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Geochemical cross sections through the Watchung of : Summary

J. H. PUFFER Department of Geology, Rutgers University, Newark, New Jersey 07102 PAUL LECHLER Indiana State Geological Survey, Bloomington, Indiana 47401

INTRODUCTION PETROGENESIS (1975) that the York Haven Basalt is a fractionation product of a more primitive The Watchung Basalt is exposed in First Watchung Basalt Quarryville (an olivine-normative north-central New Jersey as three parallel type). Mantle wall-rock reactions and crus-

ridges known as the First, Second, and The First Watchung Basalt is a high-Ti02 tal contamination were invoked by Smith Third Watchung Mountains, measuring type, on the basis of Weigand and Rag- and others (1975), in addition to fractiona- 183, 229, and 91 m thick, respectively. The land's (1970) classification scheme. The tion, to yield the York Haven type. Because

flows are in each case the result of fissure high-Ti02 type is the most abundant of the the Quarryville crops out only 125 km eruptions (Faust, 1975) in Liassic time eastern North America Mesozoic basalt southwest of the First Watchung, it might

(Cornet and Traverse, 1975). The flows are types that also include low-Ti02, high- also be considered as its parent. Bryan and

interbedded with the mudstones of the Fe203, and olivine-normative types. Other others (1977) and DeBoer and Snider

upper Brunswick Formation in the Newark high-Ti02 in basins adjacent to the (1979), however, pointed out that the high Basin. Twenty-seven samples of basalt were include the Talcot Basalt of degree of fractionation and selective con- collected at approximately 20-m intervals Connecticut (Hurtubise, 1979) and the tamination required to yield any high- along two traverses across the basalt ridges York Haven Basalt of eastern Pennsylvania Ti02—type magma out of the olivine- and were chemically analyzed. Major- and (Smith and others, 1975). Within the normative type does not agree with the very trace-element determinations indicate that Newark Basin the (Walker, consistent composition of the high-Ti02

each of the three Watchungs has a distinct 1969) is also a high-Ti02 type. type throughout eastern North America, chemical identity (Fig. 1). It has been suggested by Smith and others particularly the low-Ti02 scatter. The very

The entire article, of which this is a summary, appears in Part II of the Bulletin, v. 91, no. 1, p. 156-191.

Geological Society of America Bulletin, Part I, v. 91, p. 7-10, 1 fig., January 1980, Doc. no. S00103.

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1 1 8

MgO MgO Figure 1. MgO variation diagrams for First, Second, and Third Watchung Basalt units. This illustration is Figure 3 in the accompany- ing article in Part II.

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high degree of chemical similarity between within the Palisades sill of New Jersey, and La/Sm ratios of the Third Watchung are

the First Watchung and other high-Ti02- where very similar fractionation occurred. 1.92 and 2.29, respectively, compared to type basalts further supports that sugges- The chemical composition of the Second values of 4.50 and 2.93 for the First tion. It should also be pointed out that the Watchung Basalt very closely resembles the Watchung. Schilling (1975) and Kay and Quarryville is a picrite that has accumu- interior or the "second pulse" of magma Hubbard (1978) have clearly shown that lated considerable olivine and chrome that intruded the Palisades sill. Walker La/Yb and La/Sm ratios generally decrease spinel (Lanning, 1972). The Quarryville (1969) demonstrated that the Palisades is a away from plume centers. This further indi- and similar olivine-normative basalts are, multiple intrusion and that the second pulse cates that the magma source that was therefore, the product of another less mafic of magma represents a later fractionation of tapped to yield the parent of the Third magma and could not be the direct precur- the original magma. Watchung was much less plume-like than sor of the high-Ti02 magma. The Second Watchung also closely re- First Watchung magma. A fractionation-contamination model in- sembles the Holyoke Basalt (Hurtubise, The Third Watchung is chemically al- volving the precursor of the Quarryville 1979), which represents the second of three most identical to the Hampden Basalt, cannot be ruled out as a possibility, but the Mesozoic flows in Connecticut. Basalts which is the youngest of the three Mesozoic generation of a second magma would re- similar to the Second Watchung and flows of Connecticut (Hurtubise, 1979), but solve many of the complications presented Holyoke are not common enough to consti- the Third Watchung does not fit into the by such a model. If, however, a second tute a separate eastern North America compositional range of any of the eastern magma was generated simply through a (Weigand and Ragland, 1970) category, but North America basalt types of Weigand and shift in the degree of partial melting, it is the Second Watchung and Holyoke Basalts Ragland (1970). In accord with the Third

doubtful that the narrow range of major- approach and in many respects overlap the Watchung, the low-Ti02 type of Weigand

element composition could be maintained compositional range of the high-Fe203 and Ragland (1970) (including the Rossville over the required wide range of melting. basalt type of Weigand and Ragland Basalt of Smith and others, 1975) is also This is the reasoning that Bryan and others (1970). The Second Watchung-Holyoke younger and less depleted in incompatible (1977) and DeBoer and Snider (1979) used Basalt type and the Palisades trend itself elements than the other eastern North

to suggest that a second magma was gener- may, therefore, represent a transitional America type. The low-Ti02 type, which is

ated at a less depleted level in a vertically fractionation link between the high-Fe203 much less fractionated than the Third

heterogeneous mantle. type and the high-Ti02 type. The high- Watchung, may, therefore, be a plausible

A second magma generation would also Fe203 type is much less abundant in eastern parent for the Third Watchung. The represent a departure from the ponding North America than the high-Ti02 type, Rossville Basalt is geographically the closest models that have been suggested as pertain- probably because Palisades-type fractiona- low-Ti02 type to the Third Watchung; it is ing to the Mesozoic basalts of northwest tion only occasionally occurred. High- only 125 km southwest of the Third Africa (Manspeizer and others, 1978; Ti02—type magma more commonly in- Watchung in eastern Pennsylvania. Frac- Testa, 1978). Among the Moroccan basalts, truded rapidly enough to avoid such frac- tionation modeling (Wright, 1974) is, how- however, there is considerable compo- tionation. The high degree of compositional ever, incapable of resolving some large sitional scatter, particularly among the scatter among high-Fe203—type basalts major-element residuals in calculated Third basalts of Hettangian age (Manspeizer and (Weigand and Ragland, 1970) is consistent Watchung magma, assuming that pyrox- others, 1978). Among the Liberian dolerites with the range of composition expected of ene, plagioclase, and olivine were removed (Testa, 1978) there is also considerable local fractionation products. The addition from the Rossville. A much more realistic compositional scatter, particularly with re- of the Second Watchung and the Holyoke fractionation model is developed by assum-

spect to Ti02. Arguments that rely on com- magmas to the high-Fe203 type would in- ing that "normal" Mid-Atlantic Ridge positional consistency within basalt types crease this compositional scatter still basalt (Schilling, 1975) was the parent of do not apply as well to northwest Africa, further. the Third Watchung Basalt. An example of where some crustal ponding and contami- "normal" Mid-Atlantic Ridge basalt is the nation may well have occurred. Third Watchiing Basalt basalt found near lat 30°N (Miyashiro and others, 1969). Residuals are still rather Second Watchung Basalt On the basis of geochemical evidence, the high, and a large degree of crystallization is Third Watchung Basalt could not be de- calculated, but with all its imperfections the The origin of the Second Watchung rived by any reasonable fractionation model assuming "normal" Mid-Atlantic Basalt is best explained as a fractionation model that would assume the First or Sec- Ridge basalt as the parent is more realistic product of First Watchung magma. By ond Watchung as a parent. Although the than models that assume any of the eastern modeling the differentiation process by FeO/MgO ratio of the Third Watchung North America types as the parent. least-squares mixing procedures developed (2.35) is even greater than that of the Sec- Basalt chemically similar to Third by Wright and Doherty (1970), Wright ond Watchung (1.72), the Third Watchung Watchung and Hampden basalt is very rare (1974), and Doherty (1975), a calculated contains about half as much K20 and Sr in an oceanic setting, if it exists at all, prob- magma very closely resembling the actual and about 20% less Rb. This indicates that ably because of the absence of structures analyzed Second Watchung Basalt is de- the Third Watchung was the product of a within the oceanic crust that are capable of rived from First Watchung magma through more depleted magma source than the Sec- causing highly evolved degrees of fraction-

the removal of 11.2% plagioclase (An75), ond Watchung. Although the FeO/MgO ation. The continental crustal structures

11.0% augite (Wo41EN46Fs13), and 3.6% ratio of the Third Watchung is much that were still available during the frac-

olivine (Fo80). greater than that of the First Watchung tionation of the Third Watchung magma Support for the above First-Second (1.24) rare-earth-element analyses (Kay and may have prevented the extrusion of what Watchung fractionation model is found Hubbard, 1978) indicate that the La/Yb would have been some of the first "normal"

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oceanic magma onto the Newark and Con- Doherty, P. C., 1975, Mineral distribution pro- ical Research, v. 80, p. 1459-1473. necticut Basins. gram — MOD 111 (H444): Washington, Smith, R. C., Rose, A. W., and Lanning, R. M., D.C., Computer Center Division. 1975, Geology and geochemistry of Triassic Faust, G. T., 1975, A review and interpretation diabase in Pennsylvania: Geological Society ACKNOWLEDGMENTS of the geologic setting of the Watchung of America Bulletin, v. 86, p. 943-955. Basalt flows, New Jersey: U.S. Geological Testa, S. M., 1978, Geochemistry of Mesozoic We thank the Indiana State Geological Survey Professional Paper 864-A, 40 p. dolerites from Liberia, Africa and Spits- Survey for the use of their laboratories. We Hurtubise, D. O., 1979, Geochemistry and pe- bergen [M.S. thesis]: Northridge, California also thank Warren Manspeizer, Samuel Ag- trology of the Talcot, Holyoke, and Hamp- State University, 112 p. den basalts, southern Hartford Basin, Con- Walker, K. R., 1969, The Palisades Sill: A rein- ron, Harold Cousminer, and David Gott- necticut [M.S. thesis]: Newark, N.J., Rut- vestigation: Geological Society of America fried for ideas that have contributed to this gers University, 76 p. Special Paper 111, 178 p. report and for reading the manuscript. Kay, R. W., and Hubbard, N. J., 1978, Trace Weigand, P. W., and Ragland, P. G., 1970, elements in ocean ridge basalts: Earth and Geochemistry of Mesozoic dolerite dikes Planetary Science Letters, v. 38, p. 95-116. from eastern North America: Contributions REFERENCES CITED Lanning, R. M., 1972, An olivine tholeiite dike to Mineralogy and Petrology, v. 29, swarm in Lancaster County, Pennsylvania p. 195-214. Bryan, W. B., Frey, F. A., and Thompson, G., [M.S. thesis]: University Park, Pennsylvania Wright, T. J., 1974, Presentation and interpreta- 1977, Oldest Atlantic seafloor: Mesozoic State University, 80 p. tion of chemical data for igneous rocks: basalts from Western North Atlantic mar- Manspeizer, Warren, Puffer, J. H., and Cous- Contributions to Mineralogy and Petrol- gin and Eastern North America: Contribu- miner, H. L., 1978, The separation of ogy, v. 48, p. 233-248. tions to Mineralogy and Petrology, v. 64, p. Morocco and eastern North America: A Wright, T. J., and Doherty, P. C., 1970, A linear 223-242. Triassic-Liassic stratigraphic record: Geo- programming and least squares computer Cornet, B., and Traverse, A., 1975, Palynological logical Society of America Bulletin, v. 89, method for solving petrologic mixing prob- contributions to the chronology and stratig- p. 901-920. lems: Geological Society of America Bulle- raphy of the Hartford Basin in Connecticut Miyashiro, A., Shido, F., and Ewing, M., 1969, tin, v. 81, p. 1995-2008. and Massachusetts, in Geoscience and man: Diversity and origin of abyssal tholeiite American Association of Stratigraphie from the Mid-Atlantic Ridge near 24° and Palynologists Annual Meeting, 6th, Pro- 30° north latitude: Contributions to ceedings, v. 11, p. 1-33. Mineralogy and Petrology, v. 23, p. 38-52. DeBoer, J., and Snider, F. G., 1979, Magnetic Schilling, T. G., 1975, Rare-earth variations and chemical variations of Mesozoic across "normal segments" of the Reykjanes diabase dikes from eastern North America: Ridge, 60°-53°N, Mid-Atlantic Ridge, MANUSCRIPT RECEIVED BY THE SOCIETY Evidence for a hotspot in the Carolinas?: 29°S, and East Pacific Rise, 2-19°S, and NOVEMBER 3, 1978 Geological Society of America Bulletin, evidence on the composition of the underly- REVISED MANUSCRIPT RECEIVED JUNE 27,1979 v. 90, p. 185-198. ing low-velocity layer: Journal of Geophys- MANUSCRIPT ACCEPTED JULY 13, 1979

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