Peroxides Group F– Compatible Inorganic Acids not including Oxidizers or Combustible Group G – Not Intrinsically Reactive or Flammable or Combustible Group J* – Poison Compressed Gases Group K* – Compatible Explosive or other highly Unstable Material Group L – Non-Reactive Flammable and Combustible, including solvents Group X* – Incompatible with ALL other storage groups The following is a list of chemicals and their compatibility storage codes. This is not a complete list of chemicals, but is provided to give examples of each storage group: Storage Group A 94‐75‐7 2,4‐D (2,4‐Dichlorophenoxyacetic acid) 94‐82‐6 2,4‐DB 609-99-4 3,5-Dinitrosalicylic acid 64‐19‐7 Acetic acid (Flammable liquid @ 102°F avoid alcohols, Amines, ox agents see SDS) 631-61-8 Acetic acid, Ammonium salt (Ammonium acetate) 108-24-7 Acetic anhydride (Flammable liquid @102°F avoid alcohols see SDS) 79‐10‐7 Acrylic acid Peroxide Former 65‐85‐0 Benzoic acid 98‐07‐7 Benzotrichloride 98‐88‐4 Benzoyl chloride 107-92-6 Butyric Acid 115‐28‐6 Chlorendic acid 79‐11‐8 Chloroacetic acid 627‐11‐2 Chloroethyl chloroformate 77‐92‐9 Citric acid 5949-29-1 Citric acid monohydrate 57-00-1 Creatine 20624-25-3 -
5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28
Appendix B Classification of common chemicals by chemical band 1 1 EXHIBIT 1 2 CHEMICAL CLASSIFICATION LIST 3 4 1. Pyrophoric Chemicals 5 1.1. Aluminum alkyls: R3A1, R2A1C1, RA1C12 6 Examples: Et3A1, Et2A1C1, EtA.1111C12, Me3A1, Diethylethoxyaluminium 7 1.2. Grignard Reagents: RMgX (R=alkyl, aryl, vinyl X=halogen) 8 1.3. Lithium Reagents: RLi (R 7 alkyls, aryls, vinyls) 9 Examples: Butyllithium, Isobutylthhium, sec-Butyllithium, tert-Butyllithium, 10 Ethyllithium, Isopropyllithium, Methyllithium, (Trimethylsilyl)methyllithium, 11 Phenyllithiurn, 2-Thienyllithium, Vinyllithium, Lithium acetylide ethylenediamine 12 complex, Lithium (trimethylsilyl)acetylide, Lithium phenylacetylide 13 1.4. Zinc Alkyl Reagents: RZnX, R2Zn 14 Examples: Et2Zn 15 1.5. Metal carbonyls: Lithium carbonyl, Nickel tetracarbonyl, Dicobalt octacarbonyl 16 1.6. Metal powders (finely divided): Bismuth, Calcium, Cobalt, Hafnium, Iron, 17 Magnesium, Titanium, Uranium, Zinc, Zirconium 18 1.7. Low Valent Metals: Titanium dichloride 19 1.8. Metal hydrides: Potassium Hydride, Sodium hydride, Lithium Aluminum Hydride, 20 Diethylaluminium hydride, Diisobutylaluminum hydride 21 1.9. Nonmetal hydrides: Arsine, Boranes, Diethylarsine, diethylphosphine, Germane, 22 Phosphine, phenylphosphine, Silane, Methanetellurol (CH3TeH) 23 1.10. Non-metal alkyls: R3B, R3P, R3As; Tributylphosphine, Dichloro(methyl)silane 24 1.11. Used hydrogenation catalysts: Raney nickel, Palladium, Platinum 25 1.12. Activated Copper fuel cell catalysts, e.g. Cu/ZnO/A1203 26 1.13. Finely Divided Sulfides: -
Chemical Compatibility Storage Codes1
CHEMICAL COMPATIBILITY STORAGE CODES1 Storage Group A: Compatible Organic Bases Identifier Name 100‐46‐9 Benzylamine 100‐85‐6 Benzyltrimethylammonium hydroxide 108‐91‐8 Cyclohexylamine 111‐42‐2 Diethanolamine 109‐89‐7 Diethylamine 75‐04‐7 Ethylamine 107‐15‐3 Ethylenediamine 110‐89‐4 Piperidine 102‐71‐6 Triethanolamine 121‐44‐8 Triethylamine Storage Group B: Compatible Pyrophoric And Water Reactive Materials Identifier Name 7783‐70‐2 Antimony pentafluoride 98‐88‐4 Benzoyl chloride 353‐42‐4 Boron triflouride compound with methyl ether (1:1) 594‐19‐4 Tert‐Butyllithium 156‐62‐7 Calcium cyanamide 16853‐85‐3 Lithium aluminum hydride 4111‐54‐0 Lithium diisopropylamide 7580‐67‐8 Lithium hydride 7439‐93‐2 Lithium metal (e.g., in THF) 124‐63‐0 Methanesulfonyl chloride 917‐54‐4 Methyllithium solution (and other alkyls) 7440‐09‐7 Potassium metal 17242‐52‐3 Potassium amide 16940‐66‐2 Sodium borohydride 7646‐69‐7 Sodium hydride 7440‐66‐6 Zinc (fume or dust) Storage Group C: Compatible Inorganic Bases Identifier Name 1336‐21‐6 Ammonium hydroxide 17194‐00‐2 Barium hydroxide 1305‐62‐0 Calcium hydroxide 21351‐79‐1 Cesium hydroxide 1310‐65‐2 Lithium hydroxide 1 Adapted from Stanford University’s ChemTracker Storage System. Used with permission from Lawrence M. Gibbs, Stanford University. 1310‐58‐3 Potassium hydroxide 1310‐82‐3 Rubidium hydroxide 1310‐73‐2 Sodium hydroxide 18480‐07‐4 Strontium hydroxide Storage Group D: Compatible Organic Acids Identifier Name 64‐19‐7 Acetic acid 79‐10‐7 Acrylic acid 65‐85‐0 Benzoic acid 98‐07‐7 Benzotrichloride 98‐88‐4 -
Hazardous Waste List (California Code of Regulations, Title 22 Section 66261.126)
Hazardous Waste List (California Code of Regulations, Title 22 Section 66261.126) Appendix X - List of Chemical Names and Common Names for Hazardous Wastes and Hazardous Materials (a) This subdivision sets forth a list of chemicals which create a presumption that a waste is a hazardous waste. If a waste consists of or contains a chemical listed in this subdivision, the waste is presumed to be a hazardous waste Environmental Regulations of CALIFORNIA unless it is determined that the waste is not a hazardous waste pursuant to the procedures set forth in section 66262.11. The hazardous characteristics which serve as a basis for listing the chemicals are indicated in the list as follows: (X) toxic (C) corrosive (I) ignitable (R) reactive * =Extremely Hazardous A chemical denoted with an asterisk is presumed to be an extremely hazardous waste unless it does not exhibit any of the criteria set forth in section 66261.110 and section 66261.113. Trademark chemical names are indicated by all capital letters. 1. Acetaldehyde (X,I) 2. Acetic acid (X,C,I) 3. Acetone, Propanone (I) 4. *Acetone cyanohydrin (X) 5. Acetonitrile (X,I) 6. *2-Acetylaminofluorene, 2-AAF (X) 7. Acetyl benzoyl peroxide (X,I,R) 8. *Acetyl chloride (X,C,R) 9. Acetyl peroxide (X,I,R) 10. Acridine (X) 11. *Acrolein, Aqualin (X,I) 12. *Acrylonitrile (X,I) 13. *Adiponitrile (X) 14. *Aldrin; 1,2,3,4,10,10-Hexachloro-1,4,4a,5,8,8a-hexahydro-1,4,5,8-endo-exodimethanonaphthlene (X) 15. *Alkyl aluminum chloride (C,I,R) 16. *Alkyl aluminum compounds (C,I,R) 17. -
Permanganate Hazard Summary Identification
Common Name: AMMONIUM PERMANGANATE CAS Number: 13446-10-1 RTK Substance number: 0110 DOT Number: UN 1482 Date: February 1988 Revision: August 2000 ----------------------------------------------------------------------- ----------------------------------------------------------------------- HAZARD SUMMARY WORKPLACE EXPOSURE LIMITS * Ammonium Permanganate can affect you when breathed No occupational exposure limits have been established for in. Ammonium Permanganate. This does not mean that this * Contact can irritate the skin and eyes. substance is not harmful. Safe work practices should always * Breathing Ammonium Permanganate can irritate the be followed. nose, throat and lungs. * Ammonium Permanganate is a HIGHLY REACTIVE WAYS OF REDUCING EXPOSURE CHEMICAL and a DANGEROUS EXPLOSION * Where possible, enclose operations and use local exhaust HAZARD. ventilation at the site of chemical release. If local exhaust ventilation or enclosure is not used, respirators should be IDENTIFICATION worn. Ammonium Permanganate is a violet-brown or dark purple, * Wear protective work clothing. crystalline (sand-like) solid. * Wash thoroughly immediately after exposure to Ammonium Permanganate and at the end of the REASON FOR CITATION workshift. * Ammonium Permanganate is on the Hazardous * Post hazard and warning information in the work area. In Substance List because it is cited by DOT and NFPA. addition, as part of an ongoing education and training * This chemical is on the Special Health Hazard Substance effort, communicate all information on the health and List because it is REACTIVE. safety hazards of Ammonium Permanganate to * Definitions are provided on page 5. potentially exposed workers. HOW TO DETERMINE IF YOU ARE BEING EXPOSED The New Jersey Right to Know Act requires most employers to label chemicals in the workplace and requires public employers to provide their employees with information and training concerning chemical hazards and controls. -
Li Na K Be Mg Ca B Al Ni Au Ag
LAST NAME____________________ FIRST NAME____________________________ DATE ___________ 6.1 NAMING IONIC COMPOUNDS = Use the notes to write the correct names of the IONIC COMPOUNDS created by the Cations and Anions. SIMPLE EXAMPLES Anions Cations ↓ F Cl Br I Li Lithium Fluoride Lithium Chloride Lithium Bromide Lithium Iodide Na Sodium Fluoride Sodium Chloride Sodium Bromide Sodium Iodide K Potassium Fluoride Potassium Chloride Potassium Bromide Potassium Iodide Be Beryllium Fluoride Beryllium Chloride Beryllium Bromide Beryllium Iodide Mg Magnesium Fluoride Magnesium Chloride Magnesium Bromide Magnesium Iodide Ca Calcium Fluoride Calcium Chloride Calcium Bromide Calcium Iodide B Boron Fluoride Boron Chloride Boron Bromide Boron Iodide Al Aluminum Fluoride Aluminum Chloride Aluminum Bromide Aluminum Iodide Ni Nickel Fluoride Nickel Chloride Nickel Bromide Nickel Iodide Au Gold Fluoride Gold Chloride Gold Bromide Gold Iodide Ag Silver Fluoride Silver Chloride Silver Bromide Silver Iodide And some more Anions Cations ↓ O S N Li Lithium Oxide Lithium Sulfide Lithium Nitride Na Sodium Oxide Sodium Sulfide Sodium Nitride K Potassium Oxide Potassium Sulfide Potassium Nitride Be Beryllium Oxide Beryllium Sulfide Beryllium Nitride Mg Magnesium Oxide Magnesium Sulfide Magnesium Nitride Ca Calcium Oxide Calcium Sulfide Calcium Nitride B Boron Oxide Boron Sulfide Boron Nitride Al Aluminum Oxide Aluminum Sulfide Aluminum Nitride Ni Nickel Oxide Nickel Sulfide Nickel Nitride Au Gold Oxide Gold Sulfide Gold Nitride Ag Silver Oxide Silver Sulfide Silver -
New York City Department of Environmental Protection Community Right-To-Know: List of Hazardous Substances
New York City Department of Environmental Protection Community Right-to-Know: List of Hazardous Substances Updated: 12/2015 Definitions SARA = The federal Superfund Amendments and Reauthorization Act (enacted in 1986). Title III of SARA, known as the Emergency Planning and Community Right-to-Act, sets requirements for hazardous chemicals, improves the public’s access to information on chemical hazards in their community, and establishes reporting responsibilities for facilities that store, use, and/or release hazardous chemicals. RQ = Reportable Quantity. An amount entered in this column indicates the substance may be reportable under §304 of SARA Title III. Amount is in pounds, a "K" represents 1,000 pounds. An asterisk following the Reporting Quantity (i.e. 5000*) will indicate that reporting of releases is not required if the diameter of the pieces of the solid metal released is equal to or exceeds 100 micrometers (0.004 inches). TPQ = Threshold Planning Quantity. An amount entered in this column reads in pounds and indicates the substance is an Extremely Hazardous Substance (EHS), and may require reporting under sections 302, 304 & 312 of SARA Title III. A TPQ with a slash (/) indicates a "split" TPQ. The number to the left of the slash is the substance's TPQ only if the substance is present in the form of a fine powder (particle size less than 100 microns), molten or in solution, or reacts with water (NFPA rating = 2, 3 or 4). The TPQ is 10,000 lb if the substance is present in other forms. A star (*) in the 313 column= The substance is reportable under §313 of SARA Title III. -
The Reaction of Barium Manganate with Acids and Their Precursors
Indian Journal of Chemistry Vol. 38A. September 1999, pp.966-968 The reaction of barium manganate with fraction data were collected on a Phillips PW 3710 acids and their precursors diffractometer, with a Cu monochromator. Synthesis oj barium manganate (VI) Liszlo Kotai, Agnes Keszler, Janos Pato. Sandor Holly Chemical Research Center, Institute of Chemistry. KMn04 (15.8 g) was dissolved in 300 ml of water, Hungarian Academy of Sciences then BaCI2.2Hp (24.9 g dissolved in 100 ml of water), H-1025, Budapest, Pusztaseri u. 59-67, Hungary KOH (56 g dissolved in 100 ml of water) and KI (2.0 g and dissolved in 20 ml of water) were added with vigorous Kalyan K Banerji ' Department of Chemistry, J N V University, stirring. The mixture was boiled for 15 min, cooled, Jodhpur 342 005, India filtered, and washed. The permanganate-free product was dried at 105° C for I h, then the traces of water were Received 30 November 1998; revised 4 Mal' 1999 removed by azeotropic distillation with benzene (yield - 100%). Analysis (found/calc. fo r BaMn0 ): Ba 53.69/ 4 A simple and easy preparative route to obtain permangani c ac id 53.59%; Mn 21.40121.44%. and permanganate salts from barium manganate and sulphuric acid is described. Sulphuric acid reacts with bari um manganate to pro duce sparingly soluble bariulll sulphate and well-soluble permanga Synthesis ojpermanganic acid nic ac id or bariulll permanganate, these in turn can be usee! to pre To barium manganate (2.56 g, 0 .0 I mol) suspended pare ot her metal permanganates. -
Ammonium Permanganate in the Oxidation of Benzyl Alcohol László Kotai3, B Éla Kazinczy3, Á Gnes Keszler3, Sándor Holly3, István Gács3, and Kalyan K
Three Reagents in One: Ammonium Permanganate in the Oxidation of Benzyl Alcohol László Kotai3, B éla Kazinczy3, Á gnes Keszler3, Sándor Holly3, István Gács3, and Kalyan K. Banerjib a Institute of Chemistry, Chemical Research Center, Hungarian Academy of Sciences, H-1525 Budapest, P. O. Box 17, Hungary b Department of Chemistry, J. N. V. University, Jodhpur-342005, India Reprint requests to L. Kötai. Fax: 36-1-3257554. E-mail: [email protected] Z. Naturforsch. 56b,823-825 (2001); received December 20, 2000 Ammonium Permanganate, Oxidation The oxidation or consecutive ammoxidation reaction of benzyl alcohol with solid ammo nium permanganate was studied. The first oxidation step leads to the formation of benzalde- hyde, ammonia, and M n02. The M n02 is present in the system in a colloidal form which facilitates the reaction between aldehyde and ammonia, and this latter reactionthen yields benzonitrile. All these products are formed in a heterogeneous system under relatively mild conditions. The yield of benzaldehyde has an optimum at room temperature and increases with increasing reaction time. At higher temperature(e.g. 80 °C) benzonitrile is formed to gether with minor amounts of benzyl benzoate. Introduction the reaction of 1 and solid NH4M n04 beside the Benzyl alcohol and its ring-substituted deriva- inorganic residue. After one hour at 22 °C, only ives can be easily oxidized by various permanga the formation of benzaldehyde (2) could be ob nates [1-14]. Reaction conditions, such as the na- served, and its yield increased with increasing tem jure of the oxidant and the medium, temperature, perature. Benzonitrile (3), however, appeared only lie.