Geochemical Characterization and “Sourcing” of The

Home , Beezley Hills, Frenchman Hills, Saddle Mountains

GEOCHEMICAL CHARACTERIZATION AND “SOURCING” OF THE

BEEZLEY CHALCEDONY, ROZA MEMBER, COLUMBIA RIVER BASALT

GROUP, WASHINGTON

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A Thesis Presented to the Faculty of the Department of Earth and Atmospheric Sciences University of Houston

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In Partial Fulfilment of the Requirements for the Degree Master of Science

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By Shawn Darrin Larkin May 2015

GEOCHEMICAL CHARACTERIZATION AND “SOURCING” OF THE

BEEZLEY CHALCEDONY, ROZA MEMBER, COLUMBIA RIVER BASALT

GROUP, WASHINGTON

______Shawn D. Larkin

APPROVED:

______Dr. Thomas J. Lapen, Chairman

______Dr. Henry S. Chafetz

______Dr. Brett R. Lenz

______Dean, College of Natural Sciences and Mathematics

Acknowledgements

I express my sincere thanks and appreciation to Tom Lapen, for agreeing to advise me and for putting up with my nonsense throughout this grueling voyage. I thank Henry

Chafetz for serving on my committee and I express my gratitude to Brett Lenz and the

Grant County (WA) Public Utility District for supplying the project from the beginning and for financial support. My deepest appreciation goes to Steve Jensvold for lugging me around the Beezley Hills looking for raw material and for providing so much important background for the field area, for which I am greatly indebted. Also, thanks to Steve and his family for graciously putting me up in their home during field work. My perpetual gratefulness goes to Andy Miner at CWU for digitizing maps and locations, producing data, answering loads of questions and keeping me updated on Beezley Hills background during the compiling of this thesis. I am very grateful to Jinny Sisson for schooling me on the use of the microprobe and providing background on CL measurements, and I am thankful to Peter Anderson who helped me work the microprobe even though I’m sure he had more important things to do. I express my love and gratitude to my parents, Lyle and

Maryann, who have never given up on me, even when I seemed to be accomplishing little. My thanks go to my children, Elijah and Rachel, who are always happy to see me at the end of a long day at school. Lastly, my love and appreciation will always be with my wife, Kimberly, who believes in me even when I do not and who has stuck by me even when things seemed to be going nowhere. Thank you all—I could not have done it without you!

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GEOCHEMICAL CHARACTERIZATION AND “SOURCING” OF THE

BEEZLEY CHALCEDONY, ROZA MEMBER, COLUMBIA RIVER BASALT

GROUP, WASHINGTON

------

An Abstract of a Thesis Presented to the Faculty of the Department of Earth and Atmospheric Sciences University of Houston

------

In Partial Fulfilment of the Requirements for the Degree Master of Science

------

By Shawn Darrin Larkin May 2015

Abstract

The Beezley Chalcedony is a high-quality chert source that occurs in the Beezley Hills, northern Grant County, Washington. Archaeological collections from sites in and near

Grant County are visually similar to the Beezley Chalcedony. This study aims to geochemically characterize the chalcedony source locales material as a context for future comparisons with the Clovis tools. The Beezley Chalcedony formed from Middle

Miocene diatomite-rich lacustrine sediments of the Squaw Creek Member of the

Ellensburg Formation that is situated between the older Frenchman Springs Member and the Roza Member of the Wanapum Basalt Formation, Columbia River Basalt Group.

Laser ablation ICPMS trace element analyses of chalcedony from seven site locations in the Beezley Hills and one in the nearby Quincy Potholes area reveal significant trace element variation for several elements (e.g., Ge, U, V, Y, and Zr). Five locations in the

Beezley Hills display marked spatial variation in trace element concentrations and element ratios. The variations in trace element concentrations may be inherited from the source diatomite and minor shale units in the Squaw Creek Member or are related to element mobility during diagenesis. These trace element variations can be used as tools for linking the artifacts to source locations and for tracking artifact trade routes.

Table of Contents

1 Introduction 1

1.1 Purpose of Study 1

1.2 Statement of Problems 2

2 Geologic Background 4

2.1 Area of Interest 4

2.2 Chert Fundamentals 9

3 Archaeological Background 14

4 Methodology 17

4.1 Field Methodology 17

4.2 Analytical Methodology 18

5 Results 22

5.1 Visual Analysis 22

5.2 Major Element Compositions 22

5.3 X-ray Element Mapping 22

5.4 Cathodoluminescence 25

5.5 Rare Earth Element Composition 25

5.6 Trace Element Composition 29

5.7 Compositional Variation 35

6 Discussion 41 vi

Table of Contents (continued)

6.1 Source of Silica 41

6.2 Redox-sensitive Trace Elements 42

6.3 Spatial Geochemical Variation 42

6.4 Diagenesis 43

7 Conclusions 48

7.1 Conclusions 47

7.2 Recommendations for Future Work 48

8 References 49

9 Appendix – Data Tables 56

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List of Figures

1 Extent of Columbia River Basalt Group, Wanapum Basalt and 5

approximate field area

2 Columbia River Basalt Group stratigraphy near the Beezley Hills, WA 6

3 Map of Grant County, WA, Beezley Hills field area, and Roza member 11

4 Close-up map of Beezley Hills field area, and Roza member 12

5 Clovis-type projectile point examples 15

6 Raw chert boulder from the Ellensburg Formation, Beezley Hills, WA 20

7 Backscatter Electron image and X-ray element maps for site GCPUD008 24

8 Chondrite-normalized Rare Earth Element plot (averaged) for all 26

source locations

9 Trace element concentration plot (average U & Th) for all sites versus 27

published data

10 Trace element concentration plot (average Th & Al) for all sites versus 28

published data

11 Germanium vs zirconium concentration plot for all source locations 32

12 Yttrium vs zirconium concentration plot for all source locations 33

13 Yttrium vs boron concentration plot for all source locations 34

14 Boron/Yttrium vs vanadium concentration plot for all source locations 36

15 Boron/Yttrium vs germanium concentration plot for all source locations 37 viii

List of Figures (continued)

16 Compositional variation plot for selected elements from site GCPUD008 39

17 Compositional variation plot for selected elements from site WP75SJ7 40

18 Selected trace element concentration plot for spatial variation, Ge vs B, 44

Ge vs Y

19 Selected trace element concentration plot for spatial variation, Ge vs Zr, 45

V vs B/Y

List of Tables

1 Percent silica oxide measurements from site GCPUD008 23

Chapter 1: Introduction

1.1 Purpose of Study

Dozens of archaeological artifact sites have been discovered throughout central

Washington State and Grant County, according to the Washington State University

Museum of Anthropology; however very few published articles exist about these sites and where the associated lithic raw material may have been quarried (Daugherty, 1956;

Huckleberry et al., 2003).

Several apparent source locations exist in the Beezley Hills, west of Ephrata,

Washington, in northern Grant County (Lenz 2010). None of the raw material has ever been examined geochemically or otherwise “sourced”. The purpose of this study is to measure the trace element concentrations and geochemically characterize the Beezley

Chalcedony. By providing this information, it is hoped that in the future, artifacts may be traced to the Beezley Hills source and that the data will allow geologists and archaeologists to gain understanding into possible source locations and source travel times (Huckell et al., 2011), distances between mining areas and possible caches (Malik-

Selivanova et al., 1998), or differentiating between visually similar materials (Hoard et al., 1993).

Ancient people around the world have been shaping stone tools for thousands of years. Easily workable material includes obsidian, chert, flint, quartzite, basalt, petrified wood, even bones or shells. Materials that fracture conchoidally are particularly easy to shape by trained workers (called “flintknappers”). Such material can be made into very sharp implements like arrowheads, knives, spear points, or scrapers that may last in surficial deposits for millennia.

Paleoindian people frequently did not settle in places where necessary resources occurred. To obtain such materials, trade routes were established. These trade routes were sometimes hundreds of kilometers in length (Healy et al., 1984). In order to distinguish materials that are visually similar but may have been quarried in different locations, geologists must examine the geochemistry of each artifact and match it to the geochemistry of known source-material. These provenance analyses, or artifact

“sourcing,” give workers copious information used to decipher trade routes, procurement strategies, economic conditions, agricultural practices, and daily habits.

1.2 Statement of Problems

As stated above, no geochemical work has ever been performed on the Beezley

Chalcedony to date. This material, clearly workable and of high quality, may well have been used, carried, and traded far from the source locations in the Beezley Hills. As evidenced by the multiple archaeological sites discovered in these areas, many communities of paleoindians were in existence in central Washington in prehistoric times, according to data in possession of the Washington State University Museum of

Anthropology. Since chalcedony, a type of chert, can be up to 99% silica (Malik-

Selivanova et al., 1998), the minor and trace element geochemistry of an artifact largely determines the “chemical fingerprint” used for comparison to known source-materials.

The Beezley Hills may include archaeological sites and are therefore protected by state and federal statutes. As such, the disclosure of the precise locations of the locales is discouraged. This presents a conflict with regards to scholarly research, as disclosure of locations is generally necessary to ensure reproducibility of data and academic transparency. Compromises were reached in the course of this study which allowed for

2 the satisfaction of both legal preservation and scholarship, as no locations are disclosed here, only a general field area.

Chapter 2: Geologic Background

2.1 Area of Interest

The Columbia River Basalt Group (CRBG; Figure 1) is a Large Igneous Province produced during flood basalt events between about 17 to 6 Ma (Carson and Pogue, 1996).

The lava flows produced during these volcanic events covered large parts of Washington, northern Oregon, and some parts of Idaho, covering approximately 164,000 km2 (Martin,

1989). The stratigraphy of the CRBG (Figure 2) is well established (McDougall, 1976,

Swanson et al., 1979, Tolan et al., 1989, Hooper, 1997). Four main formations exist within this province: the Imnaha Basalt (17.6 Ma), Grande Ronde Basalt (16.5 Ma),

Wanapum Basalt (15.6Ma), and Saddle Mountains Basalt (14 Ma) (Carson and Pogue,

1996, Hooper 1997, Barry et al., 2010). The Beezley Chalcedony occurs within sedimentary interbeds between flows of the Wanapum Basalt.

Many flood basalts in the CRBG exhibit a typical stratigraphic and structural profile. Due to cooling joints in the extruded lava, several structures and macro-scale textures are present in an idealized flow structure in the Columbia River Basalt Group.

At the base of the flow, a pillow basalt zone may co-exist with a palagonite complex.

Above these structures are colonnades, sometimes called the basal or lower colonnade

(Long and Wood, 1986). The colonnade is composed of jointed, polygonal blocks of basalt that form during cooling and contraction (Lindberg, 1989). An entablature, consisting of smaller polygonal columns that may be oriented randomly within the flow structure, rests on top of the lower colonnade. This portion of the flow structure stratigraphy may constitute as much as two-thirds of the total flow thickness (Long and

Figure 1: Columbia River Basalt Group extent (blue), Wanapum Basalt extent (green), approximate location of field area (red), modified from Tolan et al., 1989.

Figure 2: Columbia River Basalt Group stratigraphy near the Beezley Hills, Wa, with approximate thicknesses, modified from Andy Miner, CWU, (pers. comm.).

Wood, 1986). Near the top of the flow lies an upper colonnade, which is usually better developed structurally than the lower colonnade. The upper colonnade may or may not grade into a vesicular flow top at the uppermost portion of the flow. These fractures within the flow allow for significant ground water circulation.

The Roza Basalt Member is a constituent of the Wanapum Basalt Formation

(Figure 1) within the CRBG and is estimated to be between 14.5 and 15.3 million years old (Martin, 1989). The Miocene-age Roza Member covers just over 40,000 km2 of

Oregon and Washington (Mackin, 1961). The Roza “is characterized by the presence of single lath-like plagioclase phenocrysts, which distinguish it from flows of the underlying

Frenchman Springs Member and from most other flows in the Columbia River Basalt

Group” (Martin 1989, p. 86).

Sedimentary rocks of the Ellensburg Formation (Smith, 1903) are intercalated with the basalt flows of the CRBG. These Miocene to Pliocene units consist of diatomite, siliceous mudstones, sandstones, and conglomerates associated with paleodrainages and lakes as well as volcaniclastic units consisting of lahars and air-fall tuffs derived from the nearby Cascade Range (Smith, 1988). At the base of the Roza Member of the CRBG are rocks dominated by diatomite with lesser fine silt and sand and these have been defined as the Squaw Creek Member of the Ellensburg Formation (Mackin, 1961). In and near the study area, the Squaw Creek Member is composed of diatomite that is overlain by a coarsening-upward sequence of laminated siltstone, cross-stratified sandstone, and pea- gravel conglomerates (Mackin, 1961; Smith, 1988). Paleogeographic reconstructions during deposition of the Squaw Creek indicate basalt flows of the Frenchman Springs

Member of the CRBG blocked the paleodrainage of the Columbia River and produced a

7 series of lakes (Mackin, 1961) that deposited diatomite, fine sand, and silt over much of the study area (Smith, 1988). The coarsening-upward sequence of sandstone and pebble conglomerate indicates a transition in sedimentation from lacustrine to fluvial facies. The diatomite of the Squaw Creek Member is the source material that formed the Beezley

Chalcedony.

The Quincy Diatomite, a local name for diatomite that occurs above the Roza

Member (Mackin, 1947), is likely related to rocks of the Squaw Creek Member. Both deposits are largely lacustrine in origin, but the extent of the Quincy Diatomite is restricted to a series of outcrops near Quincy, Wa (Mackin, 1947 and Smith, 1988). The nature of the contact relationships and the presence of Roza basalt apophyses into the overlying diatomite suggest that sections of the Squaw Creek were rafted by the Roza

Member as it flowed over and intruded into the lacustrine sediments. In this study, diatomite and associated chalcedony of the Quincy Diatomite are interpreted to be equivalent to that of the Squaw Creek Member of the Ellensburg Formation.

Superimposed on much of the CRBG stratigraphy is the Yakima Fold and Thrust

Belt, a generally ESE-WSW trending fold and thrust belt with alternating synclinal valleys and anticlinal ridges (Reidel, 1984). The roughly 16-4 Ma fold belt (Reidel et al.,

1989; T. Lapen, pers. comm.) extends from Horse Heaven Hills in the south to the

Frenchman Hills and Beezley Hills in the north. The folding was caused by N-S regional shortening that resulted in many repetitions of syncline-anticline couplings that extend from the western Columbia Plateau into the Cascade ranges (Carson et al., 1987). Some surface geological maps of the area indicate coverage of the hills by Quaternary colluvium (Grolier and Bingham, 1971).

The Beezley Hills (Figures 3 and 4) are located west of Ephrata, in central

Washington State, just north of Interstate 90 and are on the extreme northwestern arm of the Yakima Fold Belt. The study area within the Beezley Hills in reference to this thesis comprises slightly less than 38 km2. The surrounding area is mostly low rolling hills and farmland. Siliceous material very similar to the Beezley Chalcedony was also collected from the Quincy Potholes, near the Columbia Basin Wildlife Area, roughly 40 km from the Beezley Hills field area (Figure 3).

The Squaw Creek Member where the Beezley Chalcedony is located is poorly exposed in the Beezley Hills. The chalcedony is not exposed on the surface, although some large pieces of unworked material have been observed. The chalcedony is not known to exist anywhere else (S. Jensvold, personal comm.).

2.2 Chert Fundamentals

The microcrystalline and non-crystalline forms of silica (e.g., chert) are complex and not easily classifiable, as classification frequently requires microscopic examination.

The term “chert” has, in the past, commonly been used to lump together many macroscopically similar but microscopically and geochemically dissimilar rocks. Due to the variations within the rock termed “chert”, some clarification is necessary.

Chert is a common, very fine-grained, quartz-rich chemical sedimentary rock, usually of microcrystalline or cryptocrystalline form. Chert is frequently dense and may be non- detrital in origin (Boggs, 2009). Chalcedony is a type of chert consisting of fibrous quartz (giving the chalcedony its commonly waxy luster) and microscopic intergrowths of α-quartz and the quartz polymorph moganite (Moxon and Reed; 2006, Rapp, 2009).

Chalcedony also incorporates small amounts of water into its crystal structure, from one

9 to two weight percent (Graetch, 1985; Moxon and Reed, 2006). Agate is a common form of banded chalcedony, usually with a wide variety of color, and also can include water and other mineral inclusions (Götze et al., 2012). Chert and chalcedony fracture conchoidally, due to their nearly amorphous molecular structure. Relative to many other materials, SiO2 is fairly resistant to physical and chemical weathering. These physical and chemical properties, and the easily shapeable nature of chert, contribute to the durability of the material, and make it especially attractive for use in tool-making.

The amorphous forms of silica undergo a general diagenetic progression as follows: Opal-A → Opal-CT → Mixed Phases (Opal-CT, Opal-C, microcrystalline quartz) → Microcrystalline Quartz → Crystalline Quartz (Lee, 2005). The opaline forms increase in size and crystallinity as the diagenetic transformation occurs, “with the initial opaline [silica] gel converting to crystalline quartz” (Lee, 2005, p. 2). Mechanism of formation also influences diagenetic formation or alteration. Opal-A is generally biogenic in origin and is the least structured of the opal silicate forms (Hesse, 1988; Lee,

2005; Boggs, 2009). Opal-CT has undergone a greater amount of diagenetic transformation than opal-A and is consequently more ordered in structure. The “CT” refers to cristobalite and tridymite (two low pressure, high temperature quartz polymorphs), respectively. As diagenetic alteration increases, opal-CT is intermixed with opal-C and some microcrystalline quartz (Lee, 2005). Finally, microcrystalline quartz emerges after diagenetic conversion and crystal size increase.

Figure 3: Map of Grant County, Washington (outline), Beezley Hills field area (white), and Roza member (blue) with landmarks. Data from Andrew Miner (PANGA at CWU), Steve Jensvold (Jensvold GeoConsulting), and the public domain.

Figure 4: Close-up map of Beezley Hills field area (white), Roza member (blue), and Grant County (red) boundary. Data from Andrew Miner (PANGA at CWU), Steve Jensvold (Jensvold GeoConsulting), and the public domain.

Quartz is the dominant mineral in chert, and because of this diagenetic pathway, other silicate minerals may be present, such as opal-A (amorphous silica), opal-CT

(disordered cristobalite and tridymite), and opal-C (a less disordered form of opal-CT), although opal is technically classified as a “mineraloid” due to its lack of a regular internal structure (Lee, 2005 and Boggs, 2009).

More basic solutions (high pH) will generally yield more dissolved silica.

According to Williams and Crerar (1985, p. 313), “Monomeric silicic acid, H4SiO4, is the predominant aqueous species in undersaturated silica solutions. This is a weak acid…Therefore, as a solution becomes more basic, silica solubility increases.” Also, like all chemical species, quartz precipitation/dissolution is sensitive to temperature and pressure differences. As temperature of the solution increases, so does the solubility of quartz in aqueous solution. The temperature of the solution has an exponential effect on solubility (Williams & Crerar, 1985; Williams et al., 1985; Hesse, 1988,).

The Beezley Chalcedony may have formed from the mobilization of silica from the Squaw Creek Diatomite. As the Roza flows covered the pre-existing lacustrine sediments in the area, the heat from the flows may have allowed the silica to increase in crystallinity and advance in diagenetic alteration, eventually forming the chalcedony as it is today.

Chapter 3: Archaeological Background

Ancient humans made stone tools for thousands of years before the present. One geoarchaeologist noted “Humans learned early that some kinds of rocks were far better than others for chipping into tools. These turned out to be high-silica rocks that broke with a conchoidal fracture.” (Rapp, 2009, p. 69) These include such rocks and minerals as obsidian, and chert and its many variants, although other minerals and rocks have been used that do not exhibit conchoidal fracture but are nonetheless shapeable and durable, such as basalt and quartzite.

The Clovis paleoindian culture is generally agreed to have existed roughly between 13,110 and 12,760 radiocarbon years before the present (Waters and Stafford Jr.,

2007), so named for some of the first tools of this type found in Clovis, New Mexico,

U.S.A. These natives of the North American continent, believed to have been the first native human inhabitants here, lived during the late Pleistocene (Haynes, 2009). The most distinctive and obvious evidence of the Clovis Americans is the stone tools they left behind, specifically arrow points, bifaces, and spear points (Figure 5). The Clovis culture in the Americas ended roughly around the end of the Pleistocene (~12,000 years before present).

Different areas will naturally yield more abundant materials for tool-making and this may be reflected in the types of tools found in those areas. However, since not all types of raw material are present in a given area, ancient native inhabitants frequently established trade routes, some quite extensive (Nelson et al., 1977). Since the

Washington State University Museum of Washingtonof StateMuseum University

modified from from modified

type projectile point examples. A = Winchester cache, Wasteway B A point Winchester = = type examples. projectile

Anthropology. Figure 5:Figure Clovis cache, Lind Coulee

geographical extent of these trade routes can be enormous, determining the source of the raw material is crucial to determining “provenance” or the location of origin.

Present-day Native American tribes/nations in the Grant County, Washington area include the Yakama, Wenatchee, Wanapum, Umatilla, Kittitas, Colville, and Spokane tribes and nations, among others (Sturtevant, 1990). The producers of the Beezley

Chalcedony were likely ancestors of many of these groups, although determining an exact descent would be nearly impossible. Many scholars simply use the term

“paleoindian”.

Chapter 4: Methodology 4.1 Field Methodology

Field work in the Beezley Hills and Quincy Potholes was conducted between

April 29, 2014, and May 1, 2014. The Beezley Hills cover several square kilometers within Grant County but only a small portion was searched for raw lithic material. More than eight known distinct source locations were visited during this time (GCPUD003,

GCPUD004, GCPUD008, WP52SJ5, WP54SJ4, WP63SJ1, WP75SJ7, and WP114SJ2A).

Locations were obtained through the Grant County Public Utility District and are not disclosed here due to state and federal laws governing potential archaeological artifacts and sites that may exist within the source area. Chalcedony and chert raw material samples were collected based on texture, color, and size to reflect a representative sampling, then placed in numbered plastic bags indicating location and date.

Samples of Quincy Diatomite were collected just north of Frenchman Coulee and

Interstate 90, near Vantage, Washington, as a possible silica source for the Beezley

Chalcedony. Some samples of petrified wood were also collected near Vantage as a potential silica source for comparison. Samples of Squaw Creek Diatomite were collected at Quincy Potholes for the same purposes as the Quincy Diatomite, but neither the Quincy nor the Squaw Creek were used in this thesis, nor was the petrified wood.

Outcrops of the Beezley Chalcedony were not observed in the source area locations visited during field work; material in the field consisted of float. One large boulder of raw material was photographed (Figure 6) but it is unknown whether this was an outcrop in situ or also float. Raw chert material consists of numerous lithic fields

(possibly debitage, although differentiating between naturally and culturally modified

17 materials is difficult in the source area) scattered throughout the hills. The siliceous layer has been in large part covered in loess and only material that is present on bedrock benches, on lithosols or that may have been worked by former inhabitants is extant.

Much of the high quality raw material collected is visually similar to artifacts in possession of Washington State University’s Museum of Anthropology, both from the

Winchester Wasteway site (about 25 km distant) and the Lind Coulee site (about 50 km distant).

4.2 Analytical Methodology

Raw chert was cut into millimeter- to centimeter-sized pieces using a Buehler

Isomet low speed saw with a 4 inch diamond-tipped wafering blade. This was done to ensure proper size and smooth surface features. Several pieces were cut from each field site. Cut samples were mounted in epoxy resin within 1-inch cylindrical plastic blanks in preparation for geochemical evaluation. Sixteen grain mounts were made from fifteen different lithic field locations in the Beezley Hills. Once the epoxy was set, each mount was polished to a visibly smooth surface. Each grain mount was cleaned using deionized water, in an ultrasonic bath for 15 minutes, to remove any dirt, fibers, or remaining abrasive material. Two mounted samples were analyzed using a Cameca SX50 electron microprobe with the SAMx computer automation and analysis software package at the

University of Houston. Prior to electron probe microanalysis, samples were coated in a thin carbon coating. The microprobe was calibrated before analysis using standards for quartz. Several spot samples were analyzed on grains from location GCPUD008 to confirm the samples are predominantly quartz.

X-ray element mapping was performed on one section of a grain from

GCPUD008. Elements set for preliminary detection included Mn, Mg, and Fe.

However, the chalcedony fragments are chemically (in terms of major elements) and structurally homogenous, so very little variation was observable in scales greater than a few microns. Element mapping was subsequently abandoned.

Cathodoluminescence analysis was also performed using the cathodoluminescence (CL) detector on the UH microprobe to search the samples for structural features, chemical abnormalities, or obvious defects in the crystal lattice.

Accelerating voltage was ~20 kV, with a beam current of ~10nA. Beam spot size was roughly 10 µm. Very little CL response was observed and the microprobe’s magnification was not sufficiently wide enough to image entire grains in a timely manner, so further cathodoluminescence analysis was discontinued. Each sample was then analyzed for major and trace element concentrations (including rare-earth elements) on a Varian 810 Inductively-Coupled Plasma Mass Spectrometer (ICP-MS), connected to a Photon-Machines Analyte.193 Laser Ablation unit. Analytical procedures on the ICP-

MS were performed similar to Hui et al., (2011). The spectrometer was set up and allowed to stabilize for thirty minutes prior to use. During analysis of each grain, two measurements each of 2 USGS standards (BHVO-2 and BIR-1) were performed, followed by up to ten spot samples with the laser (Govindraraju, 1994). Following these analyses, 2 measurements each of the standards were repeated, followed by any remaining necessary spot samples. These procedures were repeated for all subsequent samples to maintain accuracy and for calibration.

Figure 6: Raw chert boulder from the Ellensburg Formation the infrom Ellensburg the 6:Figure boulder Raw chert & 10 = Washington.Hills, cm whiteBlack Beezley arrow

Isotopes analyzed by the ICPMS are: 7Li, 11B, 23Na, 25Mg, 27Al, 39K, 49Ti, 51V, 53Cr,

55Mn, 56Fe, 59Co, 60Ni, 65Cu, 66Zn, 71Ga, 72Ge, 88Sr, 89Y, 90Zr, 118Sn, 121Sb, 137Ba, 139La,

140Ce, 141Pr, 146Nd, 147Sm, 151Eu, 157Gd, 159Tb, 163Dy, 165Ho, 167Er, 169Tm, 173Yb, 175Lu,

181Ta, 182W, 204Pb, 206Pb, 207Pb, 208Pb, 232Th, and 238U. Silicon was used as an internal standard. Laser spot size was set to either a 64.1 µm or 83 µm circle, with a repetition rate of 20 Hz and a total laser shot count of 320 to 400 shots. Background signals were recorded for 20 seconds, followed by 40 seconds of signal obtained from the ablated material in the sample of interest. The trace element data detected on the Varian 810 were reduced using the GLITTER data reduction software package, which was developed for LA-ICPMS data reduction (van Achterbergh et al., 2001).

Trace element data were graphed on bivariate plots, sometimes with element ratios to further constrain site-to-site variability, using many trace elements exhibiting significant variations in concentration. The plots were then examined for correlations or patterns to determine if each graph revealed a geochemical “signature” unique to a specific site location or source. Plots were also examined for chemical variation with reference to distance between sites.

Chapter 5: Results

5.1 Visual Analysis

A very diverse range of rock colors was observed and collected: white to dark brown, red, orange, yellow, purple and many gradations within these end members including colorless. Luster of the samples was variable, with many locations having material exhibiting a waxy luster characteristic of chalcedony. A few samples from different lithic fields exhibited a somewhat greasy to pearly luster, probably due to opalization of quartz. Many unremarkable samples display a dull luster. A few samples display a botryoidal texture and fewer than five samples have noticeable, well developed euhedral quartz grains. Diaphaneity ranged from opaque to translucent and almost nearly transparent. None of the individual pieces displayed any characteristic that would be useful for distinguishing it from other relevant silica sources.

5.2 Major Element Compositions

Elemental analysis of all spot samples on location GCPUD008 using the electron microprobe (Table 1) revealed that the average composition of the grains is just less than

97% SiO2, confirming the identification of the material as quartz or a quartz variant

(Flörke et al., 1982).

5.3 X-ray Element Mapping

X-ray element mapping revealed very little due to the homogeneity (both chemically and structurally) of the fragments (Figure 7). Manganese, magnesium, and iron were set for detection and small iron-rich inclusions were seemingly abundant in this section of the sample. Brightly colored banding (especially as observed in the map for

Sample - Spot Ox%(Si) Ox%(Fe) Ox%(Mg) Ox%(Al) GCPUD008-1 95.14 0.0149 bdl bdl GCPUD008-2 95.77 0.0445 0.0168 0.0251 GCPUD008-3 98.57 0.0336 0.022 0.0609 GCPUD008-4 96.73 bdl 0.0182 0.0267 GCPUD008-5 97.21 0.0351 bdl bdl GCPUD008-6 98.52 bdl 0.008 0.0058 GCPUD008-7 95.62 0.0186 bdl 0.0144 GCPUD008-8 96.48 0.0241 bdl 0.0582 GCPUD008-9 96.23 0.0246 bdl 0.0528 GCPUD008-10 98.31 0.1202 bdl 0.1224 GCPUD008-11 98.66 0.0489 0.008 0.0875 GCPUD008-12 96.74 0.0074 0.013 0.1493 GCPUD008-13 96.85 0.0585 0.016 0.0841 GCPUD008-14 97.32 0.137 0.0211 0.1034 GCPUD008-15 95.74 0.0507 0.0056 0.1107 GCPUD008-16 96.13 bdl 0.0108 0.0022 GCPUD008-17 95.52 0.0075 0.0159 0.0348 GCPUD008-18 96.18 bdl bdl 0.0183 GCPUD008-19 96.05 0.0539 0.0121 0.0238 GCPUD008-20 95.42 0.0352 0.0079 0.023 GCPUD008-21 94.35 0.056 bdl 0.0456 GCPUD008-22 95.69 0.0093 bdl 0.0058 GCPUD008-23 96.37 bdl bdl 0.0271 GCPUD008-24 98.46 0.0188 0.009 0.0716 GCPUD008-25 94.86 0.0261 0.0159 0.0325 GCPUD008-26 96.83 0.0244 bdl 0.0211 GCPUD008-27 97.08 bdl 0.0174 0.0554 GCPUD008-28 97.98 bdl bdl 0.0789 GCPUD008-29 96.89 bdl bdl 0.0474 GCPUD008-30 98.55 0.0225 0.0178 0.0792 GCPUD008-31 96.44 0.0167 0.0116 0.0137 GCPUD008-32 98.23 0.0168 0.0033 0.0462 GCPUD008-33 95.89 0.0169 0.0042 0.0393 GCPUD008-34 97.07 0.0318 0.0107 0.0138 avg Ox% Silica = 96.70 bdl = below the detection limit

Table 1: Oxide percent measurements from a grain from location GCPUD008, confirming the material as a quartz variant.

Figure 7: Backscatter Electron (BSE) image and X-ray element maps for a sample from site GCPUD008, analyzing Mg, Mn, and Fe. Scale bar = 200 microns.

24 magnesium) is not a positive x-ray response but an artifact of the microprobe’s spectrometer movement. This can also be seen less strongly in the x-ray map for iron.

5.4 Cathodoluminescence

Cathodoluminescence revealed very little in terms of compositional or major element variation within the samples analyzed (GCPUD003, GCPUD008). Because of the homogeneity of the samples, no major growth bands, zoning, or lattice defects were visible at this scale. According to Rusk et al. (2011, p. 703), “Few studies clearly illustrate the distribution of trace elements in quartz via element mapping…because most other elements in quartz are not present in high enough abundance to be mapped by electron microprobe”. This is consistent with results for sample GCPUD008. Götze et al. (2001) state that this phenomenon is likely due to the lack of incorporation of

“activator” elements in quartz returning a CL response, as the incorporation of such elements in quartz is small.

5.5 Rare Earth Element Composition

Rare earth element (REE) concentrations were normalized to chondrite values reported by McDonough and Sun (1995) utilizing the GLITTER data reduction package.

These concentrations were then plotted for each sample location (Figure 8). REE results generally revealed flat patterns relative to chondrite, although concentrations varied between location sites by as much as five orders of magnitude, much higher variation than the variation in SiO2 concentrations used for internal normalization during data reduction. No statistical overlap occurs in terms of average concentration, with the

ondrite. ondrite.

ch Figure 8: Averaged rare earth elements (REE) normalized to (REE) normalized earth rare elements 8:Figure Averaged

Figure 9: Trace element concentration (average thorium and uranium), in parts per million, of all site locations versus published data.

Figure 10: Trace element concentration (average thorium and aluminum), in parts per million, of all site locations versus published data.

28 exception of locations GCPUD003 and WP63SJ1, which have similar signatures.

Location WP75SJ7 is generally Light Rare-Earth Element (LREE) enriched (La/Lu =

4.21) but not significantly. Similar signatures are observed in sites WP52SJ5 and

WP114SJ2A but with slight enrichments in Heavy Rare-Earth Elements (HREE) toward lutetium—(La/Lu = 1.19 and 1.98, respectively).

HREE enrichment is observed in sites GCPUD004 and GCPUD003 (La/Lu =

0.119 and 0.349, respectively) but similar in intensity to the LREE enrichments of the former sites. Three sites (WP54SJS4, WP63SJ1, and GCPUD008) display a “2-tailed”

REE signature, slightly enriched in both LREE and HREE, from lanthanum to lutetium.

Sites GCPUD003, GCPUD004, GCPUD008, WP52SJ5, and WP75SJ7 show a negative europium anomaly, although only slightly lower in concentration than proximal elements. Site WP114SJ2A shows no anomaly whatsoever (probably indicating its difference in location) and sites WP54SJS4 and WP63SJ1 show a slight positive europium anomaly. Every site location sampled shows a slightly positive gadolinium anomaly with site GCPUD008 showing the steepest variance. Similar Gd anomalies have been reported for Archean cherts (Allwood et al., 2010; Ledevin et al., 2015) as well as significant positive Gd anomalies in seawater (de Baar et al., 1985) prior to the significant input of anthropogenic Gd that started with the FDA declaring that it was safe to use as a contrasting agent for MRI procedures in 1988. This same site also shows a lone holmium anomaly, which is likely an outlier.

5.6 Trace Element Composition

Due to the SiO2-dominant composition of chert, significant chemical variations between samples must be constrained from the trace (or minor) element concentrations. 29

The Beezley Chalcedony is no different and demonstrates significant variation of many trace elements. Concentrations of analyzed elements can be found in Appendix 1.

In comparison to other published studies (Figures 9 and 10), the data from all site locations are variable enough from source to source to discriminate based on several minor elements (even drawn with arbitrary fields) including U vs Th, and Th vs Al.

Some overlap is expected, especially considering the study done by Cackler et al. (1995) specifically included chalcedony, not just the more general “chert”.

Trace element variation between site locations is also highly variable, even within short distances between sites. Relatively discrete groupings of site locations can indicate a distinguishable geochemical source for the suite of trace elements comprising each sample. Six elements in particular (Ge, Zr, Y, B, V, and U) are useful for preliminary sorting. These exhibit significant variation within the field area, and show some discrete groupings when plotted against each other, whereas others do not.

Zirconium exhibited marked variation within the field area, and even within some site locations. This is likely due to zirconium’s high valence charge and its general incompatibility in the mineral solid phase. Site GCPUD008 has far lower concentrations of zirconium than most other sites. This lower concentration for GCPUD008 may be useful in initial sorting of artifacts or raw material (Figures 11 and 12). Plotting germanium versus zirconium (Figure 11) reveals significant groupings of locations

GCPUD008, WP114SJ2A, WP63SJ1, and possibly WP52SJ5 and GCPUD003, although some clear overlap may exist within the latter two sites.

Yttrium behaves very similarly to the lanthanides, particularly Ho and other heavy

REEs. GCPUD008 again displays noticeably lower concentrations of yttrium when

30 plotted along with zirconium (Figure 12). Zirconium and yttrium appear to have a nearly linear relationship on this plot. When plotted against boron, the behavior of the two is not grouped nearly as closely as with other selected elements (Figure 13). However, site

GCPUD008 again displays characteristic separation from the other sites. Site

GCPUD003 has some small overlap with GCPUD004 but the groups may be distinguishable, depending on the element selected for comparison.

Uranium can be readily incorporated into chert, having concentrations in the 10 ppm range, or even higher (Götze et al., 2001; Matteson et al., 2005). The samples from the Beezley Hills and Quincy Potholes contain somewhat lower concentrations of uranium in the 0.1 to 10 ppm range (see Appendix 1). Uranium, a redox-sensitive element, can exist in its most common oxidation state of U [VI] or the generally insoluble

2+ U [IV]. The more highly oxidized form of UO2 (the uranyl ion) is soluble at high pH

(Hem, 1985). The levels of uranium in the Beezley Hills Chalcedony fall into a somewhat narrow range of concentrations, spanning only a few orders of magnitude, although uranium concentrations in one site (GCPUD003) fall well below the other sites.

Gotze et al. (2001) indicates that no structural incorporation of uranium is possible in agates, and that the element is probably present adsorbed as uranyl complexes or bound to microinclusions. Germanium sits directly below silicon on the periodic table and has similar atomic radius and valence charge. It substitutes readily for Si into the quartz crystal structure. Vanadium is a redox-sensitive element (Chang et al., 2009) that may indicate active redox processes. Vanadium exists in three oxidation states: V [III], V

[IV], and V [V] and due to this peculiarity its geochemical properties in natural waters

Figure 11: Germanium versus zirconium concentrations for all all for concentrations versus zirconium 11: Germanium Figure sites, in parts per million. sites, per in parts

Figure 12: Yttrium versus zirconium for all sites, in parts per sites,per million. all for parts inzirconium 12:versus Figure Yttrium

million. Figure 13: Yttrium versus boron for all sites, in parts per all for parts sites, inboron 13:versus Figure Yttrium

34 are not well understood (Wanty and Goldhaber, 1992). Wanty and Goldhaber (1992) also indicate that vanadium [III] is quickly and fully hydrolyzed in aqueous solution and consequently vanadium [IV] and [V] are the most likely to be mobilized in natural waters.

The Beezley Hills study locations exhibit substantial variation of these two elements within the field area and Quincy Potholes. Plotting several selected elements versus the boron/yttrium ratio shows some distinct groupings (Figures 14 and 15). B/Y mapped against both germanium and vanadium reveals that location GCPUD008 again shows a distinct geochemical division to other site localities, although the spread between sites is not as pronounced. In figures 14 and 15 some site locations form tight groupings with respect to variability of one or two variables. Vanadium is relatively dispersed with respect to B/Y in nearly every site except GCPUD008, whereas locations WP52SJ5,

WP54SJ4, and WP114SJ2A show major variability. Germanium with respect to B/Y shows a greater spread in sites WP75SJ7 and WP54SJ4 than at other localities.

Conversely, groupings are distinct for sites GCPUD008 and WP63SJ1.

5.7 Compositional Variation

Figures 16 and 17 show results of line scans performed on samples from

GCPUD003 and WP75SJ7, respectively. The intragrain variation in site GCPUD003 shows slightly elevated concentrations at spots 1 and 2, decreasing in concentration through the middle of the grain, and again showing increased concentrations toward spot

10. These trends hold true for all selected elements except yttrium, which is variable across nearly the entire grain. All variation occurs within one or two orders of magnitude and are not correlated to color variations across the material.

Figure 14: Boron/yttrium versus vanadium concentrations for all sites, all in for concentrations vanadium versus 14: Boron/yttrium Figure parts per million. parts

Figure 15: Boron/yttrium versus germanium for all sites,million. all germanium for per in versus 15:parts Figure Boron/yttrium

In contrast to this data, site WP75SJ7 displays little variation across the grain, with the exception of vanadium and, less pronounced, yttrium. This grain is far more homogenous in composition than the grain from GCPUD003. Variation only occurs within one order of magnitude.

rom site rom

Figure 16: Compositional variation for selected element concentrations f concentrations element selected for variation 16:Figure Compositional GCPUD003.

Figure 17: Compositional variation for selected element concentrations from site from concentrations element selected for variation 17:Figure Compositional WP75SJ7.

Chapter 6: Discussion

6.1 Source of Silica

The source of silica for the Beezley Chalcedony is problematic due to there being no outcrops of siliceous material directly in the field area. The Roza Member is enclosed by silica-rich interbeds (the Quincy Diatomite above, the Squaw Creek Diatomite below) which are interpreted by many to be evidence of deposition in a diatomite or lacustrine diatomite facies (Hodges, 1978; Tolan and Beeson, 1984; Smith, 1988; Ebinghaus et al.

2014;). Evidence of multiple freshwater lakes during the late Pleistocene has been found

(Lindsey et al., 2009). Although no siliceous interbed is visible in the Beezley Hills, due to erosion, raw material from the Ellensburg Formation has been seen (Figure 6).

Lava temperature ranges from ~700°—1200° C (Francis, 1993). The heat from the Roza proximal to the Squaw Creek Diatomite was therefore sufficient to mobilize the silica and convert the diatomite into chalcedony (between 0°—200° C), according to

Siever (1962). Williams and Crerar (1985) indicate a temperature of ~50° C is sufficient to transform Opal-A to Opal-CT. However, Pisciotto (1978) observed a large range of temperatures for this reaction (18°—56° C). Williams and Crerar (1985) also stated that rates of transformation are dependent upon morphology and particle solubility.

Analysis of silicon isotopes within the chalcedony could elucidate the possible origin of the silica, since diatoms prefer to incorporate the lighter isotope of 28Si over the heavier 30Si (Leng and Sloane, 2008; Chen et al., 2012). No such isotopic fractionation would presumably occur in silica without biogenic contributors. No petrographic or isotope work was performed on any samples and consequently no biogenic or abiogenic source can be determined until such work is implemented.

6.2 Redox-sensitive Trace Elements

Some of the trace elements showing discernable variation in the Beezley Hills

Chalcedony are elements that are sensitive to redox processes in aqueous solution, namely vanadium and uranium. Molybdenum is also redox-sensitive but was not included for analysis during this study.

The generally insoluble trace metals (U, V, Mo), according to Chang et al. (2009), tend to concentrate in sediments under anoxic waters. Locations WP114SJ2A and, to a lesser extent, location WP52SJ5 exhibit relatively enriched vanadium concentrations.

Location WP52SJ5 exhibits elevated uranium and vanadium concentrations, while

GCPUD003 exhibits comparatively decreased concentrations in vanadium and uranium.

The elevation of the redox-sensitive elements in some source locations suggests accumulation of these elements in environments of anoxia (Chang et al., 2009), whereas other areas may have experienced localized differences in environmental conditions.

6.3 Spatial Geochemical Variation

In terms of spatial variation between sites, several trace elements confirm that differences in concentrations correlate with distance (Figures 18 and 19), although the controls on these variations may be complex. Sites WP52SJ5 and WP54SJ4 are roughly

350 meters apart and were plotted together as a baseline. WP75SJ7 is nearly 2 km away from WP52SJ5 and WP54SJ4. Site WP63SJ1 is approximately 5 km away from locations WP52SJ5 and WP54SJ4. Site WP114SJ2A is located more than 40 km away in the Quincy Potholes area and selected trace elements show a marked deviation in many plots, especially for Ge and V.

6.4 Diagenesis

The diagenetic transformation of Opal-A (highly disordered) to α-quartz (highly ordered; crystalline) is varied and complex, depending on several different factors, some of which may not be present in every environment of deposition. Solubility of amorphous silica most strongly depends upon temperature, with less dependence upon pH and surface area of the solid silica phase, as well as pressure (Hesse, 1988). The

Beezley Chalcedony showing very little structural variation, as well as high homogeneity

(Figure 7) implies a relatively advanced stage of diagenesis, although more in-depth analysis would have to be performed to rule out higher concentrations of chert precursors such as Opal-A and Opal-CT.

Hesse (1988) also suggests that precious opal precipitates from a supersaturated solution with respect to silica, and notes that diatom frustules are mineralogically similar to precious opal. If the Beezley Chalcedony did obtain its silica from diatomite deposits, the implication is clear that the original freshwater lake was at some point originally supersaturated with respect to silica, may have had an elevated pH or that the deposits from the lake were at some point at high temperature in order to mobilize the silica.

These facts imply that either diagenesis was not uniform in the field area during formation or some other processes were dominating the chemical makeup of the material.

The presence of significant amounts of vanadium and germanium after diagenesis agrees generally with the work of Murray (1994). The compositional variation without high concentrations of chemical variation seen within grains from GCPUD003 and WP75SJ7 is also difficult to explain. Raw tool-making material (e.g., chert) is heated prior to flaking to improve the physical properties of the rock, but such heating is usually

Figure 18: Selected trace element concentration (in parts per million) related to spatial variation, Ge vs B, Ge vs Y.

Figure 19: Selected trace element concentration (in parts per million) related to spatial variation, Ge vs Zr, V vs B/Y. 45 accompanied with a change from lighter to darker colored material (Domanski and

Webb, 1992). Purdy (1974) suggested that such changes would not occur unless there were appropriate minerals present in the material containing iron. Since the white material in GCPUD003 is compositionally different from the clearer material, but is likely to contain less iron oxide (reddish-brown), this confirms Purdy’s suggestion.

However, it is unlikely this grain experienced heat treating because samples were cut prior to mounting to produce a fresh surface. Other grains may well have experienced heat treating.

Van Kranendonk and Pirajno (2004) indicate that mineral assemblages increase during hydrothermal alteration of chert, not decrease. No hydrothermal alteration is known to have taken place in the field area and no evidence was seen during field work, so this chert is a dubious candidate for alteration by hydrothermal means.

Moxon et al. (2013) state that with silica sinter each successive diagenetic phase increases in density. If the same holds true for agate, the growth in density could be attributed to added silica during each diagenetic phase. Such adding of silica might dilute or remove higher concentrations of elements in compositionally dissimilar areas of some grains during diagenetic ripening.

Chapter 7: Conclusions

7.1 Conclusions

Analysis of the Beezley Hills Chalcedony, as well as other nearby material indicates sufficient trace element variation, even within fairly short distances. The data support the following conclusions:

-Visual discrimination of chalcedony from the study area is not sufficient to group specific source locations together and assign a geochemical source. Specific trace element assemblage coupled with visual inspection is adequately variable to differentiate in the relatively small study area.

-Raw chert from the Beezley Hills is of sufficiently high quality to have been used for tool making during the Clovis period and is abundant in the field area. Its proximity to two archaeological cache sites makes this siliceous material a strong candidate for the source of many of these tools.

-Redox-sensitive elements, as well as elements of similar atomic charge and size played a significant role in the geochemical makeup of the material.

-Spatial variation can be readily seen for certain trace elements (Ge, V) but not so strongly for others. Diagenetic influence must have fluctuated over distance to produce the geochemical signature of the material.

-Compositional variation within grains may be explained by several factors including addition of silica or increased alteration during diagenetic processes.

7.2 Recommendations for Future Work

Several necessary analyses are needed to answer additional geological questions that arose during this study:

-Larger samples sizes should be analyzed to confirm the results in this study.

This will increase confidence in the analyses and enable archaeologists to see a more complete view of the trace element geochemistry of the raw material.

-Oxygen and silicon isotope analysis of the raw chalcedony will significantly constrain the source of the silica forming the material, as well as contribute possible paleoenvironmental information about the environment of deposition if the source of the silica is diatomaceous in origin.

-Petrographic examination of the chert could reveal any relict diatom frustules or other siliceous tests, further defining the source of the silica and environment of deposition.

-XRD analysis may reveal differing content levels of opal phases (if present) and may shed further light on paleoenvironmental conditions or levels of diagenetic alteration.

-Archaeological sourcing of nearby archaeological artifacts (especially the Lind

Coulee or Winchester Wasteway sites) or raw material for comparison with the Beezley

Chalcedony could determine how utilized the material was during the Clovis period in the field area and will additionally contribute to the pool of possible geochemical sources for tool-making material in the region.

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Appendix 1 - Data Tables Trace element concentrations (in parts per million) All REE (La--Lu) = chondrite-normalized values bdl = below detection limits Conc. (ppm) Spot [7Li] ±1σ [11B] ±1σ [23Na] ±1σ [25Mg] ±1σ [27Al] ±1σ [39K] ±1σ [49Ti] ±1σ GCPUD003 (83 µm ) GCPUD003A1 0.934 0.078 4.02 0.52 113.92 5.46 53.9 2.24 228.46 10.54 341.26 12.43 17.55 0.88 GCPUD003A2 0.637 0.079 3.71 0.49 95.77 4.69 70.56 2.92 284.28 13.12 314.29 11.46 35.43 1.74 GCPUD003A3 0.678 0.075 3.37 0.44 80.17 3.95 52.93 2.22 185.06 8.54 241.03 8.8 5.84 0.33 GCPUD003A4 1.59 0.12 2.19 0.3 76.08 3.78 32.11 1.42 114.22 5.28 147.3 5.42 7.52 0.41 GCPUD003A5 0.522 0.068 3.29 0.43 92.23 4.48 62.44 2.58 208.69 9.63 272.13 9.93 2.75 0.19 GCPUD003A6 0.223 0.059 3.67 0.48 88.52 4.3 54.66 2.27 138.51 6.4 230.05 8.4 5.33 0.3 GCPUD003A7 0.468 0.081 2.04 0.29 108.39 5.28 94.18 3.87 294.31 13.58 204.61 7.5 3.7 0.24 GCPUD003A8 0.363 0.071 2.61 0.35 70.36 3.52 147.04 5.95 246.03 11.35 230.97 8.44 5.3 0.3

6 GCPUD003A9 0.159 0.059 3.85 0.5 91.08 4.41 195.49 7.88 274.34 12.66 257.62 9.4 4.02 0.24 GCPUD003A10 0.843 0.077 2.98 0.39 188.01 8.92 248.39 9.99 1567.36 72.27 463.08 16.86 106.83 5.16 GCPUD003A11 0.562 0.07 3.4 0.44 122.68 5.88 68.57 2.82 256.65 11.84 339.23 12.36 11.85 0.61 GCPUD003A12 0.664 0.073 3.11 0.41 89.98 4.37 55.84 2.32 164.47 7.59 252.11 9.2 6.54 0.36 GCPUD003A13 0.329 0.066 2.97 0.39 124.62 5.97 59.87 2.48 178.75 8.25 238.84 8.72 6.8 0.37 GCPUD003A14 0.596 0.089 3.87 0.51 90.1 4.47 66.39 2.78 163.96 7.58 271.31 9.91 11.77 0.62 GCPUD003A15 0.399 0.053 3.21 0.41 60.47 2.96 56.35 2.31 154.37 7.13 203.37 7.42 73.52 3.56 GCPUD003A16 0.483 0.063 3.09 0.4 81.94 3.98 61.94 2.55 192.47 8.88 228.65 8.34 4.51 0.26 GCPUD003A17 0.534 0.067 2.61 0.35 83.77 4.07 74.35 3.04 200.6 9.26 226.24 8.26 5.11 0.29 GCPUD003A18 0.207 0.051 2.82 0.37 139.44 6.63 86.89 3.53 191.13 8.82 235.5 8.58 4.84 0.27 GCPUD003A19 0.828 0.098 3.61 0.48 124.23 6.03 321.94 12.95 242.67 11.2 239.95 8.78 3.06 0.22 GCPUD003A20 0.384 0.062 1.51 0.21 283.21 13.39 169.5 6.83 640.53 29.54 323.26 11.77 144.98 6.99 GCPUD003B1 0.62 0.1 3.99 0.53 114.09 5.62 43.6 1.94 167.4 7.74 194.85 7.17 2.01 0.2 GCPUD003B2 0.55 0.1 4.36 0.58 75.52 3.9 54.47 2.35 145.19 6.72 122.45 4.58 2.73 0.22 GCPUD003B3 0.211 0.088 3.72 0.49 105.01 5.16 48.27 2.09 137.27 6.35 138.54 5.14 2.52 0.21 GCPUD003B4 0.86 0.1 3.96 0.52 127.52 6.19 45.32 1.98 202.15 9.34 209.56 7.69 2.73 0.21 GCPUD003B5 0.566 0.085 2.46 0.34 128.2 6.18 44.58 1.93 191.69 8.85 196.73 7.21 2.33 0.19

Conc. (ppm) Spot [7Li] ±1σ [11B] ±1σ [23Na] ±1σ [25Mg] ±1σ [27Al] ±1σ [39K] ±1σ [49Ti] ±1σ GCPUD003B6 0.372 0.093 2.7 0.38 175.71 8.42 45.78 2 144.04 6.67 154.02 5.7 3.72 0.25 GCPUD003B7 0.517 0.097 2.89 0.4 49.14 2.78 47.89 2.09 152.91 7.07 161.1 5.95 3.36 0.24 GCPUD003B8 0.237 0.093 3.27 0.44 115.25 5.65 44.02 1.94 125.34 5.81 124.77 4.66 2.4 0.21 GCPUD003B9 0.517 0.088 3.27 0.43 125.11 6.06 45.88 1.98 205.59 9.49 172.98 6.36 2.1 0.18 GCPUD003B10 1.38 0.12 2.95 0.4 123.45 6 69.62 2.92 412.63 19.04 299.26 10.93 1.24 0.16 GCPUD004 (64 μm) GCPUD004A1 0.265 0.069 6.47 0.27 198.37 7.91 48.86 1.95 177.6 6.35 375.7 20.13 16.05 0.96 GCPUD004A2 0.475 0.064 7.1 0.28 254.91 10.09 49.27 1.94 185.52 6.63 413.79 22.16 17.17 1.02 GCPUD004A3 0.286 0.07 7.91 0.31 217.74 8.66 45.49 1.83 158.4 5.67 309.21 16.57 12.93 0.78 GCPUD004A4 0.402 0.073 8.33 0.32 220.98 8.8 48.88 1.95 175.28 6.27 356.41 19.1 16.19 0.97 GCPUD004A5 0.426 0.072 8.54 0.33 175.12 7.02 38.15 1.57 111.25 3.99 250.15 13.42 16.51 0.99 GCPUD004A6 0.256 0.071 7.45 0.3 235.88 9.37 47.48 1.9 179.85 6.43 321.36 17.22 15.91 0.95 GCPUD004A7 0.473 0.079 8.34 0.33 229.01 9.13 38.69 1.61 135.79 4.87 259.85 13.94 11.4 0.71

7 GCPUD004A8 0.532 0.073 7.58 0.3 222.36 8.84 48.94 1.95 203.44 7.27 343.13 18.38 16.97 1.01

GCPUD004A9 0.457 0.077 7.49 0.3 206.16 8.23 45.63 1.85 166.88 5.97 306.85 16.45 12.67 0.77 GCPUD004A10 bdl 0.075 6.79 0.28 220.76 8.8 48.71 1.96 219.44 7.84 322.47 17.29 17.1 1.02 GCPUD004A11 0.29 0.071 7.31 0.29 207.06 8.25 46.71 1.87 180.33 6.45 306.42 16.42 15.36 0.92 GCPUD004A12 0.524 0.069 7.05 0.28 222.15 8.82 48.67 1.93 182.63 6.53 365.77 19.59 17.16 1.02 GCPUD004A13 0.536 0.069 7.55 0.3 217.8 8.65 48.75 1.93 175.23 6.26 321.95 17.25 16.73 1 GCPUD004A14 0.554 0.075 7.3 0.29 203.13 8.1 51.36 2.04 233.37 8.33 339.47 18.19 15.99 0.96 GCPUD004A15 0.237 0.076 8.03 0.32 179.94 7.23 44.03 1.8 174.38 6.24 280.17 15.03 12.97 0.79 GCPUD004A16 0.456 0.07 7.79 0.3 218.61 8.69 43.86 1.76 172.87 6.18 340.88 18.26 16.62 0.99 GCPUD004A17 0.603 0.075 7.79 0.31 244 9.69 51.19 2.03 209.87 7.5 385.95 20.67 17.77 1.06 GCPUD004A18 0.757 0.077 7.37 0.29 266.56 10.56 50.66 2.01 181.55 6.49 377.37 20.21 17.21 1.02 GCPUD004A19 0.808 0.077 5.66 0.24 224.5 8.92 47.39 1.89 210.55 7.52 359.64 19.27 16.64 0.99 GCPUD004A20 0.21 0.066 5 0.22 214.28 8.52 51.84 2.05 106.07 3.81 323.18 17.32 19.68 1.16

Conc. (ppm) Spot [7Li] ±1σ [11B] ±1σ [23Na] ±1σ [25Mg] ±1σ [27Al] ±1σ [39K] ±1σ [49Ti] ±1σ GCPUD004A22 0.932 0.083 4.37 0.2 283.72 11.24 237.57 8.89 172.63 6.17 647.23 34.65 41.6 2.4 GCPUD004A23 1.291 0.091 3.65 0.18 277.45 10.99 354.13 13.2 274.21 9.79 759.57 40.66 52.84 3.04 GCPUD004B1 0.684 0.091 3.54 0.2 301.4 11.96 49.62 2.03 214.75 7.68 428.99 22.98 32.49 1.9 GCPUD004B2 0.498 0.088 3.36 0.19 154.9 6.31 72.83 2.86 238.64 8.53 377.63 20.24 59.81 3.45 GCPUD004B3 0.638 0.09 2.59 0.17 159.13 6.47 47.85 1.97 224.99 8.04 378.8 20.3 35.72 2.08 GCPUD004B4 0.582 0.099 2.85 0.19 205.88 8.3 51.77 2.14 226.86 8.12 419.39 22.48 44.98 2.61 GCPUD004B5 0.51 0.11 3.81 0.23 206.31 8.38 49.6 2.11 209.72 7.51 334.22 17.94 33.52 1.98 GCPUD004B6 1 0.1 3.37 0.19 236.1 9.44 56.27 2.28 270.64 9.67 447.92 24 41.44 2.41 GCPUD004B7 0.542 0.094 3.28 0.19 200.83 8.08 40.84 1.75 225.28 8.06 328.46 17.62 32.96 1.93 GCPUD004B8 0.6 0.11 3.78 0.22 149.86 6.22 39.66 1.77 175.12 6.28 297.32 15.97 24.97 1.5 GCPUD004B9 0.44 0.093 2.77 0.19 150.7 6.18 41.42 1.77 192.57 6.89 304.17 16.32 27.16 1.61 GCPUD004B10 0.932 0.091 3.26 0.19 207.31 8.3 61.09 2.43 265.43 9.48 426.95 22.87 46.93 2.72 GCPUD004B11 0.824 0.099 2.96 0.19 150.71 6.18 48.76 2.03 226.24 8.09 357.36 19.16 27.24 1.61

GCPUD004B12 0.937 0.095 3.06 0.18 198.49 7.97 44.99 1.87 251.42 8.98 409.75 21.95 36.91 2.15 GCPUD004B13 0.388 0.098 3.23 0.2 142.74 5.91 50.88 2.12 169.48 6.08 272.6 14.64 19.15 1.16 GCPUD004B14 0.53 0.1 2.8 0.19 206.51 8.34 50.4 2.11 233.12 8.34 337.05 18.08 33.66 1.98 GCPUD004B15 0.94 0.1 3.42 0.2 205.7 8.28 53.98 2.21 282.68 10.1 477.99 25.61 45.19 2.63 GCPUD004B16 0.54 0.1 3.42 0.2 182.48 7.43 46.97 1.99 225.21 8.06 351.32 18.84 28.4 1.68 GCPUD004B17 0.72 0.11 3.38 0.21 183.46 7.47 49.96 2.1 229.57 8.21 385.91 20.69 33.21 1.95 GCPUD004B18 1.07 0.12 3.03 0.2 201.15 8.16 55.95 2.32 266.02 9.51 424.47 22.75 42.16 2.46 GCPUD004B19 0.89 0.12 4.22 0.24 143.73 6.04 45.49 1.98 169.2 6.08 291.29 15.65 17.19 1.06 GCPUD004B20 0.567 0.053 1.384 0.089 96.63 3.9 26.72 1.09 151.96 5.43 233.12 12.49 20.27 1.18 GCPUD004B21 0.408 0.097 3.65 0.21 212.37 8.55 46.01 1.95 168.04 6.03 307.31 16.49 20.57 1.24 GCPUD004B22 1.03 0.12 3.32 0.21 177.1 7.26 53.28 2.24 227.96 8.16 391.59 21 51.75 3.01 GCPUD004B23 0.77 0.13 2.64 0.22 173.01 7.22 49.73 2.2 203.67 7.31 354.26 19.03 28.94 1.74 GCPUD004B24 0.38 0.1 3.54 0.21 166.46 6.82 46.06 1.97 173.96 6.24 254.35 13.67 19.24 1.17 GCPUD004B25 0.67 0.11 3.14 0.21 202.13 8.22 50.44 2.16 226.86 8.12 356.05 19.1 28.98 1.73

Conc. (ppm) Spot [7Li] ±1σ [11B] ±1σ [23Na] ±1σ [25Mg] ±1σ [27Al] ±1σ [39K] ±1σ [49Ti] ±1σ GCPUD008 (64 μm) GCPUD008A1 1.057 0.095 1.34 0.12 29.68 2.25 47.19 2.4 196.46 9.04 216.15 17.12 12.38 1.11 GCPUD008A2 1.3 0.1 1.47 0.12 109.25 6.36 45.7 2.32 247.72 11.38 249.13 19.72 10.28 0.93 GCPUD008A3 0.435 0.073 1.68 0.13 128.75 7.46 48.01 2.44 211.96 9.75 273.86 21.68 13.05 1.17 GCPUD008A4 0.172 0.076 1.53 0.13 147.12 8.51 43.31 2.23 180.05 8.28 239.27 18.95 9.03 0.83 GCPUD008A5 0.279 0.067 1.54 0.12 89.9 5.3 37.82 1.95 150.84 6.94 228.2 18.07 9.78 0.89 GCPUD008A6 0.226 0.078 1.93 0.15 136.57 7.93 41.82 2.16 188.7 8.68 264.66 20.96 11.69 1.06 GCPUD008A7 0.362 0.083 1.76 0.15 133.8 7.79 39.18 2.05 138.06 6.36 210.82 16.71 9.27 0.85 GCPUD008A8 0.423 0.077 2.06 0.15 29.34 2.25 46.82 2.39 225.01 10.34 229.01 18.14 12.63 1.14 GCPUD008A9 0.342 0.075 1.58 0.13 116.58 6.79 43.83 2.25 186.71 8.59 272.22 21.55 18.16 1.61 GCPUD008A10 0.278 0.075 1.67 0.14 117.94 6.88 43.66 2.24 169.17 7.78 248.86 19.7 11.75 1.06 GCPUD008A11 0.383 0.075 1.66 0.13 127.8 7.41 39.8 2.05 133.96 6.17 244.45 19.35 9.26 0.84 GCPUD008A12 3.47 0.22 1.37 0.12 205.35 11.75 80.93 4.02 602.54 27.67 502.94 39.77 12.28 1.1

GCPUD008A13 bdl 0.083 1.92 0.16 43.8 3.01 37.47 1.98 40.97 1.95 79.15 6.36 3.11 0.34 GCPUD008A14 bdl 0.089 1.49 0.15 14.78 1.96 24.27 1.39 7.56 0.64 33.98 2.95 bdl 0.18 GCPUD008A15 2.36 0.16 1.65 0.12 142.54 8.21 72.35 3.61 403.96 18.55 410.06 32.43 24.26 2.14 GCPUD008A16 2.7 0.18 1.89 0.14 168.89 9.73 77.79 3.89 537.18 24.67 429.31 33.96 11.13 1.01 GCPUD008A17 3.92 0.25 1.74 0.13 160.6 9.23 71.06 3.55 493.99 22.69 426.74 33.75 11.78 1.06 GCPUD008A18 2.59 0.18 1.99 0.15 159.14 9.17 74.03 3.7 485.18 22.28 430.23 34.03 13.11 1.18 GCPUD008A19 bdl 0.08 2.19 0.16 25.08 2.15 29.36 1.59 48.16 2.27 62.37 5.05 2.7 0.31 GCPUD008A20 0.218 0.094 0.56 0.13 61.87 3.97 7.02 0.76 bdl 0.54 bdl 1.44 bdl 0.19 GCPUD008B1 bdl 0.11 1.84 0.19 137.16 8.09 37.05 2.04 161.03 7.43 170.44 13.56 3.09 0.37 GCPUD008B2 0.308 0.091 1.7 0.15 100.28 5.96 35.07 1.88 237.59 10.93 211.96 16.8 1.77 0.25 GCPUD008B3 0.237 0.098 1.45 0.16 126.1 7.42 32.35 1.78 135.02 6.23 148.58 11.82 15.26 1.38 GCPUD008B4 0.26 0.1 1.63 0.17 126.54 7.46 28.87 1.64 162.03 7.47 172.43 13.7 1.53 0.26 GCPUD008B5 0.21 0.1 2.27 0.18 129.5 7.63 38.02 2.06 185.9 8.56 159.76 12.71 1.66 0.26 GCPUD008B6 0.275 0.088 1.76 0.15 153.35 8.88 38.09 2.01 230.59 10.6 205.8 16.31 1.3 0.22 GCPUD008B7 0.243 0.089 1.37 0.15 67.77 4.22 32.87 1.78 182.49 8.4 171.65 13.62 1.71 0.24

Conc. (ppm) Spot [7Li] ±1σ [11B] ±1σ [23Na] ±1σ [25Mg] ±1σ [27Al] ±1σ [39K] ±1σ [49Ti] ±1σ GCPUD008B8 0.489 0.094 1.44 0.15 94.69 5.66 35.49 1.9 172.87 7.96 135.64 10.79 2.75 0.31 GCPUD008B9 0.319 0.091 2 0.16 69.58 4.32 27.89 1.55 112.42 5.19 129.5 10.31 2.64 0.31 GCPUD008B10 bdl 0.093 1.63 0.16 133.06 7.77 34.51 1.86 195.07 8.98 154.83 12.3 1.58 0.24 GCPUD008B11 0.235 0.09 1.57 0.15 62.96 3.98 34.04 1.84 218.75 10.06 172.42 13.68 2.05 0.27 GCPUD008B12 bdl 0.089 1.32 0.14 76.55 4.68 31.65 1.73 137.86 6.36 144.33 11.47 2.18 0.28 GCPUD008B13 0.607 0.096 1.49 0.14 67.25 4.19 34.08 1.83 161.95 7.46 134.82 10.72 1.6 0.24 GCPUD008B14 bdl 0.094 1.61 0.15 91.65 5.52 33.56 1.83 204.89 9.43 165.88 13.17 0.9 0.22 GCPUD008B15 0.395 0.099 1.89 0.16 95.91 5.76 28.95 1.63 146.18 6.74 125.2 9.98 2.18 0.29 GCPUD008B16 bdl 0.092 1.49 0.092 107.62 6.37 32.18 1.76 171.54 7.9 142.04 11.3 1.65 0.25 GCPUD008B17 bdl 0.092 1.47 0.092 84.16 5.1 27.36 1.54 134.21 6.19 122.7 9.78 1.2 0.21 GCPUD008B18 0.236 0.1 1.46 0.1 76.89 4.77 29.13 1.65 110.41 5.11 107.77 8.62 2.1 0.28 GCPUD008B19 0.48 0.1 1 0.1 104.67 6.23 31.87 1.76 163.17 7.52 144.49 11.49 2.71 0.32 GCPUD008B20 0.21 0.096 1.33 0.096 4.42 1.85 25.93 1.49 79.28 3.69 90.85 7.29 1.26 0.23

GCPUD008B21 0.49 0.1 1.46 0.1 68.72 4.33 32.76 1.81 183.36 8.44 171.04 13.58 2.33 0.3 GCPUD008B22 bdl 0.098 1.74 0.098 41.33 3.03 29.19 1.65 125.43 5.79 114.25 9.12 1.12 0.23 GCPUD008B23 bdl 0.1 1.99 0.1 32.27 2.72 29.45 1.69 136.43 6.3 133.44 10.64 1.94 0.28 GCPUD008B24 0.41 0.11 1.91 0.11 85.92 5.28 32.72 1.83 143.26 6.61 139.79 11.14 1.42 0.26 GCPUD008B25 0.28 0.11 1.71 0.11 63.26 4.17 32.4 1.83 198.27 9.13 165.08 13.13 0.75 0.23 WP52SJ5 (83 µm ) WP52SJ5A1 0.484 0.04 5.62 1.68 241.23 10.55 42.65 1.83 184.3 8.78 345.79 13.71 15.8 0.83 WP52SJ5A2 0.435 0.035 4.7 1.41 227 9.92 39.56 1.69 157.1 7.48 279.23 11.07 12.16 0.64 WP52SJ5A3 0.384 0.04 6.42 1.92 192.19 8.47 36.86 1.61 181.69 8.65 298.57 11.84 9.24 0.52 WP52SJ5A4 0.561 0.043 4.76 1.42 154.61 6.84 38.53 1.66 226.6 10.79 323.62 12.83 9.78 0.54 WP52SJ5A5 0.556 0.044 3.72 1.11 222.06 9.74 76.92 3.21 147.39 7.02 470.64 18.66 20.96 1.09 WP52SJ5A6 0.597 0.048 2.98 0.89 217.73 9.57 55.31 2.36 179.65 8.56 342.08 13.56 10.59 0.59 WP52SJ5A7 0.689 0.082 3.86 1.16 306.73 13.68 181.06 7.59 164.95 7.88 501.15 19.88 27.62 1.5 WP52SJ5A8 1.206 0.083 4.84 1.45 209.11 9.33 188.2 7.8 211.27 10.07 509.96 20.22 17.42 0.95 WP52SJ5A9 0.534 0.055 4.63 1.39 237.64 10.51 36.47 1.67 216.12 10.3 283.35 11.24 6.03 0.42

Conc. (ppm) Spot [7Li] ±1σ [11B] ±1σ [23Na] ±1σ [25Mg] ±1σ [27Al] ±1σ [39K] ±1σ [49Ti] ±1σ WP52SJ5A10 0.85 0.057 4.88 1.46 229.57 10.07 176.15 7.27 669.28 31.86 455.38 18.05 11.59 0.63 WP52SJ5B1 1.802 0.099 1.98 0.59 190.1 8.34 70.91 2.97 387.31 18.44 539.14 21.37 6.31 0.37 WP52SJ5B2 1.399 0.08 1.67 0.5 184.94 8.13 68.53 2.87 285.8 13.61 402.93 15.97 4.39 0.29 WP52SJ5B3 0.787 0.053 1.48 0.45 112.71 5.07 53.96 2.29 175.15 8.34 269.89 10.7 3.98 0.28 WP52SJ5B4 5.39 0.28 2 0.6 251.03 10.96 97.54 4.05 672.64 32.02 863.52 34.23 105.1 5.3 WP52SJ5B5 8.29 0.44 7.75 2.32 438.5 19.41 2714.91 111.32 37819.2 1800.11 3461.46 137.2 19167.8 962.07 WP52SJ5B6 1.496 0.086 1.6 0.48 105.76 4.81 77.05 3.22 339.29 16.15 473.29 18.76 8.95 0.5 WP52SJ5B7 1.327 0.079 1.3 0.39 117.93 5.32 90.35 3.77 341.65 16.27 530.34 21.02 9.91 0.55 WP52SJ5B8 0.807 0.067 0.68 0.21 123.51 5.75 107.35 4.52 447.59 21.31 268.74 10.66 2.09 0.3 WP52SJ5B9 0.383 0.041 0.72 0.22 158.59 7.04 127.39 5.27 422.27 20.1 328.73 13.03 5.56 0.35 WP52SJ5B10 1.547 0.096 2.15 0.65 204.95 9.11 2769.56 113.51 4203.63 200.09 1549.52 61.42 1802.26 90.5 WP52SJ2C1 0.169 0.044 3.49 1.05 191.27 8.48 46.17 2.03 100.24 4.79 188.34 7.48 5.29 0.37 WP52SJ2C2 0.154 0.044 2.99 0.9 119.08 5.46 47.97 2.1 107.63 5.14 226.02 8.97 9.3 0.55

WP52SJ2C3 0.376 0.048 3.68 1.1 187.87 8.34 39.84 1.79 103.94 4.96 243.07 9.64 9.61 0.56 WP52SJ2C4 0.342 0.095 4.09 1.23 bdl 3.69 369.52 15.34 196.78 9.4 289.32 11.5 3441.07 172.81 WP52SJ2C5 0.257 0.042 3.22 0.96 141.1 6.32 49.1 2.12 123.84 5.9 270.21 10.72 28.02 1.45 WP52SJ2C6 0.096 0.055 2.75 0.83 62.4 3.47 123.09 5.16 186.34 8.88 279.04 11.07 608.84 30.6 WP52SJ2C7 1.03 0.065 3.22 0.96 152.82 6.77 150.83 6.23 321.75 15.32 322.51 12.79 735.73 36.95 WP52SJ2C8 8.69 0.45 3.6 1.08 142.65 6.43 264.49 10.9 733.72 34.93 472.21 18.72 1925 96.64 WP52SJ2C9 2.54 0.14 3.44 1.03 73.27 3.48 147.81 6.12 373.4 17.78 359.88 14.27 579.9 29.13 WP52SJ2C10 0.388 0.04 2.85 0.85 152.41 6.75 63.96 2.7 140.37 6.69 259.2 10.28 99.33 5.01 WP54SJ4 (83 µm ) WP54SJ4A1 0.616 0.053 2.56 0.28 172.06 6.54 59.12 2.11 221.2 8.51 273.99 8.5 13.15 0.5 WP54SJ4A2 0.477 0.052 2.87 0.32 125.97 4.82 58.45 2.1 219.55 8.45 237.63 7.38 9.99 0.39 WP54SJ4A3 0.731 0.054 3.11 0.34 131.02 4.99 57.23 2.04 227.65 8.76 249.53 7.74 21.18 0.78 WP54SJ4A4 0.443 0.048 2.85 0.31 161.94 6.15 57.28 2.05 202.22 7.78 235.39 7.31 9.73 0.38 WP54SJ4A5 0.659 0.055 3.3 0.36 125.5 4.79 62.12 2.22 220.9 8.5 244.02 7.58 13.71 0.52 WP54SJ4A6 1.414 0.081 3.07 0.34 185 7.02 64.7 2.3 339.38 13.05 343.39 10.65 12.9 0.49

Conc. (ppm) Spot [7Li] ±1σ [11B] ±1σ [23Na] ±1σ [25Mg] ±1σ [27Al] ±1σ [39K] ±1σ [49Ti] ±1σ WP54SJ4A7 0.991 0.064 3.26 0.36 155.71 5.92 61.42 2.19 261.12 10.04 325.52 10.09 81.55 2.92 WP54SJ4A8 1.621 0.087 3.45 0.38 183.64 6.96 64.93 2.31 285.91 10.99 385.77 11.96 38.29 1.39 WP54SJ4A9 0.783 0.056 3.6 0.39 156.5 5.95 52.78 1.89 227.91 8.77 282.55 8.76 10.56 0.41 WP54SJ4A10 0.65 0.053 3.43 0.37 137.23 5.23 53.27 1.91 197.77 7.61 245.78 7.63 8.61 0.34 WP54SJ4B1 0.331 0.05 2.66 0.3 119.03 4.56 47.64 1.73 196.95 7.58 204.83 6.37 7.69 0.31 WP54SJ4B2 0.463 0.05 2.63 0.29 118.75 4.54 51.16 1.84 186.76 7.19 202.15 6.28 9.87 0.38 WP54SJ4B3 0.197 0.043 2.77 0.31 157.56 5.99 55.35 1.98 192.48 7.41 206.48 6.41 17.08 0.64 WP54SJ4B4 0.356 0.049 2.87 0.32 131.94 5.04 55.94 2.01 187.39 7.21 198.75 6.18 12.32 0.47 WP54SJ4B5 0.447 0.049 3.01 0.33 137.79 5.25 54.14 1.94 218.38 8.4 227.84 7.07 10.26 0.4 WP54SJ4B6 0.433 0.048 2.54 0.28 133.34 5.08 56.12 2.01 203.29 7.82 204.91 6.37 7.67 0.31 WP54SJ4B7 0.22 0.044 2.41 0.27 129.03 4.92 54.35 1.95 202.28 7.78 204.62 6.36 9.53 0.37 WP54SJ4B8 0.535 0.054 1.68 0.2 141.38 5.39 58.48 2.1 252 9.69 206.82 6.43 10.93 0.43 WP54SJ4B9 0.134 0.047 2.32 0.26 108.01 4.15 51.66 1.86 126.86 4.89 130.23 4.07 16.02 0.6

WP54SJ4B10 bdl 0.046 2.29 0.26 106.78 4.1 50.34 1.82 158.99 6.12 157.46 4.91 10.66 0.42 WP54SJ4C1 0.315 0.047 1.95 0.22 92.12 3.55 43.71 1.59 149.18 5.74 150.74 4.7 18.58 0.69 WP54SJ4C2 0.47 0.05 1.92 0.22 99.63 3.83 42.97 1.56 137.96 5.31 148.84 4.64 20.99 0.78 WP54SJ4C3 0.167 0.044 1.86 0.21 95.92 3.69 42.07 1.53 143.25 5.51 149.6 4.66 15.19 0.57 WP54SJ4C4 0.2 0.043 1.69 0.2 80.39 3.11 44.85 1.63 146.49 5.64 154.36 4.8 19.73 0.73 WP54SJ4C5 bdl 0.043 2.09 0.23 80.04 3.1 47.38 1.71 162.94 6.27 163.42 5.08 21 0.78 WP54SJ4C6 0.199 0.045 1.46 0.17 87.8 3.39 45.07 1.64 156.95 6.04 163.76 5.1 24.25 0.89 WP54SJ4C7 0.558 0.054 1.93 0.22 70.46 2.77 49.28 1.78 155.45 5.98 148.63 4.63 22.81 0.84 WP54SJ4C8 0.424 0.052 2.01 0.23 111.85 4.29 44.29 1.62 158.11 6.09 162.18 5.05 32.29 1.18 WP54SJ4C9 0.268 0.043 1.91 0.22 94.14 3.61 46.91 1.69 166.75 6.42 185.64 5.77 37.53 1.36 WP54SJ4C10 0.134 0.044 1.98 0.22 88.19 3.4 43.84 1.59 152.61 5.87 159.75 4.97 32.35 1.18 WP54SJ4D1 bdl 0.033 0.344 0.058 121.02 4.6 164.97 5.76 741.94 28.52 255.65 7.93 112.27 4 WP54SJ4D2 bdl 0.034 0.209 0.053 97.69 3.73 185.23 6.46 803.32 30.88 246.24 7.64 126.13 4.49 WP54SJ4D3 bdl 0.035 0.339 0.063 98.69 3.77 175.86 6.13 767.3 29.49 233.04 7.23 93.65 3.34 WP54SJ4D4 bdl 0.035 0.235 0.052 84.98 3.26 177.99 6.2 745.23 28.64 230.4 7.15 60.5 2.17

Conc. (ppm) Spot [7Li] ±1σ [11B] ±1σ [23Na] ±1σ [25Mg] ±1σ [27Al] ±1σ [39K] ±1σ [49Ti] ±1σ WP54SJ4D5 0.111 0.039 0.416 0.071 81.84 3.16 161.05 5.63 582.72 22.4 201.73 6.26 36.4 1.32 WP54SJ4D6 0.106 0.039 bdl 0.051 107.01 4.09 171.88 6 694.3 26.69 217.65 6.76 63.97 2.29 WP54SJ4D7 bdl 0.043 0.294 0.068 113.4 4.34 186.8 6.52 810.63 31.16 241.75 7.5 112.29 4.01 WP54SJ4D8 0.115 0.042 0.234 0.06 98.29 3.77 201.66 7.03 822.89 31.63 257.64 7.99 94.66 3.38 WP54SJ4D9 bdl 0.037 0.175 0.053 77.96 3.01 170.15 5.94 730.22 28.07 220.29 6.84 80 2.86 WP54SJ4D10 bdl 0.044 0.205 0.062 136.46 5.2 177.98 6.22 769.79 29.59 245.29 7.61 106.49 3.8 WP54SJ4E1 0.385 0.064 1.55 0.19 104.37 4.06 44.2 1.66 179.77 6.92 263.86 8.2 10.63 0.43 WP54SJ4E2 0.303 0.048 1.29 0.16 87.05 3.37 51.82 1.87 157.9 6.08 289.79 8.99 14.57 0.55 WP54SJ4E3 0.89 0.06 1.46 0.17 118.05 4.51 60.99 2.18 217.37 8.36 379.12 11.75 22.11 0.82 WP54SJ4E4 0.643 0.059 1.3 0.16 84.57 3.3 54.02 1.96 166.11 6.4 303.58 9.42 14.28 0.55 WP54SJ4E5 0.825 0.063 0.73 0.11 98.59 3.81 58.52 2.11 165.01 6.35 304.91 9.46 19.76 0.74 WP54SJ4E6 1.548 0.089 0.94 0.13 110.96 4.27 65.25 2.33 247.11 9.51 438.89 13.6 36.13 1.31 WP54SJ4E7 0.393 0.063 0.72 0.11 93.53 3.66 49.6 1.83 132.35 5.1 254 7.9 13.71 0.53

3 WP54SJ4E8 0.882 0.066 1.13 0.14 101.5 3.92 55.98 2.02 182.15 7.01 329.97 10.24 24.4 0.9

WP54SJ4E9 1.459 0.099 0.82 0.13 151.16 5.82 62.23 2.28 211.31 8.14 383.49 11.9 47.56 1.74 WP54SJ4E10 0.686 0.06 1.75 0.2 121.32 4.65 52.36 1.9 177.83 6.84 322.31 **** 31.99 1.17 WP54SJ4F1 0.622 0.054 1.49 0.18 103.13 3.96 68.13 2.43 137.79 5.31 266.18 8.26 24.07 0.89 WP54SJ4F2 0.224 0.05 1.23 0.15 84.4 3.29 64.97 2.33 83.86 3.24 212.23 6.6 18.56 0.7 WP54SJ4F3 0.535 0.062 1.17 0.15 94.68 3.69 68.27 2.45 137.55 5.3 231.57 7.2 24.98 0.93 WP54SJ4F4 0.281 0.047 1.3 0.16 63.78 2.52 70.51 2.51 119.94 4.62 260.43 8.08 30.05 1.1 WP54SJ4F5 0.581 0.057 1.21 0.15 83.37 3.25 68.48 2.44 111.65 4.3 246.19 7.64 28.64 1.05 WP54SJ4F6 1.78 0.13 2.21 0.3 137.11 5.42 222.77 7.91 236.48 9.12 390.92 12.16 183.54 6.62 WP54SJ4F7 0.738 0.064 1.39 0.17 98.7 3.83 72.52 2.6 164.04 6.32 288.89 8.97 41.08 1.5 WP54SJ4F8 1.12 0.078 1.57 0.19 123.08 4.74 58.79 2.14 165.37 6.37 309.08 9.59 86.21 3.1 WP54SJ4F9 0.803 0.066 1.83 0.22 135.41 5.19 62.63 2.25 211.37 8.13 294.05 9.13 38.8 1.41 WP54SJ4F10 0.501 0.051 1.38 0.17 67.51 2.65 64.45 2.3 131.25 5.05 270.21 8.38 49.64 1.79

Conc. (ppm) Spot [7Li] ±1σ [11B] ±1σ [23Na] ±1σ [25Mg] ±1σ [27Al] ±1σ [39K] ±1σ [49Ti] ±1σ WP63SJ1 (83 µm ) WP63SJ1A1 0.503 0.051 0.5 0.13 136.06 6.33 41.35 1.65 160.63 5.81 179.76 6.56 2.19 0.26 WP63SJ1A2 0.401 0.052 0.52 0.13 167.06 7.7 47.55 1.86 216 7.8 158.61 5.79 1.19 0.25 WP63SJ1A3 0.266 0.044 0.39 0.1 63.43 3.23 40.54 1.59 161.45 5.83 151.99 5.54 16.58 0.7 WP63SJ1A4 0.417 0.051 0.67 0.16 67.16 3.46 42.26 1.69 211.98 7.66 182.5 6.65 2.09 0.26 WP63SJ1A5 0.597 0.052 0.263 0.077 130.41 6.07 50.75 1.95 223.75 8.08 210.8 7.68 2.36 0.25 WP63SJ1A6 0.424 0.045 0.58 0.14 59.46 3.04 44.53 1.7 187.93 6.79 177.63 6.47 3.42 0.25 WP63SJ1A7 0.389 0.044 0.382 0.099 86.87 4.16 42.74 1.65 142.88 5.16 161.34 5.88 2.31 0.23 WP63SJ1A8 0.276 0.044 0.49 0.12 101.93 4.81 40.38 1.58 153.78 5.56 184.11 6.71 3.54 0.26 WP63SJ1A9 0.501 0.047 0.73 0.18 32.12 2.07 46.1 1.77 150.39 5.44 189.58 6.91 4.15 0.28 WP63SJ1A10 0.498 0.052 0.48 0.13 86.57 4.22 36.51 1.51 153.66 5.56 159.42 5.82 3.66 0.28 WP63SJ1B1 0.227 0.043 0.27 0.075 82.24 3.97 71.39 2.6 372.17 13.43 150.36 5.48 61.03 2.39 WP63SJ1B2 0.265 0.044 0.304 0.081 90.26 4.32 69.65 2.54 358.22 12.92 131.56 4.8 73.4 2.86

WP63SJ1B3 0.339 0.041 0.257 0.069 140.78 6.46 69.79 2.51 389.47 14.05 151.45 5.52 80.04 3.11 WP63SJ1B4 0.202 0.044 0.366 0.095 102.3 4.83 70.97 2.58 335.2 12.09 105.86 3.87 36.85 1.47 WP63SJ1B5 0.206 0.046 0.209 0.064 128.47 5.98 63.83 2.36 351.41 12.68 136.91 5 88.8 3.46 WP63SJ1B6 0.436 0.043 0.43 0.11 42.03 2.34 64.2 2.33 368.53 13.29 160.07 5.83 85.87 3.33 WP63SJ1B7 0.458 0.044 0.276 0.074 132.39 6.1 73.93 2.66 428.11 15.44 193.56 7.05 113.68 4.4 WP63SJ1B8 0.236 0.041 0.42 0.11 41.15 2.31 68.26 2.48 355.92 12.84 141.18 5.15 57.19 2.24 WP63SJ1B9 0.286 0.041 0.285 0.076 80.36 3.86 69.29 2.51 369.9 13.34 151.82 5.54 80.06 3.12 WP63SJ1B10 0.347 0.043 0.137 0.049 54.95 2.84 69.15 2.51 346.19 12.49 159.46 5.81 58.49 2.29 WP63SJ1C1 2.54 0.1 1.43 0.34 59.96 2.95 37.24 1.43 141.69 5.12 126.89 4.63 1.22 0.18 WP63SJ1C2 3.37 0.13 1.37 0.32 47.12 2.35 36.43 1.36 142.66 5.15 150.19 5.47 2.71 0.18 WP63SJ1C3 3.72 0.14 1.47 0.34 66.92 3.18 36.69 1.37 160.6 5.8 161 5.86 3.42 0.2 WP63SJ1C4 4.93 0.19 1.14 0.27 60.65 2.94 32.21 1.24 169.91 6.13 153.49 5.59 3.96 0.23 WP63SJ1C5 3.12 0.12 1.95 0.46 57 2.76 44.44 1.63 154.33 5.57 157.69 5.74 3.81 0.22 WP63SJ1C6 2.5 0.1 1.32 0.31 91.48 4.29 36.79 1.42 150.65 5.44 135.35 4.94 4.13 0.25 WP63SJ1C7 2.144 0.089 1.14 0.27 74.85 3.58 33.04 1.29 132.52 4.79 123.01 4.49 2.15 0.19

Conc. (ppm) Spot [7Li] ±1σ [11B] ±1σ [23Na] ±1σ [25Mg] ±1σ [27Al] ±1σ [39K] ±1σ [49Ti] ±1σ WP63SJ1C8 1.794 0.08 1.08 0.26 53.97 2.8 30.09 1.24 132.07 4.77 118.89 4.34 2.93 0.23 WP63SJ1C9 2.243 0.094 1.05 0.25 bdl 1.51 29.52 1.21 130.17 4.7 116.89 4.27 7.26 0.35 WP63SJ1C10 1.406 0.065 1.72 0.4 95.27 4.44 34.87 1.35 115.34 4.17 133.66 4.87 4.81 0.26 WP63SJ1D1 0.993 0.054 1.77 0.42 85.72 4.07 40.33 1.55 192.55 6.95 191.66 6.98 44.49 1.75 WP63SJ1D2 0.964 0.054 2.23 0.52 140.21 6.43 39.85 1.55 179.84 6.5 203.6 7.42 53.08 2.09 WP63SJ1D3 0.625 0.064 1.8 0.43 74.34 3.92 41.69 1.76 177.06 6.4 173.75 6.34 29.35 1.22 WP63SJ1D4 0.473 0.062 2.26 0.53 144.47 6.8 42.07 1.76 166.03 6.01 174.12 6.36 29.87 1.23 WP63SJ1D5 0.37 0.062 2.21 0.52 106.32 5.2 45.86 1.89 166.52 6.02 170.37 6.22 23.13 0.98 WP63SJ1D6 0.915 0.07 1.76 0.42 100.08 4.94 44.99 1.85 192.81 6.97 184.6 6.74 58.3 2.31 WP63SJ1D7 2.106 0.099 1.49 0.35 57.73 3.21 33.31 1.46 180.71 6.53 177.8 6.49 52.3 2.07 WP63SJ1D8 3.02 0.12 1.15 0.27 61.79 3.11 21.57 0.99 156.2 5.64 168.88 6.16 77.93 3.03 WP63SJ1D9 1.72 0.09 1.67 0.4 95.6 4.76 30.11 1.43 172.18 6.23 171.91 6.28 46.93 1.88 WP63SJ1D10 1.282 0.086 1.53 0.37 16.63 2.42 37.92 1.74 184.5 6.68 184.89 6.75 59.22 2.38

WP63SJ1E1 0.556 0.059 0.55 0.14 102.5 4.96 53.81 2.08 233.04 8.42 217.3 7.92 24.92 1.03 WP63SJ1E2 0.476 0.059 0.59 0.15 111.62 5.36 55.77 2.16 211.65 7.65 197.57 7.21 23.73 0.99 WP63SJ1E3 0.668 0.057 0.59 0.15 26.76 2.07 46.26 1.82 209.82 7.58 209.37 7.63 85.57 3.34 WP63SJ1E4 0.607 0.059 0.67 0.17 58.06 3.18 50.58 1.98 213.86 7.73 241.52 8.8 90.21 3.53 WP63SJ1E5 0.478 0.069 0.57 0.15 135.83 6.49 47.78 2 203.86 7.37 208.4 7.6 19.71 0.88 WP63SJ1E6 0.627 0.05 0.39 0.1 61.38 3.13 48.88 1.85 219.14 7.91 251.89 9.17 50.23 1.98 WP63SJ1E7 0.808 0.05 0.51 0.13 62.09 3.09 47.97 1.8 223.87 8.08 224.26 8.17 15.56 0.65 WP63SJ1E8 0.569 0.05 0.65 0.16 94.72 4.5 49.72 1.89 235.11 8.49 242.82 8.84 13.43 0.59 WP63SJ1E9 0.747 0.05 0.68 0.16 97.9 4.61 54.24 2 308.33 11.12 283.07 10.31 90.21 3.5 WP63SJ1E10 1.134 0.066 0.314 0.086 76.8 3.8 60.01 2.25 353.56 12.76 312.17 11.37 25.25 1.04 WP63SJ1F1 0.75 0.052 2.13 0.5 141.21 6.49 47.97 1.82 195.41 7.06 231.78 8.44 22.19 0.91 WP63SJ1F2 0.793 0.059 2.03 0.48 142.62 6.61 42.61 1.69 190.74 6.89 212.86 7.76 42.55 1.69 WP63SJ1F3 1.12 0.064 1.64 0.39 116.28 5.45 36.74 1.49 179.65 6.49 210.61 7.67 34.5 1.38 WP63SJ1F4 1.246 0.063 1.63 0.38 100.09 4.69 32.18 1.3 176.86 6.39 208.78 7.61 42.94 1.69 WP63SJ1F5 1.189 0.064 1.79 0.42 93.87 4.45 41.31 1.61 185.88 6.71 218.22 7.95 41.01 1.63

Conc. (ppm) Spot [7Li] ±1σ [11B] ±1σ [23Na] ±1σ [25Mg] ±1σ [27Al] ±1σ [39K] ±1σ [49Ti] ±1σ WP63SJ1F6 0.297 0.043 1.93 0.45 83.2 3.98 45.8 1.74 136.14 4.92 166.11 6.06 18.48 0.77 WP63SJ1F7 0.751 0.049 1.68 0.39 107.96 5.02 40.52 1.56 165.98 6 196.32 7.15 70.7 2.76 WP63SJ1F8 0.403 0.042 2.15 0.5 105.08 4.9 50.77 1.88 177.38 6.4 187.79 6.84 16.87 0.7 WP63SJ1F9 0.728 0.051 2.46 0.58 167.55 7.65 49.75 1.88 199.82 7.22 228.59 8.33 42.51 1.69 WP63SJ1F10 1.199 0.062 1.7 0.4 61.98 3.09 38.47 1.5 199.56 7.2 225.27 8.21 54.8 2.15 WP75SJ7 (83 µm ) WP75SJ7A1 1.127 0.083 1.43 0.23 125.51 4.74 622.03 23.45 292.05 13.12 325.45 13.56 348.46 15.26 WP75SJ7A2 0.865 0.064 1.85 0.28 177.08 6.6 68.62 2.63 259.77 11.67 356.59 14.85 80.97 3.57 WP75SJ7A3 0.979 0.068 1.86 0.28 98.67 3.72 57.32 2.21 212.01 9.53 299.27 12.47 89.63 3.94 WP75SJ7A4 0.732 0.056 1.71 0.26 131.26 4.91 65.42 2.51 219.82 9.88 346.32 14.42 60.35 2.66 WP75SJ7A5 0.962 0.071 1.57 0.24 105.3 3.98 145.91 5.55 201.86 9.07 425.71 17.73 556.91 24.38 WP75SJ7A6 1.327 0.09 1.71 0.26 149.7 5.6 174.43 6.62 456.5 20.51 514.72 21.43 6930.65 303.03 WP75SJ7A7 1.222 0.084 1.68 0.26 139.89 5.24 182.55 6.92 262.56 11.8 383.01 15.95 57.68 2.55

WP75SJ7A8 1.193 0.08 1.34 0.21 188.79 7.03 82.09 3.14 242.52 10.9 350.44 14.59 76.92 3.39 WP75SJ7A9 1.277 0.084 1.7 0.26 221.65 8.24 79.17 3.03 252.88 11.36 315.1 13.12 280.36 12.28 WP75SJ7A10 1.309 0.091 1.38 0.22 179.28 6.7 85.7 3.29 284.8 12.8 308.6 12.86 351.03 15.38 WP75SJ7A11 0.22 0.056 0.73 0.14 123.76 4.69 58.9 2.3 203 9.13 244.74 10.21 24.72 1.12 WP75SJ7A12 0.374 0.057 0.76 0.14 146.34 5.5 65.15 2.52 212.15 9.54 284 11.84 24.67 1.11 WP75SJ7A13 0.531 0.062 0.88 0.15 150.7 5.67 67.23 2.6 289.64 13.01 310.04 12.92 23.05 1.04 WP75SJ7A14 0.389 0.059 0.65 0.13 121.78 4.61 75.64 2.92 207.85 9.34 308.52 12.86 20.33 0.93 WP75SJ7A15 0.447 0.052 0.54 0.11 119.2 4.49 79.48 3.05 204.31 9.18 276.48 11.52 26.24 1.18 WP75SJ7A16 0.687 0.071 0.48 0.12 124.97 4.74 77.45 3 199.62 8.97 296.63 12.37 15.71 0.73 WP75SJ7A17 0.419 0.064 0.58 0.13 82.44 3.22 95.98 3.69 244.86 11.01 308.8 12.87 97.62 4.31 WP75SJ7A18 0.438 0.055 0.51 0.11 126.36 4.76 62.76 2.43 209.14 9.4 274.64 11.45 10.85 0.51 WP75SJ7A19 0.351 0.052 0.38 0.096 136.92 5.14 74.89 2.88 270.68 12.16 321.12 13.38 12.43 0.58 WP75SJ7A20 0.458 0.052 0.55 0.11 105.42 3.98 71.73 2.76 228.53 10.27 290.78 12.12 11.27 0.52 WP75SJ7A21 bdl 0.042 0.332 0.084 109.97 4.14 414.79 15.65 778.92 34.98 205.61 8.57 66.43 2.93 WP75SJ7A22 0.229 0.046 0.64 0.12 169.96 6.35 704.28 26.54 1096.63 49.25 358.86 14.95 145.1 6.37

Conc. (ppm) Spot [7Li] ±1σ [11B] ±1σ [23Na] ±1σ [25Mg] ±1σ [27Al] ±1σ [39K] ±1σ [49Ti] ±1σ WP75SJ7A23 0.352 0.052 0.66 0.12 102.17 3.87 732.72 27.62 1130.95 50.79 224.58 9.36 120.99 5.32 WP75SJ7A24 0.455 0.054 0.75 0.13 298.26 11.09 1530.37 57.63 2552.78 114.64 923.56 38.45 104.15 4.58 WP75SJ7A25 0.407 0.063 1.19 0.2 201.55 7.54 1497.47 56.39 2176.13 97.73 367.81 15.32 1051.93 46.02 WP75SJ7A26 0.453 0.07 0.61 0.14 257.32 9.6 1109.87 41.82 2127.94 95.56 519.52 21.64 87.96 3.89 WP75SJ7A27 0.491 0.067 0.174 0.099 176.39 6.62 811.47 30.59 1443.34 64.82 273.82 11.42 112.56 4.96 WP75SJ7A28 bdl 0.074 0.19 0.11 92.81 3.66 369.43 13.99 888.09 39.89 177.32 7.43 60.07 2.68 WP75SJ7A29 0.493 0.08 0.35 0.13 111.65 4.33 416.35 15.75 901.98 40.51 169.33 7.1 82.01 3.64 WP75SJ7A30 0.63 0.091 0.55 0.15 90.52 3.63 390.48 14.78 888.35 39.9 199.34 8.35 79.09 3.52 WP75SJ7A31 0.786 0.059 0.65 0.11 155.69 5.8 82.98 3.17 236.18 10.61 275.34 11.47 36.91 1.64 WP75SJ7A32 0.831 0.069 1.53 0.24 183.1 6.83 101.59 3.88 193.85 8.71 315.96 13.16 55.15 2.44 WP75SJ7A33 1.26 0.096 1.73 0.27 223.92 8.36 74.3 2.89 199.61 8.97 357.08 14.88 34.95 1.57 WP75SJ7A34 0.669 0.064 1.58 0.24 173.56 6.49 78.9 3.03 159.58 7.17 301.29 12.55 53.19 2.35 WP75SJ7A35 0.913 0.074 1.83 0.28 136.87 5.14 68.26 2.63 187.83 8.44 271.57 11.32 58.04 2.57

WP75SJ7A36 0.961 0.09 1.71 0.27 142.18 5.39 64.41 2.53 187.99 8.45 301.21 12.56 50.23 2.24 WP75SJ7A37 1.5 0.11 1.57 0.26 153.34 5.8 65.46 2.58 210.27 9.46 339.44 14.15 96.71 4.28 WP75SJ7A38 1.13 0.1 1.83 0.3 127.52 4.88 74.44 2.93 260.58 11.72 332.71 13.88 109.28 4.84 WP75SJ7A39 1.301 0.095 1.7 0.27 120.27 4.55 54.79 2.15 256.61 11.53 348.99 14.54 92.09 4.06 WP75SJ7A40 0.783 0.065 1.39 0.22 126.77 4.76 52.21 2.03 227.07 10.2 281.03 11.71 114.33 5.03 WP114SJ2A (83 µm ) WP114SJ2AA1 0.07 0.034 0.411 0.073 69.64 2.84 267.6 9.38 616.4 21.11 186.62 7.08 110.18 3.79 WP114SJ2AA2 0.135 0.038 0.496 0.087 97.26 3.94 337.73 11.83 701.04 24.01 157.87 5.99 76.03 2.63 WP114SJ2AA3 bdl 0.035 0.522 0.084 74.3 3.03 272.83 9.56 442.83 15.17 123.6 4.7 892.84 30.44 WP114SJ2AA4 0.112 0.03 0.586 0.085 89.03 3.59 330.19 11.55 615.34 21.07 165.7 6.28 96.37 3.31 WP114SJ2AA5 0.082 0.041 0.362 0.078 78.29 3.2 262.64 9.22 473.95 16.23 167.73 6.37 697.69 23.81 WP114SJ2AA6 bdl 0.038 0.294 0.071 93.94 3.81 308.68 10.82 586.15 20.07 162.76 6.18 942.4 32.14 WP114SJ2AA7 bdl 0.034 bdl 0.048 72.39 2.95 217.5 7.63 579.29 19.84 180.91 6.86 451.82 15.42 WP114SJ2AA8 bdl 0.034 0.435 0.079 98.85 3.99 368.35 12.89 636.1 21.78 192.84 7.31 86.98 2.99 WP114SJ2AA9 0.165 0.038 0.63 0.098 83.07 3.38 338.31 11.85 617.89 21.16 182.53 6.93 158.59 5.44

Conc. (ppm) Spot [7Li] ±1σ [11B] ±1σ [23Na] ±1σ [25Mg] ±1σ [27Al] ±1σ [39K] ±1σ [49Ti] ±1σ WP114SJ2AA10 0.256 0.04 0.605 0.1 185.49 7.43 361.91 12.68 838.78 28.72 173.54 6.59 198.92 6.82 WP114SJ2AB1 0.748 0.082 0.91 0.16 144.32 5.89 582.18 20.39 2581.31 88.39 160.99 6.15 235.8 8.09 WP114SJ2AB2 0.667 0.077 0.46 0.12 75.29 3.21 433.44 15.21 1886.31 64.59 108.47 4.18 161.76 5.58 WP114SJ2AB3 0.804 0.094 0.29 0.13 91.21 3.9 529.96 18.6 2451.53 83.95 165.86 6.35 198.45 6.85 WP114SJ2AB4 0.304 0.064 0.42 0.1 75.01 3.16 173.94 6.16 625.96 21.44 46.54 1.89 43.98 1.56 WP114SJ2AB5 0.502 0.093 0.32 0.13 220.49 8.93 1227.36 42.92 4872.51 166.84 329.85 12.53 153.31 5.3 WP114SJ2AB6 1.3 0.11 1.01 0.18 107.59 4.5 1770 61.84 2713.94 92.93 247.93 9.43 196.79 6.78 WP114SJ2AB7 0.37 0.074 0.87 0.15 112.75 4.66 458.7 16.09 1638.16 56.1 105.72 4.08 123.63 4.28 WP114SJ2AB8 0.33 0.074 0.93 0.16 65.67 2.88 448.46 15.73 1644.97 56.33 84.02 3.28 143.54 4.95 WP114SJ2AB9 0.207 0.066 0.49 0.12 86.55 3.62 395.86 13.9 1344.16 46.03 76.61 2.99 106.8 3.7 WP114SJ2AB10 0.698 0.074 0.39 0.11 152.29 6.17 399.68 14.03 1683.85 57.66 152.44 5.82 153.05 5.28 WP114SJ2AC1 0.326 0.048 0.62 0.1 28.26 1.34 142.81 5.04 177.28 6.08 48.3 1.9 30.63 1.08 WP114SJ2AC2 0.662 0.085 1.22 0.19 130.65 5.37 874.08 30.57 471.78 16.17 679.41 25.74 142.84 4.92

WP114SJ2AC3 0.308 0.048 0.616 0.1 47.65 2.04 176.29 6.2 184.88 6.34 60.62 2.35 34.36 1.21 WP114SJ2AC4 0.271 0.05 0.99 0.14 40.22 1.78 174.44 6.14 212.79 7.3 64.64 2.5 35.26 1.24 WP114SJ2AC5 0.422 0.049 0.463 0.086 45.27 1.94 175.47 6.17 245.8 8.42 52.11 2.03 38.58 1.35 WP114SJ2AC6 0.443 0.09 0.49 0.15 62.12 2.85 177.88 6.35 239.24 8.22 50.22 2.13 33.94 1.25 WP114SJ2AC7 0.311 0.047 0.422 0.085 26.31 1.27 168.58 5.94 218 7.47 57.74 2.24 41.25 1.44 WP114SJ2AC8 0.394 0.05 0.54 0.094 20.08 1.09 185.24 6.51 269.41 9.23 54.3 2.12 39.32 1.37 WP114SJ2AC9 0.21 0.051 0.72 0.12 37.09 1.69 227.08 7.98 439.08 15.04 82.16 3.16 41.84 1.47 WP114SJ2AC10 0.224 0.046 0.51 0.09 43.98 1.9 181.47 6.39 327.26 11.21 73.45 2.83 41.59 1.46 WP114SJ2AD1 0.675 0.056 0.81 0.12 225.31 9.02 434.99 15.22 2130.89 72.96 342.29 12.97 165.47 5.67 WP114SJ2AD2 0.311 0.044 0.631 0.098 136.66 5.5 492.3 17.21 2092.27 71.64 186.07 7.06 436.28 14.89 WP114SJ2AD3 0.505 0.052 0.472 0.088 134.35 5.41 503.96 17.63 2139.6 73.26 179.4 6.81 148.53 5.1 WP114SJ2AD4 0.335 0.045 0.441 0.084 243.27 9.74 635.37 22.21 3305.39 113.17 406.07 15.38 106.83 3.67 WP114SJ2AD5 0.514 0.05 0.583 0.094 161.55 6.49 481.35 16.84 2145.14 73.45 227.42 8.62 125.81 4.32 WP114SJ2AD6 0.498 0.06 0.55 0.11 180.08 7.24 510.91 17.9 2193.61 75.11 233.94 8.88 135.48 4.68 WP114SJ2AD7 0.46 0.06 0.53 0.1 242.79 9.74 511.97 17.94 2327.06 79.68 291.65 11.06 158.14 5.45

Conc. (ppm) Spot [7Li] ±1σ [11B] ±1σ [23Na] ±1σ [25Mg] ±1σ [27Al] ±1σ [39K] ±1σ [49Ti] ±1σ WP114SJ2AD8 0.266 0.052 0.497 0.096 185.4 7.45 458.49 16.06 1814.74 62.14 214.28 8.13 122.04 4.21 WP114SJ2AD9 0.239 0.052 0.61 0.1 137.55 5.55 397.91 13.94 1757.82 60.19 193.92 7.36 110.96 3.82 WP114SJ2AD10 0.742 0.072 0.94 0.15 113.03 4.62 422.98 14.84 1864.57 63.85 137.11 5.23 142.32 4.91 WP114SJ2AE1 0.602 0.056 0.72 0.11 109.08 4.42 427.25 14.95 1991.21 68.18 134.8 5.13 165.98 5.69 WP114SJ2AE2 0.399 0.049 1.03 0.14 100.05 4.06 414.25 14.5 1872.35 64.11 121.99 4.65 180.62 6.19 WP114SJ2AE3 0.442 0.05 0.79 0.12 92.32 3.75 349.06 12.23 1481.43 50.73 114.59 4.37 126.14 4.33 WP114SJ2AE4 0.33 0.047 0.63 0.1 99.92 4.05 295.27 10.35 1243.74 42.59 107.81 4.11 109.59 3.77 WP114SJ2AE5 0.333 0.054 0.84 0.13 80.15 3.3 315.85 11.08 1373.71 47.04 117.94 4.5 113.8 3.92 WP114SJ2AE6 0.302 0.054 0.85 0.13 70.52 2.94 349.67 12.26 1454.27 49.8 98.78 3.78 129.13 4.45 WP114SJ2AE7 0.944 0.075 1.62 0.22 173.39 6.98 625.27 21.89 3027.5 103.66 202.7 7.7 262.98 9.01 WP114SJ2AE8 0.747 0.067 1.13 0.16 105.45 4.3 488.85 17.13 2294.65 78.57 141.92 5.41 203.03 6.97 WP114SJ2AE9 0.658 0.066 1.43 0.2 223.18 8.96 457.58 16.04 2050.31 70.21 227.6 8.64 188.09 6.46 WP114SJ2AE10 0.395 0.056 0.87 0.13 74.92 3.11 298.42 10.47 1295.41 44.36 105.75 4.04 93.1 3.22 6

Conc. (ppm) Spot [51V] ±1σ [53Cr] ±1σ [55Mn] ±1σ [56Fe] ±1σ [59Co] ±1σ [60Ni] ±1σ GCPUD003 (83 µm ) GCPUD003A1 1.825 0.079 0.32 0.11 1.035 0.043 497.9 20.73 0.0228 0.0094 2.96 0.2 GCPUD003A2 3.17 0.14 0.32 0.15 2.02 0.078 954.04 39.72 0.125 0.013 1.73 0.22 GCPUD003A3 0.736 0.035 0.32 0.13 0.404 0.028 204.32 8.52 0.019 0.01 3.48 0.23 GCPUD003A4 0.619 0.03 0.36 0.14 0.613 0.033 153.54 6.41 0.05 0.011 1.82 0.21 GCPUD003A5 0.801 0.037 0.31 0.13 0.381 0.026 140.2 5.85 bdl 0.01 2.14 0.2 GCPUD003A6 0.72 0.034 0.36 0.12 0.903 0.039 293.19 12.21 bdl 0.0094 4.97 0.25 GCPUD003A7 0.891 0.042 0.39 0.16 0.24 0.028 178.58 7.45 bdl 0.012 2.78 0.24 GCPUD003A8 0.562 0.028 0.35 0.14 1.247 0.052 199.48 8.32 bdl 0.011 3.16 0.23 GCPUD003A9 0.683 0.032 0.33 0.12 1.981 0.076 181.18 7.55 0.06 0.01 2.37 0.19 GCPUD003A10 2.97 0.13 0.33 0.16 12.09 0.43 1831.3 76.25 0.319 0.016 3.65 0.21 GCPUD003A11 1.287 0.056 0.33 0.13 0.793 0.036 506.07 21.07 bdl 0.01 4.23 0.23 GCPUD003A12 0.891 0.04 0.3 0.13 0.748 0.035 257.12 10.71 bdl 0.011 3.19 0.21

70 GCPUD003A13 0.868 0.04 0.37 0.13 0.506 0.029 204.35 8.52 0.021 0.011 1.78 0.19

GCPUD003A14 0.993 0.046 0.39 0.17 0.866 0.043 466.94 19.45 bdl 0.014 2.42 0.25 GCPUD003A15 0.996 0.044 0.31 0.093 1.445 0.055 277.55 11.56 0.0419 0.0081 1.82 0.15 GCPUD003A16 0.802 0.036 0.34 0.11 0.884 0.038 258.38 10.76 bdl 0.0091 3.59 0.21 GCPUD003A17 0.872 0.039 0.42 0.12 0.212 0.021 245.61 10.23 bdl 0.0094 2.18 0.19 GCPUD003A18 0.721 0.033 0.34 0.095 0.312 0.02 309.56 12.89 bdl 0.0081 1.63 0.16 GCPUD003A19 0.877 0.041 0.36 0.16 4.27 0.16 243.85 10.16 0.071 0.014 1.64 0.25 GCPUD003A20 2.8 0.12 0.41 0.12 6.2 0.22 697.19 29.03 0.13 0.011 2.29 0.18 GCPUD003B1 0.182 0.019 0.47 0.19 0.178 0.033 60.03 2.55 bdl 0.016 1.49 0.29 GCPUD003B2 0.198 0.018 0.39 0.19 0.279 0.033 22.84 1.06 bdl 0.016 bdl 0.27 GCPUD003B3 0.128 0.016 0.44 0.18 0.394 0.032 58.02 2.46 bdl 0.014 0.56 0.25 GCPUD003B4 0.219 0.018 0.44 0.17 0.34 0.032 79.39 3.34 bdl 0.014 1.48 0.26 GCPUD003B5 0.118 0.014 0.45 0.15 0.2 0.026 99.48 4.16 bdl 0.013 1.15 0.23

Conc. (ppm) Spot [51V] ±1σ [53Cr] ±1σ [55Mn] ±1σ [56Fe] ±1σ [59Co] ±1σ [60Ni] ±1σ GCPUD003B6 0.131 0.016 0.4 0.18 0.35 0.033 44.79 1.92 bdl 0.015 bdl 0.26 GCPUD003B7 0.2 0.018 0.39 0.18 0.58 0.037 63.13 2.67 bdl 0.015 1.16 0.27 GCPUD003B8 0.229 0.018 0.44 0.18 0.449 0.034 58.87 2.49 bdl 0.015 1.24 0.27 GCPUD003B9 0.214 0.016 0.47 0.16 0.348 0.03 83.66 3.51 bdl 0.013 bdl 0.24 GCPUD003B10 0.175 0.017 0.42 0.17 0.432 0.033 103.31 4.32 bdl 0.014 1.19 0.26 GCPUD004 (64 μm) GCPUD004A1 0.459 0.033 0.4 0.16 0.89 0.064 550.38 31.38 bdl 0.012 2.19 0.26 GCPUD004A2 0.459 0.032 0.56 0.14 1.059 0.072 626.36 35.71 bdl 0.011 2.74 0.25 GCPUD004A3 0.403 0.03 0.39 0.16 1.233 0.084 391.96 22.35 0.04 0.012 2.28 0.26 GCPUD004A4 0.512 0.036 0.42 0.16 1.334 0.09 505.89 28.84 bdl 0.013 1.91 0.26 GCPUD004A5 0.458 0.033 0.44 0.16 1.65 0.11 398.81 22.74 0.042 0.013 1.62 0.25 GCPUD004A6 0.537 0.037 0.41 0.16 1.181 0.081 322.29 18.38 bdl 0.012 2.44 0.27 GCPUD004A7 0.346 0.028 0.42 0.18 1.6 0.11 226.04 12.89 bdl 0.014 1.63 0.27

GCPUD004A8 0.477 0.034 0.44 0.16 1.211 0.082 336.52 19.19 bdl 0.012 2.45 0.26 GCPUD004A9 0.41 0.031 0.42 0.17 1.313 0.089 268.86 15.33 bdl 0.013 2.46 0.28 GCPUD004A10 0.629 0.043 0.52 0.18 1.056 0.074 272.96 15.57 0.031 0.013 2.32 0.28 GCPUD004A11 0.546 0.038 0.43 0.16 1.72 0.11 271.39 15.48 bdl 0.012 1.88 0.26 GCPUD004A12 0.507 0.035 0.44 0.15 1.115 0.076 322.34 18.38 bdl 0.012 1.52 0.23 GCPUD004A13 0.54 0.037 0.47 0.15 1.062 0.073 302.31 17.24 bdl 0.012 1.75 0.24 GCPUD004A14 0.496 0.035 0.46 0.17 1.088 0.075 315.81 18.01 bdl 0.013 1.75 0.26 GCPUD004A15 0.472 0.034 0.61 0.18 1.375 0.093 244.8 13.96 bdl 0.013 2 0.28 GCPUD004A16 0.478 0.034 0.34 0.15 1.433 0.095 321.58 18.34 bdl 0.012 1.86 0.24 GCPUD004A17 0.467 0.033 0.29 0.16 1.179 0.08 421.89 24.05 bdl 0.013 2.99 0.28 GCPUD004A18 0.434 0.031 0.33 0.16 1.299 0.087 562.68 32.08 0.039 0.012 2.23 0.26 GCPUD004A19 0.507 0.035 0.33 0.16 0.626 0.049 491 27.99 bdl 0.012 1.96 0.25 GCPUD004A20 0.67 0.044 0.32 0.15 0.505 0.042 715.26 40.78 0.029 0.012 1.23 0.24 GCPUD004A21 1.069 0.066 0.33 0.14 3.15 0.2 3002.08 171.13 0.028 0.011 1.69 0.22

Conc. (ppm) Spot [51V] ±1σ [53Cr] ±1σ [55Mn] ±1σ [56Fe] ±1σ [59Co] ±1σ [60Ni] ±1σ GCPUD004A22 1.73 0.11 0.37 0.17 6.44 0.41 7072.54 403.16 0.088 0.014 2.16 0.27 GCPUD004A23 3.74 0.23 0.33 0.17 14.84 0.93 12854.48 732.75 0.239 0.02 3.81 0.31 GCPUD004B1 0.834 0.055 0.35 0.2 0.462 0.046 748.82 42.69 0.038 0.016 2.85 0.33 GCPUD004B2 0.998 0.064 0.36 0.2 0.549 0.05 1077.71 61.44 0.091 0.017 0.97 0.3 GCPUD004B3 0.7 0.048 0.33 0.2 0.493 0.047 770.72 43.94 0.082 0.016 2.15 0.31 GCPUD004B4 0.769 0.052 0.31 0.21 0.515 0.051 991.58 56.53 0.078 0.019 2.8 0.36 GCPUD004B5 0.743 0.052 0.28 0.26 0.413 0.052 643.18 36.67 bdl 0.02 2.47 0.4 GCPUD004B6 0.761 0.051 0.87 0.22 0.59 0.053 1046.02 59.63 0.071 0.017 2.26 0.33 GCPUD004B7 0.685 0.047 0.36 0.2 0.426 0.046 503.45 28.71 bdl 0.016 2.03 0.33 GCPUD004B8 0.712 0.05 0.31 0.24 0.35 0.048 428.11 24.41 0.046 0.018 2.64 0.38 GCPUD004B9 0.769 0.052 0.33 0.21 0.375 0.044 440.1 25.09 0.055 0.017 0.69 0.31 GCPUD004B10 1.244 0.078 0.33 0.19 1.277 0.088 1854.52 105.72 0.156 0.018 2.3 0.3 GCPUD004B11 0.865 0.057 0.31 0.21 0.533 0.051 778.33 44.37 0.033 0.017 1.61 0.33

GCPUD004B12 0.694 0.047 0.33 0.19 0.505 0.047 728.13 41.51 0.05 0.016 1.96 0.31 GCPUD004B13 0.814 0.055 0.29 0.22 0.312 0.044 380.01 21.67 bdl 0.018 2.17 0.35 GCPUD004B14 0.723 0.05 0.55 0.23 0.977 0.075 713.26 40.67 bdl 0.019 1.91 0.36 GCPUD004B15 0.77 0.052 0.94 0.21 0.577 0.053 890.32 50.76 0.061 0.018 1.18 0.33 GCPUD004B16 0.786 0.054 0.4 0.23 0.499 0.052 613.28 34.97 bdl 0.017 1.9 0.36 GCPUD004B17 0.811 0.055 0.4 0.23 0.685 0.06 626.72 35.73 bdl 0.019 1.89 0.36 GCPUD004B18 0.943 0.063 0.4 0.24 0.43 0.051 1275.73 72.73 0.085 0.02 1.85 0.37 GCPUD004B19 0.791 0.055 0.43 0.25 0.283 0.048 379.14 21.62 bdl 0.02 1.39 0.39 GCPUD004B20 0.32 0.022 0.61 0.11 0.274 0.026 409.77 23.36 0.0202 0.0085 1.31 0.17 GCPUD004B21 0.824 0.056 0.93 0.22 0.35 0.046 377.53 21.53 bdl 0.018 3.37 0.37 GCPUD004B22 0.803 0.055 0.41 0.25 0.659 0.061 729.65 41.6 bdl 0.02 1.25 0.37 GCPUD004B23 0.9 0.063 0.86 0.28 0.735 0.07 600.45 34.24 bdl 0.023 1.8 0.45 GCPUD004B24 0.705 0.049 0.57 0.24 0.496 0.052 374.69 21.37 bdl 0.018 2.08 0.36 GCPUD004B25 1.054 0.07 0.42 0.26 1.018 0.08 1026.72 58.53 0.11 0.021 2.31 0.4

Conc. (ppm) Spot [51V] ±1σ [53Cr] ±1σ [55Mn] ±1σ [56Fe] ±1σ [59Co] ±1σ [60Ni] ±1σ GCPUD008 (64 μm) GCPUD008A1 3.65 0.32 0.43 0.16 0.5 0.058 508.31 44.25 0.02 0.01 1.18 0.23 GCPUD008A2 2.87 0.25 0.39 0.15 0.363 0.045 455.45 39.65 0.0205 0.0097 1.45 0.23 GCPUD008A3 2.56 0.23 0.46 0.16 0.487 0.057 594.33 51.74 0.021 0.01 1.25 0.23 GCPUD008A4 2.08 0.19 0.46 0.17 0.402 0.051 461.42 40.17 0.024 0.011 1.15 0.25 GCPUD008A5 2.15 0.19 0.42 0.15 0.453 0.053 429.51 37.39 0.02 0.0098 1.39 0.23 GCPUD008A6 2.44 0.22 0.48 0.18 0.658 0.074 550.93 47.96 0.024 0.012 2.75 0.31 GCPUD008A7 2.02 0.18 0.47 0.19 0.508 0.061 401.76 34.98 0.026 0.013 1.92 0.28 GCPUD008A8 2.54 0.23 0.67 0.17 1.17 0.12 584.51 50.88 0.074 0.013 1.98 0.27 GCPUD008A9 2.56 0.23 0.52 0.16 1.01 0.11 603.09 52.5 0.023 0.011 1.7 0.26 GCPUD008A10 2.42 0.22 0.21 0.16 0.835 0.09 541.12 47.1 0.041 0.012 2.32 0.29 GCPUD008A11 2.39 0.21 0.42 0.16 0.567 0.065 499.92 43.52 0.023 0.011 2.66 0.29 GCPUD008A12 2.17 0.19 0.49 0.15 1.35 0.14 576.36 50.17 0.071 0.012 3.62 0.34

GCPUD008A13 1.49 0.13 0.56 0.18 0.604 0.07 60.03 5.25 bdl 0.013 2.3 0.31 GCPUD008A14 3.7 0.33 0.45 0.2 0.134 0.036 bdl 0.5 bdl 0.013 1.97 0.31 GCPUD008A15 4.81 0.43 1.13 0.15 1.97 0.2 1107.46 96.4 0.056 0.012 4.32 0.38 GCPUD008A16 1.74 0.16 0.21 0.17 1.66 0.17 516.99 45 0.087 0.015 4.69 0.42 GCPUD008A17 2.48 0.22 0.34 0.16 1.48 0.15 644.51 56.1 0.085 0.013 4.64 0.4 GCPUD008A18 1.88 0.17 0.24 0.17 1.75 0.18 596.12 51.89 0.078 0.014 4.74 0.42 GCPUD008A19 1.25 0.11 0.49 0.18 0.634 0.072 34.63 3.05 bdl 0.012 3.03 0.34 GCPUD008A20 3.23 0.29 0.38 0.21 0.071 0.034 b.d.l 0.54 bdl 0.014 1.49 0.31 GCPUD008B1 1.81 0.16 0.37 0.24 0.49 0.065 91.84 8.02 bdl 0.017 2.78 0.4 GCPUD008B2 1.63 0.15 0.64 0.19 0.707 0.08 66.77 5.83 bdl 0.013 1.86 0.31 GCPUD008B3 1.67 0.15 0.26 0.21 2.02 0.21 128.98 11.24 0.032 0.015 2.47 0.35 GCPUD008B4 1.57 0.14 0.22 0.22 0.62 0.074 108.58 9.47 bdl 0.016 1.36 0.33 GCPUD008B5 1.67 0.15 2.37 0.22 0.788 0.09 115.03 10.03 bdl 0.016 2.04 0.35 GCPUD008B6 1.58 0.14 0.24 0.19 0.813 0.09 106.42 9.28 bdl 0.014 1.61 0.29 GCPUD008B7 1.53 0.14 0.51 0.19 0.96 0.1 102.46 8.93 0.03 0.015 2.7 0.34

Conc. (ppm) Spot [51V] ±1σ [53Cr] ±1σ [55Mn] ±1σ [56Fe] ±1σ [59Co] ±1σ [60Ni] ±1σ GCPUD008B8 1.77 0.16 0.23 0.2 0.93 0.1 104.3 9.09 bdl 0.014 1.69 0.3 GCPUD008B9 1.69 0.15 0.61 0.2 0.785 0.088 100.01 8.72 0.081 0.016 0.81 0.28 GCPUD008B10 1.74 0.16 0.169 0.2 0.97 0.11 96.69 8.43 bdl 0.014 bdl 0.29 GCPUD008B11 1.69 0.15 0.51 0.2 0.772 0.087 73.29 6.4 bdl 0.014 1.05 0.29 GCPUD008B12 1.68 0.15 0.34 0.2 1.09 0.12 79.3 6.92 bdl 0.014 1.92 0.31 GCPUD008B13 1.7 0.15 0.187 0.19 1.09 0.12 111.21 9.69 0.033 0.014 0.91 0.29 GCPUD008B14 1.67 0.15 0.32 0.2 1.37 0.15 88.21 7.7 bdl 0.015 1.43 0.31 GCPUD008B15 1.6 0.14 0.51 0.22 1.15 0.12 125.82 10.96 0.067 0.017 0.87 0.31 GCPUD008B16 1.73 0.16 0.35 0.2 1.09 0.12 103.08 8.99 0.059 0.016 0.059 0.31 GCPUD008B17 1.64 0.15 0.33 0.2 1.19 0.13 118.79 10.35 bdl 0.015 bdl 0.29 GCPUD008B18 1.75 0.16 0.5 0.22 1.06 0.12 101.31 8.84 bdl 0.016 bdl 0.31 GCPUD008B19 1.55 0.14 0.31 0.21 1.04 0.11 128.51 11.2 0.047 0.016 1.22 0.32 GCPUD008B20 1.65 0.15 0.26 0.21 0.836 0.093 113.09 9.86 bdl 0.015 2.02 0.33

GCPUD008B21 1.64 0.15 0.33 0.21 0.878 0.098 126.35 11.01 0.051 0.016 1.48 0.32 GCPUD008B22 1.68 0.15 0.37 0.22 0.747 0.085 143.25 12.48 bdl 0.017 1.41 0.33 GCPUD008B23 1.58 0.14 0.44 0.23 0.688 0.081 144.44 12.59 bdl 0.017 bdl 0.33 GCPUD008B24 1.58 0.14 0.32 0.23 0.541 0.068 83.32 7.27 0.074 0.019 1.96 0.36 GCPUD008B25 1.57 0.14 0.31 0.25 0.681 0.081 104.38 9.1 bdl 0.018 1.08 0.36 WP52SJ5 (83 µm ) WP52SJ5A1 0.323 0.018 0.17 0.098 1.081 0.051 371.38 16.69 0.0373 0.008 2.72 0.22 WP52SJ5A2 0.312 0.017 0.168 0.087 0.947 0.044 203.83 9.16 0.0422 0.0073 3.84 0.22 WP52SJ5A3 0.261 0.016 0.154 0.11 1.431 0.064 155.15 6.98 bdl 0.0087 3.2 0.25 WP52SJ5A4 0.29 0.016 0.182 0.099 0.961 0.047 186.72 8.39 bdl 0.008 1.56 0.21 WP52SJ5A5 1.132 0.055 0.173 0.11 1.242 0.057 1749.52 78.59 bdl 0.0088 3.58 0.25 WP52SJ5A6 0.871 0.043 0.186 0.11 0.58 0.039 940.57 42.25 0.0258 0.0096 2.79 0.26 WP52SJ5A7 0.48 0.031 0.532 0.24 1.687 0.093 2655.21 119.27 0.109 0.021 3.65 0.51 WP52SJ5A8 0.555 0.031 0.132 0.17 2.189 0.098 2511.57 112.82 0.145 0.016 2.89 0.36 WP52SJ5A9 0.497 0.027 0.406 0.16 0.693 0.049 122.85 5.53 bdl 0.012 3.47 0.34

Conc. (ppm) Spot [51V] ±1σ [53Cr] ±1σ [55Mn] ±1σ [56Fe] ±1σ [59Co] ±1σ [60Ni] ±1σ WP52SJ5A10 0.719 0.036 0.142 0.11 2.96 0.12 1023.39 45.97 0.14 0.012 1.77 0.24 WP52SJ5B1 1.072 0.052 0.175 0.095 0.289 0.027 513.49 23.07 0.0755 0.0088 2.93 0.22 WP52SJ5B2 0.941 0.046 0.38 0.096 0.25 0.027 347.68 15.62 bdl 0.0083 1.65 0.21 WP52SJ5B3 1.133 0.055 0.173 0.099 0.303 0.029 213.84 9.61 0.026 0.0088 1.71 0.22 WP52SJ5B4 2.36 0.11 0.344 0.092 12.01 0.47 787.36 35.37 0.0417 0.008 3.58 0.23 WP52SJ5B5 774.87 36.5 0.157 4.74 121.57 4.78 181462.78 8151.01 1.293 0.061 4.49 0.64 WP52SJ5B6 1.38 0.067 0.163 0.11 0.417 0.033 548.99 24.66 bdl 0.0093 2.09 0.24 WP52SJ5B7 1.412 0.068 0.507 0.12 0.56 0.037 883.67 39.7 bdl 0.0094 3.02 0.26 WP52SJ5B8 0.404 0.024 0.175 0.16 0.534 0.047 168.86 7.6 0.069 0.014 3.5 0.36 WP52SJ5B9 0.607 0.031 0.223 0.11 0.795 0.043 279.54 12.56 0.0437 0.01 2.28 0.25 WP52SJ5B10 279.19 13.15 0.182 1.04 116.98 4.6 95178.33 4275.21 4.08 0.16 7.5 0.41 WP52SJ2C1 1.272 0.063 0.159 0.14 0.164 0.035 219.48 9.87 0.054 0.013 3.41 0.31 WP52SJ2C2 1.769 0.086 0.167 0.14 0.411 0.039 430.34 19.34 bdl 0.012 4.51 0.33

WP52SJ2C3 2.32 0.11 0.165 0.14 0.312 0.037 554.26 24.9 0.024 0.012 4.83 0.33 WP52SJ2C4 606.04 28.55 0.146 1.11 59.1 2.33 126380.77 5676.88 1.922 0.086 30.87 1.23 WP52SJ2C5 5.4 0.26 0.16 0.13 0.796 0.045 1240.32 55.71 bdl 0.011 3.97 0.29 WP52SJ2C6 74.4 3.51 0.16 0.26 13.48 0.53 20165.1 905.78 0.264 0.02 6.45 0.42 WP52SJ2C7 100.23 4.72 0.187 0.25 21.57 0.85 25791.88 1158.51 0.35 0.018 7.41 0.34 WP52SJ2C8 255.46 12.03 0.168 0.65 58.16 2.29 66217.29 2974.33 0.921 0.04 19.21 0.71 WP52SJ2C9 82.38 3.88 0.171 0.25 16.23 0.64 20845.08 936.31 0.292 0.017 5.95 0.31 WP52SJ2C10 13.85 0.65 0.156 0.11 2.84 0.12 3652.44 164.06 0.0424 0.0096 2.01 0.22 WP54SJ4 (83 µm ) WP54SJ4A1 0.144 0.0094 0.114 0.09 0.355 0.02 142.22 4.65 bdl 0.0081 1.62 0.15 WP54SJ4A2 0.154 0.01 0.203 0.096 0.38 0.021 107.8 3.53 bdl 0.0081 1.07 0.15 WP54SJ4A3 0.263 0.012 0.125 0.086 0.587 0.025 136.67 4.47 bdl 0.0072 3.07 0.17 WP54SJ4A4 0.214 0.011 0.134 0.089 0.401 0.021 110.37 3.61 bdl 0.0076 1.32 0.14 WP54SJ4A5 0.218 0.011 0.132 0.094 0.338 0.02 121.89 3.99 bdl 0.0078 1.28 0.15 WP54SJ4A6 0.1562 0.0097 0.142 0.091 0.679 0.028 170.84 5.59 bdl 0.0077 0.9 0.14

Conc. (ppm) Spot [51V] ±1σ [53Cr] ±1σ [55Mn] ±1σ [56Fe] ±1σ [59Co] ±1σ [60Ni] ±1σ WP54SJ4A7 0.753 0.029 0.244 0.091 0.778 0.031 234.25 7.66 bdl 0.0072 2.85 0.17 WP54SJ4A8 0.337 0.015 0.572 0.08 0.936 0.035 221.26 7.23 0.0237 0.0073 2.87 0.16 WP54SJ4A9 0.177 0.0097 0.283 0.086 0.699 0.028 118.04 3.86 bdl 0.0069 2.12 0.15 WP54SJ4A10 0.1472 0.0093 0.16 0.084 0.434 0.021 115.9 3.79 bdl 0.0072 2.62 0.16 WP54SJ4B1 0.22 0.012 0.21 0.097 0.485 0.024 96 3.15 bdl 0.0083 1.42 0.16 WP54SJ4B2 0.231 0.012 0.241 0.093 0.486 0.023 107.83 3.53 bdl 0.0081 1.45 0.15 WP54SJ4B3 2.99 0.1 0.519 0.088 1.722 0.059 1380.68 45.09 0.15 0.01 2.06 0.15 WP54SJ4B4 2.013 0.071 0.17 0.096 1.292 0.046 981.51 32.06 0.148 0.011 1.44 0.16 WP54SJ4B5 0.225 0.011 0.176 0.088 0.596 0.026 125.21 4.1 0.0185 0.0078 2.18 0.16 WP54SJ4B6 0.221 0.011 0.62 0.089 0.555 0.024 99.44 3.26 0.0225 0.0077 0.8 0.14 WP54SJ4B7 0.234 0.012 0.23 0.09 0.426 0.021 113.41 3.71 bdl 0.0075 0.84 0.14 WP54SJ4B8 0.216 0.012 0.19 0.098 0.393 0.022 99.32 3.25 0.0318 0.0084 1.5 0.16 WP54SJ4B9 0.278 0.013 0.26 0.094 0.269 0.019 82.24 2.7 bdl 0.008 1.64 0.16

WP54SJ4B10 0.248 0.012 0.49 0.094 0.258 0.019 71.1 2.33 bdl 0.008 0.99 0.15 WP54SJ4C1 0.283 0.013 0.279 0.089 1.276 0.046 144.64 4.73 bdl 0.0077 0.48 0.14 WP54SJ4C2 0.275 0.013 0.26 0.09 1.145 0.042 137.41 4.49 bdl 0.0079 0.92 0.15 WP54SJ4C3 0.258 0.012 0.23 0.09 1.031 0.038 130.18 4.26 bdl 0.0075 0.87 0.14 WP54SJ4C4 0.261 0.012 0.276 0.083 1.025 0.038 143.87 4.7 0.0564 0.0079 1.01 0.14 WP54SJ4C5 0.308 0.014 0.19 0.088 1.068 0.039 153.94 5.03 0.0294 0.0076 1.25 0.15 WP54SJ4C6 0.287 0.013 8.9 0.088 0.956 0.036 142.16 4.65 bdl 0.0077 0.62 0.15 WP54SJ4C7 0.269 0.013 0.35 0.096 0.89 0.034 146.26 4.78 bdl 0.0082 0.53 0.15 WP54SJ4C8 0.347 0.015 0.32 0.094 1.149 0.042 126.59 4.14 bdl 0.0082 1.51 0.16 WP54SJ4C9 0.339 0.014 0.32 0.082 1.019 0.037 168.27 5.5 bdl 0.0072 0.94 0.14 WP54SJ4C10 0.312 0.014 0.176 0.089 0.896 0.034 124.15 4.06 0.0323 0.0078 0.72 0.15 WP54SJ4D1 2.103 0.074 4.95 0.069 0.632 0.025 97.07 3.18 bdl 0.006 2.1 0.13 WP54SJ4D2 2.23 0.078 0.315 0.071 0.793 0.029 106.67 3.49 bdl 0.006 3.04 0.15 WP54SJ4D3 1.846 0.065 0.141 0.072 0.612 0.024 93.13 3.05 bdl 0.0063 1.98 0.13 WP54SJ4D4 1.376 0.049 0.392 0.072 0.56 0.023 98.34 3.22 bdl 0.0062 3.28 0.16

Conc. (ppm) Spot [51V] ±1σ [53Cr] ±1σ [55Mn] ±1σ [56Fe] ±1σ [59Co] ±1σ [60Ni] ±1σ WP54SJ4D5 1.055 0.039 1.18 0.081 1.901 0.065 90.77 2.97 bdl 0.0068 3.23 0.17 WP54SJ4D6 1.4 0.05 2.71 0.08 2.218 0.074 107.87 3.53 bdl 0.0069 2.46 0.16 WP54SJ4D7 2.215 0.078 0.85 0.089 0.753 0.03 84.32 2.76 0.038 0.0079 3.27 0.19 WP54SJ4D8 1.922 0.068 0.422 0.091 0.665 0.027 126.77 4.15 0.0245 0.0076 2.99 0.18 WP54SJ4D9 1.787 0.063 0.138 0.08 0.657 0.026 95.64 3.13 bdl 0.0067 3.55 0.18 WP54SJ4D10 1.984 0.07 0.56 0.091 0.684 0.028 116.94 3.83 0.0189 0.0078 3.63 0.19 WP54SJ4E1 0.471 0.021 0.69 0.12 0.442 0.027 366.18 11.96 0.033 0.011 2.02 0.22 WP54SJ4E2 0.623 0.024 1 0.095 0.451 0.022 443.32 14.48 0.0285 0.0083 1.99 0.17 WP54SJ4E3 0.764 0.029 0.39 0.093 0.495 0.023 641.76 20.96 bdl 0.0075 2.94 0.18 WP54SJ4E4 0.498 0.021 0.85 0.1 0.431 0.024 421.58 13.77 0.0536 0.0093 1.6 0.18 WP54SJ4E5 0.742 0.028 1.11 0.098 0.248 0.019 516.44 16.87 bdl 0.0086 2.07 0.18 WP54SJ4E6 1.06 0.039 0.26 0.11 0.581 0.027 871.82 28.47 0.03 0.009 3.81 0.21 WP54SJ4E7 0.568 0.024 1.64 0.13 0.222 0.023 386.72 12.63 0.037 0.011 1.16 0.21

7 WP54SJ4E8 0.734 0.028 0.72 0.11 0.348 0.022 552.05 18.03 0.0255 0.009 2.17 0.19

WP54SJ4E9 1.214 0.046 0.27 0.14 0.55 0.032 842.59 27.52 0.043 0.012 2.71 0.26 WP54SJ4E10 0.936 0.035 0.77 0.1 0.746 0.031 662.05 21.62 0.0276 0.0089 0.93 0.17 WP54SJ4F1 1.007 0.037 0.97 0.094 1.437 0.051 621.74 20.31 0.0335 0.0084 1.71 0.17 WP54SJ4F2 0.859 0.032 2.6 0.1 0.895 0.035 525.01 17.15 bdl 0.0091 2.58 0.19 WP54SJ4F3 0.884 0.033 2.28 0.12 0.926 0.038 578.45 18.89 0.033 0.01 2.27 0.21 WP54SJ4F4 0.943 0.035 2.89 0.096 0.772 0.031 583.73 19.07 bdl 0.0081 1.77 0.17 WP54SJ4F5 0.969 0.036 4.15 0.1 0.693 0.029 557.38 18.21 bdl 0.0087 1.33 0.18 WP54SJ4F6 48.05 1.66 0.78 0.42 27.46 0.9 25739.64 840.63 2.148 0.078 4.55 0.38 WP54SJ4F7 1.071 0.04 1.99 0.11 0.705 0.031 586.62 19.16 0.0188 0.0097 1.01 0.19 WP54SJ4F8 1.158 0.043 0.36 0.12 0.827 0.035 565.69 18.48 0.033 0.01 2.12 0.21 WP54SJ4F9 0.894 0.034 1.58 0.11 0.809 0.034 477.67 15.6 bdl 0.0096 2.06 0.2 WP54SJ4F10 1.279 0.046 1.45 0.097 0.638 0.027 692.78 22.63 0.0283 0.0083 2.06 0.17

Conc. (ppm) Spot [51V] ±1σ [53Cr] ±1σ [55Mn] ±1σ [56Fe] ±1σ [59Co] ±1σ [60Ni] ±1σ WP63SJ1 (83 µm ) WP63SJ1A1 2.13 0.11 0.424 0.15 59.53 2.03 161.6 5.69 1.7 0.061 3.92 0.33 WP63SJ1A2 2.06 0.11 0.166 0.15 58.78 2 119.79 4.23 0.983 0.038 3.38 0.34 WP63SJ1A3 3.18 0.17 0.2 0.13 129.07 4.39 137.98 4.86 2.92 0.1 1.89 0.28 WP63SJ1A4 3.89 0.21 0.7 0.15 245.23 8.35 114.57 4.04 5.98 0.2 2.68 0.32 WP63SJ1A5 3.02 0.16 0.21 0.14 185.97 6.33 167.56 5.9 4.58 0.16 1.36 0.29 WP63SJ1A6 2.55 0.14 0.26 0.13 120.75 4.11 152.51 5.37 2.852 0.098 1.62 0.26 WP63SJ1A7 2.07 0.11 0.22 0.13 92.55 3.15 180.57 6.35 2.502 0.087 1.28 0.26 WP63SJ1A8 3.73 0.2 0.41 0.13 290.39 9.88 185.04 6.51 7.35 0.25 1.94 0.27 WP63SJ1A9 3.56 0.19 0.25 0.13 309.17 10.52 271.96 9.56 10.49 0.35 3.71 0.3 WP63SJ1A10 3.1 0.17 0.162 0.14 157.93 5.38 155.04 5.46 3.72 0.13 2.7 0.31 WP63SJ1B1 2.46 0.13 0.728 0.13 0.883 0.046 127.62 4.5 bdl 0.012 bdl 0.26 WP63SJ1B2 1.706 0.092 0.636 0.13 0.507 0.038 54.42 1.94 bdl 0.012 bdl 0.26

WP63SJ1B3 1.95 0.1 6.63 0.12 0.556 0.035 81.66 2.88 bdl 0.011 0.52 0.23 WP63SJ1B4 0.972 0.054 2.2 0.13 0.591 0.039 22.77 0.85 bdl 0.012 1.59 0.27 WP63SJ1B5 2.12 0.11 2.35 0.14 0.4 0.037 56.91 2.03 bdl 0.013 1.82 0.28 WP63SJ1B6 2.01 0.11 2.13 0.12 0.459 0.034 41.21 1.47 bdl 0.011 1.18 0.24 WP63SJ1B7 2.26 0.12 2.39 0.12 0.782 0.04 85.55 3.02 bdl 0.011 1.01 0.24 WP63SJ1B8 1.527 0.083 0.773 0.12 0.62 0.037 24.65 0.91 bdl 0.011 0.8 0.24 WP63SJ1B9 1.8 0.097 1.36 0.12 0.737 0.04 42.01 1.5 bdl 0.011 0.57 0.24 WP63SJ1B10 1.561 0.085 1.08 0.12 0.685 0.039 19.07 0.72 bdl 0.011 bdl 0.24 WP63SJ1C1 0.583 0.033 1.53 0.11 3.34 0.12 156.77 5.52 0.037 0.011 1.88 0.22 WP63SJ1C2 0.831 0.045 0.56 0.088 3.83 0.13 199.11 7 bdl 0.0085 3.27 0.21 WP63SJ1C3 1.101 0.06 1.36 0.091 4 0.14 246.28 8.66 0.0694 0.0093 1.92 0.19 WP63SJ1C4 1.162 0.063 0.26 0.097 3.01 0.11 276.05 9.7 0.0221 0.0093 2.13 0.21 WP63SJ1C5 1.046 0.057 0.83 0.089 4.11 0.14 255.5 8.98 0.0164 0.0084 2.64 0.2 WP63SJ1C6 1.08 0.059 2.02 0.11 4.46 0.16 252.1 8.86 0.043 0.01 2.12 0.23 WP63SJ1C7 0.397 0.023 1.17 0.11 3.24 0.11 132.5 4.66 0.07 0.011 1.95 0.22

Conc. (ppm) Spot [51V] ±1σ [53Cr] ±1σ [55Mn] ±1σ [56Fe] ±1σ [59Co] ±1σ [60Ni] ±1σ WP63SJ1C8 0.664 0.037 0.27 0.12 4.07 0.14 168.54 5.93 0.052 0.012 1.79 0.25 WP63SJ1C9 0.963 0.053 1.45 0.12 6.86 0.24 235.74 8.29 0.065 0.012 0.62 0.24 WP63SJ1C10 0.933 0.051 1 0.11 5.21 0.18 247.6 8.7 0.103 0.011 0.82 0.21 WP63SJ1D1 1.597 0.086 0.42 0.12 2.488 0.091 260.15 9.15 0.037 0.011 1.32 0.23 WP63SJ1D2 2.37 0.13 1.68 0.12 3.91 0.14 506.03 17.78 0.043 0.012 2.85 0.25 WP63SJ1D3 0.995 0.056 0.181 0.18 2.75 0.11 245.22 8.63 bdl 0.017 0.58 0.35 WP63SJ1D4 0.703 0.041 0.37 0.18 2.82 0.11 214.33 7.54 bdl 0.017 2.48 0.36 WP63SJ1D5 0.583 0.035 0.271 0.18 2.8 0.11 195.17 6.87 0.033 0.018 1.61 0.36 WP63SJ1D6 1.763 0.096 0.56 0.18 3.1 0.12 343.15 12.07 0.047 0.017 1.53 0.36 WP63SJ1D7 1.119 0.062 0.471 0.17 1.696 0.072 213.79 7.52 bdl 0.016 bdl 0.32 WP63SJ1D8 1.779 0.096 0.2 0.13 2.382 0.088 309.71 10.89 0.054 0.012 1.8 0.25 WP63SJ1D9 1.826 0.1 0.5 0.18 2.359 0.094 297.38 10.46 bdl 0.017 2.5 0.37 WP63SJ1D10 6.73 0.36 0.418 0.21 8.02 0.28 1504.44 52.87 0.225 0.023 4.46 0.43

WP63SJ1E1 1.89 0.1 1.37 0.17 1.163 0.057 347.77 12.23 0.055 0.016 1.58 0.32 WP63SJ1E2 2.01 0.11 1.25 0.17 1.054 0.055 309.08 10.87 bdl 0.016 3.19 0.35 WP63SJ1E3 8.74 0.47 1.04 0.15 5.78 0.2 1200.03 42.17 0.372 0.021 1.62 0.3 WP63SJ1E4 7.57 0.4 0.716 0.17 2.562 0.098 714.23 25.1 bdl 0.015 2.42 0.32 WP63SJ1E5 2.86 0.16 0.843 0.2 0.661 0.054 284.2 **** bdl 0.019 2.26 0.39 WP63SJ1E6 4.49 0.24 0.88 0.13 1.681 0.067 426.09 14.98 0.064 0.013 2.58 0.27 WP63SJ1E7 2.03 0.11 1.26 0.12 0.681 0.037 234.2 8.23 0.05 0.011 3.35 0.26 WP63SJ1E8 2.31 0.12 0.62 0.14 0.826 0.043 252.34 8.87 0.032 0.013 2.84 0.28 WP63SJ1E9 8.31 0.44 1.02 0.13 4.05 0.14 747.64 26.27 0.049 0.012 0.83 0.24 WP63SJ1E10 2.78 0.15 1.25 0.15 0.981 0.049 254.32 8.94 0.024 0.014 2.16 0.29 WP63SJ1F1 0.539 0.031 0.89 0.13 2.91 0.11 172.14 6.06 0.051 0.012 4.16 0.29 WP63SJ1F2 1.121 0.062 1.09 0.15 2.371 0.09 246.03 8.65 bdl 0.014 2.44 0.3 WP63SJ1F3 0.676 0.038 0.97 0.13 2.138 0.082 195.9 6.89 bdl 0.014 bdl 0.27 WP63SJ1F4 0.759 0.042 0.68 0.13 2.08 0.078 200.07 7.04 bdl 0.012 2.15 0.24 WP63SJ1F5 0.879 0.049 0.82 0.13 2.301 0.086 231.17 8.13 bdl 0.012 1.27 0.25

Conc. (ppm) Spot [51V] ±1σ [53Cr] ±1σ [55Mn] ±1σ [56Fe] ±1σ [59Co] ±1σ [60Ni] ±1σ WP63SJ1F6 0.972 0.054 0.18 0.12 3.5 0.12 250.12 8.79 0.024 0.012 1.38 0.24 WP63SJ1F7 3.46 0.19 1.54 0.12 4.11 0.14 605.9 21.29 0.104 0.012 1.14 0.23 WP63SJ1F8 1.141 0.062 0.91 0.12 4.07 0.14 303.6 10.67 0.048 0.012 2.18 0.24 WP63SJ1F9 8.13 0.43 1.14 0.12 9.36 0.32 1799.22 63.22 0.36 0.019 2.1 0.25 WP63SJ1F10 1.439 0.078 0.3 0.12 2.92 0.11 253.04 8.9 0.024 0.012 1.6 0.24 WP75SJ7 (83 µm ) WP75SJ7A1 359.22 15.76 0.173 0.24 60.98 2.13 101135.5 4197.58 1.086 0.041 5.62 0.26 WP75SJ7A2 1.412 0.064 0.159 0.089 0.964 0.038 730.02 30.3 bdl 0.0065 2 0.15 WP75SJ7A3 0.983 0.045 0.52 0.081 1.084 0.041 547.39 22.72 0.0223 0.0062 2.53 0.15 WP75SJ7A4 0.745 0.034 0.193 0.08 0.676 0.028 831.65 34.52 bdl 0.0059 1.68 0.13 WP75SJ7A5 6.09 0.27 0.2 0.12 8.23 0.29 3797.51 157.62 0.148 0.01 2.2 0.17 WP75SJ7A6 28.16 1.24 0.21 0.16 4.99 0.18 3438.91 142.73 0.048 0.008 1.95 0.16 WP75SJ7A7 3.92 0.17 0.36 0.11 2.61 0.094 3447.04 143.07 0.0269 0.0076 2.06 0.16

WP75SJ7A8 2.91 0.13 0.28 0.084 1.913 0.069 897.72 37.26 0.0136 0.0065 1.86 0.14 WP75SJ7A9 1.434 0.065 0.68 0.081 1.507 0.056 388.32 16.12 0.0447 0.0069 2.66 0.16 WP75SJ7A10 1.897 0.085 0.19 0.11 0.977 0.039 415.93 17.27 bdl 0.0078 1.28 0.16 WP75SJ7A11 1.473 0.067 0.21 0.13 15.77 0.55 770.9 32 0.0311 0.0097 3.26 0.22 WP75SJ7A12 2.71 0.12 0.165 0.13 13.14 0.46 965.85 40.09 0.0216 0.0092 2.32 0.2 WP75SJ7A13 1.454 0.066 0.157 0.12 14.79 0.52 850.39 35.3 0.0354 0.0092 2.41 0.2 WP75SJ7A14 1.923 0.087 0.16 0.12 14.28 0.5 1084.2 45 0.0323 0.0094 1.47 0.19 WP75SJ7A15 3.62 0.16 123.84 0.11 18.51 0.65 1411.93 58.6 0.0332 0.0079 2.68 0.18 WP75SJ7A16 2.08 0.094 0.27 0.13 20.12 0.7 1156.75 48.01 0.0367 0.0098 3.08 0.22 WP75SJ7A17 7.04 0.31 0.26 0.15 14.5 0.51 2269.38 94.19 0.06 0.01 3.68 0.24 WP75SJ7A18 1.952 0.088 0.41 0.11 12.25 0.43 932.13 38.69 0.0366 0.0083 2.97 0.19 WP75SJ7A19 2.31 0.1 0.27 0.1 10.83 0.38 1018.59 42.28 0.0206 0.0082 2.6 0.19 WP75SJ7A20 2.04 0.091 26.24 0.1 8.16 0.29 981.45 40.74 bdl 0.0072 2.06 0.17 WP75SJ7A21 2.76 0.12 0.42 0.1 3.39 0.12 3703.64 153.72 0.178 0.011 1.13 0.15 WP75SJ7A22 6.54 0.29 0.68 0.15 6.63 0.23 7827.77 324.89 0.271 0.014 2.43 0.17

Conc. (ppm) Spot [51V] ±1σ [53Cr] ±1σ [55Mn] ±1σ [56Fe] ±1σ [59Co] ±1σ [60Ni] ±1σ WP75SJ7A23 5.66 0.25 0.23 0.15 6.64 0.23 8284.92 343.86 0.219 0.013 0.65 0.16 WP75SJ7A24 10.41 0.46 26.14 0.16 12.26 0.43 21873.78 907.86 0.405 0.018 3.48 0.2 WP75SJ7A25 552.88 24.25 0.47 0.22 27.56 0.96 123642.11 5131.71 1.149 0.043 20.98 0.77 WP75SJ7A26 7.01 0.31 4.23 0.14 8.51 0.3 14437.07 599.21 0.216 0.015 2.48 0.23 WP75SJ7A27 4.74 0.21 5.37 0.16 5.48 0.19 8657.5 359.33 0.188 0.013 0.49 0.2 WP75SJ7A28 2.59 0.12 16.11 0.16 2.81 0.1 3156.95 131.03 0.043 0.013 2.74 0.27 WP75SJ7A29 3.55 0.16 5.47 0.18 3.64 0.13 3766.26 156.32 0.147 0.014 1.38 0.25 WP75SJ7A30 2.75 0.12 0.74 0.19 3.44 0.13 3291.89 136.63 0.146 0.015 bdl 0.27 WP75SJ7A31 1.698 0.076 0.47 0.078 4.24 0.15 788.55 32.73 0.0385 0.0064 1.36 0.13 WP75SJ7A32 1.28 0.058 0.31 0.099 5.1 0.18 1102.14 45.75 0.053 0.0083 1.5 0.17 WP75SJ7A33 1.229 0.057 0.25 0.12 8.2 0.29 786.56 32.65 bdl 0.0098 3.16 0.23 WP75SJ7A34 1.817 0.082 0.54 0.11 11.75 0.41 847.32 35.17 0.0395 0.0083 2.78 0.19 WP75SJ7A35 1.402 0.063 0.23 0.1 5.05 0.18 724.65 30.08 bdl 0.008 3.26 0.2

WP75SJ7A36 1.991 0.09 0.24 0.14 3.58 0.13 788.82 32.74 bdl 0.011 1.96 0.24 WP75SJ7A37 1.452 0.067 0.24 0.14 2.554 0.095 877.6 36.43 bdl 0.011 3.36 0.26 WP75SJ7A38 2.37 0.11 0.44 0.16 4.2 0.15 724.15 30.06 bdl 0.012 3.49 0.29 WP75SJ7A39 1.183 0.054 0.22 0.12 3.95 0.14 562.97 23.37 0.0449 0.0098 1.47 0.2 WP75SJ7A40 1.52 0.068 0.22 0.092 3.5 0.12 599.09 24.87 bdl 0.0073 1.62 0.16 WP114SJ2A (83 µm ) WP114SJ2AA1 1.157 0.043 0.56 0.087 4.25 0.15 109.53 3.6 bdl 0.0064 4.05 0.2 WP114SJ2AA2 0.998 0.038 0.24 0.093 3.27 0.12 75.06 2.47 0.0428 0.0074 3.48 0.19 WP114SJ2AA3 3.65 0.13 0.25 0.26 14.28 0.51 205.33 6.74 0.1349 0.0091 4.62 0.22 WP114SJ2AA4 1.102 0.041 0.24 0.11 2.84 0.1 76.32 2.51 bdl 0.0055 2.88 0.16 WP114SJ2AA5 3.27 0.12 0.43 0.14 4.03 0.15 254.24 8.35 0.158 0.011 8.27 0.35 WP114SJ2AA6 4.23 0.15 0.24 0.13 2.352 0.087 206.55 6.78 0.089 0.0086 4.05 0.21 WP114SJ2AA7 1.993 0.073 0.26 0.13 3.26 0.12 167.72 5.51 0.0583 0.007 3.94 0.2 WP114SJ2AA8 1.04 0.039 0.22 0.086 2.609 0.095 75.3 2.48 0.0209 0.0067 3.79 0.2 WP114SJ2AA9 1.318 0.049 0.22 0.11 3.13 0.11 121.13 3.98 0.0444 0.0076 3.27 0.19

Conc. (ppm) Spot [51V] ±1σ [53Cr] ±1σ [55Mn] ±1σ [56Fe] ±1σ [59Co] ±1σ [60Ni] ±1σ WP114SJ2AA10 1.594 0.059 0.21 0.1 7.9 0.28 158.67 5.21 0.101 0.0089 3.19 0.19 WP114SJ2AB1 43.11 1.53 0.79 0.18 19.62 0.7 3851.95 126.4 0.328 0.02 3.04 0.3 WP114SJ2AB2 33.67 1.2 0.162 0.16 12.51 0.45 2762.35 90.65 0.178 0.016 2.57 0.27 WP114SJ2AB3 39.53 1.41 0.181 0.2 18.97 0.68 3489.81 114.52 0.275 0.02 2.36 0.33 WP114SJ2AB4 15 0.54 0.18 0.14 2.97 0.11 857.22 28.13 0.054 0.012 3.79 0.28 WP114SJ2AB5 31.73 1.13 0.16 0.21 24.27 0.87 3429.31 112.54 0.262 0.021 1.75 0.34 WP114SJ2AB6 70.5 2.5 0.2 0.21 30.55 1.09 17936.46 588.57 1.14 0.047 3.97 0.34 WP114SJ2AB7 28.81 1.02 0.19 0.18 10.51 0.38 3447.38 113.13 0.217 0.017 2.51 0.29 WP114SJ2AB8 31.42 1.12 0.24 0.16 10.29 0.37 3112.99 102.15 0.204 0.017 2.45 0.29 WP114SJ2AB9 27.49 0.98 0.25 0.16 8.72 0.31 2844.55 93.35 0.238 0.016 1.6 0.26 WP114SJ2AB10 32.27 1.15 0.45 0.15 7.3 0.26 3172.43 104.1 0.202 0.015 3.32 0.28 WP114SJ2AC1 33.14 1.18 0.22 0.1 2.92 0.11 475.38 15.6 0.114 0.01 2.59 0.2 WP114SJ2AC2 129.85 4.61 0.18 0.19 70.64 2.52 14568.17 478.04 2.259 0.085 2.94 0.31

WP114SJ2AC3 40.15 1.43 0.3 0.1 5.2 0.19 827.66 27.16 0.245 0.013 2.66 0.2 WP114SJ2AC4 42.39 1.5 0.37 0.11 6.26 0.23 755.05 24.78 0.26 0.014 2.81 0.21 WP114SJ2AC5 50.72 1.8 0.32 0.097 5.02 0.18 712.93 23.4 0.254 0.013 1.35 0.17 WP114SJ2AC6 48.38 1.72 0.71 0.2 4.42 0.16 659.18 21.64 0.16 0.018 bdl 0.33 WP114SJ2AC7 50.23 1.78 0.43 0.1 4.82 0.17 730.46 23.97 0.22 0.013 2.8 0.2 WP114SJ2AC8 55.35 1.96 0.34 0.1 4.24 0.15 694.26 22.78 0.216 0.013 2.38 0.19 WP114SJ2AC9 62.18 2.21 0.31 0.11 5.96 0.22 939 30.82 0.439 0.02 1.55 0.2 WP114SJ2AC10 44.66 1.59 0.32 0.1 4.72 0.17 699.65 22.96 0.215 0.013 1.71 0.18 WP114SJ2AD1 35.85 1.27 0.4 0.11 9.28 0.33 2477.77 81.31 0.183 0.011 2.43 0.19 WP114SJ2AD2 34.22 1.21 0.32 0.11 19.05 0.68 3638.85 119.4 0.31 0.015 2.17 0.18 WP114SJ2AD3 27.97 0.99 0.25 0.11 18.93 0.68 3676.16 120.63 0.331 0.016 1.92 0.19 WP114SJ2AD4 23.89 0.85 0.68 0.099 17.7 0.63 2471.96 81.12 0.211 0.012 2.23 0.18 WP114SJ2AD5 25.57 0.91 0.31 0.1 10.66 0.38 3150.72 103.39 0.175 0.011 1.59 0.17 WP114SJ2AD6 27.77 0.99 0.23 0.13 9.09 0.33 3482.19 114.27 0.221 0.014 2.68 0.23 WP114SJ2AD7 24.4 0.87 0.22 0.14 7.69 0.28 2984.92 97.95 0.208 0.014 3.22 0.25

Conc. (ppm) Spot [51V] ±1σ [53Cr] ±1σ [55Mn] ±1σ [56Fe] ±1σ [59Co] ±1σ [60Ni] ±1σ WP114SJ2AD8 21.53 0.77 0.3 0.12 6.7 0.24 3179.28 104.33 0.172 0.013 1.71 0.2 WP114SJ2AD9 25.66 0.91 0.61 0.12 6.39 0.23 2790.27 91.56 0.157 0.012 4.26 0.25 WP114SJ2AD10 32.18 1.14 0.66 0.15 8.37 0.3 3122.93 102.48 0.209 0.015 3.03 0.26 WP114SJ2AE1 22.16 0.79 0.22 0.11 13.74 0.49 3111.25 102.09 0.532 0.023 1.95 0.19 WP114SJ2AE2 22.17 0.79 0.27 0.11 16.13 0.58 2977.69 97.71 0.516 0.022 2.6 0.2 WP114SJ2AE3 18.56 0.66 0.25 0.11 18.76 0.67 2404.79 78.91 0.661 0.027 2.15 0.19 WP114SJ2AE4 16.03 0.57 0.5 0.1 17.3 0.62 2011.87 66.02 0.649 0.027 2.68 0.2 WP114SJ2AE5 16.04 0.57 0.23 0.12 21.85 0.78 2187.3 71.78 1.238 0.048 2.36 0.22 WP114SJ2AE6 18 0.64 0.22 0.12 21 0.75 2500.11 82.04 0.601 0.026 1.44 0.21 WP114SJ2AE7 31.12 1.11 0.19 0.14 18.77 0.67 4582.32 150.37 0.609 0.027 1.77 0.22 WP114SJ2AE8 24.89 0.89 0.22 0.13 15.57 0.56 3717.54 121.99 0.47 0.022 1.87 0.22 WP114SJ2AE9 22.86 0.81 0.24 0.14 14.26 0.51 3638.75 119.4 0.585 0.026 3.16 0.25 WP114SJ2AE10 13.76 0.49 0.2 0.12 14.75 0.53 1967.57 64.57 0.448 0.021 1.81 0.21 8

Conc. (ppm) Spot [65Cu] ±1σ [66Zn] ±1σ [71Ga] ±1σ [72Ge] ±1σ [88Sr] ±1σ [89Y] ±1σ GCPUD003 (83 µm ) GCPUD003A1 0.891 0.054 0.292 0.037 0.049 0.02 4.76 0.22 0.413 0.02 0.0563 0.0042 GCPUD003A2 3.6 0.14 0.887 0.066 0.045 0.031 6.01 0.27 0.574 0.027 0.1129 0.0076 GCPUD003A3 1.028 0.064 0.479 0.046 0.049 0.019 4.51 0.21 0.389 0.019 0.0207 0.0028 GCPUD003A4 0.487 0.052 0.48 0.049 0.052 0.019 3.16 0.15 0.241 0.012 0.1098 0.0073 GCPUD003A5 0.648 0.049 0.248 0.036 0.045 0.018 5.57 0.25 0.431 0.021 0.0242 0.0027 GCPUD003A6 0.185 0.042 0.178 0.034 0.051 0.036 6.32 0.29 0.426 0.02 0.0515 0.0042 GCPUD003A7 bdl 0.051 0.12 0.036 0.054 0.025 3.11 0.15 1.004 0.047 0.0379 0.0038 GCPUD003A8 0.24 0.046 0.155 0.035 0.05 0.031 3.7 0.17 2.36 0.11 0.0358 0.0035 GCPUD003A9 0.71 0.051 0.439 0.042 0.052 0.03 3.9 0.18 2.76 0.13 0.0753 0.0054 GCPUD003A10 56.06 1.91 5.32 0.28 0.051 0.051 5.2 0.24 3.86 0.17 0.446 0.026 GCPUD003A11 1.012 0.058 0.402 0.041 0.051 0.025 5.7 0.26 0.507 0.024 0.0602 0.0045 GCPUD003A12 1.029 0.059 0.383 0.042 0.111 0.021 5.57 0.25 0.37 0.018 0.044 0.0037

4 GCPUD003A13 0.932 0.058 0.356 0.039 0.135 0.018 5.32 0.24 0.433 0.021 0.0229 0.0028

GCPUD003A14 1.174 0.074 0.581 0.055 0.055 0.028 5.32 0.25 0.462 0.022 0.049 0.0044 GCPUD003A15 0.397 0.036 0.242 0.029 0.124 0.019 5.63 0.25 0.381 0.018 0.0299 0.0026 GCPUD003A16 0.182 0.036 0.103 0.027 0.158 0.024 5.39 0.24 0.589 0.028 0.0382 0.0032 GCPUD003A17 0.135 0.038 0.153 0.03 0.134 0.03 5.65 0.25 0.798 0.037 0.0326 0.003 GCPUD003A18 bdl 0.031 0.106 0.025 0.165 0.033 5.69 0.26 1.333 0.061 0.0353 0.0029 GCPUD003A19 0.2 0.055 bdl 0.039 0.053 0.04 4.96 0.23 3.13 0.14 0.0267 0.0035 GCPUD003A20 6.23 0.22 1.22 0.075 0.059 0.044 3.9 0.18 2.53 0.11 0.1156 0.0074 GCPUD003B1 0.226 0.065 0.326 0.053 0.076 0.029 6.85 0.31 0.306 0.016 0.0532 0.0053 GCPUD003B2 0.208 0.062 0.286 0.048 0.059 0.031 7.66 0.35 0.29 0.015 0.039 0.0042 GCPUD003B3 0.268 0.057 0.178 0.043 0.065 0.029 7.74 0.35 0.256 0.014 0.075 0.0059 GCPUD003B4 0.252 0.059 0.872 0.07 0.068 0.025 6.74 0.31 0.327 0.017 0.0608 0.0051 GCPUD003B5 0.355 0.053 0.363 0.046 0.065 0.027 6.36 0.29 0.384 0.019 0.172 0.011

Conc. (ppm) Spot [65Cu] ±1σ [66Zn] ±1σ [71Ga] ±1σ [72Ge] ±1σ [88Sr] ±1σ [89Y] ±1σ GCPUD003B6 0.562 0.064 0.268 0.051 0.064 0.028 7.14 0.32 0.289 0.015 0.0523 0.0049 GCPUD003B7 0.503 0.063 0.309 0.05 0.058 0.029 7.19 0.33 0.31 0.016 0.291 0.018 GCPUD003B8 0.543 0.062 0.394 0.05 0.06 0.028 7.04 0.32 0.293 0.015 0.0304 0.0037 GCPUD003B9 0.386 0.055 0.231 0.041 0.061 0.025 6.39 0.29 0.361 0.018 0.0958 0.0066 GCPUD003B10 0.11 0.055 0.269 0.046 0.063 0.028 5.54 0.26 0.672 0.032 0.0527 0.0048 GCPUD004 (64 μm) GCPUD004A1 bdl 0.069 0.303 0.052 0.061 0.028 2.98 0.2 0.471 0.052 0.534 0.046 GCPUD004A2 0.543 0.057 0.319 0.046 0.062 0.026 2.8 0.19 0.496 0.055 0.699 0.059 GCPUD004A3 2.21 0.13 0.523 0.056 0.058 0.029 2.54 0.17 0.445 0.049 0.581 0.05 GCPUD004A4 0.62 0.069 0.57 0.061 0.066 0.03 2.81 0.19 0.456 0.05 0.7 0.06 GCPUD004A5 0.425 0.068 0.676 0.061 0.065 0.034 1.55 0.11 0.364 0.041 0.511 0.044 GCPUD004A6 0.734 0.069 0.612 0.061 0.063 0.032 2.7 0.18 0.403 0.045 0.846 0.072 GCPUD004A7 0.709 0.073 0.728 0.068 0.061 0.031 1.96 0.14 0.673 0.074 0.581 0.05

GCPUD004A8 0.575 0.065 0.472 0.054 0.066 0.034 2.53 0.17 0.447 0.049 0.94 0.08 GCPUD004A9 0.529 0.068 0.67 0.064 0.063 0.029 2.51 0.17 0.402 0.045 0.727 0.062 GCPUD004A10 0.785 0.074 0.446 0.059 0.062 0.028 3.42 0.23 0.461 0.051 1.26 0.11 GCPUD004A11 0.684 0.068 0.498 0.058 0.065 0.027 2.97 0.2 0.383 0.043 0.77 0.065 GCPUD004A12 0.782 0.069 0.717 0.061 0.065 0.027 2.68 0.18 0.448 0.05 0.927 0.079 GCPUD004A13 0.575 0.062 0.536 0.056 0.07 0.027 2.87 0.19 0.433 0.048 0.993 0.084 GCPUD004A14 0.769 0.071 0.683 0.062 0.068 0.029 2.62 0.18 0.461 0.051 1.042 0.088 GCPUD004A15 1.02 0.082 0.73 0.068 0.092 0.033 2.56 0.17 0.7 0.077 0.652 0.056 GCPUD004A16 0.748 0.068 0.698 0.059 0.167 0.033 2.49 0.17 0.421 0.047 1.155 0.098 GCPUD004A17 0.772 0.07 0.671 0.061 0.156 0.032 3.08 0.2 0.449 0.05 0.675 0.057 GCPUD004A18 0.865 0.072 0.681 0.061 0.155 0.028 3.1 0.21 0.448 0.05 0.769 0.065 GCPUD004A19 0.619 0.066 0.446 0.054 0.189 0.026 5.17 0.33 0.452 0.05 0.591 0.05 GCPUD004A20 0.908 0.073 0.325 0.051 0.284 0.024 6.81 0.43 0.437 0.048 0.428 0.037 GCPUD004A21 3.62 0.18 0.604 0.054 0.215 0.026 4.84 0.31 0.908 0.1 0.433 0.037

Conc. (ppm) Spot [65Cu] ±1σ [66Zn] ±1σ [71Ga] ±1σ [72Ge] ±1σ [88Sr] ±1σ [89Y] ±1σ GCPUD004A22 9.25 0.44 1.489 0.089 0.157 0.029 4.68 0.3 1.32 0.15 0.429 0.037 GCPUD004A23 14.76 0.69 3.66 0.16 0.272 0.026 5.16 0.33 1.72 0.19 0.644 0.055 GCPUD004B1 4.42 0.23 5.74 0.25 0.103 0.033 4.37 0.29 0.537 0.06 0.0725 0.0077 GCPUD004B2 0.419 0.069 0.145 0.058 0.079 0.03 4.54 0.3 0.539 0.06 0.123 0.012 GCPUD004B3 0.411 0.071 0.381 0.064 0.099 0.031 4.25 0.28 0.49 0.054 0.0792 0.0081 GCPUD004B4 0.217 0.077 0.43 0.072 0.154 0.036 4.21 0.28 0.504 0.056 0.0975 0.0098 GCPUD004B5 0.313 0.088 0.389 0.084 0.111 0.043 3.95 0.27 0.51 0.057 0.0647 0.0076 GCPUD004B6 0.298 0.075 0.648 0.072 0.137 0.034 4.39 0.29 0.561 0.062 0.0972 0.0097 GCPUD004B7 bdl 0.069 0.366 0.063 0.196 0.032 4.35 0.29 0.476 0.053 0.0676 0.0073 GCPUD004B8 bdl 0.081 0.371 0.072 0.265 0.036 4.48 0.3 0.442 0.049 0.0538 0.0067 GCPUD004B9 bdl 0.07 0.371 0.068 0.201 0.032 4.62 0.3 0.457 0.051 0.0503 0.0062 GCPUD004B10 1.218 0.093 1.046 0.078 0.114 0.029 4.24 0.28 0.595 0.066 0.187 0.017 GCPUD004B11 0.314 0.075 0.396 0.071 0.081 0.037 4.52 0.3 0.544 0.06 0.0658 0.0073

GCPUD004B12 0.136 0.067 0.454 0.068 0.049 0.03 3.97 0.26 0.555 0.061 0.0919 0.0091 GCPUD004B13 bdl 0.075 0.187 0.067 0.05 0.036 5.32 0.35 0.477 0.053 0.0504 0.0062 GCPUD004B14 0.35 0.082 0.512 0.073 0.061 0.036 4.34 0.29 0.491 0.055 0.0759 0.0082 GCPUD004B15 bdl 0.073 0.39 0.07 0.055 0.033 4.54 0.3 0.596 0.066 0.0737 0.008 GCPUD004B16 0.453 0.081 0.374 0.07 0.067 0.035 4.27 0.28 0.514 0.057 0.0424 0.0057 GCPUD004B17 0.236 0.08 0.539 0.078 0.06 0.036 4.89 0.32 0.518 0.058 0.0752 0.0082 GCPUD004B18 0.367 0.084 0.473 0.077 0.064 0.037 4.5 0.3 0.582 0.065 0.121 0.012 GCPUD004B19 0.809 0.099 1.15 0.1 0.144 0.038 4.52 0.3 0.406 0.046 0.0635 0.0072 GCPUD004B20 0.142 0.037 0.226 0.033 0.086 0.016 2.13 0.14 0.3 0.033 0.0478 0.0048 GCPUD004B21 0.724 0.087 1.215 0.093 0.07 0.036 4.51 0.3 0.41 0.046 0.0496 0.0064 GCPUD004B22 0.413 0.086 0.807 0.084 0.064 0.036 4.69 0.31 0.539 0.06 0.0767 0.0086 GCPUD004B23 0.4 0.1 0.707 0.099 0.071 0.046 4.37 0.3 0.495 0.056 0.094 0.01 GCPUD004B24 bdl 0.078 0.484 0.077 0.063 0.035 5.29 0.35 0.386 0.043 0.046 0.0061 GCPUD004B25 0.615 0.094 0.581 0.084 0.057 0.04 5.13 0.34 0.487 0.054 0.145 0.014

Conc. (ppm) Spot [65Cu] ±1σ [66Zn] ±1σ [71Ga] ±1σ [72Ge] ±1σ [88Sr] ±1σ [89Y] ±1σ GCPUD008 (64 μm) GCPUD008A1 0.404 0.066 0.392 0.058 0.074 0.026 2.24 0.24 0.62 0.12 0.0147 0.0037 GCPUD008A2 0.508 0.067 0.485 0.059 0.061 0.021 2.2 0.23 0.62 0.12 0.0409 0.0069 GCPUD008A3 0.53 0.069 0.305 0.057 0.122 0.025 1.48 0.16 0.65 0.13 0.0252 0.0048 GCPUD008A4 0.326 0.067 0.538 0.065 0.072 0.025 1.75 0.19 0.58 0.11 0.0228 0.0047 GCPUD008A5 0.632 0.073 0.933 0.076 0.082 0.022 1.56 0.17 0.57 0.11 0.0251 0.0047 GCPUD008A6 0.552 0.076 0.706 0.072 0.071 0.025 1.54 0.17 0.66 0.13 0.0329 0.0059 GCPUD008A7 0.134 0.065 0.481 0.067 0.114 0.027 1.53 0.17 0.57 0.11 0.0118 0.0036 GCPUD008A8 0.792 0.083 0.796 0.074 0.074 0.024 1.6 0.17 0.7 0.14 0.0153 0.0036 GCPUD008A9 0.409 0.066 0.69 0.069 0.078 0.027 1.62 0.17 0.67 0.13 0.0315 0.0057 GCPUD008A10 0.503 0.069 0.554 0.064 0.031 0.024 1.42 0.15 0.6 0.12 0.0264 0.0049 GCPUD008A11 0.363 0.063 0.436 0.058 0.071 0.026 1.49 0.16 0.54 0.11 0.0165 0.0037 GCPUD008A12 0.678 0.074 1.062 0.082 0.073 0.026 1.78 0.19 1.63 0.32 0.0325 0.0057

GCPUD008A13 0.256 0.068 0.717 0.076 0.091 0.032 2.7 0.28 0.453 0.089 0.0069 0.0031 GCPUD008A14 bdl 0.067 0.233 0.061 0.068 0.028 2.5 0.26 0.197 0.039 bdl 0.0031 GCPUD008A15 0.513 0.065 0.989 0.078 0.08 0.027 2.11 0.22 1.41 0.28 0.081 0.013 GCPUD008A16 0.512 0.072 0.815 0.077 0.248 0.033 2.02 0.21 1.63 0.32 0.0132 0.0037 GCPUD008A17 0.412 0.062 0.889 0.074 0.548 0.029 1.45 0.16 1.47 0.29 0.0293 0.0052 GCPUD008A18 0.175 0.061 2.05 0.13 0.133 0.034 1.9 0.2 1.56 0.31 0.0307 0.0055 GCPUD008A19 0.272 0.065 0.295 0.058 0.122 0.027 2.92 0.3 0.55 0.11 bdl 0.0029 GCPUD008A20 bdl 0.067 0.127 0.057 0.158 0.029 1.48 0.16 0.052 0.012 bdl 0.0029 GCPUD008B1 0.609 0.096 1.22 0.11 0.77 0.054 1.42 0.17 0.397 0.079 0.0185 0.0051 GCPUD008B2 bdl 0.069 0.446 0.067 0.243 0.029 1.62 0.18 0.441 0.087 0.0212 0.0047 GCPUD008B3 0.453 0.081 1.18 0.1 0.577 0.033 1.59 0.18 0.329 0.065 0.0124 0.0039 GCPUD008B4 0.247 0.077 0.666 0.08 0.581 0.035 1.52 0.17 0.338 0.067 0.0159 0.0044 GCPUD008B5 0.466 0.085 0.676 0.081 1.209 0.032 1.58 0.18 0.401 0.079 0.0113 0.004 GCPUD008B6 0.361 0.07 0.529 0.07 0.388 0.045 1.52 0.17 0.441 0.087 0.023 0.0049 GCPUD008B7 0.168 0.066 0.528 0.07 0.29 0.029 1.45 0.16 0.337 0.067 0.0248 0.0051

Conc. (ppm) Spot [65Cu] ±1σ [66Zn] ±1σ [71Ga] ±1σ [72Ge] ±1σ [88Sr] ±1σ [89Y] ±1σ GCPUD008B8 0.146 0.068 0.708 0.075 0.096 0.03 1.63 0.18 0.386 0.076 0.0147 0.0039 GCPUD008B9 0.188 0.068 0.522 0.066 0.308 0.033 1.84 0.2 0.276 0.055 0.0098 0.0034 GCPUD008B10 bdl 0.069 0.542 0.069 0.312 0.031 1.47 0.16 0.382 0.076 0.0114 0.0039 GCPUD008B11 0.191 0.069 0.498 0.068 0.418 0.033 1.43 0.16 0.371 0.073 0.0155 0.004 GCPUD008B12 0.265 0.07 0.433 0.068 0.603 0.034 1.51 0.17 0.314 0.062 0.015 0.004 GCPUD008B13 0.161 0.067 0.365 0.065 0.733 0.029 1.42 0.16 0.332 0.066 0.017 0.0042 GCPUD008B14 0.168 0.07 0.504 0.07 0.767 0.035 1.27 0.15 0.408 0.081 0.013 0.0039 GCPUD008B15 0.339 0.075 0.401 0.071 1.01 0.032 1.43 0.16 0.314 0.062 0.0231 0.0051 GCPUD008B16 bdl 0.069 0.408 0.067 0.052 0.033 1.54 0.17 0.341 0.068 0.0242 0.0052 GCPUD008B17 bdl 0.069 0.484 0.066 0.307 0.031 1.26 0.14 0.302 0.06 0.0138 0.0039 GCPUD008B18 0.224 0.074 0.321 0.068 0.293 0.038 1.49 0.17 0.269 0.053 0.0239 0.0052 GCPUD008B19 bdl 0.071 0.498 0.072 0.188 0.033 1.65 0.18 0.339 0.067 0.0229 0.005 GCPUD008B20 0.311 0.074 0.406 0.068 0.321 0.032 1.4 0.16 0.255 0.051 0.0199 0.0047

GCPUD008B21 0.255 0.076 0.765 0.081 0.183 0.032 1.51 0.17 0.352 0.07 0.0145 0.0041 GCPUD008B22 bdl 0.074 0.666 0.08 0.282 0.032 1.33 0.15 0.299 0.059 0.02 0.0047 GCPUD008B23 bdl 0.08 0.662 0.083 0.294 0.035 1.39 0.16 0.311 0.062 0.0246 0.0055 GCPUD008B24 0.639 0.093 0.708 0.085 0.23 0.034 1.38 0.16 0.332 0.066 0.02 0.0048 GCPUD008B25 1.07 0.12 0.463 0.08 0.302 0.037 1.36 0.16 0.372 0.074 0.0166 0.0047 WP52SJ5 (83 µm ) WP52SJ5A1 0.634 0.046 0.32 0.044 0.526 0.013 3.98 0.21 0.438 0.029 1.054 0.075 WP52SJ5A2 0.456 0.038 0.367 0.043 0.365 0.012 3.25 0.17 0.326 0.021 1.348 0.095 WP52SJ5A3 0.39 0.045 0.455 0.054 0.448 0.014 2.43 0.13 0.386 0.025 0.462 0.033 WP52SJ5A4 0.316 0.04 0.242 0.04 0.418 0.013 3.44 0.18 0.453 0.029 0.517 0.037 WP52SJ5A5 2.252 0.098 0.545 0.06 0.412 0.014 5.12 0.27 0.788 0.051 0.723 0.051 WP52SJ5A6 1.209 0.068 0.356 0.051 0.67 0.014 4.26 0.23 0.63 0.041 0.332 0.024 WP52SJ5A7 3.19 0.17 0.87 0.11 0.589 0.031 3.99 0.23 1.336 0.087 0.541 0.04 WP52SJ5A8 4.62 0.19 1.58 0.14 0.669 0.021 2.91 0.16 1.254 0.081 0.74 0.053 WP52SJ5A9 0.837 0.068 0.271 0.055 0.516 0.021 1.4 0.088 0.547 0.036 1.404 0.1

Conc. (ppm) Spot [65Cu] ±1σ [66Zn] ±1σ [71Ga] ±1σ [72Ge] ±1σ [88Sr] ±1σ [89Y] ±1σ WP52SJ5A10 1.269 0.068 1.65 0.14 0.578 0.017 1.055 0.065 2.63 0.17 2.17 0.15 WP52SJ5B1 0.313 0.038 0.314 0.042 0.026 0.014 3.78 0.2 0.675 0.044 0.198 0.015 WP52SJ5B2 bdl 0.036 0.16 0.038 0.084 0.015 3.79 0.2 0.557 0.036 0.0866 0.0068 WP52SJ5B3 0.146 0.039 0.135 0.038 0.11 0.019 4.15 0.22 0.404 0.027 0.1183 0.0091 WP52SJ5B4 0.368 0.038 0.37 0.045 0.024 0.016 3.53 0.19 1.02 0.066 0.428 0.031 WP52SJ5B5 28.8 1.09 51.79 4.01 0.055 0.57 6.62 0.36 38.31 2.45 65.15 4.58 WP52SJ5B6 0.273 0.042 0.157 0.039 0.061 0.021 3.4 0.18 0.72 0.047 0.43 0.031 WP52SJ5B7 0.471 0.048 0.284 0.047 0.073 0.022 3.16 0.17 0.94 0.061 0.619 0.044 WP52SJ5B8 0.394 0.063 0.518 0.072 0.038 0.02 0.214 0.046 1.018 0.066 0.28 0.021 WP52SJ5B9 1.242 0.068 1.75 0.15 0.028 0.014 0.128 0.031 1.316 0.085 0.412 0.03 WP52SJ5B10 39.39 1.46 28.13 2.18 0.023 0.096 1.82 0.11 18.95 1.21 15.14 1.06 WP52SJ2C1 bdl 0.05 0.15 0.048 0.022 0.018 6.67 0.35 0.318 0.021 1.18 0.084 WP52SJ2C2 0.453 0.054 0.236 0.052 0.07 0.017 6.73 0.35 0.32 0.021 1.76 0.12

WP52SJ2C3 0.273 0.052 0.583 0.069 0.057 0.018 6.37 0.34 0.296 0.02 1.107 0.079 WP52SJ2C4 26.2 1 27.81 2.17 0.038 0.052 10.26 0.55 23.4 1.5 30.92 2.18 WP52SJ2C5 0.22 0.046 0.56 0.063 0.05 0.016 5.76 0.3 0.384 0.025 1.45 0.1 WP52SJ2C6 5.28 0.22 3.92 0.32 0.105 0.022 6.5 0.35 3.89 0.25 5.77 0.41 WP52SJ2C7 9 0.34 4.21 0.33 0.029 0.015 6 0.31 6.42 0.41 7.55 0.53 WP52SJ2C8 30.86 1.14 7.97 0.62 0.077 0.022 6.55 0.34 13.04 0.83 11.58 0.81 WP52SJ2C9 7.54 0.29 3.68 0.29 0.095 0.015 6.41 0.34 7.15 0.46 7.41 0.52 WP52SJ2C10 1.162 0.063 0.934 0.085 0.093 0.014 6.15 0.32 0.926 0.06 1.65 0.12 WP54SJ4 (83 µm ) WP54SJ4A1 0.413 0.035 0.074 0.023 0.106 0.024 4.71 0.23 0.387 0.016 0.325 0.016 WP54SJ4A2 0.337 0.035 0.125 0.024 0.249 0.02 4.65 0.22 0.335 0.014 0.255 0.013 WP54SJ4A3 0.451 0.034 0.391 0.029 0.142 0.021 3.97 0.19 0.395 0.016 0.414 0.02 WP54SJ4A4 0.353 0.033 0.172 0.025 0.142 0.02 4.86 0.23 0.315 0.013 0.369 0.018 WP54SJ4A5 0.471 0.036 0.318 0.028 0.163 0.02 4.82 0.23 0.359 0.015 0.569 0.027 WP54SJ4A6 0.446 0.035 0.282 0.027 0.234 0.027 4 0.19 0.504 0.021 0.203 0.01

Conc. (ppm) Spot [65Cu] ±1σ [66Zn] ±1σ [71Ga] ±1σ [72Ge] ±1σ [88Sr] ±1σ [89Y] ±1σ WP54SJ4A7 0.808 0.044 0.404 0.032 0.178 0.025 3.87 0.19 0.45 0.019 0.793 0.037 WP54SJ4A8 0.572 0.036 0.278 0.026 0.181 0.027 3.08 0.15 0.521 0.022 0.935 0.044 WP54SJ4A9 0.484 0.034 0.192 0.024 0.114 0.023 3.48 0.17 0.403 0.017 0.287 0.014 WP54SJ4A10 0.661 0.04 0.268 0.026 0.11 0.025 4.24 0.2 0.349 0.015 0.239 0.012 WP54SJ4B1 0.193 0.033 0.277 0.03 0.051 0.015 4.49 0.22 0.359 0.015 0.145 0.0077 WP54SJ4B2 0.277 0.033 0.334 0.029 0.053 0.013 5.52 0.26 0.337 0.014 0.218 0.011 WP54SJ4B3 2.073 0.082 0.54 0.035 0.064 0.013 4.34 0.21 0.412 0.017 0.594 0.028 WP54SJ4B4 2.023 0.081 0.661 0.04 0.027 0.013 5.02 0.24 0.373 0.016 0.337 0.016 WP54SJ4B5 0.563 0.039 0.413 0.031 0.028 0.013 4.62 0.22 0.363 0.015 0.1038 0.0057 WP54SJ4B6 0.636 0.038 0.356 0.028 0.03 0.013 4.81 0.23 0.341 0.014 0.227 0.011 WP54SJ4B7 0.817 0.045 0.387 0.029 0.092 0.013 4.62 0.22 0.31 0.013 0.0999 0.0055 WP54SJ4B8 1.057 0.053 0.475 0.034 0.029 0.014 4.75 0.23 0.34 0.014 0.1589 0.0083 WP54SJ4B9 1.401 0.062 0.413 0.033 0.04 0.013 5.9 0.28 0.2127 0.0095 0.282 0.014

WP54SJ4B10 2.82 0.11 0.603 0.038 0.026 0.013 5.25 0.25 0.296 0.013 0.1083 0.006 WP54SJ4C1 0.326 0.034 0.384 0.031 0.025 0.012 5.33 0.25 0.291 0.013 0.0474 0.0032 WP54SJ4C2 0.316 0.033 0.359 0.03 0.027 0.013 5.55 0.26 0.314 0.013 0.0629 0.0038 WP54SJ4C3 0.317 0.032 0.609 0.036 0.033 0.013 5.46 0.26 0.303 0.013 0.0682 0.004 WP54SJ4C4 0.263 0.03 0.325 0.028 0.025 0.012 5.24 0.25 0.309 0.013 0.212 0.011 WP54SJ4C5 0.092 0.029 0.421 0.03 0.074 0.012 5.28 0.25 0.32 0.014 0.0718 0.0042 WP54SJ4C6 0.195 0.03 0.352 0.029 0.06 0.014 5.38 0.26 0.314 0.013 0.0677 0.0041 WP54SJ4C7 0.506 0.038 0.771 0.044 0.031 0.014 5.55 0.26 0.383 0.016 0.0946 0.0053 WP54SJ4C8 1.451 0.064 5.45 0.21 0.078 0.014 5.6 0.27 0.394 0.017 0.1137 0.0062 WP54SJ4C9 0.368 0.032 0.49 0.032 0.031 0.013 5.56 0.26 0.334 0.014 0.1005 0.0055 WP54SJ4C10 0.328 0.033 0.554 0.035 0.026 0.013 5.2 0.25 0.345 0.015 0.0648 0.004 WP54SJ4D1 0.63 0.035 0.325 0.025 0.435 0.012 bdl 0.018 1.734 0.069 0.1288 0.0067 WP54SJ4D2 0.555 0.033 0.189 0.021 0.187 0.014 bdl 0.019 1.789 0.071 0.1881 0.0094 WP54SJ4D3 0.395 0.03 0.23 0.022 0.143 0.012 bdl 0.019 1.772 0.071 0.1504 0.0077 WP54SJ4D4 0.314 0.027 0.285 0.023 0.159 0.012 0.082 0.02 1.736 0.069 0.1173 0.0061

Conc. (ppm) Spot [65Cu] ±1σ [66Zn] ±1σ [71Ga] ±1σ [72Ge] ±1σ [88Sr] ±1σ [89Y] ±1σ WP54SJ4D5 0.371 0.031 0.211 0.024 0.176 0.014 bdl 0.021 1.362 0.055 0.1101 0.006 WP54SJ4D6 0.481 0.034 0.267 0.025 0.292 0.015 0.042 0.021 1.526 0.061 0.141 0.0073 WP54SJ4D7 0.373 0.034 0.289 0.027 0.095 0.015 bdl 0.024 1.834 0.073 0.1764 0.0091 WP54SJ4D8 0.9 0.046 0.391 0.029 0.123 0.015 0.041 0.022 1.87 0.075 0.1908 0.0097 WP54SJ4D9 0.93 0.044 0.376 0.027 0.118 0.013 bdl 0.021 1.585 0.063 0.1606 0.0082 WP54SJ4D10 0.892 0.047 0.51 0.033 0.089 0.015 0.052 0.024 1.689 0.068 0.1487 0.0078 WP54SJ4E1 0.493 0.046 0.209 0.033 0.034 0.019 6.89 0.33 0.319 0.014 0.317 0.016 WP54SJ4E2 0.331 0.034 0.253 0.027 0.029 0.014 8.18 0.39 0.324 0.014 0.502 0.024 WP54SJ4E3 0.364 0.033 0.368 0.029 0.033 0.014 7.72 0.37 0.397 0.017 0.587 0.028 WP54SJ4E4 0.158 0.034 0.28 0.031 0.04 0.016 7.29 0.35 0.322 0.014 0.468 0.023 WP54SJ4E5 0.276 0.035 0.271 0.029 0.031 0.015 9.37 0.44 0.351 0.015 0.562 0.027 WP54SJ4E6 0.223 0.036 0.38 0.033 0.084 0.016 6.96 0.33 0.456 0.019 0.713 0.034 WP54SJ4E7 0.223 0.043 0.267 0.035 0.042 0.02 9.73 0.46 0.308 0.014 0.648 0.031

1 WP54SJ4E8 0.23 0.035 0.313 0.031 0.026 0.017 7.52 0.36 0.359 0.015 0.87 0.041

WP54SJ4E9 0.293 0.049 0.351 0.04 0.027 0.022 7.39 0.35 0.442 0.019 1.417 0.067 WP54SJ4E10 0.404 0.039 0.342 0.032 0.044 0.015 5.89 0.28 0.401 0.017 0.663 0.032 WP54SJ4F1 0.517 0.039 0.362 0.031 1.251 0.014 4.51 0.22 0.406 0.017 0.1133 0.0062 WP54SJ4F2 0.923 0.052 0.934 0.051 2.15 0.015 4.61 0.22 0.379 0.016 0.1305 0.0072 WP54SJ4F3 0.575 0.046 0.339 0.034 1.848 0.017 4.27 0.21 0.428 0.018 0.1183 0.0066 WP54SJ4F4 0.454 0.037 0.475 0.034 4.11 0.014 4.75 0.23 0.428 0.018 0.1253 0.0068 WP54SJ4F5 0.504 0.041 0.563 0.037 2.439 0.015 4.68 0.22 0.391 0.016 0.1052 0.0058 WP54SJ4F6 16.03 0.57 7.23 0.31 2.134 0.031 4.82 0.25 1.783 0.074 5.36 0.25 WP54SJ4F7 0.895 0.053 0.481 0.038 1.837 0.017 4.28 0.21 0.452 0.019 0.219 0.011 WP54SJ4F8 1.412 0.069 0.464 0.038 0.883 0.018 3.98 0.19 0.44 0.019 0.1724 0.0092 WP54SJ4F9 1.539 0.07 0.444 0.035 0.924 0.017 3.43 0.17 0.507 0.021 0.1473 0.0079 WP54SJ4F10 2.097 0.083 0.437 0.032 1.09 0.014 4.56 0.22 0.443 0.018 0.1605 0.0083

Conc. (ppm) Spot [65Cu] ±1σ [66Zn] ±1σ [71Ga] ±1σ [72Ge] ±1σ [88Sr] ±1σ [89Y] ±1σ WP63SJ1 (83 µm ) WP63SJ1A1 1.066 0.071 0.349 0.054 0.02 0.018 0.918 0.069 0.509 0.024 0.052 0.004 WP63SJ1A2 0.138 0.056 bdl 0.048 0.041 0.018 1.008 0.074 0.493 0.023 0.0303 0.0029 WP63SJ1A3 bdl 0.047 0.22 0.045 0.03 0.017 0.946 0.068 0.411 0.02 0.0374 0.0032 WP63SJ1A4 0.155 0.052 0.203 0.048 0.06 0.018 0.96 0.071 0.505 0.024 0.0525 0.0039 WP63SJ1A5 0.103 0.049 0.091 0.044 0.051 0.018 0.922 0.07 0.549 0.026 0.0549 0.0042 WP63SJ1A6 0.142 0.046 0.319 0.046 0.038 0.016 0.903 0.065 0.51 0.024 0.0541 0.0038 WP63SJ1A7 0.248 0.047 0.097 0.042 0.119 0.015 0.915 0.065 0.354 0.017 0.0325 0.0028 WP63SJ1A8 0.6 0.054 0.312 0.046 0.115 0.015 0.784 0.06 0.543 0.026 0.0773 0.005 WP63SJ1A9 1.43 0.078 0.28 0.046 0.127 0.016 0.99 0.069 0.573 0.027 0.0584 0.0042 WP63SJ1A10 1.704 0.092 0.468 0.056 0.175 0.017 0.822 0.066 0.472 0.023 0.0506 0.0041 WP63SJ1B1 0.47 0.052 bdl 0.041 0.022 0.015 1.081 0.074 0.666 0.031 0.0426 0.0034 WP63SJ1B2 0.29 0.047 0.338 0.046 0.023 0.015 0.622 0.053 0.69 0.032 0.0592 0.0042

WP63SJ1B3 0.107 0.041 0.289 0.04 0.421 0.013 0.652 0.05 0.714 0.033 0.0469 0.0034 WP63SJ1B4 0.231 0.047 0.128 0.042 0.121 0.015 0.251 0.039 0.645 0.03 0.0197 0.0023 WP63SJ1B5 0.219 0.049 0.348 0.048 0.705 0.015 0.653 0.055 0.691 0.032 0.0471 0.0037 WP63SJ1B6 0.221 0.042 0.128 0.04 0.5 0.014 0.829 0.059 0.733 0.034 0.0532 0.0037 WP63SJ1B7 0.167 0.043 0.207 0.037 0.187 0.015 0.7 0.053 0.901 0.041 0.0781 0.0048 WP63SJ1B8 0.15 0.042 bdl 0.036 0.119 0.014 0.745 0.056 0.73 0.034 0.045 0.0034 WP63SJ1B9 0.092 0.042 0.278 0.042 0.104 0.014 0.668 0.052 0.766 0.035 0.0569 0.004 WP63SJ1B10 0.344 0.044 0.273 0.043 0.191 0.014 0.699 0.054 0.7 0.033 0.0441 0.0034 WP63SJ1C1 1.525 0.074 0.207 0.037 0.612 0.013 1.384 0.087 0.36 0.017 0.0766 0.0048 WP63SJ1C2 1.782 0.079 0.54 0.043 0.717 0.01 1.558 0.094 0.392 0.018 0.1027 0.0059 WP63SJ1C3 0.439 0.037 0.268 0.035 0.717 0.011 1.626 0.097 0.339 0.016 0.0913 0.0053 WP63SJ1C4 0.42 0.039 0.376 0.038 0.371 0.012 1.411 0.086 0.374 0.018 0.0728 0.0045 WP63SJ1C5 0.409 0.037 0.428 0.04 0.26 0.011 2 0.12 0.399 0.019 0.1026 0.0059 WP63SJ1C6 0.362 0.041 0.31 0.039 1.227 0.013 1.481 0.092 0.424 0.02 0.1066 0.0063 WP63SJ1C7 0.237 0.038 bdl 0.033 0.757 0.012 1.233 0.079 0.262 0.013 0.0686 0.0044

Conc. (ppm) Spot [65Cu] ±1σ [66Zn] ±1σ [71Ga] ±1σ [72Ge] ±1σ [88Sr] ±1σ [89Y] ±1σ WP63SJ1C8 0.251 0.044 0.25 0.041 0.46 0.014 1.068 0.072 0.354 0.017 0.0645 0.0042 WP63SJ1C9 0.159 0.042 0.466 0.045 0.359 0.014 1.033 0.069 0.273 0.013 0.0791 0.0049 WP63SJ1C10 0.268 0.039 0.238 0.037 0.431 0.013 1.325 0.083 0.326 0.016 0.0847 0.0052 WP63SJ1D1 1.367 0.071 0.364 0.043 0.03 0.015 1.263 0.081 0.474 0.022 0.23 0.012 WP63SJ1D2 1.23 0.069 0.247 0.04 0.138 0.016 1.254 0.082 0.513 0.024 0.29 0.016 WP63SJ1D3 1.055 0.081 0.298 0.056 0.031 0.022 1.06 0.082 0.357 0.018 0.196 0.012 WP63SJ1D4 0.879 0.075 0.239 0.056 0.03 0.021 1.177 0.087 0.351 0.018 0.1553 0.0094 WP63SJ1D5 0.57 0.068 bdl 0.053 0.03 0.021 1.281 0.092 0.392 0.019 0.0994 0.0067 WP63SJ1D6 0.625 0.07 0.284 0.058 0.05 0.022 1.118 0.083 0.341 0.017 0.197 0.011 WP63SJ1D7 0.254 0.059 0.331 0.056 0.035 0.02 1.189 0.085 0.238 0.012 0.1047 0.0068 WP63SJ1D8 0.26 0.044 0.194 0.039 0.031 0.014 0.69 0.054 0.395 0.019 0.1216 0.0071 WP63SJ1D9 0.25 0.063 0.143 0.056 0.029 0.02 0.85 0.073 0.324 0.017 0.0893 0.0064 WP63SJ1D10 1.357 0.098 0.225 0.066 0.035 0.025 0.956 0.084 0.387 0.02 0.546 0.03

WP63SJ1E1 0.474 0.06 0.347 0.055 0.574 0.02 0.853 0.068 0.969 0.045 0.0594 0.0045 WP63SJ1E2 0.525 0.063 0.332 0.057 0.806 0.02 0.775 0.067 0.978 0.045 0.0381 0.0036 WP63SJ1E3 0.279 0.053 bdl 0.045 0.752 0.017 1.115 0.079 0.751 0.035 0.1301 0.008 WP63SJ1E4 0.582 0.062 0.395 0.056 0.403 0.019 0.889 0.071 0.733 0.035 0.1101 0.0071 WP63SJ1E5 0.551 0.076 0.209 0.063 0.713 0.024 1.317 0.098 0.547 0.027 0.0204 0.0034 WP63SJ1E6 0.601 0.055 0.389 0.047 0.71 0.016 1.054 0.073 0.599 0.028 0.0576 0.0042 WP63SJ1E7 0.428 0.045 0.289 0.04 0.645 0.015 0.93 0.065 0.594 0.028 0.0172 0.0021 WP63SJ1E8 0.559 0.052 0.245 0.045 0.579 0.016 0.889 0.066 0.578 0.027 0.0277 0.0027 WP63SJ1E9 0.562 0.049 0.34 0.042 0.658 0.014 0.96 0.066 0.91 0.042 0.095 0.0057 WP63SJ1E10 0.298 0.051 0.163 0.044 0.995 0.017 1.216 0.084 0.808 0.038 0.0335 0.0032 WP63SJ1F1 0.617 0.052 0.228 0.04 0.706 0.015 1.146 0.077 0.417 0.02 0.1183 0.0071 WP63SJ1F2 0.895 0.066 0.266 0.048 0.773 0.018 1.385 0.092 0.378 0.018 0.1702 0.0098 WP63SJ1F3 0.469 0.053 bdl 0.042 0.72 0.017 0.952 0.069 0.339 0.017 0.1695 0.0096 WP63SJ1F4 0.312 0.042 0.107 0.038 0.574 0.015 1.14 0.075 0.295 0.014 0.0961 0.0059 WP63SJ1F5 0.705 0.056 0.142 0.038 0.729 0.016 1.122 0.076 0.426 0.02 0.197 0.011

Conc. (ppm) Spot [65Cu] ±1σ [66Zn] ±1σ [71Ga] ±1σ [72Ge] ±1σ [88Sr] ±1σ [89Y] ±1σ WP63SJ1F6 0.683 0.052 0.158 0.038 0.778 0.016 1.101 0.074 0.391 0.019 0.1255 0.0074 WP63SJ1F7 1.411 0.073 0.198 0.039 1.143 0.015 1.198 0.078 0.401 0.019 0.398 0.021 WP63SJ1F8 0.907 0.055 0.101 0.036 0.99 0.014 1.093 0.072 0.393 0.019 0.1199 0.0069 WP63SJ1F9 2.67 0.12 0.239 0.041 0.961 0.015 1.326 0.087 0.437 0.021 0.648 0.034 WP63SJ1F10 1.806 0.087 0.252 0.041 0.65 0.015 1.191 0.078 1.014 0.047 0.148 0.0085 WP75SJ7 (83 µm ) WP75SJ7A1 5.02 0.19 8.33 0.38 0.079 0.025 5.17 0.34 10.55 0.48 9.85 0.54 WP75SJ7A2 1.468 0.066 0.091 0.022 0.088 0.016 3.58 0.23 1.172 0.054 1.511 0.084 WP75SJ7A3 1.555 0.066 0.161 0.021 0.078 0.013 3.54 0.23 0.931 0.043 4.88 0.27 WP75SJ7A4 1.171 0.054 0.088 0.02 0.051 0.013 3.26 0.21 1.156 0.054 0.874 0.049 WP75SJ7A5 4.4 0.17 1.377 0.074 0.085 0.016 3.76 0.25 2.009 0.093 1.88 0.1 WP75SJ7A6 3.18 0.13 1.424 0.076 0.039 0.019 3.37 0.22 8.27 0.38 21.04 1.16 WP75SJ7A7 2.477 0.1 0.912 0.053 0.214 0.015 2.76 0.18 3.53 0.16 1.777 0.099

WP75SJ7A8 1.926 0.079 0.734 0.044 0.12 0.013 2.87 0.19 1.133 0.053 1.85 0.1 WP75SJ7A9 2.42 0.095 1.063 0.057 0.158 0.013 3.13 0.2 1.019 0.047 1.752 0.097 WP75SJ7A10 1.023 0.056 0.324 0.03 0.185 0.015 2.91 0.19 1.296 0.06 1.618 0.09 WP75SJ7A11 1.444 0.071 0.422 0.039 0.13 0.018 0.848 0.067 2.5 0.12 9.62 0.53 WP75SJ7A12 2.037 0.088 0.728 0.047 0.167 0.016 1.029 0.076 4.65 0.21 7.04 0.39 WP75SJ7A13 1.578 0.073 0.526 0.04 0.277 0.016 0.936 0.071 2.42 0.11 8.44 0.47 WP75SJ7A14 1.311 0.067 0.403 0.036 0.206 0.016 1.369 0.096 2.39 0.11 8.07 0.45 WP75SJ7A15 2.131 0.087 0.395 0.032 13.33 0.014 0.895 0.065 2.71 0.13 9.45 0.52 WP75SJ7A16 1.914 0.088 0.54 0.043 0.34 0.018 1.151 0.085 2.81 0.13 11.17 0.62 WP75SJ7A17 5.19 0.2 0.566 0.043 0.345 0.018 0.999 0.077 2.53 0.12 6.79 0.37 WP75SJ7A18 1.247 0.062 0.451 0.035 0.031 0.014 0.96 0.071 2.03 0.094 6.15 0.34 WP75SJ7A19 1.433 0.067 0.318 0.031 0.038 0.015 0.9 0.067 2.29 0.11 6.14 0.34 WP75SJ7A20 2.94 0.11 0.311 0.028 2.122 0.013 0.943 0.068 1.962 0.091 4.95 0.27 WP75SJ7A21 1.545 0.068 2.05 0.1 0.032 0.052 bdl 0.026 2.9 0.13 3.77 0.21 WP75SJ7A22 5.75 0.21 4.3 0.2 0.042 0.086 0.179 0.03 4.01 0.18 2.71 0.15

Conc. (ppm) Spot [65Cu] ±1σ [66Zn] ±1σ [71Ga] ±1σ [72Ge] ±1σ [88Sr] ±1σ [89Y] ±1σ WP75SJ7A23 4.11 0.16 3.45 0.16 0.03 0.075 0.098 0.029 5.18 0.24 11.29 0.62 WP75SJ7A24 20.17 0.71 8.19 0.37 0.6 0.16 1.84 0.12 15.77 0.72 379.37 20.88 WP75SJ7A25 49.11 1.71 19.54 0.87 0.029 0.098 5.81 0.38 13.92 0.64 28.84 1.59 WP75SJ7A26 7.78 0.29 5.03 0.24 0.038 0.088 0.17 0.04 8.81 0.41 21.4 1.18 WP75SJ7A27 4.53 0.17 3.18 0.15 0.084 0.076 0.122 0.037 6.08 0.28 4.53 0.25 WP75SJ7A28 2.92 0.13 1.063 0.071 0.272 0.045 0.08 0.044 3.34 0.15 3.99 0.22 WP75SJ7A29 4.16 0.17 1.644 0.093 0.099 0.046 bdl 0.043 3.41 0.16 3.1 0.17 WP75SJ7A30 2.5 0.12 1.681 0.096 0.087 0.053 0.267 0.052 54.14 2.48 1.374 0.077 WP75SJ7A31 2.31 0.091 0.316 0.026 0.033 0.011 3.03 0.2 3.13 0.14 5.87 0.32 WP75SJ7A32 2.98 0.12 0.494 0.037 0.037 0.015 5.03 0.33 3.8 0.18 5.65 0.31 WP75SJ7A33 3.3 0.13 0.358 0.037 0.041 0.018 4.66 0.3 4.09 0.19 7.55 0.42 WP75SJ7A34 5.77 0.21 0.449 0.034 0.035 0.015 5.15 0.33 6.94 0.32 12.58 0.69 WP75SJ7A35 3.38 0.13 0.381 0.032 0.029 0.015 5.06 0.33 4.14 0.19 6.73 0.37

WP75SJ7A36 1.673 0.084 0.282 0.037 0.03 0.022 4.12 0.27 2.88 0.13 3.95 0.22 WP75SJ7A37 1.788 0.09 0.147 0.033 0.029 0.023 3.56 0.24 2.45 0.11 3.31 0.18 WP75SJ7A38 2.35 0.11 bdl 0.034 0.027 0.025 2.95 0.2 2.78 0.13 4.54 0.25 WP75SJ7A39 3.18 0.13 0.098 0.026 0.073 0.019 3.72 0.24 2.9 0.13 4.26 0.24 WP75SJ7A40 1.329 0.062 0.138 0.022 0.026 0.016 3.35 0.22 1.671 0.077 4.59 0.25 WP114SJ2A (83 µm ) WP114SJ2AA1 3.42 0.16 0.235 0.025 0.026 0.014 bdl 0.025 2.574 0.09 1.132 0.048 WP114SJ2AA2 2.51 0.12 0.198 0.025 0.029 0.014 0.056 0.026 2.97 0.1 0.909 0.039 WP114SJ2AA3 24 1.03 3.02 0.15 0.028 0.023 0.188 0.028 10.22 0.35 15.78 0.66 WP114SJ2AA4 6.7 0.29 0.319 0.025 0.028 0.012 bdl 0.02 3.7 0.13 2.56 0.11 WP114SJ2AA5 6.76 0.3 0.559 0.04 0.025 0.034 0.204 0.031 2.97 0.1 5.22 0.22 WP114SJ2AA6 3.58 0.16 0.802 0.049 0.027 0.027 0.08 0.027 3.11 0.11 5.87 0.24 WP114SJ2AA7 4.18 0.19 0.241 0.025 0.029 0.016 bdl 0.023 2.738 0.095 3.18 0.13 WP114SJ2AA8 3.55 0.16 0.287 0.025 0.025 0.014 bdl 0.023 2.773 0.096 0.922 0.039 WP114SJ2AA9 3.67 0.17 0.318 0.028 0.025 0.014 0.07 0.025 2.799 0.098 1.321 0.056

Conc. (ppm) Spot [65Cu] ±1σ [66Zn] ±1σ [71Ga] ±1σ [72Ge] ±1σ [88Sr] ±1σ [89Y] ±1σ WP114SJ2AA10 3.87 0.18 1.059 0.062 0.024 0.017 bdl 0.025 4.99 0.17 2.138 0.09 WP114SJ2AB1 6.87 0.31 9.29 0.44 0.035 0.039 bdl 0.052 4.33 0.15 1.148 0.049 WP114SJ2AB2 4.83 0.23 5.9 0.29 0.04 0.041 bdl 0.045 3.32 0.12 1.076 0.047 WP114SJ2AB3 5.83 0.27 7.77 0.38 0.062 0.045 bdl 0.056 4.52 0.16 3.34 0.14 WP114SJ2AB4 1.24 0.079 1.307 0.079 0.075 0.029 0.082 0.042 2.076 0.073 0.292 0.014 WP114SJ2AB5 3.59 0.18 6.7 0.33 0.02 0.036 bdl 0.06 17.13 0.59 1.25 0.054 WP114SJ2AB6 15.22 0.67 16.54 0.78 0.06 0.06 0.47 0.064 8.48 0.29 1.218 0.053 WP114SJ2AB7 4.43 0.21 5.42 0.27 0.023 0.044 bdl 0.049 3.71 0.13 0.762 0.034 WP114SJ2AB8 4.74 0.22 6.21 0.3 0.027 0.034 bdl 0.051 3.62 0.13 0.868 0.038 WP114SJ2AB9 3.63 0.17 4.8 0.24 0.029 0.03 bdl 0.045 3.1 0.11 0.551 0.025 WP114SJ2AB10 9.51 0.42 6.19 0.3 0.037 0.031 bdl 0.043 3.91 0.14 0.766 0.034 WP114SJ2AC1 0.887 0.057 4.99 0.24 0.039 0.018 bdl 0.031 1.13 0.04 0.1095 0.0057 WP114SJ2AC2 27.37 1.18 4.24 0.21 0.107 0.027 0.568 0.065 6.01 0.21 2.89 0.12

WP114SJ2AC3 1.471 0.077 1.122 0.063 0.054 0.017 bdl 0.03 1.288 0.045 0.0726 0.0041 WP114SJ2AC4 1.384 0.076 0.964 0.058 0.059 0.017 0.064 0.033 1.249 0.044 0.1464 0.0072 WP114SJ2AC5 1.443 0.075 0.903 0.052 0.038 0.015 bdl 0.03 1.178 0.042 0.1001 0.0051 WP114SJ2AC6 1.202 0.094 0.974 0.075 0.153 0.03 bdl 0.058 1.493 0.054 0.1347 0.0082 WP114SJ2AC7 1.43 0.075 0.871 0.053 0.068 0.015 0.06 0.03 1.229 0.043 0.0888 0.0048 WP114SJ2AC8 1.429 0.075 0.939 0.054 0.041 0.015 bdl 0.031 1.534 0.054 0.0904 0.0047 WP114SJ2AC9 1.961 0.099 1.523 0.083 0.035 0.016 0.126 0.034 2.728 0.095 0.0817 0.0047 WP114SJ2AC10 1.513 0.079 1.264 0.07 0.084 0.015 bdl 0.03 1.84 0.065 0.05 0.0032 WP114SJ2AD1 4.73 0.21 4.95 0.24 0.105 0.03 0.191 0.032 5.28 0.18 0.866 0.037 WP114SJ2AD2 3.92 0.18 5.17 0.24 0.109 0.036 bdl 0.027 5.38 0.19 0.868 0.037 WP114SJ2AD3 3.81 0.17 5.47 0.26 0.029 0.036 0.07 0.031 5.87 0.2 1.281 0.054 WP114SJ2AD4 2.92 0.14 4.17 0.2 0.073 0.024 0.074 0.029 13.13 0.45 3.49 0.15 WP114SJ2AD5 3.32 0.15 5.03 0.24 0.036 0.033 0.096 0.03 6.71 0.23 0.723 0.031 WP114SJ2AD6 3.7 0.18 5.86 0.28 0.06 0.037 0.056 0.037 6.37 0.22 0.83 0.036 WP114SJ2AD7 3 0.15 5.01 0.25 0.065 0.035 0.201 0.04 8.09 0.28 0.75 0.033

Conc. (ppm) Spot [65Cu] ±1σ [66Zn] ±1σ [71Ga] ±1σ [72Ge] ±1σ [88Sr] ±1σ [89Y] ±1σ WP114SJ2AD8 3.03 0.14 4.55 0.22 0.085 0.032 0.162 0.036 5.99 0.21 0.619 0.027 WP114SJ2AD9 2.59 0.12 4.43 0.21 0.027 0.033 0.112 0.035 5.25 0.18 0.908 0.039 WP114SJ2AD10 3.07 0.15 6.35 0.31 0.037 0.049 bdl 0.04 4.13 0.14 1.025 0.044 WP114SJ2AE1 2.62 0.12 5.06 0.24 0.026 0.035 bdl 0.032 3.14 0.11 0.423 0.019 WP114SJ2AE2 2.56 0.12 4.26 0.2 0.089 0.037 bdl 0.031 2.585 0.09 0.5 0.022 WP114SJ2AE3 2.06 0.1 3.34 0.16 0.085 0.034 0.097 0.03 2.35 0.082 0.371 0.016 WP114SJ2AE4 1.754 0.089 2.92 0.14 0.094 0.03 0.054 0.03 1.847 0.065 0.379 0.017 WP114SJ2AE5 2.13 0.11 3.12 0.16 0.107 0.036 0.203 0.037 2.049 0.072 0.811 0.035 WP114SJ2AE6 2.06 0.11 3.77 0.19 0.122 0.038 0.072 0.035 2.087 0.073 0.341 0.016 WP114SJ2AE7 5.05 0.23 8.1 0.39 0.122 0.052 0.13 0.038 7.07 0.25 0.583 0.026 WP114SJ2AE8 3.64 0.17 6.51 0.31 0.061 0.047 0.061 0.037 2.93 0.1 0.607 0.027 WP114SJ2AE9 7.78 0.35 8.09 0.39 0.07 0.046 0.135 0.039 2.688 0.094 0.735 0.032 WP114SJ2AE10 2.16 0.11 3.42 0.17 0.059 0.034 0.091 0.035 2.078 0.073 0.483 0.021 9

Conc. (ppm) Spot [90Zr] ±1σ [118Sn] ±1σ [121Sb] ±1σ [137Ba] ±1σ [139La] [140Ce] [141Pr] [146Nd] GCPUD003 (83 µm ) GCPUD003A1 6.01 0.34 0.363 0.023 0.0041 0.0016 0.666 0.037 0.0297 0.0631 0.0105 0.0101 GCPUD003A2 10.88 0.61 0.503 0.031 0.0024 0.0022 0.938 0.051 0.0765 0.0521 0.0121 0.053 GCPUD003A3 2.91 0.17 0.424 0.027 0.0054 0.0044 0.495 0.029 0.00749 0.0155 0.00189 0.0069 GCPUD003A4 1.646 0.095 0.421 0.027 0.0031 0.0023 0.348 0.022 0.0566 0.0462 0.00138 0.0222 GCPUD003A5 2.13 0.12 0.291 0.02 0.0028 0.0024 0.522 0.03 bdl 0.0118 0.0044 0.0159 GCPUD003A6 2.92 0.17 0.338 0.022 0.0046 0.0011 1.131 0.06 0.018 0.0221 0.0053 0.0198 GCPUD003A7 3.45 0.2 0.442 0.029 0.0029 0.0017 0.896 0.05 0.0072 0.0068 0.00169 0.0089 GCPUD003A8 3.62 0.2 0.344 0.023 0.0033 0.0021 0.931 0.05 0.002 0.00688 0.00128 0.0198 GCPUD003A9 3.08 0.18 0.348 0.023 0.0034 0.0029 3.64 0.18 0.0129 0.0276 0.0087 0.039 GCPUD003A10 15.28 0.86 1.061 0.06 0.0019 0.036 17.17 0.83 0.283 0.486 0.0028 0.005 GCPUD003A11 9.38 0.53 0.3 0.02 0.0024 0.0038 0.706 0.039 0.0124 0.0174 0.0033 0.0069 GCPUD003A12 2.81 0.16 0.242 0.017 0.0026 0.0011 0.394 0.023 0.0142 0.0244 0.0087 0.039

8 GCPUD003A13 2.91 0.17 0.279 0.019 0.0022 0.0061 0.508 0.03 0.0103 0.0158 0.0013 0.0068

GCPUD003A14 5.41 0.31 0.312 0.022 0.0045 0.0013 0.694 0.04 0.0127 0.0143 0.00141 0.0046 GCPUD003A15 3.25 0.18 0.221 0.015 0.005 0.00075 0.391 0.023 0.00341 0.00655 0.0137 0.057 GCPUD003A16 3.97 0.22 0.257 0.017 0.0046 0.0021 0.524 0.03 0.00498 0.0128 0.0037 0.0095 GCPUD003A17 5.71 0.32 0.218 0.016 0.0089 0.002 0.359 0.022 0.00551 0.0069 0.00224 0.0216 GCPUD003A18 6.88 0.39 0.196 0.014 0.0087 0.0019 0.274 0.017 0.0059 0.00885 0.0042 0.0162 GCPUD003A19 3.63 0.21 0.324 0.023 0.0116 0.0013 0.745 0.042 0.00533 0.00392 0.00127 0.0047 GCPUD003A20 7.55 0.42 0.381 0.024 0.0034 0.0095 11.5 0.56 0.0593 0.0668 0.00148 0.0061 GCPUD003B1 3.64 0.21 0.251 0.021 0.0139 0.0034 0.936 0.053 0.0044 0.0107 0.0021 0.0061 GCPUD003B2 5.03 0.29 0.325 0.024 0.0035 0.005 0.538 0.033 0.00197 bdl 0.00133 0.0059 GCPUD003B3 6.4 0.36 0.269 0.021 0.0135 0.0031 0.295 0.021 bdl bdl 0.00143 0.0067 GCPUD003B4 6.68 0.38 0.255 0.02 0.0064 0.0014 0.402 0.026 0.00308 0.0052 0.0036 0.0092 GCPUD003B5 10.84 0.61 0.236 0.018 0.0043 0.0017 1.313 0.07 0.0153 0.00797 0.0018 0.0103

Conc. (ppm) Spot [90Zr] ±1σ [118Sn] ±1σ [121Sb] ±1σ [137Ba] ±1σ [139La] [140Ce] [141Pr] [146Nd] GCPUD003B6 4.34 0.25 0.259 0.021 0.0063 0.0061 0.244 0.018 bdl 0.0102 0.0015 0.0061 GCPUD003B7 4.99 0.28 0.289 0.022 0.0062 0.0047 0.418 0.027 0.0138 0.0226 0.00147 0.0069 GCPUD003B8 4.13 0.23 0.356 0.025 0.0108 0.0043 0.257 0.019 bdl 0.00361 0.0018 0.0055 GCPUD003B9 4.23 0.24 0.308 0.022 0.0034 0.0024 0.738 0.041 0.0109 0.00197 0.00142 0.0065 GCPUD003B10 6.22 0.35 0.33 0.024 0.003 0.005 1.093 0.06 0.00264 0.0104 0.00149 0.0057 GCPUD004 (64 μm) GCPUD004A1 14.46 0.052 0.181 0.022 0.0042 0.0019 0.81 0.12 0.0229 0.025 0.00198 0.0058 GCPUD004A2 20.67 0.046 0.202 0.023 0.0035 0.0021 0.82 0.12 0.0454 0.0246 0.00124 0.0077 GCPUD004A3 12.05 0.056 0.217 0.025 0.0029 0.0018 0.81 0.12 0.0261 0.0195 0.00189 0.02 GCPUD004A4 17.78 0.061 0.189 0.023 0.0039 0.002 0.74 0.11 0.0605 0.0375 0.00133 0.0069 GCPUD004A5 5.27 0.061 0.246 0.028 0.0035 0.0016 0.91 0.13 0.0547 0.0468 0.0026 0.0068 GCPUD004A6 15.34 0.061 0.211 0.025 0.0038 0.002 0.674 0.099 0.0713 0.0466 0.00171 0.0075 GCPUD004A7 7.18 0.068 0.233 0.028 0.0071 0.0017 0.645 0.095 0.0724 0.064 0.00135 0.0082

GCPUD004A8 18.77 0.054 0.217 0.025 0.0035 0.0023 0.85 0.12 0.091 0.0329 0.0028 0.0105 GCPUD004A9 11.14 0.064 0.239 0.028 0.0067 0.0019 0.536 0.079 0.0737 0.0329 0.00125 0.0064 GCPUD004A10 14.03 0.059 0.27 0.031 0.0033 0.0017 1.01 0.15 0.079 0.0397 0.00176 0.0066 GCPUD004A11 11.2 0.058 0.218 0.025 0.0034 0.0021 0.571 0.084 0.0625 0.0299 0.0018 0.0085 GCPUD004A12 17.31 0.061 0.178 0.021 0.0069 0.0018 0.75 0.11 0.073 0.0332 0.00138 0.0091 GCPUD004A13 17.07 0.056 0.211 0.024 0.0036 0.0018 1.4 0.2 0.0627 0.0305 0.00169 0.0066 GCPUD004A14 20.69 0.062 0.253 0.029 0.0039 0.0019 0.635 0.093 0.094 0.0425 0.0024 0.0066 GCPUD004A15 7.34 0.068 0.036 0.016 0.0039 0.002 6.88 0.98 0.0489 0.0354 0.00172 0.0058 GCPUD004A16 18.93 0.059 0.273 0.03 0.0036 0.0022 0.75 0.11 0.094 0.0429 0.0118 0.061 GCPUD004A17 30.97 0.061 0.207 0.025 0.0067 0.002 0.92 0.13 0.08 0.0283 0.0219 0.114 GCPUD004A18 20.94 0.061 0.258 0.029 0.0038 0.0012 1.4 0.2 0.071 0.039 0.0098 0.061 GCPUD004A19 14.03 0.054 0.214 0.025 0.0036 0.0016 0.573 0.084 0.0173 0.0128 0.024 0.138 GCPUD004A20 6.95 0.051 0.209 0.025 0.003 0.0019 0.593 0.087 0.0127 0.0131 0.031 0.109 GCPUD004A21 15.32 0.054 0.237 0.027 0.0039 0.0018 1.52 0.22 0.0402 0.0476 0.0353 0.14

Conc. (ppm) Spot [90Zr] ±1σ [118Sn] ±1σ [121Sb] ±1σ [137Ba] ±1σ [139La] [140Ce] [141Pr] [146Nd] GCPUD004A22 17.76 0.089 0.295 0.033 0.0033 0.0019 3.45 0.49 0.0504 0.0214 0.0221 0.089 GCPUD004A23 19.07 0.16 0.316 0.035 0.0066 0.002 6.67 0.95 0.104 0.0294 0.031 0.175 GCPUD004B1 8.24 0.67 0.381 0.042 0.0038 0.0033 1.02 0.15 0.0162 0.0596 0.0285 0.124 GCPUD004B2 9.61 0.78 0.299 0.034 0.0053 0.0023 1.63 0.24 0.0207 0.089 0.0384 0.188 GCPUD004B3 8.7 0.7 0.261 0.03 0.0048 0.002 0.85 0.12 0.0103 0.0464 0.0212 0.177 GCPUD004B4 9.45 0.77 0.379 0.042 0.0079 0.0023 0.98 0.14 0.015 0.0556 0.028 0.181 GCPUD004B5 7.83 0.63 0.366 0.042 0.0045 0.0023 0.89 0.13 0.0042 0.0389 0.0314 0.142 GCPUD004B6 10.59 0.86 0.334 0.038 0.0035 0.0021 1.06 0.15 0.0117 0.0467 0.0406 0.19 GCPUD004B7 7.68 0.62 0.28 0.033 0.0039 0.0021 0.83 0.12 0.0088 0.0367 0.0211 0.086 GCPUD004B8 6.93 0.56 0.227 0.03 0.0059 0.0033 0.72 0.11 0.0037 0.0206 0.041 0.21 GCPUD004B9 7.36 0.6 0.27 0.032 0.0085 0.0023 0.85 0.12 0.0064 0.0354 0.0321 0.144 GCPUD004B10 9.71 0.79 0.27 0.031 0.0024 0.0022 1.21 0.18 0.0396 0.068 0.0335 0.162

100 GCPUD004B11 8.58 0.7 0.252 0.031 0.0034 0.0027 0.93 0.14 0.0075 0.0334 0.0124 0.0556 GCPUD004B12 9.37 0.76 0.256 0.031 0.0042 0.0021 1.03 0.15 0.0121 0.0529 0.0058 0.0335

GCPUD004B13 6.57 0.53 0.324 0.037 0.0042 0.0013 0.69 0.1 0.0063 0.0184 0.0148 0.08 GCPUD004B14 8.02 0.65 0.388 0.043 0.0081 0.0023 0.88 0.13 0.0188 0.0407 0.0212 0.097 GCPUD004B15 9.11 0.74 0.369 0.041 0.0062 0.0023 1.03 0.15 0.0097 0.0608 0.0346 0.212 GCPUD004B16 7.94 0.64 0.28 0.034 0.0168 0.0025 0.89 0.13 0.0071 0.0374 0.0056 0.0266 GCPUD004B17 8.52 0.69 0.35 0.04 0.0041 0.0025 1.04 0.15 0.0097 0.0363 0.0076 0.036 GCPUD004B18 8.93 0.72 0.4 0.045 0.0043 0.0027 1.14 0.17 0.0176 0.0509 0.00297 0.0176 GCPUD004B19 5.17 0.42 0.305 0.037 0.0042 0.0026 0.595 0.089 0.0075 0.0156 0.0054 0.0176 GCPUD004B20 5.23 0.42 0.155 0.018 0.0051 0.0011 0.536 0.078 0.0079 0.0168 0.00197 0.022 GCPUD004B21 5.64 0.46 0.345 0.039 0.0046 0.003 0.622 0.092 0.007 0.0133 0.0042 0.026 GCPUD004B22 9.46 0.77 0.291 0.036 0.0039 0.0027 0.89 0.13 0.0096 0.0531 0.00256 0.0065 GCPUD004B23 8.12 0.66 0.331 0.041 0.0071 0.0026 0.72 0.11 0.0099 0.0189 0.0037 0.0077 GCPUD004B24 6.74 0.55 0.286 0.034 0.0046 0.002 0.568 0.085 0.0094 0.0174 0.00375 0.0113 GCPUD004B25 8.04 0.65 0.363 0.042 0.0053 0.0026 0.8 0.12 0.02 0.0327 0.0122 0.0514

Conc. (ppm) Spot [90Zr] ±1σ [118Sn] ±1σ [121Sb] ±1σ [137Ba] ±1σ [139La] [140Ce] [141Pr] [146Nd] GCPUD008 (64 μm) GCPUD008A1 0.121 0.02 0.138 0.029 0.0052 0.0014 1.48 0.4 0.0146 0.0145 0.00224 0.0167 GCPUD008A2 0.085 0.015 0.158 0.032 0.0038 0.0013 1.48 0.4 0.041 0.053 0.00312 0.0159 GCPUD008A3 0.113 0.018 0.176 0.036 0.0028 0.0019 1.36 0.37 0.0134 0.0109 0.00173 0.0101 GCPUD008A4 0.094 0.016 0.157 0.033 0.0053 0.0015 1.12 0.3 0.0064 0.0113 0.0033 0.0437 GCPUD008A5 0.229 0.034 0.161 0.033 0.005 0.0013 1.18 0.32 0.0095 0.0184 0.0045 0.0116 GCPUD008A6 0.124 0.02 0.184 0.038 0.0055 0.0017 1.31 0.35 0.0134 0.0167 0.00161 0.0115 GCPUD008A7 0.102 0.017 0.169 0.035 0.0046 0.0014 1.09 0.3 0.0042 0.0061 0.0023 0.0242 GCPUD008A8 0.179 0.028 0.13 0.027 0.0069 0.0015 2.07 0.56 0.0129 0.0163 0.0077 0.0365 GCPUD008A9 0.189 0.029 0.146 0.03 0.0057 0.0016 1.58 0.43 0.0305 0.0269 0.0038 0.0097 GCPUD008A10 0.192 0.03 0.179 0.036 0.0033 0.0011 1.65 0.45 0.0129 0.0134 0.00188 0.0091 GCPUD008A11 0.163 0.025 0.136 0.029 0.0051 0.0011 1.2 0.32 0.0071 0.0074 0.00212 0.0151

10 GCPUD008A12 0.41 0.06 0.133 0.028 0.0052 0.0012 4.3 1.16 0.032 0.053 0.0047 0.0273

1 GCPUD008A13 0.08 0.015 0.144 0.031 0.0068 0.0013 0.94 0.25 0.0038 bdl 0.0057 0.0116

GCPUD008A14 bdl 0.0093 0.135 0.029 0.0046 0.0015 0.232 0.064 bdl 0.00168 0.00129 0.0193 GCPUD008A15 0.222 0.033 0.175 0.036 0.0044 0.0015 4.01 1.08 0.044 0.062 0.0066 0.047 GCPUD008A16 0.385 0.057 0.151 0.032 0.0024 0.0018 4.48 1.21 0.0096 0.0193 0.00975 0.0303 GCPUD008A17 0.418 0.061 0.145 0.03 0.0035 0.002 4.21 1.13 0.0132 0.0172 0.0139 0.0738 GCPUD008A18 0.426 0.063 0.217 0.044 0.0082 0.0024 3.87 1.04 0.0078 0.016 0.00201 0.0167 GCPUD008A19 bdl 0.0084 0.16 0.033 0.0038 0.0026 0.89 0.24 bdl bdl 0.0129 0.0637 GCPUD008A20 bdl 0.0094 0.202 0.042 0.004 0.0017 0.041 0.014 0.002 0.0047 0.00235 0.0039 GCPUD008B1 0.269 0.042 0.267 0.054 0.0019 0.0035 0.42 0.12 0.0028 0.0087 0.00604 0.0397 GCPUD008B2 0.285 0.043 0.142 0.031 0.0023 0.0014 0.65 0.18 bdl 0.0024 0.00569 0.0165 GCPUD008B3 0.181 0.029 0.199 0.041 0.0032 0.003 0.37 0.1 0.0067 0.0049 0.00182 0.0158 GCPUD008B4 0.221 0.034 0.18 0.038 0.0052 0.0025 0.49 0.13 0.0043 0.0103 0.0118 0.0227 GCPUD008B5 0.216 0.034 0.196 0.041 0.071 0.0023 0.68 0.18 bdl 0.006 0.1209 0.288 GCPUD008B6 0.276 0.042 0.175 0.037 0.0071 0.002 0.64 0.17 bdl bdl 0.00298 0.0252 GCPUD008B7 0.232 0.036 0.134 0.029 0.002 0.0019 0.55 0.15 0.003 0.0051 0.00474 0.0195

Conc. (ppm) Spot [90Zr] ±1σ [118Sn] ±1σ [121Sb] ±1σ [137Ba] ±1σ [139La] [140Ce] [141Pr] [146Nd] GCPUD008B8 0.242 0.037 0.176 0.037 0.0115 0.0027 0.54 0.15 bdl 0.0036 0.00083 0.0159 GCPUD008B9 0.161 0.026 0.208 0.043 0.0023 0.0019 0.336 0.092 0.003 0.0044 0.00538 0.0231 GCPUD008B10 0.264 0.04 0.185 0.039 0.00131 0.0017 0.39 0.11 0.0054 0.0044 0.00169 0.006 GCPUD008B11 0.21 0.033 0.211 0.043 0.0035 0.0019 0.44 0.12 0.0029 0.048 0.00106 0.0062 GCPUD008B12 0.216 0.033 0.188 0.039 0.0033 0.002 0.43 0.12 0.0032 0.0054 0.0019 0.0122 GCPUD008B13 0.22 0.034 0.192 0.04 0.0033 0.0016 0.4 0.11 0.0132 0.0188 0.00054 0.0088 GCPUD008B14 0.243 0.037 0.224 0.046 0.0025 0.0018 0.46 0.12 0.0042 bdl 0.00365 0.0094 GCPUD008B15 0.161 0.026 0.224 0.046 0.0184 0.0019 0.43 0.12 0.0019 bdl 0.0139 0.073 GCPUD008B16 0.187 0.03 0.257 0.052 0.0056 0.0019 0.55 0.15 0.0054 0.0046 0.00114 0.0241 GCPUD008B17 0.211 0.033 0.165 0.035 0.009 0.0022 0.38 0.1 bdl bdl 0.0012 0.0051 GCPUD008B18 0.155 0.026 0.188 0.039 0.005 0.0019 0.4 0.11 0.0076 0.0092 0.00093 0.0183 GCPUD008B19 0.204 0.032 0.234 0.048 0.0024 0.0022 0.48 0.13 0.0023 0.0067 0.00133 0.0127

10 GCPUD008B20 0.106 0.019 0.243 0.049 0.0026 0.0019 0.251 0.07 0.0033 0.0066 0.00322 0.0137

2 GCPUD008B21 0.258 0.039 0.185 0.039 0.0112 0.0017 0.81 0.22 0.0034 0.0025 0.00101 0.0191

GCPUD008B22 0.145 0.024 0.18 0.039 0.004 0.0032 0.38 0.1 bdl 0.0047 0.00814 0.0159 GCPUD008B23 0.14 0.024 0.259 0.053 0.0075 0.002 0.53 0.14 0.0054 0.0081 0.0011 0.0047 GCPUD008B24 0.165 0.027 0.147 0.034 0.0037 0.0023 0.51 0.14 0.0085 0.0069 0.00152 0.0171 GCPUD008B25 0.238 0.037 0.309 0.062 0.0087 0.0022 0.51 0.14 bdl bdl 0.00159 0.0051 WP52SJ5 (83 µm ) WP52SJ5A1 6.36 0.43 0.134 0.012 0.00163 0.001 1.173 0.071 0.0986 0.0802 0.00792 0.0188 WP52SJ5A2 5.05 0.34 0.114 0.01 0.0038 0.0039 0.892 0.055 0.087 0.0504 0.00237 0.0252 WP52SJ5A3 3.24 0.22 0.104 0.011 0.0014 0.004 1.016 0.063 0.0439 0.0267 0.0088 0.0501 WP52SJ5A4 4.93 0.34 0.112 0.01 0.0019 0.002 1.239 0.075 0.0457 0.0235 0.00567 0.0305 WP52SJ5A5 7.13 0.49 0.154 0.013 0.0018 0.0053 2.15 0.13 0.0558 0.0605 0.01146 0.0566 WP52SJ5A6 4.35 0.3 0.114 0.012 0.0058 0.0017 1.5 0.091 0.0252 0.0289 0.00369 0.0177 WP52SJ5A7 6.63 0.45 0.153 0.02 0.0023 0.0052 5.29 0.32 0.0429 0.0369 0.0249 0.1474 WP52SJ5A8 5.16 0.35 0.152 0.016 0.00128 0.0027 5.39 0.32 0.0984 0.0451 0.0307 0.145 WP52SJ5A9 6.6 0.45 0.176 0.017 0.0019 0.0017 0.628 0.041 0.18 0.037 0.00625 0.0498

Conc. (ppm) Spot [90Zr] ±1σ [118Sn] ±1σ [121Sb] ±1σ [137Ba] ±1σ [139La] [140Ce] [141Pr] [146Nd] WP52SJ5A10 4.62 0.32 0.175 0.015 0.0015 0.004 33.66 1.96 0.57 0.631 0.00109 0.0121 WP52SJ5B1 10.88 0.74 0.126 0.011 0.0048 0.0019 1.101 0.067 0.00573 0.00941 0.00524 0.0267 WP52SJ5B2 7.66 0.52 0.104 0.011 0.0022 0.0059 0.758 0.047 0.0034 0.0063 0.01114 0.0557 WP52SJ5B3 3.22 0.22 0.0587 0.0083 0.005 0.0012 0.424 0.029 0.00643 0.0151 0.0323 0.1514 WP52SJ5B4 7 0.48 0.12 0.011 0.0028 0.0026 1.7 0.1 0.0694 0.1124 0.0202 0.0948 WP52SJ5B5 136.37 9.27 7.53 0.49 0.0042 0.047 116.16 6.75 30.41 29.79 0.0038 0.0162 WP52SJ5B6 8.79 0.6 0.148 0.013 0.0079 0.002 0.847 0.052 0.0161 0.0173 0.00976 0.0517 WP52SJ5B7 12.22 0.83 0.123 0.012 0.0014 0.0021 3.17 0.19 0.0315 0.0238 0.0025 0.0192 WP52SJ5B8 1.5 0.1 0.143 0.016 0.0023 0.0098 8.34 0.49 0.169 0.0243 0.00471 0.0226 WP52SJ5B9 1.63 0.11 0.179 0.015 0.0018 0.014 6.83 0.4 0.0178 0.009 0.01029 0.0497 WP52SJ5B10 11.63 0.79 0.526 0.039 0.0036 0.21 53.76 3.13 9.47 9.13 0.00418 0.0129 WP52SJ2C1 4.44 0.3 0.127 0.014 0.0013 0.0022 1.222 0.076 0.0511 0.0604 0.00123 0.0075

103 WP52SJ2C2 7.07 0.48 0.136 0.014 0.0041 0.0022 0.658 0.043 0.0702 0.0895 0.0028 0.0139 WP52SJ2C3 7.13 0.49 0.177 0.016 0.0021 0.0018 0.753 0.049 0.0718 0.0895 0.00305 0.0091

WP52SJ2C4 27.03 1.84 2.23 0.15 0.0025 0.17 232.05 13.48 10.72 11.59 0.00219 0.0217 WP52SJ2C5 5.36 0.37 0.134 0.014 0.0024 0.01 1.78 0.11 0.0629 0.201 0.00104 0.0098 WP52SJ2C6 10.43 0.71 0.565 0.041 0.0057 0.018 40.34 2.35 2.44 1.89 0.00059 0.0135 WP52SJ2C7 9.64 0.66 0.581 0.04 0.011 0.029 51.72 3 3.31 2.34 0.00874 0.041 WP52SJ2C8 10.23 0.7 1.458 0.096 0.038 0.062 137.15 7.96 8.04 3.6 0.00235 0.0161 WP52SJ2C9 8.86 0.6 0.562 0.039 0.0035 0.017 41.89 2.44 3.28 2.19 0.00344 0.0122 WP52SJ2C10 7.89 0.54 0.156 0.014 0.0035 0.0025 6.06 0.36 0.325 0.351 0.00139 0.0119 WP54SJ4 (83 µm ) WP54SJ4A1 9.16 0.41 0.1382 0.01 0.0041 0.00086 0.602 0.027 0.00598 0.00563 0.0205 0.0753 WP54SJ4A2 6.92 0.31 0.199 0.013 0.004 0.0023 0.541 0.025 0.00657 0.00546 0.0327 0.1321 WP54SJ4A3 7.86 0.36 0.19 0.012 0.0013 0.0013 0.747 0.033 0.0192 0.0169 0.0334 0.1031 WP54SJ4A4 6.97 0.32 0.164 0.011 0.0069 0.0013 0.617 0.028 0.0141 0.00562 0.01473 0.073 WP54SJ4A5 8 0.36 0.202 0.013 0.0009 0.0013 0.733 0.032 0.0234 0.0121 0.01269 0.0437 WP54SJ4A6 11.79 0.53 0.164 0.011 0.0016 0.0034 1.046 0.044 0.00675 0.006 0.0163 0.0645

Conc. (ppm) Spot [90Zr] ±1σ [118Sn] ±1σ [121Sb] ±1σ [137Ba] ±1σ [139La] [140Ce] [141Pr] [146Nd] WP54SJ4A7 9.91 0.45 0.196 0.013 0.0112 0.0015 1.264 0.053 0.0796 0.0532 0.0272 0.0936 WP54SJ4A8 10.83 0.49 0.187 0.012 0.0055 0.00089 1.232 0.052 0.0712 0.0365 0.0208 0.0916 WP54SJ4A9 8.05 0.36 0.1183 0.0093 0.0017 0.0013 0.767 0.034 0.0154 0.00542 0.0262 0.1132 WP54SJ4A10 8.82 0.4 0.142 0.01 0.0108 0.0013 0.703 0.032 0.00891 0.00476 0.022 0.1056 WP54SJ4B1 4.13 0.19 0.15 0.011 0.002 0.0029 0.777 0.034 0.01005 0.00679 0.0684 0.311 WP54SJ4B2 5.62 0.26 0.158 0.011 0.00128 0.0014 0.68 0.03 0.0677 0.0168 0.1083 0.506 WP54SJ4B3 5.58 0.25 0.155 0.011 0.002 0.003 1.243 0.052 0.1083 0.0692 0.1556 0.705 WP54SJ4B4 4.62 0.21 0.175 0.012 0.00117 0.0019 0.992 0.042 0.0547 0.0344 0.1362 0.505 WP54SJ4B5 6.64 0.3 0.177 0.012 0.0013 0.0025 0.728 0.032 0.01034 0.00986 0.1244 0.516 WP54SJ4B6 5.18 0.24 0.154 0.011 0.0016 0.0047 0.623 0.028 0.0243 0.01124 0.1398 0.555 WP54SJ4B7 6.06 0.27 0.162 0.011 0.0019 0.001 0.619 0.028 0.00978 0.00506 0.159 0.571 WP54SJ4B8 6.65 0.3 0.201 0.013 0.0019 0.0016 0.659 0.03 0.00643 0.00559 0.426 0.913

10 WP54SJ4B9 2.98 0.14 0.171 0.012 0.005 0.0013 0.627 0.029 0.0415 0.0208 0.384 2.04

4 WP54SJ4B10 3.62 0.17 0.139 0.011 0.0014 0.0023 1.846 0.075 0.0133 0.01093 0.1311 0.595

WP54SJ4C1 9.44 0.43 0.183 0.012 0.0044 0.001 0.643 0.029 0.00547 0.00968 0.00521 0.0337 WP54SJ4C2 9.18 0.42 0.18 0.012 0.0047 0.0025 0.685 0.03 0.00512 0.00913 0.00552 0.0243 WP54SJ4C3 9.36 0.42 0.188 0.012 0.00146 0.0014 0.692 0.031 0.00383 0.00612 0.0073 0.0344 WP54SJ4C4 9.18 0.42 0.159 0.011 0.0053 0.0016 0.749 0.033 0.00387 0.00805 0.00933 0.0248 WP54SJ4C5 9.15 0.41 0.181 0.012 0.00162 0.0016 0.755 0.033 0.00591 0.00804 0.0062 0.0339 WP54SJ4C6 9.44 0.43 0.143 0.01 0.005 0.0034 0.763 0.034 0.00734 13.83 0.341 1.352 WP54SJ4C7 9.64 0.44 0.197 0.013 0.0031 0.0064 0.819 0.036 0.0322 0.00887 0.01158 0.0577 WP54SJ4C8 10.58 0.48 0.181 0.013 0.0018 0.022 0.804 0.036 0.00409 0.00953 0.0127 0.0308 WP54SJ4C9 10.89 0.49 0.172 0.011 0.0038 0.0021 0.819 0.035 0.00432 0.00831 0.0184 0.0669 WP54SJ4C10 11.41 0.52 0.159 0.011 0.0014 0.0021 0.667 0.03 0.00699 0.0097 0.00699 0.0363 WP54SJ4D1 7.97 0.36 0.1447 0.0098 0.07 0.0025 1.511 0.062 0.0766 0.0518 0.421 2.09 WP54SJ4D2 8.38 0.38 0.18 0.011 0.0091 0.0024 1.672 0.068 0.1014 0.0932 0.0989 0.47 WP54SJ4D3 8.58 0.39 0.2 0.012 0.0057 0.0011 1.567 0.064 0.0719 0.0598 0.1574 0.765 WP54SJ4D4 8.39 0.38 0.182 0.011 0.0024 0.004 1.389 0.057 0.0533 0.0515 0.067 0.29

Conc. (ppm) Spot [90Zr] ±1σ [118Sn] ±1σ [121Sb] ±1σ [137Ba] ±1σ [139La] [140Ce] [141Pr] [146Nd] WP54SJ4D5 6.29 0.29 0.153 0.011 0.0029 0.0006 1.203 0.051 0.0538 0.0372 0.1478 0.728 WP54SJ4D6 7.35 0.33 0.168 0.011 0.396 0.0012 1.402 0.058 0.0597 0.0597 1.282 5.7 WP54SJ4D7 10.24 0.46 0.213 0.014 0.0111 0.0065 1.732 0.071 0.0906 0.074 0.1238 0.576 WP54SJ4D8 10.32 0.47 0.197 0.013 0.0114 0.0033 1.665 0.068 0.0818 0.0834 0.152 0.651 WP54SJ4D9 9.09 0.41 0.164 0.011 0.0101 0.0014 1.615 0.066 0.0694 0.0544 0.1404 0.616 WP54SJ4D10 10.42 0.47 0.152 0.011 0.0029 0.0063 1.553 0.064 0.0751 0.0473 0.0835 0.433 WP54SJ4E1 5.16 0.24 0.203 0.015 0.0164 0.0025 0.598 0.029 0.2158 0.299 0.875 4.26 WP54SJ4E2 5.81 0.26 0.17 0.012 0.0028 0.00077 0.698 0.031 0.398 0.475 0.666 3 WP54SJ4E3 8.78 0.4 0.187 0.012 0.019 0.0014 1.069 0.046 0.442 0.928 0.746 3.56 WP54SJ4E4 6.67 0.3 0.173 0.013 0.009 0.001 0.807 0.037 0.343 0.503 0.77 3.53 WP54SJ4E5 8.89 0.4 0.203 0.014 0.0034 0.001 0.879 0.039 0.359 0.514 0.908 4.24 WP54SJ4E6 14.14 0.64 0.205 0.014 0.0021 0.0012 1.486 0.062 0.363 0.585 1.038 4.91

10 WP54SJ4E7 7.06 0.32 0.246 0.017 0.0114 0.001 0.761 0.035 0.435 0.597 0.655 2.88

5 WP54SJ4E8 10.28 0.47 0.178 0.013 0.0023 0.0017 1.159 0.05 0.717 1.333 0.598 2.73

WP54SJ4E9 12.9 0.58 0.269 0.018 0.0105 0.0032 2.108 0.088 1.094 1.38 0.555 2.62 WP54SJ4E10 12.36 0.56 0.186 0.013 0.0044 0.0011 1.51 0.063 0.405 0.62 0.462 2 WP54SJ4F1 1.665 0.077 0.236 0.015 0.132 0.0027 1.164 0.049 0.0211 0.0244 0.839 3.23 WP54SJ4F2 1.054 0.05 0.206 0.014 0.133 0.0029 0.972 0.043 0.0185 0.0325 0.629 2.46 WP54SJ4F3 1.354 0.063 0.2 0.014 0.129 0.00095 1.137 0.049 0.0223 0.0363 0.788 3.64 WP54SJ4F4 1.305 0.061 0.192 0.013 0.078 0.0033 1.146 0.049 0.0224 0.0319 39.15 157.92 WP54SJ4F5 1.158 0.054 0.195 0.013 0.91 0.00089 1.058 0.045 0.0195 0.0346 3.59 14.23 WP54SJ4F6 2.12 0.1 0.624 0.04 0.0428 0.0037 8.43 0.34 0.963 1.32 1.83 7.12 WP54SJ4F7 1.605 0.075 0.21 0.014 0.082 0.002 1.197 0.051 0.0401 0.0476 0.441 1.892 WP54SJ4F8 1.742 0.081 0.209 0.015 0.0323 0.001 1.31 0.056 0.0412 0.0854 0.358 1.344 WP54SJ4F9 1.75 0.081 0.231 0.015 0.0407 0.0024 1.449 0.061 0.0571 0.0891 0.352 1.321 WP54SJ4F10 1.392 0.065 0.233 0.015 0.0419 0.001 1.379 0.057 0.0273 0.0515 0.1495 0.644

Conc. (ppm) Spot [90Zr] ±1σ [118Sn] ±1σ [121Sb] ±1σ [137Ba] ±1σ [139La] [140Ce] [141Pr] [146Nd] WP63SJ1 (83 µm ) WP63SJ1A1 1.58 0.08 0.178 0.015 0.0049 0.002 12.88 0.58 0.0253 0.187 0.527 2.31 WP63SJ1A2 1.423 0.072 0.136 0.014 0.0026 0.002 10.75 0.48 0.0177 0.141 0.522 2.38 WP63SJ1A3 1.443 0.073 0.114 0.012 0.0205 0.0043 25.31 1.13 0.0387 0.289 0.711 2.98 WP63SJ1A4 1.497 0.076 0.147 0.015 0.0092 0.0016 51.08 2.27 0.0752 0.451 1.131 5.07 WP63SJ1A5 1.592 0.081 0.119 0.014 0.0026 0.0018 35.72 1.59 0.0499 0.315 0.534 2.37 WP63SJ1A6 1.529 0.077 0.063 0.01 0.0108 0.0019 23.4 1.04 0.0302 0.206 0.335 1.488 WP63SJ1A7 1.311 0.066 0.127 0.012 0.0051 0.002 16.66 0.74 0.0334 0.1768 0.329 1.209 WP63SJ1A8 1.521 0.077 0.117 0.012 0.0027 0.0049 56.24 2.5 0.0692 0.473 0.414 1.813 WP63SJ1A9 1.615 0.081 0.106 0.012 0.0093 0.0042 58.84 2.61 0.0886 0.632 0.391 1.795 WP63SJ1A10 1.465 0.075 0.134 0.014 0.0059 0.0023 35.88 1.6 0.0496 0.366 0.392 1.749 WP63SJ1B1 8.34 0.41 0.149 0.014 0.0028 0.0077 0.91 0.046 0.0092 0.0187 0.1323 0.44

10 WP63SJ1B2 8.44 0.41 0.23 0.016 0.0041 0.002 0.917 0.046 0.00947 0.0139 0.1155 0.434

6 WP63SJ1B3 9.11 0.45 0.229 0.015 0.0048 0.0058 0.912 0.044 0.01115 0.0206 2.363 10.96

WP63SJ1B4 7.44 0.36 0.146 0.013 0.00117 0.0047 0.623 0.033 0.00467 0.00895 0.2099 0.953 WP63SJ1B5 8.53 0.42 0.134 0.014 0.006 0.0038 0.923 0.047 0.0089 0.0155 0.52 2.229 WP63SJ1B6 8.62 0.42 0.219 0.015 0.0018 0.0037 1.03 0.05 0.0094 0.0174 0.912 3.74 WP63SJ1B7 13.62 0.67 0.262 0.017 0.0059 0.0039 1.492 0.07 0.01082 0.0246 0.336 1.51 WP63SJ1B8 9.48 0.46 0.196 0.015 0.00169 0.0036 0.864 0.043 0.00883 0.0122 0.089 0.388 WP63SJ1B9 10.44 0.51 0.232 0.016 0.0084 0.0014 1.002 0.049 0.01036 0.0145 0.2 0.888 WP63SJ1B10 9.77 0.48 0.182 0.014 0.0056 0.0023 1.032 0.051 0.0119 0.014 0.506 2.108 WP63SJ1C1 1.63 0.082 0.208 0.015 0.022 0.0015 1.956 0.092 0.01054 0.0238 0.1745 0.772 WP63SJ1C2 1.348 0.067 0.197 0.013 0.0128 0.0015 2.157 0.099 0.0353 0.0843 0.2127 0.809 WP63SJ1C3 1.562 0.078 0.178 0.012 0.022 0.0024 1.344 0.063 0.0138 0.0556 0.677 3.02 WP63SJ1C4 1.442 0.072 0.116 0.01 bdl 0.0034 2.77 0.13 0.0153 0.043 0.0672 0.25 WP63SJ1C5 1.639 0.082 0.131 0.01 0.016 0.0014 1.219 0.058 0.0179 0.0428 0.1629 0.714 WP63SJ1C6 1.434 0.072 0.131 0.011 0.039 0.0014 3.05 0.14 0.0225 0.0545 0.1814 0.914 WP63SJ1C7 1.4 0.07 0.139 0.012 0.017 0.0023 1.059 0.051 0.0208 0.0513 0.1477 0.49

Conc. (ppm) Spot [90Zr] ±1σ [118Sn] ±1σ [121Sb] ±1σ [137Ba] ±1σ [139La] [140Ce] [141Pr] [146Nd] WP63SJ1C8 1.312 0.066 0.15 0.013 0.053 0.0014 1.833 0.086 0.0229 0.0738 0.1601 0.64 WP63SJ1C9 1.445 0.072 0.117 0.011 0.026 0.0023 1.45 0.068 0.043 0.0854 0.1023 0.446 WP63SJ1C10 1.606 0.08 0.099 0.01 0.019 0.0029 1.325 0.064 0.0187 0.048 0.131 0.514 WP63SJ1D1 4.9 0.24 0.139 0.012 0.011 0.0026 1.372 0.066 0.0362 0.0488 0.0337 0.1215 WP63SJ1D2 5.03 0.25 0.121 0.012 0.34 0.0016 1.357 0.067 0.06 0.0852 0.427 1.789 WP63SJ1D3 2.85 0.14 0.185 0.018 0.005 0.0036 1.059 0.055 0.0207 0.0428 0.042 0.1084 WP63SJ1D4 4.5 0.22 0.178 0.017 0.0065 0.0026 0.989 0.052 0.0213 0.0352 0.0355 0.1357 WP63SJ1D5 3.14 0.16 0.196 0.018 0.017 0.0069 0.913 0.048 0.0156 0.0342 0.0319 0.1108 WP63SJ1D6 3.38 0.17 0.249 0.02 0.0148 0.0082 1.114 0.057 0.0355 0.072 0.0456 0.159 WP63SJ1D7 3.08 0.15 0.148 0.015 0.01 0.0063 0.811 0.043 0.019 0.1462 0.0339 0.1194 WP63SJ1D8 1.69 0.085 0.117 0.012 0.02 0.0015 5.33 0.24 0.0672 0.277 0.0293 0.1363 WP63SJ1D9 2.78 0.14 0.222 0.02 0.0111 0.0049 0.963 0.051 0.0219 0.1238 0.0385 0.158

10 WP63SJ1D10 2.5 0.13 0.129 0.018 0.021 0.0035 1.495 0.079 0.0817 0.1318 0.024 0.0703

7 WP63SJ1E1 2.8 0.14 0.191 0.017 0.022 0.0038 1.862 0.089 0.0227 0.0629 0.1745 0.671

WP63SJ1E2 2.81 0.14 0.138 0.015 0.02 0.003 1.662 0.08 0.02 0.0659 0.1766 0.724 WP63SJ1E3 3.16 0.16 0.208 0.017 0.021 0.0032 2.46 0.12 0.1519 0.429 0.2173 0.943 WP63SJ1E4 3.72 0.18 0.227 0.019 0.0109 0.0054 1.542 0.076 0.0959 0.419 0.666 3.09 WP63SJ1E5 3.06 0.15 0.237 0.021 0.0141 0.0034 0.637 0.038 0.015 0.0457 0.1334 0.549 WP63SJ1E6 3.52 0.17 0.187 0.015 0.015 0.0041 0.948 0.048 0.07 0.214 0.1623 0.546 WP63SJ1E7 3.11 0.15 0.173 0.014 0.023 0.0021 0.659 0.034 0.00885 0.0296 0.1292 0.474 WP63SJ1E8 3.55 0.18 0.182 0.015 0.02 0.0016 0.717 0.038 0.00572 0.025 0.1082 0.389 WP63SJ1E9 3.75 0.18 0.174 0.014 0.017 0.014 1.931 0.09 0.137 0.466 0.0988 0.445 WP63SJ1E10 2.97 0.15 0.129 0.014 0.02 0.002 1 0.051 0.0191 0.0685 0.2106 0.788 WP63SJ1F1 2.95 0.15 0.134 0.013 0.02 0.0054 1.285 0.063 0.0107 0.0418 0.1074 0.358 WP63SJ1F2 5.7 0.28 0.118 0.013 0.026 0.0029 1 0.051 0.0236 0.0437 0.0453 0.274 WP63SJ1F3 3.94 0.19 0.114 0.013 0.023 0.0043 1.147 0.057 0.0255 0.0396 0.0667 0.192 WP63SJ1F4 4.43 0.22 0.103 0.011 0.0154 0.0039 0.893 0.045 0.0144 0.1131 0.0363 0.1562 WP63SJ1F5 4.54 0.22 0.166 0.014 0.0114 0.0028 1.092 0.054 0.021 0.0483 0.113 0.551

Conc. (ppm) Spot [90Zr] ±1σ [118Sn] ±1σ [121Sb] ±1σ [137Ba] ±1σ [139La] [140Ce] [141Pr] [146Nd] WP63SJ1F6 2.29 0.11 0.099 0.011 0.02 0.0043 0.997 0.049 0.0116 0.0256 0.0389 0.1553 WP63SJ1F7 4.64 0.23 0.145 0.013 0.018 0.0018 1.151 0.057 0.1113 0.1525 0.1115 0.382 WP63SJ1F8 2.83 0.14 0.104 0.011 0.025 0.0015 0.987 0.048 0.0131 0.0285 0.0643 0.262 WP63SJ1F9 4.58 0.23 0.155 0.014 0.023 0.0016 1.448 0.071 0.076 0.1347 0.0798 0.388 WP63SJ1F10 3.33 0.16 0.105 0.012 0.035 0.0029 16.73 0.75 0.0312 0.0559 0.0499 0.257 WP75SJ7 (83 µm ) WP75SJ7A1 12.44 0.66 0.261 0.016 0.0018 0.014 40.98 1.76 1.708 3.21 0.033 0.192 WP75SJ7A2 53.68 2.86 0.186 0.012 0.0057 0.0023 3.13 0.14 0.288 0.574 0.0364 0.193 WP75SJ7A3 38.16 2.03 0.181 0.012 0.0056 0.0017 2.56 0.11 0.334 0.837 0.0188 0.0739 WP75SJ7A4 25.32 1.35 0.205 0.013 0.0024 0.0012 2.81 0.12 0.1634 0.367 0.0186 0.1013 WP75SJ7A5 23.18 1.24 0.243 0.015 0.0079 0.0017 5.67 0.25 0.454 0.816 0.0263 0.1194 WP75SJ7A6 54.63 2.91 0.982 0.051 0.0021 0.076 33.17 1.43 3.1 8.3 0.00966 0.0459

10 WP75SJ7A7 8.8 0.47 0.203 0.013 0.006 0.0028 48.36 2.08 0.408 0.691 0.0185 0.122

8 WP75SJ7A8 8.73 0.47 0.201 0.013 0.0029 0.0029 5.75 0.25 0.416 0.762 0.0274 0.165

WP75SJ7A9 7.81 0.42 0.174 0.012 0.003 0.0026 6.67 0.29 0.372 0.842 0.0574 0.272 WP75SJ7A10 10.72 0.57 0.169 0.012 0.0055 0.0015 12.17 0.53 0.283 0.611 0.157 0.693 WP75SJ7A11 0.911 0.051 0.25 0.016 0.0022 0.0039 3.31 0.15 2.38 3.42 0.0042 0.0152 WP75SJ7A12 0.894 0.05 0.233 0.015 0.0087 0.0017 110.04 4.72 1.548 2.44 0.00198 0.0088 WP75SJ7A13 1.367 0.074 0.27 0.017 0.0016 0.0044 4.35 0.19 1.9 2.73 0.00157 0.0064 WP75SJ7A14 0.985 0.055 0.262 0.017 0.0034 0.0026 3.64 0.16 1.949 2.98 0.0296 0.1262 WP75SJ7A15 1.03 0.057 0.226 0.014 0.071 0.0016 4.13 0.18 2.26 3.2 10.65 58.5 WP75SJ7A16 0.869 0.049 0.167 0.013 0.0024 0.0012 3.72 0.17 2.53 3.78 0.00458 0.0334 WP75SJ7A17 1.312 0.072 0.227 0.016 0.0028 0.003 4.08 0.18 1.647 2.5 0.01014 0.0663 WP75SJ7A18 0.683 0.038 0.197 0.013 0.0144 0.0014 5.37 0.23 1.45 2.206 0.256 0.204 WP75SJ7A19 1.008 0.056 0.195 0.013 0.022 0.0028 3.31 0.15 1.473 2.144 0.00485 0.0386 WP75SJ7A20 0.893 0.049 0.208 0.013 0.32 0.0016 2.9 0.13 1.076 1.742 2.37 9.91 WP75SJ7A21 2.17 0.12 0.267 0.016 0.0034 0.026 2.35 0.1 3.69 3.12 0.0201 0.1041 WP75SJ7A22 3.52 0.19 0.36 0.021 0.0028 0.026 3.4 0.15 2.45 1.088 0.0243 0.1057

Conc. (ppm) Spot [90Zr] ±1σ [118Sn] ±1σ [121Sb] ±1σ [137Ba] ±1σ [139La] [140Ce] [141Pr] [146Nd] WP75SJ7A23 3.33 0.18 0.275 0.017 0.003 0.025 3.09 0.14 2.22 0.761 0.0128 0.0771 WP75SJ7A24 9.1 0.49 0.33 0.019 0.26 0.015 22.32 0.96 165.63 24.48 2.05 9.74 WP75SJ7A25 83.66 4.46 0.261 0.017 0.016 0.17 19.93 0.86 15.65 5.62 0.0186 0.1177 WP75SJ7A26 6.15 0.33 0.362 0.023 0.028 0.009 9.31 0.41 7.47 1.649 0.513 2.14 WP75SJ7A27 4.29 0.23 0.363 0.022 0.045 0.016 3.64 0.16 1.82 0.519 0.587 2.65 WP75SJ7A28 2.07 0.11 0.255 0.019 0.096 0.0074 2.47 0.11 1.329 0.456 1.256 5.33 WP75SJ7A29 2.78 0.15 0.267 0.019 0.026 0.0089 2.46 0.11 1.13 0.518 0.585 2.54 WP75SJ7A30 2.14 0.12 0.328 0.023 0.003 0.0093 1321.91 56.66 0.561 0.337 0.078 0.331 WP75SJ7A31 2.52 0.14 0.164 0.011 0.0033 0.0015 9.84 0.43 1.354 2.78 0.00657 0.0373 WP75SJ7A32 4.78 0.26 0.206 0.014 0.0036 0.0017 13.05 0.56 1.252 2.57 0.00394 0.0297 WP75SJ7A33 5.49 0.29 0.226 0.016 0.0071 0.0049 12.65 0.55 1.62 3.27 0.00619 0.0302 WP75SJ7A34 5.68 0.3 0.189 0.013 0.0027 0.0025 23.91 1.03 2.98 5.28 0.0121 0.053

10 WP75SJ7A35 5.28 0.28 0.183 0.013 0.0027 0.0017 14.45 0.62 1.449 2.7 0.0137 0.0584

9 WP75SJ7A36 6.72 0.36 0.237 0.017 0.0034 0.003 9.16 0.4 0.855 1.652 0.00707 0.0233

WP75SJ7A37 6.47 0.35 0.146 0.014 0.0034 0.0023 8.39 0.37 0.733 1.471 0.00488 0.0104 WP75SJ7A38 6.1 0.33 0.241 0.018 0.0082 0.0017 9.34 0.41 1.035 2.5 0.0133 0.0582 WP75SJ7A39 14.26 0.76 0.207 0.014 0.0069 0.0026 9.09 0.39 1.104 2.206 0.0135 0.0422 WP75SJ7A40 12 0.64 0.171 0.012 0.0028 0.0019 5.11 0.22 0.963 1.856 0.0105 0.0451 WP114SJ2A (83 µm ) WP114SJ2AA1 17.4 0.7 0.211 0.012 0.0135 0.002 1.373 0.056 0.322 0.8 0.00372 0.0204 WP114SJ2AA2 19.74 0.79 0.202 0.012 0.0029 0.0028 0.946 0.04 0.272 0.641 0.00482 0.01 WP114SJ2AA3 23.86 0.96 0.43 0.021 0.0102 0.0033 16.61 0.62 7.49 11.12 0.00383 0.0262 WP114SJ2AA4 16.3 0.65 0.1704 0.01 0.0082 0.0009 0.938 0.038 0.402 0.798 0.001 0.0099 WP114SJ2AA5 22.08 0.89 0.339 0.018 0.0061 0.0041 2.301 0.091 1.629 6.51 0.00549 0.0114 WP114SJ2AA6 7.28 0.29 0.293 0.016 0.0059 0.0013 3.53 0.14 3.05 10.31 0.00333 0.0231 WP114SJ2AA7 19.69 0.79 0.236 0.013 0.0066 0.0039 1.723 0.069 0.952 4.49 0.00345 0.0251 WP114SJ2AA8 15.25 0.61 0.216 0.012 0.0059 0.00095 0.723 0.031 0.1655 0.547 0.00363 0.0183 WP114SJ2AA9 15.23 0.61 0.202 0.012 0.0025 0.0055 1.595 0.064 0.565 1.235 0.0059 0.0144

Conc. (ppm) Spot [90Zr] ±1σ [118Sn] ±1σ [121Sb] ±1σ [137Ba] ±1σ [139La] [140Ce] [141Pr] [146Nd] WP114SJ2AA10 17.97 0.72 0.206 0.013 0.0028 0.0038 1.075 0.046 1.548 4.08 0.00236 0.0173 WP114SJ2AB1 8.14 0.33 0.226 0.017 0.0022 0.014 0.493 0.026 0.585 1.186 0.00361 0.0187 WP114SJ2AB2 6.37 0.26 0.235 0.017 0.0019 0.0086 0.522 0.027 0.652 1.237 0.01076 0.0306 WP114SJ2AB3 10.95 0.44 0.18 0.017 0.004 0.014 0.788 0.04 2.098 3.95 0.00432 0.0186 WP114SJ2AB4 1.644 0.069 0.086 0.011 0.0056 bdl 0.17 0.013 0.287 0.403 0.00322 0.013 WP114SJ2AB5 25.94 1.04 0.183 0.017 0.0017 0.011 2.334 0.097 0.561 1.113 0.00781 0.0261 WP114SJ2AB6 17.25 0.69 0.346 0.022 0.0022 0.025 2.78 0.11 0.573 1.451 0.00638 0.0173 WP114SJ2AB7 6.65 0.27 0.235 0.017 0.0034 0.011 0.686 0.034 0.423 0.978 0.00503 0.0083 WP114SJ2AB8 8.91 0.36 0.15 0.014 0.0026 0.034 0.76 0.036 0.489 1.171 0.00434 0.0298 WP114SJ2AB9 4.22 0.17 0.179 0.015 0.0035 0.017 0.518 0.027 0.31 0.848 0.00911 0.0383 WP114SJ2AB10 5.11 0.21 0.176 0.015 0.0047 0.012 0.78 0.037 0.414 0.953 0.00549 0.0192 WP114SJ2AC1 1.19 0.05 0.1201 0.0094 0.0039 0.0072 0.223 0.013 0.1091 0.283 0.01057 0.0396

1 WP114SJ2AC2 4 0.16 0.211 0.016 0.0017 0.22 8.58 0.33 1.648 15.56 0.0129 0.0797

10 WP114SJ2AC3 1.293 0.054 0.15 0.011 0.0053 0.0035 0.33 0.017 0.1229 0.248 0.0086 0.0419

WP114SJ2AC4 1.37 0.057 0.131 0.01 0.003 0.0044 0.393 0.02 0.1297 0.298 0.00796 0.0485 WP114SJ2AC5 1.674 0.069 0.1197 0.0092 0.0118 0.011 0.303 0.015 0.0986 0.2201 0.00378 0.0343 WP114SJ2AC6 1.71 0.074 0.152 0.016 0.0143 0.0098 0.396 0.025 0.1533 0.297 0.0134 0.0484 WP114SJ2AC7 1.384 0.058 0.173 0.011 0.0106 0.0065 0.379 0.019 0.129 0.711 0.00457 0.0521 WP114SJ2AC8 1.637 0.067 0.18 0.012 0.0025 0.013 0.406 0.019 0.1168 0.2192 0.00763 0.0315 WP114SJ2AC9 2.89 0.12 0.19 0.013 0.0079 0.0073 1.018 0.043 0.1815 0.298 0.0076 0.0199 WP114SJ2AC10 2.365 0.097 0.147 0.011 0.0037 0.013 0.696 0.031 0.0937 0.1887 0.033 0.155 WP114SJ2AD1 9.19 0.37 0.219 0.013 0.0055 0.014 0.683 0.03 0.576 1.251 0.00483 0.0218 WP114SJ2AD2 9.16 0.37 0.204 0.012 0.004 0.013 0.945 0.039 0.574 1.246 0.00524 0.0279 WP114SJ2AD3 8.96 0.36 0.163 0.011 0.005 0.013 1.046 0.044 0.671 1.504 0.0309 0.146 WP114SJ2AD4 26.14 1.05 0.198 0.012 0.009 0.0071 2.424 0.095 1.8 3.54 0.0299 0.134 WP114SJ2AD5 10.31 0.41 0.182 0.011 0.0043 0.0091 1.428 0.058 0.399 1.019 0.00221 0.0128 WP114SJ2AD6 11.85 0.48 0.201 0.014 0.0066 0.01 0.792 0.037 0.476 1.072 0.0135 0.0506 WP114SJ2AD7 20.14 0.81 0.15 0.012 0.0028 0.015 0.829 0.038 0.389 0.829 0.00327 0.0026

Conc. (ppm) Spot [90Zr] ±1σ [118Sn] ±1σ [121Sb] ±1σ [137Ba] ±1σ [139La] [140Ce] [141Pr] [146Nd] WP114SJ2AD8 10.53 0.42 0.166 0.012 0.0027 0.013 0.784 0.036 0.266 0.642 0.00262 0.006 WP114SJ2AD9 23.6 0.95 0.158 0.011 0.025 0.011 0.608 0.028 0.323 0.761 0.0349 0.127 WP114SJ2AD10 7.74 0.31 0.139 0.013 0.0026 0.013 0.91 0.042 0.667 1.494 0.0038 0.0202 WP114SJ2AE1 6.05 0.24 0.195 0.012 0.0093 0.013 0.9 0.038 0.667 1.236 0.00384 0.0234 WP114SJ2AE2 6.11 0.25 0.174 0.011 0.0039 0.016 1.049 0.044 0.1081 0.281 0.01023 0.0495 WP114SJ2AE3 5.11 0.21 0.1224 0.0097 0.0072 0.015 1.018 0.043 0.295 0.556 0.0061 0.0444 WP114SJ2AE4 4.21 0.17 0.127 0.0098 0.0062 0.0099 0.7 0.031 0.0913 0.267 0.00463 0.028 WP114SJ2AE5 4.56 0.19 0.154 0.012 0.0038 0.0075 1.386 0.058 0.2165 0.585 0.00901 0.0403 WP114SJ2AE6 4.45 0.18 0.154 0.012 0.007 0.013 1.147 0.049 0.0814 0.26 0.00373 0.0156 WP114SJ2AE7 7.99 0.32 0.258 0.016 0.0025 0.012 3.92 0.15 0.949 1.434 0.0337 0.151 WP114SJ2AE8 7.03 0.28 0.197 0.014 0.0021 0.016 1.05 0.046 0.147 0.391 0.00875 0.0208 WP114SJ2AE9 6.72 0.27 0.221 0.015 0.0019 0.015 1.794 0.074 0.1601 0.468 0.0245 0.0935

11 WP114SJ2AE10 5.18 0.21 0.156 0.012 0.0046 0.022 1.023 0.044 0.1223 0.374 0.01048 0.0452

Conc. (ppm) Spot [208Pb] ±1σ [232Th] ±1σ [238U] ±1σ GCPUD003 (83 µm ) GCPUD003A1 0.0188 0.0026 0.0355 0.0031 1.376 0.074 GCPUD003A2 0.0397 0.0041 0.0542 0.0045 1.474 0.08 GCPUD003A3 0.0284 0.0033 0.0162 0.0022 1.207 0.065 GCPUD003A4 0.0567 0.005 0.0145 0.0021 0.929 0.05 GCPUD003A5 0.012 0.0025 0.0137 0.0019 1.277 0.069 GCPUD003A6 0.0114 0.0024 0.0196 0.0022 1.693 0.091 GCPUD003A7 0.0268 0.0034 0.0122 0.0023 0.99 0.054 GCPUD003A8 0.0124 0.0025 0.0183 0.0023 1.364 0.074 GCPUD003A9 0.17 0.012 0.0188 0.0022 1.129 0.061 GCPUD003A10 27.1 1.73 0.305 0.021 0.305 0.074 GCPUD003A11 0.0128 0.0025 0.0237 0.0025 0.0237 0.078

11 GCPUD003A12 0.1011 0.0075 0.0185 0.0023 0.0185 0.085

2 GCPUD003A13 0.0567 0.0049 0.012 0.002 0.012 0.078

GCPUD003A14 0.0733 0.0063 0.0269 0.003 0.0269 0.079 GCPUD003A15 0.0209 0.0024 0.0138 0.0017 0.0138 0.077 GCPUD003A16 0.0185 0.0025 0.0179 0.0021 0.0179 0.073 GCPUD003A17 0.0056 0.0021 0.0233 0.0025 0.0233 0.081 GCPUD003A18 0.0084 0.0019 0.025 0.0023 0.025 0.087 GCPUD003A19 0.0104 0.003 0.011 0.0025 0.011 0.09 GCPUD003A20 0.784 0.051 0.0413 0.0034 0.0413 0.063 GCPUD003B1 0.0424 0.0049 0.0071 0.0027 0.0071 0.035 GCPUD003B2 0.0298 0.0042 0.0121 0.0026 0.0121 0.037 GCPUD003B3 0.035 0.0043 0.0125 0.0026 0.0125 0.036 GCPUD003B4 0.0443 0.0047 0.0111 0.0024 0.0111 0.033 GCPUD003B5 0.0264 0.0036 0.0098 0.0022 0.0098 0.03

Conc. (ppm) Spot [208Pb] ±1σ [232Th] ±1σ [238U] ±1σ GCPUD003B6 0.0195 0.0035 0.0091 0.0025 0.0091 0.036 GCPUD003B7 0.0146 0.0034 0.0147 0.0028 0.0147 0.037 GCPUD003B8 0.0164 0.0036 bdl 0.0024 bdl 0.038 GCPUD003B9 0.0106 0.0028 0.0045 0.002 0.0045 0.035 GCPUD003B10 0.0187 0.0034 0.0082 0.0023 0.0082 0.028 GCPUD004 (64 μm) GCPUD004A1 0.264 0.03 0.0725 0.0084 0.65 0.091 GCPUD004A2 0.198 0.023 0.0743 0.0085 0.679 0.095 GCPUD004A3 0.281 0.032 0.0657 0.0078 0.634 0.088 GCPUD004A4 0.353 0.04 0.0683 0.0081 0.76 0.11 GCPUD004A5 0.48 0.054 0.0862 0.0099 0.68 0.095 GCPUD004A6 0.367 0.042 0.0577 0.0071 0.85 0.12

11 GCPUD004A7 0.447 0.051 0.0592 0.0073 0.75 0.1

3 GCPUD004A8 0.269 0.031 0.0608 0.0073 0.86 0.12

GCPUD004A9 0.35 0.04 0.0486 0.0062 0.81 0.11 GCPUD004A10 0.321 0.037 0.0532 0.0066 0.78 0.11 GCPUD004A11 0.386 0.044 0.0465 0.0059 0.75 0.1 GCPUD004A12 0.348 0.04 0.062 0.0073 0.82 0.11 GCPUD004A13 0.257 0.03 0.0545 0.0066 0.79 0.11 GCPUD004A14 0.334 0.038 0.0578 0.007 0.79 0.11 GCPUD004A15 0.439 0.05 0.0578 0.0071 0.75 0.1 GCPUD004A16 0.392 0.045 0.0652 0.0077 0.81 0.11 GCPUD004A17 0.346 0.04 0.0675 0.008 0.78 0.11 GCPUD004A18 0.396 0.045 0.0727 0.0085 0.76 0.11 GCPUD004A19 0.196 0.023 0.0544 0.0067 0.73 0.1 GCPUD004A20 0.112 0.014 0.0438 0.0056 0.91 0.13 GCPUD004A21 0.29 0.033 0.08 0.0091 0.84 0.12

Conc. (ppm) Spot [208Pb] ±1σ [232Th] ±1σ [238U] ±1σ GCPUD004A22 0.37 0.042 0.093 0.011 0.78 0.11 GCPUD004A23 1.51 0.17 0.0741 0.0086 0.671 0.094 GCPUD004B1 0.622 0.071 0.0298 0.0047 1.18 0.16 GCPUD004B2 0.4 0.046 0.0541 0.007 1.2 0.17 GCPUD004B3 0.498 0.057 0.0362 0.0053 1.08 0.15 GCPUD004B4 0.597 0.068 0.0622 0.0079 1.13 0.16 GCPUD004B5 0.487 0.056 0.0345 0.0057 1.09 0.15 GCPUD004B6 0.544 0.062 0.0468 0.0064 1.18 0.16 GCPUD004B7 0.375 0.043 0.0155 0.0038 1.1 0.15 GCPUD004B8 0.346 0.04 0.0219 0.0045 1.26 0.18 GCPUD004B9 0.331 0.038 0.0124 0.0035 1.19 0.17 GCPUD004B10 0.692 0.078 0.0491 0.0063 1.24 0.17

11 GCPUD004B11 0.532 0.061 0.0249 0.0044 1.18 0.16

4 GCPUD004B12 0.472 0.054 0.027 0.0044 1.13 0.16

GCPUD004B13 0.153 0.019 0.0153 0.0036 1.37 0.19 GCPUD004B14 0.415 0.048 0.0246 0.0044 1.12 0.16 GCPUD004B15 0.451 0.052 0.0355 0.0052 1.22 0.17 GCPUD004B16 0.429 0.049 0.0234 0.0043 1.26 0.18 GCPUD004B17 0.579 0.066 0.0275 0.0048 1.26 0.18 GCPUD004B18 0.598 0.068 0.0484 0.0067 1.13 0.16 GCPUD004B19 0.637 0.073 0.0121 0.004 1.4 0.19 GCPUD004B20 0.253 0.029 0.0199 0.0028 0.543 0.076 GCPUD004B21 0.407 0.047 0.0126 0.0036 1.33 0.19 GCPUD004B22 0.739 0.084 0.0466 0.0065 1.24 0.17 GCPUD004B23 0.703 0.08 0.036 0.006 1.24 0.17 GCPUD004B24 0.5 0.057 0.0221 0.0043 1.12 0.16 GCPUD004B25 0.514 0.059 0.0235 0.0048 1.2 0.17

Conc. (ppm) Spot [208Pb] ±1σ [232Th] ±1σ [238U] ±1σ

GCPUD008A1 0.2 0.043 bdl 0.0022 0.201 0.054 GCPUD008A2 0.354 0.075 bdl 0.0021 0.217 0.058 GCPUD008A3 0.425 0.09 bdl 0.0023 0.296 0.08 GCPUD008A4 0.53 0.11 bdl 0.0025 0.319 0.086 GCPUD008A5 0.63 0.13 bdl 0.0021 0.274 0.074 GCPUD008A6 0.66 0.14 bdl 0.0026 0.324 0.087 GCPUD008A7 0.47 0.1 bdl 0.0025 0.281 0.076 GCPUD008A8 0.63 0.13 bdl 0.0024 0.299 0.08 GCPUD008A9 0.56 0.12 bdl 0.0024 0.311 0.084 GCPUD008A10 0.54 0.11 bdl 0.0023 0.321 0.086 GCPUD008A11 0.64 0.13 bdl 0.0025 0.3 0.081

11 GCPUD008A12 1.41 0.3 0.0087 0.0028 0.306 0.082

5 GCPUD008A13 0.71 0.15 bdl 0.0027 0.67 0.18

GCPUD008A14 0.0187 0.0061 bdl 0.0028 0.3 0.081 GCPUD008A15 1.58 0.33 0.0075 0.0026 0.5 0.13 GCPUD008A16 1.77 0.37 bdl 0.0025 0.39 0.1 GCPUD008A17 1.28 0.27 bdl 0.0023 0.296 0.08 GCPUD008A18 1.78 0.37 bdl 0.0024 0.44 0.12 GCPUD008A19 0.394 0.084 0.0051 0.0027 0.81 0.22 GCPUD008A20 0.0177 0.006 bdl 0.0029 0.067 0.018 GCPUD008B1 0.405 0.086 bdl 0.0035 0.75 0.2 GCPUD008B2 0.67 0.14 bdl 0.003 0.62 0.17 GCPUD008B3 0.424 0.09 bdl 0.0028 0.73 0.2 GCPUD008B4 0.468 0.099 0.0079 0.0033 0.72 0.19 GCPUD008B5 0.47 0.1 bdl 0.0031 0.75 0.2 GCPUD008B6 0.56 0.12 bdl 0.0029 0.63 0.17 GCPUD008B7 0.66 0.14 bdl 0.0027 0.69 0.19

Conc. (ppm) Spot [208Pb] ±1σ [232Th] ±1σ [238U] ±1σ GCPUD008B8 0.6 0.13 bdl 0.0025 0.73 0.2 GCPUD008B9 0.51 0.11 bdl 0.0025 0.79 0.21 GCPUD008B10 0.55 0.12 bdl 0.0029 0.65 0.17 GCPUD008B11 0.456 0.097 bdl 0.0028 0.6 0.16 GCPUD008B12 0.49 0.1 bdl 0.0028 0.74 0.2 GCPUD008B13 0.396 0.084 bdl 0.0029 0.65 0.18 GCPUD008B14 0.7 0.15 bdl 0.0029 0.6 0.16 GCPUD008B15 0.56 0.12 bdl 0.003 0.67 0.18 GCPUD008B16 0.413 0.088 bdl 0.0029 0.58 0.16 GCPUD008B17 0.371 0.079 bdl 0.003 0.64 0.17 GCPUD008B18 0.415 0.088 bdl 0.003 0.64 0.17 GCPUD008B19 0.51 0.11 bdl 0.0029 0.63 0.17

11 GCPUD008B20 0.433 0.092 bdl 0.003 0.73 0.2

6 GCPUD008B21 0.57 0.12 bdl 0.0032 0.57 0.15

GCPUD008B22 0.409 0.087 bdl 0.0031 0.64 0.17 GCPUD008B23 0.429 0.091 bdl 0.0034 0.64 0.17 GCPUD008B24 0.323 0.069 bdl 0.0034 0.61 0.16 GCPUD008B25 0.256 0.055 bdl 0.0034 0.56 0.15 WP52SJ5 (83 µm ) WP52SJ5A1 0.0146 0.0017 0.0309 0.0031 0.767 0.059 WP52SJ5A2 0.0114 0.0014 0.0173 0.0018 0.717 0.055 WP52SJ5A3 0.0133 0.0017 0.0157 0.0018 0.686 0.053 WP52SJ5A4 0.0093 0.0013 0.0141 0.0016 0.706 0.055 WP52SJ5A5 0.0179 0.0019 0.0419 0.004 0.886 0.068 WP52SJ5A6 0.0073 0.0015 0.00551 0.00091 0.761 0.059 WP52SJ5A7 0.0119 0.0027 0.0124 0.0021 0.726 0.057 WP52SJ5A8 0.0094 0.002 0.0113 0.0016 0.488 0.038 WP52SJ5A9 0.0139 0.002 0.0103 0.0014 0.417 0.033

Conc. (ppm) Spot [208Pb] ±1σ [232Th] ±1σ [238U] ±1σ WP52SJ5A10 0.0772 0.0055 0.0262 0.0027 0.1253 0.01 WP52SJ5B1 0.017 0.0019 0.0102 0.0013 1.56 0.12 WP52SJ5B2 0.0186 0.002 0.0075 0.001 1.8 0.14 WP52SJ5B3 0.01 0.0015 0.008 0.0011 2.03 0.16 WP52SJ5B4 0.0379 0.003 1.062 0.094 1.47 0.11 WP52SJ5B5 3.3 0.19 0.443 0.04 15.22 1.17 WP52SJ5B6 0.0108 0.0015 0.0178 0.0019 1.75 0.14 WP52SJ5B7 0.0099 0.0016 0.0158 0.0018 1.66 0.13 WP52SJ5B8 0.32 0.02 0.0052 0.0011 0.165 0.013 WP52SJ5B9 0.0618 0.0045 0.0084 0.0011 0.198 0.015 WP52SJ5B10 0.976 0.059 1.4 0.12 0.801 0.062 WP52SJ2C1 0.0131 0.002 0.0229 0.0025 3.45 0.27

11 WP52SJ2C2 0.0194 0.0023 0.0292 0.0031 3.25 0.25

7 WP52SJ2C3 0.0189 0.0023 0.0203 0.0023 3.09 0.24

WP52SJ2C4 1.612 0.098 2.23 0.2 14.92 1.15 WP52SJ2C5 0.0156 0.0019 0.0324 0.0033 2.86 0.22 WP52SJ2C6 0.207 0.014 0.434 0.039 5.39 0.41 WP52SJ2C7 0.278 0.017 0.5 0.044 4.87 0.37 WP52SJ2C8 0.689 0.041 1.2 0.11 5.85 0.45 WP52SJ2C9 0.22 0.014 0.37 0.033 4.45 0.34 WP52SJ2C10 0.0428 0.0034 0.0762 0.0071 3.19 0.25 WP54SJ4 (83 µm ) WP54SJ4A1 0.0074 0.0017 0.0218 0.0018 1.749 0.073 WP54SJ4A2 0.0083 0.0018 0.0214 0.0018 1.666 0.07 WP54SJ4A3 0.0209 0.002 0.0232 0.0018 1.647 0.069 WP54SJ4A4 0.0073 0.0016 0.0186 0.0016 1.774 0.074 WP54SJ4A5 0.0089 0.0017 0.023 0.0018 1.713 0.072 WP54SJ4A6 0.0154 0.0019 0.0243 0.0018 1.524 0.064

Conc. (ppm) Spot [208Pb] ±1σ [232Th] ±1σ [238U] ±1σ WP54SJ4A7 0.0603 0.0038 0.0635 0.0035 1.9 0.079 WP54SJ4A8 0.0385 0.0028 0.0351 0.0023 1.563 0.065 WP54SJ4A9 0.0259 0.0023 0.0176 0.0016 1.447 0.061 WP54SJ4A10 0.029 0.0024 0.0195 0.0016 1.618 0.068 WP54SJ4B1 0.01 0.0019 0.0121 0.0016 2.102 0.088 WP54SJ4B2 0.1095 0.006 0.0172 0.0016 2.145 0.09 WP54SJ4B3 0.0605 0.0038 0.0362 0.0024 2.036 0.085 WP54SJ4B4 0.0821 0.0048 0.0268 0.002 2.184 0.091 WP54SJ4B5 0.0323 0.0026 0.0237 0.0018 2.042 0.085 WP54SJ4B6 0.0261 0.0023 0.0172 0.0016 1.987 0.083 WP54SJ4B7 0.0177 0.002 0.0179 0.0016 1.924 0.08 WP54SJ4B8 0.0299 0.0026 0.0177 0.0017 1.942 0.081

11 WP54SJ4B9 0.046 0.0032 0.0201 0.0017 1.921 0.08

8 WP54SJ4B10 0.1276 0.0069 0.0143 0.0015 1.908 0.08

WP54SJ4C1 0.0237 0.0023 0.0332 0.0022 1.808 0.076 WP54SJ4C2 0.0278 0.0023 0.0288 0.002 1.889 0.079 WP54SJ4C3 0.0534 0.0034 0.0262 0.0019 1.81 0.076 WP54SJ4C4 0.0421 0.003 0.0319 0.0021 1.779 0.074 WP54SJ4C5 0.0392 0.0028 0.0268 0.0019 1.805 0.075 WP54SJ4C6 0.0611 0.0038 0.0298 0.0021 1.766 0.074 WP54SJ4C7 0.248 0.012 0.0341 0.0022 1.698 0.071 WP54SJ4C8 0.944 0.044 0.0279 0.0021 1.758 0.074 WP54SJ4C9 0.178 0.009 0.0329 0.0021 1.811 0.076 WP54SJ4C10 0.1502 0.0078 0.0255 0.0019 1.788 0.075 WP54SJ4D1 0.0356 0.0025 0.0178 0.0014 0.264 0.011 WP54SJ4D2 0.0165 0.0017 0.0234 0.0016 0.29 0.012 WP54SJ4D3 0.0098 0.0014 0.0159 0.0014 0.249 0.011 WP54SJ4D4 0.0119 0.0015 0.013 0.0012 0.2205 0.0095

Conc. (ppm) Spot [208Pb] ±1σ [232Th] ±1σ [238U] ±1σ WP54SJ4D5 0.0061 0.0015 0.0065 0.0011 0.2033 0.0089 WP54SJ4D6 0.0123 0.0017 0.0116 0.0013 0.2136 0.0093 WP54SJ4D7 0.0163 0.0019 0.024 0.0018 0.327 0.014 WP54SJ4D8 0.0281 0.0023 0.0192 0.0016 0.285 0.012 WP54SJ4D9 0.015 0.0017 0.0182 0.0015 0.258 0.011 WP54SJ4D10 0.0329 0.0026 0.0186 0.0016 0.285 0.012 WP54SJ4E1 0.02 0.0026 0.0987 0.0052 0.709 0.03 WP54SJ4E2 0.0194 0.0021 0.1498 0.0071 0.76 0.032 WP54SJ4E3 0.0219 0.0021 0.1829 0.0085 0.727 0.031 WP54SJ4E4 0.0153 0.0022 0.1455 0.0071 0.734 0.031 WP54SJ4E5 0.0187 0.0022 0.1613 0.0077 0.79 0.033 WP54SJ4E6 0.0528 0.0036 0.1986 0.0092 0.826 0.035

11 WP54SJ4E7 0.0262 0.0028 0.1606 0.0078 0.81 0.034

9 WP54SJ4E8 0.0321 0.0028 0.22 0.01 0.775 0.033

WP54SJ4E9 0.0796 0.0053 0.414 0.019 0.891 0.038 WP54SJ4E10 0.0642 0.0042 0.2138 0.01 0.806 0.034 WP54SJ4F1 0.0196 0.0021 0.0163 0.0016 1.422 0.06 WP54SJ4F2 0.0633 0.0041 0.0141 0.0016 1.469 0.062 WP54SJ4F3 0.0325 0.0029 0.0128 0.0017 1.452 0.061 WP54SJ4F4 0.0283 0.0025 0.0131 0.0015 1.502 0.063 WP54SJ4F5 0.0363 0.0028 0.0098 0.0014 1.549 0.065 WP54SJ4F6 0.774 0.039 0.246 0.013 4.06 0.17 WP54SJ4F7 0.02 0.0024 0.0144 0.0017 1.589 0.067 WP54SJ4F8 0.0307 0.0029 0.0286 0.0024 1.748 0.073 WP54SJ4F9 0.028 0.0026 0.0318 0.0024 1.495 0.063 WP54SJ4F10 0.0236 0.0023 0.0137 0.0016 1.705 0.071

Conc. (ppm) Spot [208Pb] ±1σ [232Th] ±1σ [238U] ±1σ WP63SJ1 (83 µm ) WP63SJ1A1 0.0258 0.0031 0.00647 0.00095 0.548 0.03 WP63SJ1A2 0.0145 0.0022 0.00285 0.00073 0.423 0.023 WP63SJ1A3 0.0177 0.0023 0.00263 0.00063 0.53 0.029 WP63SJ1A4 0.0177 0.0024 0.00215 0.00064 0.503 0.027 WP63SJ1A5 0.015 0.0023 0.00429 0.00082 0.502 0.027 WP63SJ1A6 0.01 0.0016 0.00359 0.00069 0.522 0.028 WP63SJ1A7 0.0067 0.0015 0.00287 0.00064 0.587 0.032 WP63SJ1A8 0.0193 0.0025 0.00286 0.0007 0.585 0.032 WP63SJ1A9 0.0159 0.0023 0.00324 0.00071 0.617 0.033 WP63SJ1A10 0.011 0.002 0.00352 0.00081 0.564 0.031 WP63SJ1B1 0.0202 0.0026 0.0259 0.0021 0.248 0.014

1 WP63SJ1B2 0.0164 0.0023 0.0232 0.0019 0.225 0.012

20 WP63SJ1B3 0.0174 0.0021 0.0247 0.0018 0.251 0.014

WP63SJ1B4 0.0098 0.0017 0.0134 0.0013 0.1353 0.0077 WP63SJ1B5 0.0152 0.0023 0.026 0.0022 0.249 0.014 WP63SJ1B6 0.0122 0.0018 0.0224 0.0017 0.243 0.013 WP63SJ1B7 0.0274 0.003 0.0384 0.0026 0.255 0.014 WP63SJ1B8 0.0121 0.0018 0.02 0.0017 0.206 0.011 WP63SJ1B9 0.013 0.0019 0.0284 0.0021 0.201 0.011 WP63SJ1B10 0.0123 0.0019 0.0197 0.0017 0.1773 0.0099 WP63SJ1C1 0.012 0.0018 0.00602 0.00082 0.372 0.02 WP63SJ1C2 0.0158 0.0019 0.0205 0.0015 0.332 0.018 WP63SJ1C3 0.0235 0.0025 0.00711 0.00075 0.354 0.019 WP63SJ1C4 0.0403 0.004 0.0107 0.001 0.312 0.017 WP63SJ1C5 0.0256 0.0028 0.00952 0.00094 0.412 0.022 WP63SJ1C6 0.0189 0.0023 0.00897 0.00098 0.32 0.017 WP63SJ1C7 0.0066 0.0013 0.0095 0.001 0.254 0.014

Conc. (ppm) Spot [208Pb] ±1σ [232Th] ±1σ [238U] ±1σ WP63SJ1C8 0.0146 0.002 0.0135 0.0012 0.241 0.013 WP63SJ1C9 0.0281 0.003 0.0328 0.0023 0.255 0.014 WP63SJ1C10 0.0257 0.0029 0.00917 0.00099 0.324 0.018 WP63SJ1D1 0.0097 0.0016 0.0299 0.0022 0.282 0.015 WP63SJ1D2 0.0155 0.0022 0.0268 0.0022 0.314 0.017 WP63SJ1D3 0.0109 0.0022 0.0245 0.0023 0.284 0.016 WP63SJ1D4 0.0105 0.0022 0.0217 0.0021 0.322 0.018 WP63SJ1D5 0.0108 0.0023 0.0237 0.0022 0.326 0.018 WP63SJ1D6 0.0224 0.0032 0.0443 0.0033 0.279 0.016 WP63SJ1D7 0.0108 0.0021 0.0233 0.002 0.181 0.01 WP63SJ1D8 0.0124 0.0019 0.0296 0.0022 0.1478 0.0083 WP63SJ1D9 0.0484 0.0053 0.0324 0.0027 0.191 0.011

12 WP63SJ1D10 0.0417 0.0053 0.035 0.0032 0.239 0.014

1 WP63SJ1E1 0.0491 0.0052 0.0862 0.0055 0.329 0.018

WP63SJ1E2 0.0309 0.0037 0.0807 0.0052 0.323 0.018 WP63SJ1E3 0.208 0.019 0.378 0.021 0.304 0.017 WP63SJ1E4 0.177 0.016 0.341 0.019 0.425 0.023 WP63SJ1E5 0.0267 0.0037 0.0706 0.0051 0.377 0.021 WP63SJ1E6 0.141 0.013 0.185 0.011 0.392 0.021 WP63SJ1E7 0.0183 0.0023 0.0706 0.0044 0.384 0.021 WP63SJ1E8 0.0127 0.002 0.0497 0.0034 0.365 0.02 WP63SJ1E9 0.359 0.032 0.326 0.018 0.363 0.02 WP63SJ1E10 0.0577 0.006 0.0543 0.0038 0.335 0.019 WP63SJ1F1 0.0079 0.0015 0.0183 0.0016 0.301 0.017 WP63SJ1F2 0.0142 0.0022 0.0303 0.0024 0.29 0.016 WP63SJ1F3 0.0055 0.0014 0.0236 0.002 0.234 0.013 WP63SJ1F4 0.0089 0.0016 0.0201 0.0017 0.23 0.013 WP63SJ1F5 0.004 0.0013 0.0218 0.0018 0.247 0.014

Conc. (ppm) Spot [208Pb] ±1σ [232Th] ±1σ [238U] ±1σ WP63SJ1F6 0.0065 0.0014 0.019 0.0016 0.354 0.019 WP63SJ1F7 0.0246 0.0029 0.0624 0.0041 0.314 0.017 WP63SJ1F8 0.008 0.0015 0.0211 0.0017 0.343 0.019 WP63SJ1F9 0.0388 0.0043 0.0284 0.0023 0.306 0.017 WP63SJ1F10 0.0109 0.0017 0.0298 0.0023 0.307 0.017 WP75SJ7 (83 µm ) WP75SJ7A1 0.225 0.016 0.1239 0.0083 1.626 0.078 WP75SJ7A2 0.0063 0.0016 0.0571 0.0041 0.474 0.023 WP75SJ7A3 0.0094 0.0016 0.0865 0.0059 0.508 0.025 WP75SJ7A4 0.0182 0.002 0.0418 0.0031 0.43 0.021 WP75SJ7A5 0.0719 0.0058 0.0955 0.0066 0.484 0.024 WP75SJ7A6 0.454 0.032 0.834 0.053 0.586 0.028

12 WP75SJ7A7 0.046 0.004 0.0903 0.0062 0.461 0.022

2 WP75SJ7A8 0.0443 0.0038 0.0603 0.0043 0.399 0.019

WP75SJ7A9 0.0523 0.0043 0.1015 0.0068 0.385 0.019 WP75SJ7A10 0.0157 0.0022 0.0442 0.0034 0.396 0.019 WP75SJ7A11 0.0084 0.0022 0.139 0.0093 0.632 0.031 WP75SJ7A12 0.0253 0.0028 0.1023 0.007 0.572 0.028 WP75SJ7A13 0.0242 0.0028 0.169 0.011 0.544 0.026 WP75SJ7A14 0.0136 0.0023 0.1171 0.008 0.569 0.028 WP75SJ7A15 0.0153 0.0021 0.1324 0.0088 0.545 0.026 WP75SJ7A16 0.0137 0.0024 0.151 0.01 0.54 0.026 WP75SJ7A17 0.0199 0.0027 0.0972 0.0068 0.599 0.029 WP75SJ7A18 0.0107 0.0019 0.0854 0.0059 0.509 0.025 WP75SJ7A19 0.0099 0.0019 0.0913 0.0063 0.551 0.027 WP75SJ7A20 0.0076 0.0017 0.0717 0.005 0.54 0.026 WP75SJ7A21 0.598 0.041 0.0103 0.0015 0.987 0.047 WP75SJ7A22 0.306 0.022 0.0174 0.0018 1.622 0.078

Conc. (ppm) Spot [208Pb] ±1σ [232Th] ±1σ [238U] ±1σ WP75SJ7A23 0.0286 0.003 0.0106 0.0016 1.842 0.088 WP75SJ7A24 0.0845 0.0065 0.1088 0.0073 1.637 0.078 WP75SJ7A25 0.689 0.048 0.876 0.055 5.12 0.24 WP75SJ7A26 0.058 0.0052 0.0278 0.0028 0.605 0.029 WP75SJ7A27 0.0417 0.004 0.0276 0.0027 1.198 0.058 WP75SJ7A28 0.0219 0.0033 0.0533 0.0044 0.375 0.019 WP75SJ7A29 0.0271 0.0036 0.0753 0.0057 0.48 0.024 WP75SJ7A30 0.0253 0.0037 0.0615 0.0051 0.505 0.025 WP75SJ7A31 0.0289 0.0027 0.0886 0.006 0.454 0.022 WP75SJ7A32 0.0301 0.003 0.0757 0.0053 0.615 0.03 WP75SJ7A33 0.0553 0.005 0.095 0.0067 0.6 0.029 WP75SJ7A34 0.0428 0.0038 0.1492 0.0098 0.729 0.035

12 WP75SJ7A35 0.0219 0.0026 0.0904 0.0062 0.646 0.031

3 WP75SJ7A36 0.0258 0.0033 0.0564 0.0045 0.61 0.03

WP75SJ7A37 0.0228 0.0033 0.0591 0.0047 0.584 0.029 WP75SJ7A38 0.0303 0.0039 0.0828 0.0063 0.484 0.024 WP75SJ7A39 0.0179 0.0025 0.0852 0.006 0.446 0.022 WP75SJ7A40 0.0207 0.0023 0.0853 0.0058 0.456 0.022 WP114SJ2A (83 µm ) WP114SJ2AA1 0.187 0.011 0.365 0.016 0.353 0.018 WP114SJ2AA2 0.1054 0.0069 0.1972 0.009 0.389 0.02 WP114SJ2AA3 3.87 0.22 3.62 0.15 0.951 0.048 WP114SJ2AA4 0.0829 0.0054 0.1007 0.0048 0.39 0.02 WP114SJ2AA5 0.748 0.043 0.812 0.035 1.577 0.08 WP114SJ2AA6 1.054 0.061 0.651 0.028 1.382 0.07 WP114SJ2AA7 0.394 0.023 0.629 0.027 0.639 0.032 WP114SJ2AA8 0.0617 0.0042 0.0778 0.0038 0.415 0.021 WP114SJ2AA9 0.212 0.013 0.396 0.017 0.429 0.022

Conc. (ppm) Spot [208Pb] ±1σ [232Th] ±1σ [238U] ±1σ WP114SJ2AA10 0.343 0.02 0.327 0.015 0.506 0.026 WP114SJ2AB1 0.252 0.016 0.1494 0.0075 1.746 0.088 WP114SJ2AB2 0.182 0.012 0.1594 0.008 2.14 0.11 WP114SJ2AB3 0.252 0.016 0.302 0.014 1.39 0.071 WP114SJ2AB4 0.0488 0.0043 0.0465 0.0032 2.25 0.11 WP114SJ2AB5 0.149 0.01 0.1543 0.0081 0.26 0.014 WP114SJ2AB6 0.24 0.015 0.1815 0.0091 1.596 0.081 WP114SJ2AB7 0.1066 0.0078 0.1811 0.009 1.695 0.086 WP114SJ2AB8 0.179 0.012 0.1329 0.0069 1.863 0.094 WP114SJ2AB9 0.1436 0.0097 0.0901 0.0051 1.796 0.091 WP114SJ2AB10 0.269 0.017 0.1395 0.0071 1.925 0.097 WP114SJ2AC1 0.0247 0.0027 0.0413 0.0027 2.23 0.11

12 WP114SJ2AC2 0.663 0.039 1.069 0.046 1.663 0.084

4 WP114SJ2AC3 0.0329 0.003 0.0328 0.0023 2.3 0.12

WP114SJ2AC4 0.0744 0.0052 0.0436 0.0027 2.25 0.11 WP114SJ2AC5 0.0315 0.0028 0.0371 0.0024 2.13 0.11 WP114SJ2AC6 0.0321 0.0044 0.0424 0.0037 2.16 0.11 WP114SJ2AC7 0.0488 0.0038 0.0818 0.0042 2.07 0.1 WP114SJ2AC8 0.0349 0.0029 0.0471 0.0027 2.1 0.11 WP114SJ2AC9 0.0507 0.004 0.0565 0.0033 1.889 0.095 WP114SJ2AC10 0.0686 0.0049 0.042 0.0026 2.08 0.1 WP114SJ2AD1 0.222 0.013 0.1298 0.0062 1.094 0.055 WP114SJ2AD2 0.659 0.038 0.1392 0.0065 1.271 0.064 WP114SJ2AD3 0.1174 0.0076 0.1568 0.0074 1.159 0.059 WP114SJ2AD4 0.1214 0.0077 0.2176 0.0098 0.382 0.02 WP114SJ2AD5 0.1116 0.0071 0.1144 0.0055 1.241 0.063 WP114SJ2AD6 0.1229 0.0083 0.1272 0.0065 1.472 0.075 WP114SJ2AD7 0.182 0.012 0.1004 0.0053 0.985 0.05

Conc. (ppm) Spot [208Pb] ±1σ [232Th] ±1σ [238U] ±1σ WP114SJ2AD8 0.1209 0.008 0.0927 0.0049 1.153 0.058 WP114SJ2AD9 0.231 0.014 0.0931 0.0047 1.195 0.06 WP114SJ2AD10 0.394 0.024 0.1701 0.0083 1.952 0.099 WP114SJ2AE1 0.1207 0.0077 0.1051 0.0052 0.783 0.04 WP114SJ2AE2 0.0827 0.0056 0.0773 0.004 0.811 0.041 WP114SJ2AE3 0.166 0.01 0.1311 0.0062 0.737 0.037 WP114SJ2AE4 0.0795 0.0055 0.071 0.0038 0.805 0.041 WP114SJ2AE5 0.082 0.0058 0.0847 0.0045 0.837 0.043 WP114SJ2AE6 0.0944 0.0065 0.0668 0.0038 0.852 0.043 WP114SJ2AE7 0.292 0.018 0.0886 0.0048 0.766 0.039 WP114SJ2AE8 0.1048 0.0073 0.0845 0.0046 1.011 0.051 WP114SJ2AE9 0.1293 0.0087 0.1179 0.0061 1.128 0.057

12 WP114SJ2AE10 0.362 0.022 0.0898 0.0047 0.996 0.051