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History of the Chlor-Alkali Industry
2 History of the Chlor-Alkali Industry During the last half of the 19th century, chlorine, used almost exclusively in the textile and paper industry, was made [1] by reacting manganese dioxide with hydrochloric acid 100–110◦C MnO2 + 4HCl −−−−−−→ MnCl2 + Cl2 + 2H2O (1) Recycling of manganese improved the overall process economics, and the process became known as the Weldon process [2]. In the 1860s, the Deacon process, which generated chlorine by direct catalytic oxidation of hydrochloric acid with air according to Eq. (2) was developed [3]. ◦ 450–460 C;CuCl2 cat. 4HCl + O2(air) −−−−−−−−−−−−−−→ 2Cl2 + 2H2O(2) The HCl required for reactions (1) and (2) was available from the manufacture of soda ash by the LeBlanc process [4,5]. H2SO4 + 2NaCl → Na2SO4 + 2HCl (3) Na2SO4 + CaCO3 + 2C → Na2CO3 + CaS + 2CO2 (4) Utilization of HCl from reaction (3) eliminated the major water and air pollution problems of the LeBlanc process and allowed the generation of chlorine. By 1900, the Weldon and Deacon processes generated enough chlorine for the production of about 150,000 tons per year of bleaching powder in England alone [6]. An important discovery during this period was the fact that steel is immune to attack by dry chlorine [7]. This permitted the first commercial production and distribu- tion of dry liquid chlorine by Badische Anilin-und-Soda Fabrik (BASF) of Germany in 1888 [8,9]. This technology, using H2SO4 for drying followed by compression of the gas and condensation by cooling, is much the same as is currently practiced. 17 “chap02” — 2005/5/2 — 09Brie:49 — page 17 — #1 18 CHAPTER 2 In the latter part of the 19th century, the Solvay process for caustic soda began to replace the LeBlanc process. -
Evaluating the Acute and Chronic Toxicity of Potassium Carbonate and the Interactive Effects Between Sodium and Potassium on Rainbow Trout (Oncorhynchus Mykiss)
University of New Hampshire University of New Hampshire Scholars' Repository Master's Theses and Capstones Student Scholarship Fall 2020 Evaluating the acute and chronic toxicity of potassium carbonate and the interactive effects between sodium and potassium on rainbow trout (Oncorhynchus mykiss) Ashutosh Rao University of New Hampshire, Durham Follow this and additional works at: https://scholars.unh.edu/thesis Recommended Citation Rao, Ashutosh, "Evaluating the acute and chronic toxicity of potassium carbonate and the interactive effects between sodium and potassium on rainbow trout (Oncorhynchus mykiss)" (2020). Master's Theses and Capstones. 1395. https://scholars.unh.edu/thesis/1395 This Thesis is brought to you for free and open access by the Student Scholarship at University of New Hampshire Scholars' Repository. It has been accepted for inclusion in Master's Theses and Capstones by an authorized administrator of University of New Hampshire Scholars' Repository. For more information, please contact [email protected]. Evaluating the acute and chronic toxicity of potassium carbonate and the interactive effects between sodium and potassium on rainbow trout (Oncorhynchus mykiss) By Ashutosh Rao BS in Marine, Freshwater, & Estuarine Biology, University of New Hampshire, 2017 THESIS Submitted to the University of New Hampshire in Partial Fulfillment of the Requirements for the Degree of Master of Science in Biological Sciences: Marine Biology September 2020 i This thesis was examined and approved in partial fulfillment of the requirements for the degree of Master’s in Biological Sciences: Marine Biology by: Thesis/Dissertation Director, Dr. Elizabeth Fairchild, Research Associate Professor in Biological Sciences, University of New Hampshire Dr. Todd Guerdat, Assistant Professor of Agricultural Engineering, University of New Hampshire Dr. -
Suppression Mechanisms of Alkali Metal Compounds
SUPPRESSION MECHANISMS OF ALKALI METAL COMPOUNDS Bradley A. Williams and James W. Fleming Chemistry Division, Code 61x5 US Naval Research Lnhoratory Washington, DC 20375-5342, USA INTRODUCTION Alkali metal compounds, particularly those of sodium and potassium, are widely used as fire suppressants. Of particular note is that small NuHCOi particles have been found to be 2-4 times more effective by mass than Halon 1301 in extinguishing both eountertlow flames [ I] and cup- burner flames [?]. Furthermore, studies in our laboratory have found that potassium bicarbonate is some 2.5 times more efficient by weight at suppression than sodium bicarhonatc. The primary limitation associated with the use of alkali metal compounds is dispersal. since all known compounds have very low volatility and must he delivered to the fire either as powders or in (usually aqueous) solution. Although powders based on alkali metals have been used for many years, their mode of effective- ness has not generally been agreed upon. Thermal effects [3],namely, the vaporization of the particles as well as radiative energy transfer out of the flame. and both homogeneous (gas phase) and heterogeneous (surface) chemistry have been postulated as mechanisms by which alkali metals suppress fires [4]. Complicating these issues is the fact that for powders, particle size and morphology have been found to affect the suppression properties significantly [I]. In addition to sodium and potassium, other alkali metals have been studied, albeit to a consider- ably lesser extent. The general finding is that the suppression effectiveness increases with atomic weight: potassium is more effective than sodium, which is in turn more effective than lithium [4]. -
Ryflor™ Chemical Compatibility List
Chemical Compatibility List The following information is based on known chemical compatibility data for RyFlor™, and should only be considered as reference. Further laboratory tests may be required to verify the compatibility of a particular chemical with expanded RyFlor™ products. Chemicals Compatible with RyFlor™ Acetaldehyde Barium Sulfide Cetane (Hexadecane) Acetamide Beer Chloric Acid Acetic Acid Benzaldehyde Chlorinated Water Acetic Anhydride Benzene Chlorine Acetone Benzoic Acid Chlorine Dioxide Acetophenone Benzonitrile Chloroacetic Acid Acetylene Benzyl Alcohol Chlorobenzene Acrylic Anhydride Benzyl Chloride Chloroethylene Adipic Acid Black Liquor (Sulfate Chloroform Allyl Acetate Liquor) Chlorosulfonic Acid Allyl Alcohol Borax Chromic Acid Allyl Chloride Boric Acid Chromic Anhydride Aluminum Chloride Brine Citric Acid Aluminum Flouride Bromine Copper Acetate Aluminum Hydroxide Butadiene Copper Chloride Aluminum Nitrate Butane Copper Fluoride Aluminum Potassium Butyl Acetate Copper Sulfate Sulfate (Alum) Butyl Alcohol (Butanol) Cottonseed Oil Aluminum Sulfate Butyl Amine Creosote Ammonia Butyl Chloride Cresols (Cresylic Acid) Ammonium Carbonate Butyl Ether Crude Oil Ammonium Chloride Butyl Phthalate Cyanic Acid Ammonium Fluoride Butyl Methacrylate Cyclohexane Ammonium Hydroxide Butylene Cyclohexanol Ammonium Nitrate Butyric Acid Cyclohexanone Ammonium Phosphate Calcium Bisulfite Dibutyl Phthalate Ammonium Sulfate Calcium Chloride Dichlorobenzen Amyl Acetate Calcium Hydroxide Dichloroethane Amyl Alcohol Calcium Hypochlorite Dichloroethylene -
Alkali-Silica Reactivity: an Overview of Research
SHRP-C-342 Alkali-Silica Reactivity: An Overview of Research Richard Helmuth Construction Technology Laboratories, Inc. With contributions by: David Stark Construction Technology Laboratories, Inc. Sidney Diamond Purdue University Micheline Moranville-Regourd Ecole Normale Superieure de Cachan Strategic Highway Research Program National Research Council Washington, DC 1993 Publication No. SHRP-C-342 ISBN 0-30cL05602-0 Contract C-202 Product No. 2010 Program Manager: Don M. Harriott Project Maxtager: Inam Jawed Program AIea Secretary: Carina Hreib Copyeditor: Katharyn L. Bine Brosseau May 1993 key words: additives aggregate alkali-silica reaction cracking expansion portland cement concrete standards Strategic Highway Research Program 2101 Consti!ution Avenue N.W. Washington, DC 20418 (202) 334-3774 The publicat:Lon of this report does not necessarily indicate approval or endorsement by the National Academy of Sciences, the United States Government, or the American Association of State Highway and Transportation Officials or its member states of the findings, opinions, conclusions, or recommendations either inferred or specifically expressed herein. ©1993 National Academy of Sciences 1.5M/NAP/593 Acknowledgments The research described herein was supported by the Strategic Highway Research Program (SHRP). SHRP is a unit of the National Research Council that was authorized by section 128 of the Surface Transportation and Uniform Relocation Assistance Act of 1987. This document has been written as a product of Strategic Highway Research Program (SHRP) Contract SHRP-87-C-202, "Eliminating or Minimizing Alkali-Silica Reactivity." The prime contractor for this project is Construction Technology Laboratories, with Purdue University, and Ecole Normale Superieure de Cachan, as subcontractors. Fundamental studies were initiated in Task A. -
Research Module: Scheme 2A. N-Benzylation Using Benzyl Bromide 63
Research Module: Scheme 2A. N-Benzylation Using Benzyl Bromide 63 O Scheme 2 Option O Methanol Solvent NH N-Benzylation + Br NH2 N via Alkyl Halide 1 K2CO3 Workup NH 8 R1 R1 (0.139g/mmol) 6a-e Synthesis of 3a-e Benzyl Bromide N-Benzyl 171 g/mol N-Benzyl 1.438 g/ml Pyrazolidinone Pyrazolidinones 119 ml/mol Scheme 2 Part A: Redissolve in Methanol 1. Turn hot plate to 5. 2. To the flask with your product 3 from Scheme 1, attach a condener with gentle water flow. 3. Add 15 mL of methanol. • For 4-methoxy compoud 3c, you may need to add 20 mL of methanol, since the 4-methoxy substrates is probably less soluble. 4. Heat the mixture on the hot plate with the stirrer at 6 until the material dissolves and becomes completely homogeneous. Once it’s dissolved, reduce the hot plate setting to 4. • If the stir bar isn’t coming free even after several minutes, you may wish to detach the condenser and poke the stir-bar free with a spatula • Make sure that there aren’t chunks or blobs of undissolved material on the outside. Everything needs to be dissolved. 5. Calculate 0.9 equivalents of benzyl bromide. Calculate how many mL of benzyl bromide (119 mL/mol) you need to add 0.90 mmol benzyl bromide per mmol of 3. In other words, if you have 20.0 mmol of 3c, how many mL of benzaldehyde will it take to provide 18.0 mmol? • You need to know how many mmol of reactant 3 you are working with. -
Safety Data Sheet - Patina Gel Revision 11/14/2016
Safety Data Sheet - Patina Gel Revision 11/14/2016 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Patina Gel / Sulfurated Potash 39365-88-3 CAS #: 39365-88-3 Manufacturer: Cool Tools 945 N. Parkway St Jefferson, WI 53549 Telephone: 888-478-5060 Fax: 262-546-5275 Emergency Phone #: Chemtrec USA & Canada 800-424-9300 International 703-527-38 2. HAZARDS IDENTIFICATION GHSClassification Acute Toxicity, Oral (Category 3) Skin Irritation (Category 2) Serious Eye Irritation (Category 2) GH3 Label elements, including precautionary statements Signal Word: Warning Hazard statement(s) H303 May be harmful if swallowed. H315 Causes skin irritation. H320 Causes eye irritation. Precautionary statement(s) P264 Wash hands, face and clothing after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well ventilated area. P280 Wear protective gloves/clothing/eye protection P305 & P351 If in eyes, rinse cautiously with water for several minutes. P338 Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a poison center/doctor if you feel unwell. HMIS Classification NFPA Classification Health hazard: 2 Health hazard: 2 Contact: 1 Reactivity: 0 Flammability 0 Flammability: 0 Physical hazards: 2 Personal B Distributed by: Cool Tools 945 N Parkway St Jefferson, WI 53549 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms: Liver of Sulfur, Sulfurated potassa, hepar sulfuris Potassium Trisulfide CAS No. 37488-75-8: 6.25% Potassium Thiosulfate Hydrated CAS No. 10294-66-3: 18.75% Glycerin CAS No. 56-81-5: 75% 4. FIRST AID MEASURES Inhalation: Not likely to occur except as a mist. -
Spe-128 the Catalysis of Potassium Carbonate Solutions in Carbon Dioxide Absorption
SPE-128 THE CATALYSIS OF POTASSIUM CARBONATE SOLUTIONS IN CARBON DIOXIDE ABSORPTION By A. G. Eickmeyer, Chemical Engineering Consultant Prairie Village, Kansas ABS~:RACT bing. The activity o£ hot potassium car THEORY AND DEPINITIONS Downloaded from http://onepetro.org/speatce/proceedings-pdf/61fm/all-61fm/spe-128-ms/2087284/spe-128-ms.pdf by guest on 01 October 2021 bonate solutions has been £ound to be a function of contaminants, having a de The absorption of an acid gas in leterious effect, and catalysts, which any alkaline solution is classed as activate the solution. A small amount chemi-sorption, that is, absorption ll of "Catacarb catalyst cancels the e£ accompanied by chemical reaction. The £ect o£ contamination and larger amounts rate o£ chemical reaction determines give a much more active solution than the size of the towers required by the pure potassium carbonate. In commercial process. plant tests in existing carbonate Unlike caustic, a carbonate solu plants, the Catacarb Process resulted tion has very few hydroxyl ions to re in increased capacity, reduced steam act directly with CO , Therefore, it usaze, and less residual CO , In 2 2 is believed that CO2 must £irst become new plant construction, ~ ss equipment ·hydrated, or react with water to £orm and utility requirements o£ the Catacarb carbonic acid, which in turn reacts Process permit savings in capital in with a carbonate ion to form two bi vestment and operating costs. carbonate ions. INTRODUC '1'1 ON (1) CO2 • H2 0 = H2 CO 3 The hot potassium carbonate £r~cess, developed by the Bureau o£ Mines, ,-, has been applied extensively in recent years to CO 2 removal in the puri£ica Con£irmation o£ the reaction with tion of hydrogen and natural Gas. -
Effect of Immersion in Water Or Alkali Solution on the Structures and Properties of Epoxy Resin
polymers Article Effect of Immersion in Water or Alkali Solution on the Structures and Properties of Epoxy Resin Bin Wang 1, Dihui Li 2,3,4, Guijun Xian 2,3,4 and Chenggao Li 2,3,4,* 1 Central Research Institute of Building and Construction Co., Ltd., Beijing 100088, China; [email protected] 2 Key Lab of Structures Dynamic Behavior and Control, Ministry of Education, Harbin Institute of Technology, Harbin 150090, China; [email protected] (D.L.); [email protected] (G.X.) 3 Key Lab of Smart Prevention and Mitigation of Civil Engineering Disasters of the Ministry of Industry and Information Technology, Harbin Institute of Technology, Harbin 150090, China 4 School of Civil Engineering, Harbin Institute of Technology, Harbin 150090, China * Correspondence: [email protected]; Tel./Fax: +86-451-8628-3120 Abstract: The durability of fiber-reinforced polymer (FRP) composites is significantly dependent on the structures and properties of the resin matrix. In the present paper, the effects of physical or chemical interactions between the molecular chain of the epoxy resin matrix and water molecules or alkaline groups on the water absorption, mechanical structures, and microstructures of epoxy resin samples were studied experimentally. The results showed that the water uptake curves of the epoxy resin immersed in water and an alkali solution over time presented a three-stage variation. At different immersion stages, the water uptake behavior of the resin showed unique characteristics owing to the coupling effects of the solution concentration gradient diffusion, molecular hydrolysis reaction, and molecular segment movement. In comparison with the water immersion, the alkali solution environment promoted the hydrolysis reaction of the epoxy resin molecular chain. -
Effect of Alkalies on Wool
U. S. DEPARTMENT OF COMMERCE NATIONAL BUREAU OF STANDARDS RESEARCH PAPER RP810 Part of Journal of Research of the N.ational Bureau of Standards, Volume 15, July 1935 EFFECT OF ALKALIES ON WOOL By Milton Harris 1 ABSTRACT Data on the effect of various alkaline reagents on the physical and chemical properties of wool yarn are presented. When wool is treated with dilute sodium hydroxide solutions, a rapid splitting off of a portion of the sulphur occurs. On continued treatment, the sulphur content of the residual wool approaches a con stant value of about 1.8 percent. The results indicate that the alkaline treatment has changed a portion of the sulphur to a form which tends to resist further split ting from the molecule. Oxidizing and reducing agents attack the disulphide groups and make wool more susceptible to alkaline treatments. The susceptibil ity of untreated wool to alkaline reagents appears to be closely associated with the lability of its sulphur in alkaline solutions. CONTENTS Page I. Introduction________ _____ _______ _____ ____ _______ ____ ___________ 63 II. Materials and methods_ _ _ _ _ __ _ ___ _ _ _ _ __ __ _ __ _ __ ______ _________ __ 64 nI. Results and discussion___ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ __ _ _ _ _ __ _ _ _ _ _ _ __ _ _ _ _ _ _ 65 1. Effect of alkaline reagents on wool yarn___ __________ ________ 65 2. Nature of the action of alkalies on the sulphur of wooL_ __ ____ 66 3. -
Possible Hazards for CHEM-101 Introduction to Chemistry
Possible Hazards for CHEM-101 Introduction to Chemistry This list of substances represents the possible hazards currently identified for this course; however, substitutions or additions are possible. Do not assume a substance is safe if it is not listed. You will be notified of changes as soon as they are available. If you are aware of any known allergies or sensitivities to chemicals, please let your professor know prior to the first lab class. Gold Metal 6M Sodium Hydroxide Granular Zinc 0.1 M Barium Chloride Hardness Test Tablets 0.1 M Barium Nitrate Hexamethylenedamine 0.1 M Calcium Chloride hexane 0.1 M Calcium Nitrate Household Ammonia 0.1 M Cobalt Chloride household vinegar 0.1 M Cobalt Nitrate Hydrogen Peroxide 3% 0.1 M Lithium Chloride Iodine powder 0.1 M Magnesium Chloride Iron Sulfate 0.1 M Magnesium Sulfate Iron Tablets 0.1 M Potassium Iodide latex, red, blue, white 0.1 M Potassium Nitrate lemon juice 0.1 M Strontium Chloride Lithium Chloride 0.1M Ammonium Hydroxide Magnesium Chloride 0.1M and 2M Sodium Hydroxide Magnesium Metal 0.1M Copper Chloride Magnesium metal strips Chloride Test tablets Manganese Dioxide Citric Acid milk of magnesia Cobalt Chloride Mossy Zinc Metal Concentrated Nitric Acid Mr. Clean Copper Sulfate Muriatic Acid (HCl) Copper Test Tablets Nickel Chloride Copper Wire Nitrate tablets Cupric Nitrate Oxalic Acid food coloring pH buffer 10 Fructose pH buffer 4 pH buffer 7 pH Tablets polyvinyl alcohol Potassium Iodide Salt 0.1M Copper Sulfate 0.1M Hydrochloric Acid 0.1M Hydrochloric Acid 0.1M Magnesium Chloride 0.1M Phosphoric Acid 0.1M Sodium Hydroxide 0.2M Sodium Hydroxide 1% alcoholic phenolphthalein 10% Hydrochloric Acid 3.5% Sea water 5% borax 5% Sodium Hydroxide 6M Sulfuric Acid Acetone Albumin Alka-Seltzer tablets Aluminum metal Ascorbic Acid aspirin tablets Caffeine Calcium Chloride Calcium Hydroxide Calcium Oxide Calcium w/Vit D Carbon 100% Alcohol 1M Sulfuric Acid Updated: August 23, 2019 ss Complete List of Chemicals These chemicals are stored in an adjacent area. -
The European Chlor-Alkali Industry: an Electricity Intensive Sector Exposed to Carbon Leakage
Brussels, December 2010 The European Chlor-Alkali industry: an electricity intensive sector exposed to carbon leakage The revised EU ETS (Emission Trading Scheme) Directive 2009/29/EC will have financial consequences for all energy-intensive industries. The chlor-alkali industry is in particular exposed to a significant risk of carbon leakage due to CO 2 costs passed through in the electricity prices. The Directive recognises the need to avoid carbon leakage whilst at the same time fulfilling the climate change objective of reducing CO 2 emissions and, consequently, it allows Member States to adopt financial measures to compensate energy-intensive sectors for the additional costs of carbon passed through in electricity prices. This document aims at explaining why and how the chlor-alkali industry is highly impacted by the EU Emission Trading Scheme. 1. The chlor-alkali industry 1.1. The importance of the European chlor-alkali industry Chlorine and caustic soda are basic building blocks for thousands of useful substances and products. The chlor-alkali industry underpins about 55% of the European chemicals and pharmaceuticals industry which realised in 2009 a turnover of almost 660 billion euro. About 20 million tonnes of chlorine, caustic soda and hydrogen are produced each year at 76 manufacturing sites in 22 European countries. The chlor-alkali sector employs about 39,000 people. About two thirds of European chlorine production is used in engineering materials – polymers, resins and elastomers. The largest single end use (35%) is PVC plastic for primarily the construction, automotive, electronic and electrical industries. The manufacturing processes of many chemicals, plastics and medicines use chlorine, although the end product is chlorine-free, such as the plastics polyurethane and polycarbonate which have increasing numbers of applications.