Carbonate Sedimentology and Facies Correlation of the Mason Mountain Wildlife Management Area: Mason, TX
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Determination of Carbonate Rock Chemistry Using Laboratory-Based Hyperspectral Imagery
Remote Sens. 2014, 6, 4149-4172; doi:10.3390/rs6054149 OPEN ACCESS remote sensing ISSN 2072-4292 www.mdpi.com/journal/remotesensing Article Determination of Carbonate Rock Chemistry Using Laboratory-Based Hyperspectral Imagery Nasrullah Zaini 1,2,*, Freek van der Meer 1 and Harald van der Werff 1 1 Department of Earth Systems Analysis, Faculty of Geo-Information Science and Earth Observation (ITC), University of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands; E-Mails: [email protected] (F.M.); [email protected] (H.W.) 2 Department of Physics, Faculty of Mathematics and Natural Sciences, Syiah Kuala University, Darussalam, Banda Aceh, 23111 Aceh, Indonesia * Author to whom correspondence should be addressed; E-Mail: [email protected]; Tel.: +31-534-874-444; Fax: +31-534-874-400. Received: 6 December 2013; in revised form: 11 April 2014 / Accepted: 28 April 2014 / Published: 5 May 2014 Abstract: The development of advanced laboratory-based imaging hyperspectral sensors, such as SisuCHEMA, has created an opportunity to extract compositional information of mineral mixtures from spectral images. Determining proportions of minerals on rock surfaces based on spectral signature is a challenging approach due to naturally-occurring minerals that exist in the form of intimate mixtures, and grain size variations. This study demonstrates the application of SisuCHEMA hyperspectral data to determine mineral components in hand specimens of carbonate rocks. Here, we applied wavelength position, spectral angle mapper (SAM) and linear spectral unmixing (LSU) approaches to estimate the chemical composition and the relative abundance of carbonate minerals on the rock surfaces. The accuracy of these classification methods and correlation between mineral chemistry and mineral spectral characteristics in determining mineral constituents of rocks are also analyzed. -
Dissolution of Carbonate Rocks in a Laboratory Setting: Rates and Textures
minerals Article Dissolution of Carbonate Rocks in a Laboratory Setting: Rates and Textures Erik B. Larson 1,* and Ronald V. Emmons 1,2 1 Department of Natural Sciences, Shawnee State University, 940 Second St, Portsmouth, OH 45662, USA; [email protected] 2 Department of Chemistry and Biochemistry, The University of Toledo, 2801 W. Bancroft St, Toledo, OH 43606, USA * Correspondence: [email protected]; Tel.: +1-740-351-3144 Abstract: Determining the dissolution rates of carbonate rocks is vital to advancing our under- standing of cave, karst, and landscape processes. Furthermore, the role of carbonate dissolution is important for the global carbon budget and climate change. A laboratory experiment was setup to calculate the dissolution rates of two whole rock carbonate samples with different petrographic makeup (ooids and brachiopods). The carbonate rock samples were also explored under a scanning electron microscope to evaluate the textures that developed after dissolution The oolitic limestone dissolved at a rate of 1579 cm yr−1, and the pentamerous limestone (dolostone) dissolved at a rate of 799 cm yr−1. Both rocks did not dissolve evenly across their surface as indicated by scanning electron microscopy, it appears the allochems dissolved preferentially to the matrix/cement of the rocks and that some mechanical weathering happened as well. This work reports that the petrography and mineralogy of carbonate rocks is important to consider when exploring the cave, karst, and landscape evolution and that attention should be paid to the petrography of carbonate rocks when considering Citation: Larson, E.B.; Emmons, R.V. the global carbon budget. -
Carbonate Factory Response and Recovery After Ocean Anoxic Event 1A, Pearsall Formation, Central Texas
Copyright by Esben Skjold Pedersen 2020 The Thesis Committee for Esben Skjold Pedersen Certifies that this is the approved version of the following Thesis: Carbonate Factory Response and Recovery after Ocean Anoxic Event 1a, Pearsall Formation, Central Texas APPROVED BY SUPERVISING COMMITTEE: Charles Kerans, Supervisor Toti E. Larson, Co-Supervisor Daniel O. Breecker Carbonate Factory Response and Recovery after Ocean Anoxic Event 1a, Pearsall Formation, Central Texas by Esben Skjold Pedersen Thesis Presented to the Faculty of the Graduate School of The University of Texas at Austin in Partial Fulfillment of the Requirements for the Degree of Master of Science in Geological Sciences The University of Texas at Austin August 2020 Dedication To my parents for their endless support. To my sister, aunt, and uncle for opening my eyes to the world of the geological sciences. Acknowledgements Firstly, I would like to thank my co-supervisors, Charlie Kerans and Toti Larson, for the opportunity to continue my education as a graduate student at the University of Texas at Austin, and their wisdom both within and outside of the realm of geoscience. I would also like to thank Dan Breecker for serving on my committee, and for his advice during my time at UT. I am grateful to Equinor for investing in my research and education in the geological sciences while as a graduate student. I would like to thank Rob Forkner in particular, for his guidance and direction. I would like to thank the Staff at the Bureau of Economic Geology, including Nathan Ivicic, Brandon Williamson, and Rudy Lucero for their help and problem solving in the core warehouse, especially during COVID-19 restrictions, and to Evan Sivil for his help with pXRF dataset acquisition and guidance. -
Contribution of Carbonate Rock Weathering to the Atmospheric CO2
Cases and solutions Contribution of carbonate rock weathering to the atmospheric CO2 sink Z. Liu ´ J. Zhao Introduction Abstract To accurately predict future CO2 levels in the atmosphere, which is crucial in predicting It is known Quay 1992; Watson and others 1990) that global climate change, the sources and sinks of the the combustion of fossil fuels releases about 5.4 billion atmospheric CO and their change over time must 2 tons of carbon a year as CO2 into the atmosphere. In be determined. In this paper, some typical cases addition, deforestation practices contribute about 1.6 bil- are examined using published and unpublished lion tons of carbon a year to atmospheric CO . Therefore, data. Firstly, the sensitivity of carbonate rock 2 the total input of CO2 from human activities is about weathering including the effects by both dissolu- 7.0 billion tons of carbon annually. However, only about tion and reprecipitation of carbonate) to the change 3.4 billion tons of carbon a year accumulates in the of soil CO and runoff will be discussed, and then 2 atmosphere. That means there is an atmospheric CO2 the net amount of CO2 removed from the atmos- sink of about 3.6 billion tons of carbon a year. phere in the carbonate rock areas of mainland To accurately predict future CO2-levels in the atmos- China and the world will be determined by the phere, which is crucial in predicting climate change, the hydrochem-discharge and carbonate-rock-tablet CO2 sinks and their change with time must be deter- methods, to obtain an estimate of the contribution mined. -
Constraints on Sedimentary Ages of the Chuanlinggou Formation in the Ming Tombs, Beijing, North China Craton: LA-ICP-MS and SHRIMP U–Pb Dating of Detrital Zircons
Acta Geochim (2018) 37(2):257–280 https://doi.org/10.1007/s11631-017-0211-1 ORIGINAL ARTICLE Constraints on sedimentary ages of the Chuanlinggou Formation in the Ming Tombs, Beijing, North China Craton: LA-ICP-MS and SHRIMP U–Pb dating of detrital zircons 1,2 1 1,3 4 Jing Ding • Yuruo Shi • Alfred Kro¨ner • J. Lawford Anderson Received: 13 November 2016 / Revised: 10 February 2017 / Accepted: 16 August 2017 / Published online: 1 September 2017 Ó Science Press, Institute of Geochemistry, CAS and Springer-Verlag GmbH Germany 2017 Abstract Detrital zircons in five sedimentary samples, the Chuanlinggou Formation in the Ming Tombs District MC1 to MC5, from the bottom of the Chuanlinggou For- was deposited in a low-energy mud flat sedimentary mation in the Ming Tombs District, Beijing, were dated environment in the inter-supra tidal zone because it is with the LA-ICP-MS and SHRIMP U–Pb methods. Age mainly composed of silty mudstone and fine-grained spectra of the five samples show a major peak at 2500 Ma sandstone with relatively simple sedimentary structures. and a secondary peak at 2000 Ma, suggesting their provenances were mainly from the crystalline basement of Keywords Detrital zircon Á LA-ICP-MS U–Pb ages Á the North China Craton and the Trans-North China Orogen. SHRIMP Á Chuanlinggou Formation Á Ancient sedimentary The youngest zircon has an age of 1673 ± 44 Ma, indi- environment Á North China Craton cating that the Chuanlinggou Formation was deposited after this age. From sample MC4 to MC5, lithology changed from a clastic rock (fine-grained sandstone) to a 1 Introduction carbonate rock (fine-grained dolomite), suggesting that the depositional basin became progressively deeper. -
Carbonate Geology and Hydrology of the Edwards Aquifer in the San
Report 296 Carbonate Gec>logy and Hydrology ()f the Edwards Aquifer in the San Antonio Ar~ea, Texas November 1986 TEXAS WATER DEVELOPMENT BOARD REPORT 296 CARBONATE GEOLOGY AND HYDROLOGY OF THE EDWARDS AQUIFER IN THE SAN ANTONIO AREA, TEXAS By R. W. Maclay and T. A. Small U.S. Geological Survey This report was prepared by the U.S. Geological Survey under cooperative agreement with the San Antonio City Water Board and the Texas Water Development Board November 1986 TEXAS WATER DEVELOPMENT BOARD Charles E. Nemir. Executive Administrator Thomas M. Dunning, Chairman Stuart S. Coleman. Vice Chairman Glen E. Roney George W. McCleskey Charles W. Jenness Louie Welch A uthorization for use or reproduction ofany originalmaterial containedin this publication. i.e., not obtained from other sources. is freely granted. The Board would appreciate acknowledgement. Published and distributed by the Texas Water Development Board Post Office Box 13231 Austin. Texas 78711 ii ABSTRACT Regional differences in the porosity and permeability of the Edwards aquifer are related to three major depositional areas, the Maverick basin, the Devils River trend, and the San Marcos platform, that existed during Early Cretaceous time. The rocks of the Maverick basin are predominantly deep basinal deposits of dense, homogeneous mudstones of low primary porosity. Permeability is principally associated with cavernous voids in the upper part of the Salmon Peak Formation in the Maverick basin. The rocks of the Devils River trend are a complex of marine and supratidal deposits in the lower part and reefal or inter-reefal deposits in the upper part. Permeable zones, which occur in the upper part ofthe trend, are associated with collapse breccias and rudist reefs. -
The Clumped-Isotope Geochemistry of Exhumed Marbles from Naxos, Greece U
The clumped-isotope geochemistry of exhumed marbles from Naxos, Greece U. Ryb, M.K. Lloyd, D.A. Stolper, J.M. Eiler Abstract Exhumation and accompanying retrograde metamorphism alter the compositions and textures of metamorphic rocks through deformation, mineral–mineral reactions, water–rock reactions, and diffusion-controlled intra- and inter-mineral atomic mobility. Here, we demonstrate that these processes are recorded in the clumped- and single-isotope (δ13Cand δ18O) compositions of marbles, which can be used to constrain retrograde metamorphic histories. We collected 27 calcite and dolomite marbles along a transect from the rim to the center of the metamorphic core-complex of Naxos (Greece), and analyzed their carbonate single- and clumped-isotope compositions. The majority of Δ47 values of whole-rock samples are consistent with exhumation- controlled cooling of the metamorphic complex. However, the data also reveal that water–rock interaction, deformation driven recrystallization and thermal shock associated with hydrothermal alteration may considerably impact the overall distribution of Δ47 values. We analyzed specific carbonate fabrics influenced by deformation and fluid– rock reaction to study how these processes register in the carbonate clumped-isotope system. Δ47 values of domains drilled from a calcite marble show a bimodal distribution. Low Δ47 values correspond to an apparent temperature of 260 °C and are common in static fabrics; high Δ47values correspond to an apparent temperature of 200 °C and are common in dynamically recrystallized fabrics. We suggest that the low Δ47 values reflect diffusion-controlled isotopic reordering during cooling, whereas high Δ47 values reflect isotopic reordering driven by dynamic recrystallization. We further studied the mechanism by which dynamic recrystallization may alter Δ47 values by controlled heating experiments. -
Acidic Weathering of Carbonate Building Stones: Experimental Assessment (Preliminary Results)
Studia Universitatis Babeş-Bolyai, Geologia, 2009, 54 (1), 33 – 36 Acidic weathering of carbonate building stones: experimental assessment (preliminary results) Ryszard KRYZA, Marta PRELL, Franciszek CZECHOWSKI Malgorzata DOMARADZKA University of Wroclaw, ul. Cybulskiego 30, 50-205 Poland Received February 2009; accepted April 2009 Available online June 2009 ABSTRACT. Three types of carbonate rocks, travertine, limestone, and marble have been studied to determine their selected technical parameters (water absorption, resistance to salt crystallization damage) and reaction to experimentally modelled acid rain weathering, imitating the polluted urban atmospheric conditions. The acidic agents present in the natural acid rain precipitation, H2SO4, HCl, HNO3, CH3COOH, and the mixture of these acids (“Acid mix”), were tested. The initial stages of acid weathering involve, apart from chemical dissolution, particularly intense physical detachment of rock particles (granular disintegration) significantly contributing to the total mass loss. Travertine was found to be most prone to salt crystallization damage and to acid weathering, and these features should be taken into account especially in external architectural usage of this stone in cold climate conditions and polluted urban atmosphere. Key words: building stones, travertine, limestone, marble, chemical weathering, acid rain, atmospheric pollution. INTRODUCTION (L) from Morawica (central Poland) and marble (M) from Stronie Slaskie (SW Poland). All these carbonate rocks are Carbonate rocks have been widely used as building commonly used as architectural building and ornamental stones since ancient times, e.g. in Rome and across the materials in Poland and other countries in Central Europe. whole Mediterranean. Carbonates are formed in various Travertine is a sedimentary carbonate rock, with marine and terrestrial environments; therefore, they are macroscopically distinct porosity and parallel banded composed of various amounts of matrix, biogenic and non- structure (bedding). -
Hydrothermal Processes and Mineral Systems Hydrothermal Processes and Mineral Systems
Hydrothermal Processes and Mineral Systems Hydrothermal Processes and Mineral Systems Franco Pirajno Geological Survey of Western Australia, Perth, WA, Australia Foreword by Peter A. Cawood 13 Geological Survey of Western Australia Franco Pirajno Geological Survey of Western Australia 100 Plain St. East Perth WA 6004 Australia [email protected] First published 2009 Reprinted with corrections 2010 ISBN: 978-1-4020-8612-0 e-ISBN: 978-1-4020-8613-7 Library of Congress Control Number: 2008933283 # Springer ScienceþBusiness Media B.V. 2009, 2010 No part of this work may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, microfilming, recording or otherwise, without written permission from the Publisher, with the exception of any material supplied specifically for the purpose of being entered and executed on a computer system, for exclusive use by the purchaser of the work. Cover illustration: Fig. 3.1 in this book. Figure designed and produced by Murray C. Jones. Printed on acid-free paper 987654321 springer.com To my wife Foreword The Earth is a complex and dynamic system that over 4.5 billion years has evolved to form the environment we live in and the resources we depend on. Franco Pirajno’s book ‘‘Hydrothermal Processes and Mineral Systems’’ provides an authoritative and comprehensive overview of hyrdrothermally controlled major mineral resources that have developed in this dynamic system, and where appropriate their links with the development of life and extraterres- trial hydrothermal systems. Discovery and recovery of mineral resources are fundamental to sustaining human society. -
Groundwater Flow Systems in Multiple Karst Aquifers of Central Texas
GROUNDWATER FLOW SYSTEMS IN MULTIPLE KARST AQUIFERS OF CENTRAL TEXAS Brian A. Smith Barton Springs/Edwards Aquifer Conservation District, 1124 Regal Row, Austin, Texas, 78748, USA, [email protected] Brian B. Hunt Barton Springs/Edwards Aquifer Conservation District, 1124 Regal Row, Austin, Texas, 78748, USA, [email protected] Douglas A. Wierman Blue Creek Consulting, LLC, 400 Blue Creek Drive, Dripping Springs, Texas, 78620, USA, [email protected] Marcus O. Gary Edwards Aquifer Authority, 1615 N. St. Mary’s Street, San Antonio, Texas, 78215, USA, [email protected] Abstract hydrogeologic and resource evaluations and modeling of Increased demand for groundwater in central Hays the Middle Trinity Aquifer. County is prompting studies to evaluate the availability of groundwater in the Trinity Aquifers of central Texas. Introduction These aquifers, consisting mostly of limestone, dolomite, With limited surface water, central Texas is fortunate to and marl, exhibit varying degrees of karstification. Near have the Edwards and Middle Trinity karst aquifer systems the surface, karst features such as caves and sinkholes are that provide a variety of groundwater resources. The karstic evident, but are widely scattered. Even at depths greater Edwards Aquifer has been recognized for decades as a vital than 400 m (1,300 ft), units that are mostly limestone show groundwater resource, and thus many studies have been some degree of karstification where dissolution along published from Hill and Vaugh (1898) to recent (Hauwert fractures has caused development of conduits. Studies are and Sharp, 2014) that characterize the nature of the aquifer being conducted to better understand the horizontal and and its groundwater flow system. -
Guidebook to the Geology of Travis County.Pdf (4.815Mb)
Page | 1 Guidebook to the Geology of Travis County: Preface Geology of the Austin Area, Travis County, Texas Keith Young When Robert T. Hill first came to Austin, Texas, as the first professor of geology, he described Austin and its surrounding area as an ideal site for a school of geology because it offered such varied outcrops representing rocks of many ages and varieties. Although Hill resigned his position about 85 years ago, the opportunities of the local geology have not changed. Hill (Hill, 1889) implies the intent of writing a series of papers to describe the geology of the local area for all who might be interested. The authors of this volume hope that they have fulfilled in large measure Hill's original intent. No product can ever be all things to all users, but we have presented here common geological phenomenon for many, including the description of an ancient volcano, the description of faulting that occurred in the Austin area in the past, a geologic history of the Austin area, a description of the local rocks, including their classification, field trips for interested observers of the geologic scene, collecting localities for the lovers of fossils, and resource places and agencies. We cannot emphasize enough that many unique geological phenomena are on private property. Please do not trespass, obtain permission. And if permission is not granted, observe from a distance. There are sufficient areas of geologic interest in the Austin area to please all without antagonizing landowners and making it even more difficult for the next person. Page | 2 Guidebook to the Geology of Travis County: Author's Note A useful guide to the geology of the Austin area has long been a goal. -
Studies on the Mechanisms of Alkali ".'Carbonate Reaction Part I. Chemical Reactions
Studies on the Mechanisms of Alkali ".'Carbonate Reaction Part I. Chemical Reactions W. CULLEN SHERWOOD and HOWARD H. NEWLON, JR., respectively, Geologist and Highway Research Engineer, Virginia Council of Highway Investigation and Research •AN understanding of the mechanisms of alkali-carbonate rock reaction which result in expansion of concrete is of primary importance in dealing with the resultant prob lems on a practical level. This paper reports results of laboratory studies made to determine the contributory chemical reactions that may take place. Results of parallel studies on such physical aspects as internal structure of and access of alkalies into various carbonate rock types are not included, but will be published at a later date. The method of approach has been to consider each of the three major minerals or groups of minerals that normally make up carbonate rocks; i.e., quartz, clays and carbonates. These were investigated through studies of pure minerals, as well as re active and non-reactive rocks, to determine what possible role each might play in ob served expansion in the composite system. These major constituents were analyzed and measured by a variety of methods to determine chemical composition, phase composition, and volume and mass of the ma terials before and after exposure to sodium and potassium hydroxide solutions. (Mass and weight are used interchangeably throughout this paper.) Evidences of reactions noted during this portion of the study were then sought in thin sections, test prisms, and in aggregate from laboratory and field concrete. MINERALS AND ROCKS UTILIZED The calcite and dolomite minerals used in this study were high-purity coarsely crystalline materials.