A New High Strength Gold Bond Wire
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A NEW HIGH STRENGTH GOLD BOND WIRE Giles Humpston e'r David M. Jacobson, Hrst Research Centre, GEC-Marconi Ltd., Wembley, Middlesex HA9 7PP United Kingdom As semiconductor technology develops, conventional bond wires are reaching the limits of their capability. Industry is demanding finer diameter wire coupled with higher strength, and the retention of this strength at elevated temperatures would be a decided advantage. It has been demonstrated that a fine wire of the composition Au-lwt.%Ti, which was originally formulated for high carat jewellery, can be endowed with these beneficial properties by appropriate thermomechanical treatments. A three-fold increase in the strength of 25 µm diameter wire over that of conventional gold wire has been achieved. The mechanical properties are stable even when the wire is subjected to heating at 400 °C for over a year. Wire based on the Au-1 wt. %Ti alloy can be made comparable to that of the standard gold products in terms of its electrical properties and bonding characteristics. Moreover, it is more resilient to the demands of the fabrication process. 132 Gold Bull., 1992, 25 (4) INTRODUCTION individual wire bond are illustrated schematically in Figure 2. A semiconductor chip connected to its pack- Electronic circuitry normally contains semiconductor age with gold bond wires is shown in Figure 3. chips, which are elaborate miniature circuits processed In TAB, the device is joined using a `gang' bonding in thin slices of silicon or gallium arsenide, typically operation to a set of cantilever beams on a polymeric 1 to 500 mm2 in size. These semiconductor chips are tape (inner lead bonding) and subsequently these beam housed in hermetic packages to protect them from leads are attached to the circuit board or package (outer moisture and mechanical damage. A ceramic package lead bonding). In flip-chip bonding, the silicon chip is containing a chip, before attachment of the lid, is mounted face down and its bond pads are directly shown in Figure 1, Three main methods are used for soldered to those of the substrate. Representative con- making electrical connection between contact pads figurations for these two types of interconnection are on the microchips and the external circuitry, namely shown in Figures 4, 5 and 6 (pages 135, 136), respec- wire bonding, tape automated bonding (TAB) and tively. flip-chip bonding. The principal features of the three interconnection Wire bonding entails using fine wires, typically technologies referred to above are listed in Table 1 33 sm diameter or less, to connect the bond pads on (page 137). Despite the apparent technical merits of semiconductor devices to the headers on their pack- the TAB and flip-chip processes, the wire bonding ages or to the tracks on circuit boards in hybrid assem- method has the commercial advantages of low set-up costs and adaptability to changing com- ponent design. The materials traditionally used for bond wire are gold, aluminium and oc- casionally copper, containing minor ad- ditions of other elements. This choice has been determined by a diversity of re- quirements, not least ot which is the ability to prepare essentially continuous lengths of wire in suitable diameters, which may be as little as 4 µm, by either drawing or extrusion. Gold has special merits as bond wire including good resis- tance to corrosion, high electrical con- ductivity and the relative ease with which it can be bonded into position in an Figure 1 ambient environment by standard mi- A silicon semiconductor chip soldered into a gold meta lised cro-welding techniques. For these rea- recess in a ceramic package. This style of component is sons, more than 90 % of the wire bonds finished by connectingfine gold wires between produced each year are made with gold contact pads on the chip and terminals in the package wire [1], and then soldering a lid on The versatility of wire bonding is likely to ensure that its use will continue and blies. In this method, the bond pads on the devices and even grow for the foreseeable future [2]. Indeed, the the headers on the packages or circuit boards are met- consumption of fine gold wire by the electronics indus- allised with either gold or an aluminium alloy, de- try has increased by roughly 20 % per annum since pending on the intended application of the device. 1970 and, despite the fineness of the product and the The ends of the fine wire interconnect are attached to minuteness of the quantity of gold used in an inter- the appropriate device pad and header by micro-weld- connect (typically 20 µg), sales of gold bond wire ing. The sequence of steps involved in making an exceeded $ 150 million in 1991 [3]. Gold Bull., 1992, 25 (4) 133 Figure 2 The value of fine bond wire is dominated Capillary Wire spoot Schematic illustra- u tool by the manufacturing cost rather than the met- tion of the sequence al content. This is highlighted in Figure 7 _ Gold ofsteps involved in Flame-off (page 138), which shows the price mark-up f balt making a single electrode of precious metal fine wire in relation to gold Packsge interconnect using heoder bullion. Gold wire of 25 tm diameter com- bond wire: Bond pads mands a price that is roughly eight times the bullion price, but this factor rises to almost a hundred for 10 4m diameter wire, reflecting Silicon chip ] ) the technical difficulties in fabricating such Step 1: fine wire and the higher processing costs. This A spark or small Ceramic package explains the relatively small price differential flame is used to Lead between gold, copper and aluminium wire de- locally melt the end of the wire so as to spite the approximate 60,000:6:1 ratio of the form a spherical balt value of the respective metals on a volume basis. that is approximately Toot twice the diameter Balt bond movemeni of the wire LIMITATIONS OF EXISTING Step 2: BOND WIRE MATERIALS The balt is thermo- sonically welded to The functional requirements of bond wire an aluminium metallised pad on the used in semiconductor manufacture are as semiconductor follows: a) High electrical conductivity Step 3: b) Ease of welding a o —^ c) Adequate strength to permït use in mod- A loop of wire is formed as the ern high-speed bonding machines bonding capillary d) Retention of strength during the heating moves across to the liii routines encountered through device contact pad of the packaging and use. device package or circuit board In order to meet these requirements, existing bond wires comprise alloys of gold, alu- Wire loop minium and copper that exploit solid solu- Step 4: tion strengthening and work hardening The wire is thermo- mechanisms to attain adequate mechanical sonically welded to properties. However, this approach is in- the gold metallised II pad of the package creasingly less able to meet the Bemand for finer diameter wires in order to achieve Wedge increased miniaturisation coupled with Step 5: bond boosted rates of production, which means A sharp edge on the using faster mïcrowelding machines. Rapid tool is used to cut the manipulation of the wire imposes signifi- wire, leaving a length cant forces on it; modern automated bond- protruding from the capillary that is of the ing machines can form a wire loop with a correct length to form bond at each end in less than 0.1 second„ the next hall It is perhaps significant that, in recent years, 134 Gold Bull., 1992, 25 (4) tallisat on temperature of the Gold worked microstructure. By a judicious selection of the doping elements, it is possible to in- crease the recrystallisation temperature of gold bond wire up to a maximum of about 350 °C without sign ficantly de- grading its electrival characteristcs [5]. At first sight this might seem adequate but recrystallisation temperature is de- fined as `the temperature at which recrys- tallisation is complete within one hour', This is an insufficiently demanding cri- terion for fine wire interconnects because the wire is often required to maintain its mechanical integrity over a long service life. The aluminium and copper alloys used for bond wire anneal at tempera- Figure 3 tures comparable to those for the gold A close-up view of the gold bond wires ofa silicon chip alloys, so that all commercially available housed in a ceramic package bond wire will soften progressively through the Toss of its work-hardened there has been a tendency to revert to 33 µm diameter microstructure and grain growth. A collation of data wire in place of 25 gm gauge in order to cope with the culled from the literature, presented in Figure 8 (page high stresses imposed on the wire by modern bonding 139), shows that when exposed to temperatures above machines, notwithstanding the requrement for finer 300 °C, conventional gold alloys used for bond wire lose diameter wires consistent with higher interconnect half of their strength in under one hour. densities. Furthermore, ongoing progress in semiconductor technology means that Inner leads bond to the upper operating temperature of de- 0 contact pads on the vices is being progressively raised which semiconductor reduces the need for forced cooling with its associated space and colt penalties. Devices capable of continuous service at 300 °C are currently available and micron valves [4] are likely to be capable of operating in even harsher environ- ments. Pure gold will anneal through Polymeric tape recrystallisation and regrowth of the de- containing sprocket formed grains at temperatures as low as drive holes 100 °C. When the grains grow to dimen- Window throuah which outer lead bond is made sions that are comparable to the diameter of the wire, the strength and fatigue prop- erties of the wire greatly deteriorate.