Silver Iodate 1

Total Page:16

File Type:pdf, Size:1020Kb

Silver Iodate 1 SILVER IODATE 1 Silver Iodate a,c-Biladienes with exocyclic rings have been utilized in silver iodate–zinc acetate mediated cyclization.7,8 The reaction of a,c-biladienes bearing six-membered carbocyclic rings with silver AgIO 3 iodate in dimethylformamide followed by demetalation with 5% sulfuric acid in trifluoroacetic acid affords the isolated porphyrin in [7783-97-3] IO3Ag (MW 282.77) 12% yield (eq 3). The syntheses of petroporphyrin bearing a seven- 9 InChI = 1/Ag.HIO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1/fAg.IO3/ membered exocyclic ring, such as C32 15,17-butanoporphyrin qm;-1 and its 3-methyl homolog,10 have been reported by Lash and John- InChIKey = YSVXTGDPTJIEIX-YIVJLXCRCQ son (eq 4).8 Treatment of a,c-biladiene salts with silver iodate and zinc acetate affords desired petroporphyrins via oxidative cycliza- (reagent used as a versatile oxidative amidation and cyclization tion in good yields under mild conditions.5 However, attempts to component) cyclize a,c-biladienes bearing exocyclic rings under other condi- Physical Data: mp >200 ◦C; d 5.53 g cm−3. tions such as copper(II) chloride in dimethylformamide or cop- Solubility: soluble in aqueous ammonia; practically insoluble in per(II) acetate in pyridine result in only trace amounts of the water (0.3 g L−1 at 10 ◦C). cyclized petroporphyrins due to the geometry enforced on the Form Supplied in: white crystalline powder; commercially avail- tetrapyrrolic intermediate by the carbocyclic ring conformation.11 able. It has been shown that the silver iodate–zinc acetate mediated Handling, Storage, and Precautions: irritant; light sensitive; conditions can increase the stability of the cyclizing tetrapyrroles, causes ignition with reducing agents or combustibles; store in resulting in improvement of the cyclization yield.12 cool and dry conditions in well-sealed containers; handle in fume hood. Et 1 Et Oxidative Cyclizations. Like copper(II) acetate and other NH HN metal salts,2 silver iodate has been utilized as an oxidant to AgIO3, Zn(OAc)2 3,4 5 2Br transform a,c-biladienes into porphyrins via cyclization. For CuCl , DMF, rt NH HN 2 example, treatment of an a,c-biladiene containing a free β-position 12% adjacent to the terminal methyl group with zinc acetate and silver iodate delivers the corresponding porphyrin in 31% yield Et Et in dimethylformamide at high temperature (160 ◦C) after the removal of zinc (eq 1). It is necessary to use anhydrous zinc acetate Me Et as a chelating agent to bring the methyl groups in close proxim- N N 1,6 ity and promote the cyclization. In the absence of chelating Cu (2) agents or in the presence of other agents such as magnesium or N N mercuric salts, the cyclization gives low yields under the same conditions. In the presence of copper(II) chloride, silver iodate can also promote the cyclization at room temperature rather than Et the typical harsh conditions involving boiling dimethylformamide (eq 2).3,5 It has been shown that the formation of a stable square Silver iodate has been applied toward the multistep synthesis planar chelate between copper and the a,c-biladiene results in 13,14 the straightforward oxidation to the planar porphyrin.1 of meso- and β-substituted chlorin building blocks. Chlorins provide the basis for plant photosynthesis,15,16 but the unavailability of suitable chlorin building blocks has led to the inevitable use of synthetic model systems that employ sur- Et rogate porphyrins.17,18 A bromodipyrromethane carbinol is prepared by acylation and bromination of a 5-substituted dipyrro- Et methane followed by reduction. Chlorin formation is achieved NH HN 1. AgIO3, Zn(OAc)2 DMF, 160 °C by acid-catalyzed condensation and metal-mediated oxidative cy- 2Br 2. TFA clization. The applied copper-free conditions use zinc acetate, ◦ NH HN 31% silver iodate, and piperidine in toluene at 80 Cfor2htoob- tain the zinc chlorins in around 10% yield (eq 5). These can be easily demetalated to give the corresponding base chlorins. This Et Et general synthetic process is applicable to a range of meso- and Me Et β-substituents (eq 6). The metal-mediated oxidative cyclization NH N of a dihydrobilene results in the final formation of the chlorins. (1) This process proceeds in five steps: oxidation of the dihydrobi- N HN lene intermediate to afford a dihydrobilatriene, imine–enamine tautomerization, metal complexation with a divalent metal ion, carbon–carbon bond formation through an 18π-electrocycli- Et zation,19 and hydrogen bromide (HBr) elimination to yield the Avoid Skin Contact with All Reagents 2 SILVER IODATE final chlorin.13,20,21 Although very little is known of the reactiv- vides the dinaphthoporphyrin in 6.8% yield (eq 7). This low yield ity of the intermediates or the efficacy of the individual reactions, is thought to be due to deleterious steric interactions between the factors that can affect the outcome of this process include choice two naphthalene units. In addition, the purity of the a,c-biladiene of solvent, metal complex, oxidant, temperature, and base. As may also be an important factor.22 described above, silver iodate is more commonly used in the cy- clization of a,c-biladienes and it is believed that silver cations Br facilitate the elimination of bromides during chlorin formation. HN In studies of the cyclization reaction, it has been found that vari- N H 1. TFA, CH3CN, 0 °C ous quinines and oxidants in place of silver iodate do not produce + Ms 2. AgIO3, Zn(OAc)2 the desired product. Similarly, combinations of the oxidants man- N NH piperidine, toluene ganese dioxide and silver iodate in toluene or 1,4-dioxane show 80 °C, 2 h 13,14 no improvement in the yield of the chlorin product. Ts 10% Et N N Zn Ms (5) NH HN N N 1. AgIO3, Zn(OAc)2 2Br 2. H SO , TFA NH HN 2 4 12% Ts Et Et Et NH N HO (3) 1. TFA, CH3CN N HN NH HN 2. AgIO3, Zn(OAc)2 + piperidine, toluene Et Et N HN 80 °C, 2.5 h I 18% Br NH HN 1. AgIO3, Zn(OAc)2 2Br NH HN 2. H2SO4, TFA Et 26% N N (6) Zn Et N N I N HN (4) Oxidative Amidations. The use of silver iodate has been NH N Et reported in the copper-catalyzed oxidative amidation reactions of simple aldehydes and amines.23 After screening a variety of Et copper salts, copper(I) iodide has been determined to be the most effective catalyst to generate the desired amide. Reducing cata- lyst loading results in a significant increase in amide formation. The synthesis of Type E dinaphthoporphyrin systems has been For example, the amidation of benzaldehyde with ethylamine hy- achieved using cyclization of a,c-biladiene intermediates with sil- drochloride gives a quantitative yield under silver iodate mediated ver iodate and zinc acetate.22 While the conventional cyclization conditions (eq 8). A proposed mechanism of the oxidative amida- procedure using copper(II) chloride in dimethylformamide pro- tion with silver iodate and copper(I) iodide includes several steps duces virtually none of the desired porphyrin products, treatment such as deprotonation of amine hydrochloride salts to obtain free with silver iodate and zinc acetate in dimethylformamide results amines, nucleophilic addition to generate carbinolamine interme- in the zinc complex.5,8 Demetalation with trifluoroacetic acid pro- diates, and final oxidation to deliver desired amide products.24,25 A list of General Abbreviations appears on the front Endpapers SILVER IODATE 3 O The addition of a base improves the amidation reaction signifi- CuI, AgIO3 cantly. Although the base has been shown to be critical for the + NH2·HCl Ph H CaCO3, t-BuOOH success of the amidation reaction, it is also the source of unde- MeCN, 40 °C, 6 h sirable side reactions. An insoluble base such as CaCO3 allows 73% clean and successful reactions. O (9) Ph N H O O H CuI, AgIO3 1. AgIO3, Zn(OAc)2 NH HN + EtOCCH2NH2·HCl CaCO , t-BuOOH DMF, 160 °C 3 2Br MeO MeCN, 40 °C, 6 h 2. TFA 78% NH HN 6.8% O O Bu Bu CH COEt (10) N 2 H MeO O CuI, AgIO NH N + 3 (7) Ph H CaCO3, t-BuOOH MeOOC NH2·HCl N HN MeCN, 40 °C, 6 h 91% Bu Bu O (11) Ph N COOMe H O O CuI, AgIO3 1. Johnson, A. W.; Kay, I. T., J. Chem. Soc. 1961, 2418. + EtNH2·HC1 Et (8) Ph H NaHCO3, t-BuOOH Ph N 2. (a) Grigg, R.; Johnson, A. W.; Kenyon, R.; Math, V. B.; Richardson, K., 80 °C, overnight H J. Chem. Soc. 1969, 176. (b) Clarke, D. A.; Grigg, R.; Harris, R. L. N.; 99% Johnson, A. W.; Kay, I. T.; Shelton, K. W., J. Chem. Soc. 1967, 1648. (c) Dolphin, D.; Harris, R. L. N.; Huppatz, J.; Johnson, A. W.; Kay, I. T., J. Chem. Soc. 1966, 30. 3. Smith, K. M.; Kehres, L. A., J. Chem. Soc., Perkin Trans. 1 1983, 2329. The scope of the oxidative amidation reaction includes a 4. Smith, K. M.; Langry, K. C.; Minnetian, O. M., J. Org. Chem. 1985, 49, variety of aldehydes and amine hydrochloride salts. The optimized 4602. reaction conditions entail the use of 1.0 equiv of aldehyde, 1.5 5. Smith, K. M.; Minnetian, O. M., J. Chem. Soc., Perkin Trans. 1 1986, equiv of amine hydrochloride salt, 1.1 equiv of calcium carbonate, 277. 1.1 equiv of tert-butyl hydroperoxide,26 1.0 mol % of copper(I) 6. Cavaleiro, J.
Recommended publications
  • Reproducibility of Silver-Silver Halide Electrodes
    U. S. DEPARTMENT OF COMMERCE NATIONAL BUREAU OF STANDARDS RESEARCH PAPER RP1183 Part of Journal of Research of the National Bureau of Standards, Volume 22, March 1939 REPRODUCIBILITY OF SILVER.SILVER HALIDE ELECTRODES 1 By John Keenan Taylor and Edgar Reynolds Smith ABSTRACT Tests of the reproducibility in potential of the electrolytic, thermal-electrolytic, and thermal types of silver-silver chloride, silver-silver bromide, and silver-silver iodide electrodes, in both acid and neutral solutions, are reported. All of these silver-silver halide electrodes show an aging effect, such that freshly prepared electrodes behave as cathodes towards electrodes previously aged in the solution. They are not affected in potential by exposure to light, but the presence of oxygen disturbs the potentials of the silver-silver chloride and silver-silver bromide elec­ trodes in acid solutions, and of the silver-silver iodide electrodes in both acid and neutral solutions. Except in the case of the silver-silver iodide electrodes, of which the thermal-electrolytic type seems more reliable than the electrolytic or the thermal type, the equilibrium potential is independent of the type, within about 0.02 mv. CONTENTS Page I. Introduetion_ __ _ _ _ __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ __ _ _ _ _ _ __ _ _ _ _ _ _ _ _ _ _ _ 307 II. Apparatus and materials_ _ _ _ _ _ _ _ _ _ _ _ _ __ __ _ _ ___ _ _ ____ _ _ _ _ ___ _ _ _ _ 308 III.
    [Show full text]
  • United States P Patented July 18, 1972
    3,677,840 United States P Patented July 18, 1972 iodide of the invention is obtained in a highly active form 3,677,840 ideally suited for nucleating purposes. PYROTECHNICS COMPRISING OXDE OF SILVER The metathesis reaction proceeds substantially accord FOR WEATHERMODIFICATION USE ing to the following equation: Graham C. Shaw, Garland, and Russell Reed, Jr. Brigham City, Utah, assignors to Thiokol Chemical Corporation, Bristol, Pa. No Drawing. Filed Sept. 18, 1969, Ser. No. 859,165 In accordance with the invention, the pyrotechnic com int, C. C06d 3/00 o position comprises, by weight, the cured product produced U.S. C. 149-19 5 Claims by mixing and curing together from about 0.5% to about 10 20% of oxide of silver; from about 2% to about 45% of an alkali iodate present in about a stoichiometric amount ABSTRACT OF THE DISCLOSURE relative to the amount of oxide of silver present in the A pyrotechnic composition which upon combustion composition; from about 25% to about 75% of a solid in produces mixed silver halide nuclei for use in influencing organic oxidizer selected from the perchlorates and the weather comprises a composition made by curing a mix 5 nitrates of ammonium and of Group I-A and Group II-A ture comprising silver oxide, an alkali iodate, an alkali metals of the Periodic Table; and from about 10% to perchlorate and a curable oxygenated or fluorinated or about 20% of a curable, fluid polymer binder for pyro ganic liquid polymer binder. The composition burns technic compositions, especially a combined-halogen-rich smoothly to provide by metathesis a mixture of silver or combined-oxygen-rich polymer binder, preferably a halides as substantially the only solid or condensed phase 20 polyester-urethane terminated with amine or hydroxyl reaction products, and leaves substantially no residue.
    [Show full text]
  • Maine Remedial Action Guidelines (Rags) for Contaminated Sites
    Maine Department of Environmental Protection Remedial Action Guidelines for Contaminated Sites (RAGs) Effective Date: May 1, 2021 Approved by: ___________________________ Date: April 27, 2021 David Burns, Director Bureau of Remediation & Waste Management Executive Summary MAINE DEPARTMENT OF ENVIRONMENTAL PROTECTION 17 State House Station | Augusta, Maine 04333-0017 www.maine.gov/dep Maine Department of Environmental Protection Remedial Action Guidelines for Contaminated Sites Contents 1 Disclaimer ...................................................................................................................... 1 2 Introduction and Purpose ............................................................................................... 1 2.1 Purpose ......................................................................................................................................... 1 2.2 Consistency with Superfund Risk Assessment .............................................................................. 1 2.3 When to Use RAGs and When to Develop a Site-Specific Risk Assessment ................................. 1 3 Applicability ................................................................................................................... 2 3.1 Applicable Programs & DEP Approval Process ............................................................................. 2 3.1.1 Uncontrolled Hazardous Substance Sites ............................................................................. 2 3.1.2 Voluntary Response Action Program
    [Show full text]
  • Chemical Names and CAS Numbers Final
    Chemical Abstract Chemical Formula Chemical Name Service (CAS) Number C3H8O 1‐propanol C4H7BrO2 2‐bromobutyric acid 80‐58‐0 GeH3COOH 2‐germaacetic acid C4H10 2‐methylpropane 75‐28‐5 C3H8O 2‐propanol 67‐63‐0 C6H10O3 4‐acetylbutyric acid 448671 C4H7BrO2 4‐bromobutyric acid 2623‐87‐2 CH3CHO acetaldehyde CH3CONH2 acetamide C8H9NO2 acetaminophen 103‐90‐2 − C2H3O2 acetate ion − CH3COO acetate ion C2H4O2 acetic acid 64‐19‐7 CH3COOH acetic acid (CH3)2CO acetone CH3COCl acetyl chloride C2H2 acetylene 74‐86‐2 HCCH acetylene C9H8O4 acetylsalicylic acid 50‐78‐2 H2C(CH)CN acrylonitrile C3H7NO2 Ala C3H7NO2 alanine 56‐41‐7 NaAlSi3O3 albite AlSb aluminium antimonide 25152‐52‐7 AlAs aluminium arsenide 22831‐42‐1 AlBO2 aluminium borate 61279‐70‐7 AlBO aluminium boron oxide 12041‐48‐4 AlBr3 aluminium bromide 7727‐15‐3 AlBr3•6H2O aluminium bromide hexahydrate 2149397 AlCl4Cs aluminium caesium tetrachloride 17992‐03‐9 AlCl3 aluminium chloride (anhydrous) 7446‐70‐0 AlCl3•6H2O aluminium chloride hexahydrate 7784‐13‐6 AlClO aluminium chloride oxide 13596‐11‐7 AlB2 aluminium diboride 12041‐50‐8 AlF2 aluminium difluoride 13569‐23‐8 AlF2O aluminium difluoride oxide 38344‐66‐0 AlB12 aluminium dodecaboride 12041‐54‐2 Al2F6 aluminium fluoride 17949‐86‐9 AlF3 aluminium fluoride 7784‐18‐1 Al(CHO2)3 aluminium formate 7360‐53‐4 1 of 75 Chemical Abstract Chemical Formula Chemical Name Service (CAS) Number Al(OH)3 aluminium hydroxide 21645‐51‐2 Al2I6 aluminium iodide 18898‐35‐6 AlI3 aluminium iodide 7784‐23‐8 AlBr aluminium monobromide 22359‐97‐3 AlCl aluminium monochloride
    [Show full text]
  • A Characterization of Mixed Silver Iodide-Silver Chloride Ice Nuclei
    A Characterization of Mixed Silver Iodide-Silver Chloride Ice Nuclei by Paul J. DeMott Department of Atmospheric Science Colorado State University Fort Collins, Colorado A CHARACTERIZATION OF MIXED SILVER IODID~~SILV~R CHLORIDE ICE NUCLEi P~ul J. D~ott Th~s repQrt was pr~pared witp ~upport provid~d by National Sc~ence Founqat~on Gran~ ~TM Y9~~6~04 Prtncipal Investig~tor, LeWlS 0, Grant Department of Atmospheric Science Colorado State Un~versity Fort Collins, Colqrado August 1962 Atwospheric Sci~nce Paper No.3~9 ABSTRACT A new approach and methodology to study the ice nucleation proper- ties of aerosols used for weather modification is introduced in this thesis. This approach and methodology is termed mixed aerosol phase change kinetics and is based on an analogy to chemical reaction kinet- ics. Utlizing this methodology, measurements of the rates of ice cry- stal formation in a cloudy environment by ice nucleating ae,osols, can give inferences to the inter-relationships existing between ice ~u~lea- tion effectiveness, mechanisms for ice crystal formation, and aerosol physical and chemical characteristics. The chemical kinetic methodology is applied to the study of a specific ice nucleating aerosol in the CSU isothermal cloud chamber. This aerosol, mixed silver iodide - silver chloride (Ag! - AgCI), was suspected to be a highly efficient ice nucleus. The mixed Ag! - AgCI aerosols were generated by simple solu- tion combustion methods. The major conclusions in this thesis are the following: a. The analogy to chemical reaction kinetics appears valid for the study of ice nucleation. An analysis of data based on the kinetic methodology produces clear and detailed information about the nucleation process.
    [Show full text]
  • A Method for the Determination of Halogens in Organic Compounds
    METHOD FOR THE DETERMINATION OF HALOGENS IN ORGANIC COMPOUNDS BY JOHN FREDERICK LEMP THESIS FOR THE DEGREE OF BACHELOR OF SCIENCE IN CHEMICAL ENGINEERING COLLEGE OF LIBERAL ARTS AND SCIENCES UNIVERSITY OF ILLINOIS 1917 X Lsrf UNIVERSITY OF ILLINOIS .S^..^r 191. THIS IS TO CERTIFY THAT THE THESIS PREPARED UNDER MY SUPERVISION BY IS APPROVED BY ME AS FULFILLING THIS PART OF THE REQUIREMENTS FOR THE DEGREE OF Instructor in Charge Approved :. HEAD OF DEPARTMENT OF. The author wishes to express his appreciation to Dr. H. J. Broderson for his suggestions and help both in the experimental work and in the writing of this thesis. Thanks are also due Dr. Oliver Kamm, who by supplying pure organic compounds has made the laboratory work possible. TABLE OF 0OIJTSI T TS Page Introduction L Experimental 3 I Plate showing cross-section of the fusion cup used 4 II Description of procedure III Tabulated results 11 Interpretation of Results 14 Summary 15 Bib liography 17 Digitized by the Internet Archive in 2014 http://archive.org/details/methodfordetermiOOIemp INTRODUCTION The growth and the importance of the field of Organic Chemistry has induced a similar growth in the study and the establishment of methods of analysis with which to prove the structures and test the purities of the various compounds. At the present time, however, very few books exist which deal with the systematic analysis of organic substances. Fewer still are the reliable methods of analysis which may be applied to all types of organic compounds. The ;work covered in this thesis deals with several types of compounds containing halogens.
    [Show full text]
  • Chemical Capabilities Listing Laboratory, R&D, Industrial and Manufacturing Applications
    Page 1 of 3 Chemical Capabilities Listing Laboratory, R&D, Industrial and Manufacturing Applications Acacia, Gum Arabic Barium Oxide Chromium Trioxide Acetaldehyde Bentonite, White Citric Acid, Anhydrous Acetamide Benzaldehyde Citric Acid, Monohydrate Acetanilide Benzoic Acid Cobalt Oxide Acetic Acid Benzoyl Chloride Cobaltous Acetate Acetic Anhydride Benzyl Alcohol Cobaltous Carbonate Acetone Bismuth Chloride Cobaltous Chloride Acetonitrile Bismuth Nitrate Cobaltous Nitrate Acetyl Chloride Bismuth Trioxide Cobaltous Sulfate Aluminium Ammonium Sulfate Boric Acid Cottonseed Oil Aluminon Boric Anhydride Cupferron Aluminum Chloride, Anhydrous Brucine Sulfate Cupric Acetate Aluminum Chloride, Hexahydrate n-Butyl Acetate Cupric Bromide Aluminum Fluoride n-Butyl Alcohol Cupric Carbonate, Basic Aluminum Hydroxide tert-Butyl Alcohol Cupric Chloride Aluminum Nitrate Butyric Acid Cupric Nitrate Aluminum Oxide Cadmium Acetate Cupric Oxide Aluminum Potassium Sulfate Cadmium Carbonate Cupric Sulfate, Anhydrous Aluminum Sulfate Cadmium Chloride, Anhydrous Cupric Sulfate, Pentahydrate 1-Amino-2-Naphthol-4-Sulfonic Acid Cadmium Chloride, Hemipentahydrate Cuprous Chloride Ammonium Acetate Cadmium Iodide Cuprous Oxide, Red Ammonium Bicarbonate Cadmium Nitrate Cyclohexane Ammonium Bifluoride Cadmium Oxide Cyclohexanol Ammonium Bisulfate Cadmium Sulfate, Anhydrous Cyclohexanone Ammonium Bromide Cadmium Sulfate, Hydrate Devarda's Alloy Ammonium Carbonate Calcium Acetate Dextrose, Anhydrous Ammonium Chloride Calcium Carbide Diacetone Alcohol Ammonium Citrate
    [Show full text]
  • Precious Metal Compounds and Catalysts
    Precious Metal Compounds and Catalysts Ag Pt Silver Platinum Os Ru Osmium Ruthenium Pd Palladium Ir Iridium INCLUDING: • Compounds and Homogeneous Catalysts • Supported & Unsupported Heterogeneous Catalysts • Fuel Cell Grade Products • FibreCat™ Anchored Homogeneous Catalysts • Precious Metal Scavenger Systems www.alfa.com Where Science Meets Service Precious Metal Compounds and Table of Contents Catalysts from Alfa Aesar When you order Johnson Matthey precious metal About Us _____________________________________________________________________________ II chemicals or catalyst products from Alfa Aesar, you Specialty & Bulk Products _____________________________________________________________ III can be assured of Johnson Matthey quality and service How to Order/General Information ____________________________________________________IV through all stages of your project. Alfa Aesar carries a full Abbreviations and Codes _____________________________________________________________ 1 Introduction to Catalysis and Catalysts ________________________________________________ 3 range of Johnson Matthey catalysts in stock in smaller catalog pack sizes and semi-bulk quantities for immediate Precious Metal Compounds and Homogeneous Catalysts ____________________________ 19 shipment. Our worldwide plants have the stock and Asymmetric Hydrogenation Ligand/Catalyst Kit __________________________________________________ 57 Advanced Coupling Kit _________________________________________________________________________ 59 manufacturing capability to
    [Show full text]
  • Iodato-Silver Complexing Equilibria James Joseph Renier Iowa State College
    Iowa State University Capstones, Theses and Retrospective Theses and Dissertations Dissertations 1955 Iodato-silver complexing equilibria James Joseph Renier Iowa State College Follow this and additional works at: https://lib.dr.iastate.edu/rtd Part of the Physical Chemistry Commons Recommended Citation Renier, James Joseph, "Iodato-silver complexing equilibria" (1955). Retrospective Theses and Dissertations. 15140. https://lib.dr.iastate.edu/rtd/15140 This Dissertation is brought to you for free and open access by the Iowa State University Capstones, Theses and Dissertations at Iowa State University Digital Repository. It has been accepted for inclusion in Retrospective Theses and Dissertations by an authorized administrator of Iowa State University Digital Repository. For more information, please contact [email protected]. U i'% ktAj Title; •lodato-Sllirwr Compl«xing Equllibrlii" / Author: Jamea Joseph R«nl«r (official certification of the classification shown is filed in the Aroes Laboratory Document Library) Signature was redacted for privacy. W. E. Dreeszen Secretary to Declassification Committee UNCLASriHED lOmTO-SILVER COMPLEXING EQUILIBRU by- James J, Renter A Dissertatiffli Submitted to the Graduate Faculty in Partial Fulfillment of The Requirements for the Degree of DOCTCE OF PHILOSOPHT Major Subject* Physical Chemistry Approved! Signature was redacted for privacy. In Charge of Major Work Signature was redacted for privacy. Head of Major Department Signature was redacted for privacy. ]^ian of Graduate College Iowa State College 1955 UMI Number: DP12925 INFORMATION TO USERS The quality of this reproduction is dependent upon the quality of the copy submitted. Broken or indistinct print, colored or poor quality illustrations and photographs, print bleed-through, substandard margins, and improper alignment can adversely affect reproduction.
    [Show full text]
  • SILVER AS a REDUCING AGENT. As Has Been Pointed Out, Silver, in A
    SILVER AS A REDUCING AGENT. BY W S HEXDRIXSON Receired \larch 21, 1903. As has been pointed out, silver, in a finely divided condition, is dissolved by ammonia in the presence of atmospheric oxygen, and it slowly reduces a neutral solution of potassium permanganate.' It occurred to the writer that it might be of interest to study in a systematic and quantitative way the behavior of finely divided silver toward substances that readily give up oxygen, such as chromic, chloric, bromic, iodic and permanganic acids. Thus far the action of silver on chromic, chloric and iodic acids has been studied and the results and related proS!ems are of sufficient in- terest to make the author desirous of studying the subject some- what exhaustively. It is deemed best, in view of the absence of aid and the small amount of time at his disposal, to give some of the results in this preliminary statement and reserve the details for a future communication. Three separate preparations of silver were made, two from the ordinary commercial nitrate, and one, which was used in most of the following experiments, from pure silver obtained by the method of Stas. In each case the silver was precipitated from an alkaline solution of silver oxide by formaline. It was mashed and heated alternately with ammonia and dilute sulphuric acid, and washed until every trace of the acid was removed. The prepara- tions were dried and heated at various temperatures, from 125', in one case, to low red heat in another. Actioii of Sil71ey 011 Chroimk Acid.-A solution of potassium bi- chromate was prepared by weighing the salt which had been ob- tained by crystallizing three times from water the chemically pure salt of commerce, and drying to constant weight.
    [Show full text]
  • Safety Data Sheet CS: 3.4.17
    Safety Data Sheet CS: 3.4.17 Page: 1 of 7 Infosafe No ™ 1CH6J Issue Date : November 2020 RE-ISSUED by CHEMSUPP Product Name :SODIUM METAL Classified as hazardous 1. Identification GHS Product SODIUM METAL Identifier Company Name CHEM-SUPPLY PTY LTD (ABN 19 008 264 211) Address 38 - 50 Bedford Street GILLMAN SA 5013 Australia Telephone/Fax Tel: (08) 8440-2000 Number Emergency phone CHEMCALL 1800 127 406 (Australia) / +64-4-917-9888 (International) number E-mail Address www.chemsupply.com.au Recommended use of Tetraethyl and tetramethyl lead, titanium reduction, sodium peroxide, sodium the chemical and hydride, polymerisation catalyst for synthetic rubber, analytical chemistry, restrictions on use to make sodium salts, reducing agent (ketones), laboratory reagent, coolant in nuclear reactors, electric power cable (encased in polyethylene), non-glare lighting for highways and heat transfer agent in solar powered electric generators. Other Names Name Product Code Natrium SODIUM METAL LR SL074 Other Information Chem- Supply Pty Ltd does not warrant that this product is suitable for any use or purpose. The user must ascertain the suitability of the product before use or application intended purpose. Preliminary testing of the product before use or application is recommended. Any reliance or purported reliance upon Chem-Supply Pty Ltd with respect to any skill or judgement or advice in relation to the suitability of this product of any purpose is disclaimed. Except to the extent prohibited at law, any condition implied by any statute as to the merchantable quality of this product or fitness for any purpose is hereby excluded. This product is not sold by description.
    [Show full text]
  • Medical Laboratory Technician (Chemistry and Urinalysis).(AFSC
    DOCUMENT RESUME ED 272 711 CE 044 810 AUTHOR Thompson, Joselyn H. TITLE Medical Laboratory Technician (Chemistry and Urinalysis). (AFSC 92470). INSTITUTION Air Univ., Gunter AFS, Ala. Extension Course Inst. PUB DATE 85 NOTE 441p.; Supersedes ED 224 891. PUB TYPE Guides - Classroom Use Materials (For Learner) (051) EDRS PRICE MF01/PC18 Plus Postage. DESCRIPTORS *Allied Health Occupations Education; Behavioral Objectives; Biomedical Equipment; *Chemical Analysis; Correspondence Study; Equipment Utilization; *Laboratory Procedures; *Laboratory Technology; Learning Activities; *Medical Laboratory Assistants; *Medical Technologists; Military Personnel; Military Training; Postsecondary Education; Quality Control IDENTIFIERS Air Force; Military Curriculum Materials; *Urinalysis ABSTRACT This four-volume student text is designed for use by Air Force personnel enrolled in a self-study extension course for medical laboratory technicians. Covered in the individual volumes are medical laboratory administration and clinical chemistry (career opportunities, general laboratory safety and materials, general medical laboratory administration, basic chemistry, solutions, photometry and spectrophotometry, automation, quality control in collection and handling of specimens); laboratory procedures in clinical chemistry (body metabolism; proteins, carbohydrates, and enzymes; liver and kidney function tests; gastric analysis;special chemistry tests; toxicology) and laboratory procedures in urinalysis (general considerations, renal functions, physical characteristics
    [Show full text]