AP Environmental Science Air Pollution Formulas
4FeS2 11 O 2 2 Fe 2 O 3 8 SO 2 Impurities such as pyrite or iron pyrite are found in coal, when we burn coal it interacts with atmospheric oxygen to form iron oxide and sulfur dioxide (a primary air pollutant).
22SO2 O 2 SO 3 The primary air pollutant, sulfur dioxide, is oxidized, once in the atmosphere, to sulfur trioxide.
SO3 H 2 O H 2 SO 4 Sulfur trioxide dissolves it atmospheric water droplets to form sulfuric acid. Sulfuric acid is a major component of acid rain. Sulfuric acid is considered a secondary air pollutant
SOx The generalized representation of sulfur oxides, whether it be sulfur dioxide or sulfur trioxide. The Sulfur oxides are considered primary air pollutants.
N22 O2 NO Molecules of nitrogen and atmospheric oxygen combine AT VERY HIGH TEMPERATURES to form nitric oxide, a colorless gas. The high temperatures of natural processes like lightening or those of the combustion chambers of an engine are effective in causing this conversion. Nitric oxide is a primary air pollutant
22NO O22 NO Once in the atmosphere, nitric acid reacts with additional oxygen to form nitrogen dioxide, a red- brown toxic gas that causes irritation to the eyes and respiratory system
NO2 H 2 O HNO 3 Further reaction of nitrogen dioxide with water can produce nitric acid, another component of acid rain
Photochemical Smog
N22 O Energy 2 NO Nitrogen oxide is an essential ingredient of photochemical smog that is produced during the high temperatures associated with combustion of vehicle’s engines.
sunlight NO2 NO O Initial reaction of nitrogen dioxide with sunlight
OOO23 The oxygen atom generated from the initial reaction reacts with atmospheric, diatomic oxygen, to form ozone. This is not the good, protective ozone of the stratosphere, this is the polluting ozone of the troposphere, which traps heat and contributes to thermal inversion.
Photochemical Smog (cont)
Hydrocarbons Sunlight O2 CO NOxx O 3 NO Organic Compounds CO 2 H 2 O (auto exhaust/VOC's) (oxidizing agents and irritants)
This simplified equation represents the key ingredients and products of photochemical smog. Hydrocarbons (including VOC’s), carbon monoxide, and nitrogen oxides from vehicle exhausts are irradiated by sunlight in the presence of oxygen gas. The resulting reactions produce a potentially dangerous mixture that includes other nitrogen oxides, ozone, and irritating organic compounds, as well as carbon dioxide and water vapor.
Air Pollution Control and Prevention
SO2 Ca() OH 2 CaSO 3 H 2 O Formula that represents the process of “scrubbing” products of industrial combustion processes. Sulfur dioxide gas is removes by using an aqueous solution of calcium hydroxide, also called limewater. The sulfur dioxide reacts with the limewater to form solid calcium sulfite. Scrubbers that utilize this “wet” scrubbing method can remove up to 95% of sulfur oxides.
SO2 Mg() OH 2 MgSO 3 H 2 O
MgSO32 SO MgO Another process for scrubbing that utilizes magnesium hydroxide instead of limewater. The sulfur dioxide dissolves in the water and reacts with the magnesium hydroxide to form a salt. The magnesium sulfite that is formed can be isolated and heated to regenerate sulfur dioxide. The recovered sulfur dioxide can be collected and used as a raw material in other commercial processes.
Acid Rain
CO2 H 2 O H 2 CO 3 The pH of rainwater is normally slightly acidic, at about 5.6, due mainly to reaction of carbon dioxide with water to form carbonic acid.
SO2 H 2 O H 2 SO 3
SO3 H 2 O H 2 SO 4
2NO2 H 2 O HNO 3 HNO 2 Other natural events can contribute to the acidity of precipitation. Volcanic eruptions, forest fires, and lightning produce sulfur dioxide, sulfur trioxide, and nitrogen dioxide. These gases can react with atmospheric water in much the same way that carbon dioxide does to produce sulfurous acid, sulfuric acid, nitric acid and nitrous acid.
Ozone Formation and Destruction
OOO2 high-energy UVphoton
OOMOM23 As sunlight penetrates into the stratosphere, high-energy UV photons react with oxygen gas molecules, splitting them into individual oxygen atoms. These highly reactive oxygen atoms are examples of free radicals; they quickly enter into chemical reactions that allow them to attain stable arrangements of electrons. In the stratosphere free radicals can combine with oxygen molecules to form ozone. A third molecule, typically nitrogen gas or atmospheric oxygen (represented by M in the equation), carries away excess energy from the reaction but remains unchanged.
OOO32 medium-energy UV photon
OOMOM23 Each ozone molecule formed in the stratosphere can absorb a UV photon with a wavelength of less than 320nm. This energy absorption prevents potentially harmful UV rays from reaching the earth’s surface. The energy also causes the ozone to decomposed, producing an oxygen molecule and an oxygen free radical. These products can then carry on the cycle by replacing ozone in the protective stratospheric layer.
Cl O32 ClO O
ClO O Cl O2
CFC’s (chlorofluorocarbons) are highly stable molecules in the troposphere, however, high-energy UV photons in the stratosphere split chlorine radicals from CFC’s by breaking their C-Cl bond. The freed chlorine radicals are very reactive and can participate in a series of reaction that destroy ozone by converting it to diatomic oxygen. Every chlorine radical that participates in the first reaction can later be regenerated. Thus each chlorine radical acts as a catalyst participating in not just one, but also an average of 100,000 ozone –destroying reactions. In doing so, it speeds up ozone destruction but remains unchanged.