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Ocena Ekološkega in Kemijskega Stanja Rek V Sloveniji V Letih 2007 in 2008

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Ocena Ekološkega in Kemijskega Stanja Rek V Sloveniji V Letih 2007 in 2008 MINISTRSTVO ZA OKOLJE IN PROSTOR REPUBLIKA SLOVENIJA AGENCIJA REPUBLIKE SLOVENIJE ZA OKOLJE OCENA EKOLOŠKEGA IN KEMIJSKEGA STANJA REK V SLOVENIJI V LETIH 2007 IN 2008 Ljubljana, marec 2010 MINISTRSTVO ZA OKOLJE IN PROSTOR REPUBLIKA SLOVENIJA AGENCIJA REPUBLIKE SLOVENIJE ZA OKOLJE OCENA EKOLOŠKEGA IN KEMIJSKEGA STANJA REK V SLOVENIJI V LETIH 2007 IN 2008 Nosilki naloge: mag. Irena Cvitani č, Bernarda Rotar Priprava poro čila: mag. Irena Cvitani č, mag. Mojca Dobnikar Tehovnik, dr. Jasna Grbovi ć, Brigita Jesenovec, mag. Špela Kozak Legiša, mag. Polona Mihorko, Bernarda Rotar, Edita Sodja, Špela Ambroži č Karte pripravila: Petra Krsnik mag. Mojca Dobnikar Tehovnik dr. Silvo Žlebir VODJA SEKTORJA GENERALNI DIREKTOR Ocena ekološkega in kemijskega stanja rek v Sloveniji v letih 2007 in 2008 Vsi izpisi rezultatov za leti 2007 in 2008 so objavljeni na spletni strani Agencije RS za okolje http://www.arso.gov.si/vode/podatki/ in so rezultat kontroliranih meritev v mreži za spremljanje kakovosti voda ter imajo javnopravni pomen (uradni podatki). Poro čilo in podatki so zaš čiteni po dolo čilih avtorskega prava, tisk in uporaba podatkov sta dovoljena le v obliki izvle čkov z navedbo vira. ISSN 1855 - 0320 Deskriptorji: Slovenija, reke, kakovost, onesnaženje, vzor čenje, ocena stanja, kemijsko stanje, ekološko stanje Descriptors: Slovenia, rivers, quality, pollution, sampling, quality status, chemical status, ecological status Ocena ekološkega in kemijskega stanja rek v Sloveniji v letih 2007 in 2008 KAZALO VSEBINE 1 POVZETEK..................................................................................................................................................................1 2 UVOD...........................................................................................................................................................................5 3 PROGRAM SPREMLJANJA EKOLOŠKEGA IN KEMIJSKEGA STANJA REK .......................................................7 3.1 VRSTE MONITORINGOV REK..........................................................................................................................8 3.1.1 Nadzorni monitoring.......................................................................................................................................8 3.1.2 Operativni monitoring.....................................................................................................................................9 3.2 VODNA TELESA REK VKLJU ČENA V PROGRAM MONITORINGA ..............................................................10 3.3 MREŽA MERILNIH MEST................................................................................................................................19 3.3.1 Metodologija za izbor reprezentativnih merilnih mest ..................................................................................19 3.4 LETNI NA ČRT POGOSTOSTI VZOR ČENJA IN OBSEG ANALIZ...................................................................20 3.5 REALIZACIJA PROGRAMOV MONITORINGOV.............................................................................................23 3.6 IZVAJALCI MONITORINGA KAKOVOSTI REK ...............................................................................................40 4 HIDROLOŠKO STANJE............................................................................................................................................41 5 FIZIKALNE IN KEMIJSKE ANALIZE........................................................................................................................42 5.1 VZOR ČENJE IN PRIPRAVA VZORCEV..........................................................................................................42 5.1.1 Osnovni fizikalni in kemijski parametri v vodi...............................................................................................42 5.1.2 Kovine v vodi ...............................................................................................................................................43 5.1.3 Organske spojine v vodi ..............................................................................................................................43 5.2 ANALIZNE METODE........................................................................................................................................48 5.2.1 Merilni principi..............................................................................................................................................48 5.3 ZAGOTAVLJANJE IN KONTROLA KAKOVOSTI.............................................................................................65 6 BIOLOŠKE ANALIZE................................................................................................................................................66 7 METODOLOGIJE OCENJEVANJA KEMIJSKEGA IN EKOLOŠKEGA STANJA REK...........................................67 7.1 KEMIJSKO STANJE REK ................................................................................................................................67 7.2 EKOLOŠKO STANJE.......................................................................................................................................69 7.3 RAVEN ZAUPANJA OCENE KEMIJSKEGA IN EKOLOŠKEGA STANJA REK...............................................72 7.3.1 Raven zaupanja ocene kemijskega stanja...................................................................................................72 7.3.2 Raven zaupanja ocene ekološkega stanja rek ............................................................................................73 8 OCENA KEMIJSKEGA IN EKOLOŠKEGA STANJA REK.......................................................................................75 8.1 OCENA KEMIJSKEGA STANJA REK..............................................................................................................75 8.2 OCENA EKOLOŠKEGA STANJA REK ............................................................................................................78 8.3 IZPOSTAVLJENI PROBLEMI STANJA VODA V LETIH 2007, 2008 ...............................................................88 8.3.1 Slabo kemijsko stanje rek ............................................................................................................................88 8.3.2 Slabo ekološko stanje rek............................................................................................................................90 9 KVANTIFIKACIJE PESTICIDOV V REKAH V LETIH 2007 IN 2008 ........................................................................93 10 ANALIZA SPREMEMB POSAMEZNIH PARAMETROV PO PORE ČJIH V DALJŠEM ČASOVNEM OBDOBJU ......99 10.1 KEMIJSKA POTREBA PO KISIKU...................................................................................................................99 10.2 BIOKEMIJSKA POTREBA PO KISIKU...........................................................................................................101 10.3 AMONIJ..........................................................................................................................................................103 10.4 FOSFOR ........................................................................................................................................................105 11 VIRI..........................................................................................................................................................................108 Ocena ekološkega in kemijskega stanja rek v Sloveniji v letih 2007 in 2008 SEZNAM TABEL Tabela 1: Pogostost vzorčenja za posamezne elemente kakovosti v okviru nadzornega monitoringa rek .............9 Tabela 2: Pogostost vzor čenja za posamezne elemente kakovosti v okviru operativnega monitoringa rek..........10 Tabela 3: Seznam vodnih teles in merilna mesta, na katerih se je izvajal monitoring rek v letu 2007...................12 Tabela 4: Seznam vodnih teles in merilna mesta, na katerih se je izvajal monitoring rek v letu 2008...................15 Tabela 5: Seznam podpornih fizikalno kemijskih elementov kakovosti za dolo čanjeekološkega stanja rek v Sloveniji..................................................................................................................................................20 Tabela 6: Biološki elementi kakovosti, metrike in obremenitve, ki jo kaže posamezna metrika ............................22 Tabela 7: Realizacija programa monitoringa rek v letu 2007 .................................................................................24 Tabela 8: Realizacija programa monitoringa rek v letu 2008 .................................................................................28 Tabela 9: Realizacija programa monitoringa bioloških elementov kakovosti rek v letu 2007 ................................34 Tabela 10: Realizacija programa monitoringa bioloških elementov kakovosti rek v letu 2008 ................................36 Tabela 11: Merjeni parametri v programu monitoringa rek ......................................................................................39 Tabela 12a: Merilni principi, standardi ali viri, meje zaznavnosti (LOD) in meje dolo čljivosti (LOQ) fizikalnih in kemijskih analiz v letu 2007 na ARSO ...................................................................................................48 Tabela 12b: Merilni principi, standardi ali viri, meje zaznavnosti (LOD) in meje dolo čljivosti (LOQ) fizikalnih in kemijskih analiz v letu 2007 in 2008 na ZZV-MB ...................................................................................52
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