DOCSLIB.ORG

United States Patent Office 2,988,421

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text

Load more

United States Patent Office Patented June2,988,421 13, 196 heavailaaaar 1 2 contain more than 200 gms. alkali metal and chloride ions 2,988,421 per litre. The following tables show the loss of thorium PROCESS FOR THE SEPARATION OF THORUM and lanthanons under various conditions in the presence WilliamANDRARE Palmer Kemp, EARTHS Shenfield, FROM and MONAZTE James Johnston, 5 of sodium and potassium chloride. Hainault, England, assignors to Thorium Limited, Lon don, England, a corporation of Great Britain NaCl, ThO Ln2O No Drawing. Filed Aug. 20, 1957, Ser. No. 679,126 Acidity gm.fl. loss, loss, Claim priority, application Great Britain Aug. 24, 1956 gm.fl. gm.fl. 9 Claims. (C. 23-145) -ror-rm-m-m------- 10 : 122 This invention relates to a process for separating thori- 4.5 8: um and lanthanon salts from other materials present in : g monazite. The invention is particularly useful in that it 55 i. provides a process for separating salts of thorium and the : 8. lanthanons from phosphate and impurities present in 1655 400 6.65 ground mineral monazite. The term lanthanon in this specification includes the elements with atomic numbers KC ThO Ln2O from 57-71; this group is also known as the rare earth Acidity fi. is is elements. gm.fl. gm.fl. Monazite sand is a mineral phosphate containing thori- .am-m-m-m-m-m-m-wn um and the lanthanon phosphates to the extent of about 38 o' 95-98% by weight. Another source is ground mineral 300 0.005 1.0 monazite which is far less pure than monazite sand and contains only about 75% of the thorium and lanthanon In a preferred form of the process the filtered extract phosphates. has an acidity greater than 4.5 N. Further, more eco An approximate analysis of a typical sample of ground nomic results are obtainable with a concentration of 200 mineral monazite is as follows: 400 gms, alkali metal and chloride ions per litre with the Percent normal concentration of thorium and lanthanon being ThoaLanthanon -------------------------------------- oxide ------------------------------ 46 50-60It has gms./litre been found of mostsolution satisfactory expressed to asadd oxide. a portion of CaO ---------------------------------------- 5 the filtered extract to the alkali metal chloride to form Feaos --------------------------------------- 5 a slurry and then add to the slurry the remainder of Al2O3, etc. ----------------------------------- 4. the extract. The precipitation of the double sulphates CuO ------------------- wrk or m r milm me a were man wa'w owns w i wo air 85 should preferably take place at about 60° C. as below this PbO ---------------------------------------- 0.3 temperature losses tend to increase; higher temperatures Usos --------------------------------------- 0.1 may be used but are not necessary. The double sulphate EQs ---------------------------------------- 27 is then filtered off and washed carefully with an alkali SiO2 ---------------------------------------- 5 metal chloride solution, care being taken to avoid un In the process for obtaining thorium and the lanthanons 40 necessary Washing, so keeping losses at a minimum. from these materials the monazite in finely divided state In its preferred form this process enables more than is treated with sulphuric acid and extracted with water. 99% of the thorium and lanthanon compounds to be pre Insoluble matter is filtered off and then by means of our cipitated from solution. A certain amount of phosphate invention the thorium and lanthanon compounds are sepa- remains with the thorium and lanthanon double sulphate ratedThis from invention the impurities provides present a process in thefor extract.the separation of As butwith the the amountsalts produced is substantially by earlier less processes. than that associated thorium and lanthanon salts from impurities such as iron, calcium, copper and aluminium, phosphate present in Example I monazite, in which process thorium and lanthanon double 200 lbs., ground mineral monazite (containing about sulphate is precipitated from a filtered acidic extract of 50 75% monazite) were mixed with 400 lbs. 96% sulphuric ground monazite in the presence of alkali metal and chlo- acid and stirred and heated to 200 C. This reaction mix ride ions. ture was allowed to stand overnight and then added to The chloride ions may be most easily introduced in the 130 gallons of water and stirred. The mixture was passed form of hydrochloric acid or as an alkali metal chloride. through a filter-press to remove insoluble material. A The alkali metal chlorides which it is preferred to use 55 portion of the clear liquor, containing 51 gm./I. of in the invention are those of sodium or potassium. For Ln2O-ThC) was added to 350 lbs. sodium chloride to reasons of economy and efficiency it is preferable to use form a thick slurry and then heated to 60° C. The re sodium chloride. maining liquor was then added to the slurry slowly while The separation of thorium from the lanthanons pre- heating sufficiently to keep the temperature at 60° C. cipitated as the double salt is carried out in the normal 60 After settling the clear mother liquor contained only 0.01 way, that is to say, the double salt is converted with ex- gm./1. of Tho, indicating over 99% of the thorium was cess caustic soda to hydroxides from which on careful precipitated. The solid was filtered on a rubber-lined treatment with mineral acid can be obtained a solution spinner and washed on the spinner to remove undesirable containing the lanthanons which may be separated from impurities in the mother liquor. This washing is kept the thorium hydroxide precipitate. 65 down to a minimum to avoid losses. A wash liquor con The acidity of the filtered acidic extract with which the taining 200 gm./l. NaCl and 50 gm./l. Na2SO4 is used. alkali metal and chloride ions are mixed must be care- The double sulphate contains about 35% Ln2O--Tho, fully controlled to obtain maximum precipitation of the and POs:ThO ratio of 0.2. double salt. Likewise, the concentration in the solution What we claim is: of the alkali metal and chloride ions must be carefully 70 1. A process for the separation from monazite of thori chosen to obtain the best results. um and rare earths substantially free from impurities The solution should be acid and preferably should present in monazite, comprising digesting with excess sul 2,988,421 3. 4. phuric acid a finely-divided monazite selected from the divided monazite seleceted from the group consisting of group consisting of monazite sand and ground mineral monazite sand and ground mineral monazite, diluting the monazite, diluting the digest with water, filtering the digest with water, filtering the resulting product to re resulting product to remove insoluble material, treating move insoluble material, treating the filtrate so obtained the filtrate so obtained with material providing alkali with sodium chloride in a concentration of 200-400 metal and chloride ions, and removing the precipitate thus gins./liter of filtrate, the concentration of acid in the obtained containing thorium and rare earths, the concen filtrate being from 4.5 N to 5.5 N, and removing the tration of Sulphuric acid in the filtrate being at least 3 N precipitate thus obtained containing thorium and rare and the concentration of alkali metal and chloride ions earths. taken together being at least 50 gms./liter. O 9. A process according to claim 8, in which the filtrate 2. A process according to claim 1, in which the mate is treated with sodium chloride at a temperature of at rial providing the chloride ions is hydrochloric acid. least about 60 C, 3. A process according to claim 1, in which the mate rial providing alkali metal and chloride ions is an alkali References Cited in the file of this patent metal chloride. UNITED STATES PATENTS 4. A process according to claim 3, in which the alkali metal chloride is one selected from the group consisting 1,100,743 Keetman et al. -------- June 23, 1914 of sodium chloride and potassium chloride. 2,425,573 Soddy ----------------- Aug. 12, 1947 5. A process according to claim 4, in which the con centration of acid in the filtrate is from 4.5 N to 5.5 N. 20 OTHER REFERENCES 6. A process according to claim 4, in which the con Pilkington et al.: Rare Earths and Thorium Compounds centration of the alkali metal chloride in the filtrate is from Monazite J. Soc. Chem. Ind. (London), 66; 387 94, 1947 (Copy in Sci. Lib.). - greater than 200 gms./liter. Mellor: Comprehensive Treatise on Inorganic and 7. A process according to claim 6, in which the con 25 Theoretical Chemistry, vol. 7, pp. 178-181 (1927), Long centration of alkali metal chloride in the filtrate is 200 mans, Green & Co., London. Copy in Div. 59. 400 gms./liter. Audsley et al.: Extraction and Refining of the Rarer 8. A process for the separation from monazite of thori Metals, pp. 351-360, March 22 and 23, 1956, Stephen um and rare earths substantially free from impurities, Austin & Sons, Ltd., Great Britain. Copy in Div. 46. comprising digesting with excess sulphuric acid a finely 30 .
Recommended publications
  • Separation of Radioactive Elements from Rare Earth Element-Bearing Minerals

    Separation of Radioactive Elements from Rare Earth Element-Bearing Minerals

    metals Review Separation of Radioactive Elements from Rare Earth Element-Bearing Minerals Adrián Carrillo García 1, Mohammad Latifi 1,2, Ahmadreza Amini 1 and Jamal Chaouki 1,* 1 Process Development Advanced Research Lab (PEARL), Chemical Engineering Department, Ecole Polytechnique de Montreal, C.P. 6079, Succ. Centre-ville, Montreal, QC H3C 3A7, Canada; [email protected] (A.C.G.); mohammad.latifi@polymtl.ca (M.L.); [email protected] (A.A.) 2 NeoCtech Corp., Montreal, QC H3G 2N7, Canada * Correspondence: [email protected] Received: 8 October 2020; Accepted: 13 November 2020; Published: 17 November 2020 Abstract: Rare earth elements (REE), originally found in various low-grade deposits in the form of different minerals, are associated with gangues that have similar physicochemical properties. However, the production of REE is attractive due to their numerous applications in advanced materials and new technologies. The presence of the radioactive elements, thorium and uranium, in the REE deposits, is a production challenge. Their separation is crucial to gaining a product with minimum radioactivity in the downstream processes, and to mitigate the environmental and safety issues. In the present study, different techniques for separation of the radioactive elements from REE are reviewed, including leaching, precipitation, solvent extraction, and ion chromatography. In addition, the waste management of the separated radioactive elements is discussed with a particular conclusion that such a waste stream can be
  • Thorium–Ligand Multiple Bonds Via Reductive Deprotection of a Trityl Group† Cite This: Chem

    Thorium–Ligand Multiple Bonds Via Reductive Deprotection of a Trityl Group† Cite This: Chem

    Chemical Science View Article Online EDGE ARTICLE View Journal | View Issue Thorium–ligand multiple bonds via reductive deprotection of a trityl group† Cite this: Chem. Sci.,2015,6, 3891 Danil E. Smiles,a Guang Wu,a Nikolas Kaltsoyannis*b and Trevor W. Hayton*a Reaction of [Th(I)(NR2)3](R¼ SiMe3)(2) with KECPh3 (E ¼ O, S) affords the thorium chalcogenates, [Th(ECPh3)(NR2)3](3,E¼ O; 4,E¼ S), in moderate yields. Reductive deprotection of the trityl group from 3 and 4 by reaction with KC8, in the presence of 18-crown-6, affords the thorium oxo complex, [K(18- Received 7th April 2015 crown-6)][Th(O)(NR ) ](6), and the thorium sulphide complex, [K(18-crown-6)][Th(S)(NR ) ](7), Accepted 30th April 2015 2 3 2 3 respectively. The natural bond orbital and quantum theory of atoms-in-molecules approaches are DOI: 10.1039/c5sc01248a employed to explore the metal–ligand bonding in 6 and 7 and their uranium analogues, and in particular www.rsc.org/chemicalscience the relative roles of the actinide 5f and 6d orbitals. Introduction be rationalized by the higher energy of the thorium 5f orbitals, Creative Commons Attribution-NonCommercial 3.0 Unported Licence. relative to uranium, which likely weakens metal–ligand The study of actinide–ligand multiple bonds has intensied in p-bonding.50 However, this hypothesis requires further veri- recent years due to the need to understand the extent of both f- cation, highlighting the need for new complexes that feature orbital participation and covalency in actinide–ligand thorium–ligand multiple bonds.
  • High Coordination Number Compounds of Thorium Borohydride, and of Calcium and Strontium �,� �Dimethylaminodiboranates

    High Coordination Number Compounds of Thorium Borohydride, and of Calcium and Strontium , Dimethylaminodiboranates

    HIGH COORDINATION NUMBER COMPOUNDS OF THORIUM BOROHYDRIDE, AND OF CALCIUM AND STRONTIUM , -DIMETHYLAMINODIBORANATES BY ANDREW CLIFFORD DUNBAR DISSERTATION Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy in Chemistry in the Graduate College of the University of Illinois at Urbana-Champaign, 2011 Urbana, Illinois Doctoral Committee: Professor Gregory S. Girolami, Chair Professor Andrew A. Gewirth Professor Ralph G. Nuzzo Professor Thomas B. Rauchfuss ABSTRACT We have determined the crystal structure of Th(BH 4)4 and confirmed that it is - isomorphous with the tetragonal form of its uranium analogue. Of the four BH 4 groups per formula unit, two are terminal and are bound to thorium in a tridentate κ 3 fashion, and - 2 2 the other two BH 4 groups bridge between neighboring Th centers in a bis(bidentate) κ ,κ - fashion. In this arrangement each Th center is bound to six BH 4 groups which form a total of 14 Th-H bonds (2 × 3 + 4 × 2). If one ignores the hydrogen atoms, the six boron atoms about each Th center describe a distorted octahedral arrangement, in which the two 3 - terminal κ -BH 4 groups are mutually cis . The 14 hydrogen atoms surrounding the central thorium atom do not describe a simple regular coordination polyhedron, although it is possible to view the arrangement as a highly distorted bicapped hexagonal antiprism. The metal centers are linked into a three-dimensional polymer that consists of interconnected helical chains wound about fourfold screw axes. The most interesting result is that the Th and U complexes show some systematic differences in bond distances and angles, which is tentatively attributed either to the different f-electron configurations of these two ions (f 0 vs f 2) or to the lower energies of the f-orbitals on uranium.
  • Ab Initio Study of Elastic and Electronic Properties of Cubic Thorium Pnictides Thpn and Th3pn4 (Pn = P, As, and Sb)

    Ab Initio Study of Elastic and Electronic Properties of Cubic Thorium Pnictides Thpn and Th3pn4 (Pn = P, As, and Sb)

    Accepted in Solid State Sciences Ab initio study of elastic and electronic properties of cubic thorium pnictides ThPn and Th3Pn4 (Pn = P, As, and Sb) I.R. Shein, * A.L. Ivanovskii Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 620990, Ekaterinburg, Russia A B S T R A C T Full-potential linearized augmented plane-wave method with the generalized gradient approximation for the exchange-correlation potential was applied for comparative study of elastic and electronic properties of six cubic thorium pnictides ThPn and Th3Pn4, where Pn = P, As, and Sb. Optimized lattice parameters, theoretical density, independent elastic constants (Cij), bulk moduli (B), shear moduli (G), Young’s moduli (Y), and Poisson’s ratio (ν) were obtained for the first time and analyzed in comparison with available theoretical and experimental data. The electronic band structures, total and partial densities of states for all ThPn and Th3Pn4 phases were examined systematically. Moreover, the inter-atomic bonding pictures in thorium pnictides, as well as the relative stability of ThPn versus Th3Pn4 phases were discussed. Keywords: Cubic thorium pnictides ThPn, Th3Pn4; Electronic, Elastic Properties; Chemical bonding; ab initio calculations ---------------- * Corresponding author: E-mail address: [email protected] (I.R. Shein) 1 1. Introduction Binary compounds formed by thorium with sp elements have attracted much attention owing to their unique physical and chemical properties making them interesting from the fundamental point of view, as well as for a variety of technical applications, for example as alternative fertile materials to be used in nuclear breeder systems etc., see [1-5].
  • Preparation of Highly Pure Thorium Nitrate Via Thorium Sulfate And

    Preparation of Highly Pure Thorium Nitrate Via Thorium Sulfate And

    L Journal of Alloys and Compounds 323±324 (2001) 53±56 www.elsevier.com/locate/jallcom Preparation of highly pure thorium nitrate via thorium sulfate and thorium peroxide Alcõdio AbraoÄ * , Antonio Alves de Freitas, Fatima Maria Sequeira de Carvalho Instituto de Pesquisas Energeticas e Nucleares (IPEN), ComissaoÄ Nacional de Energia Nuclear (CNEN), Travessa R, 400 Cidade Universitaria -USP, CEP 05508-900, SaoÄ Paulo, Brazil Abstract A simple alternative and selective method has been proposed for the preparation of thorium nitrate using as raw material a hydrated crystalline technical grade thorium sulfate. This salt was produced industrially [1] from the alkaline chemical processing of monazite sand in S. Paulo. From a crude thorium hydroxide as the raw material containing uranium and rare earth elements was prepared a technical grade thorium sulfate [Th(SO42 ) .9H 2 O]. A typical analysis of this salt had shown the following composition: ThO223 47±53%, R O (rare earth oxides) 0.5±0.9%, and UO3 0.01% and minor amounts of iron, titanium, phosphorus, and silicon oxides. The thorium sulfate is dissolved into water and the thorium peroxide is precipitated from acidic medium by addition of hydrogen peroxide. The thorium peroxide is ®ltered, washed and ®nally dissolved with nitric acid. Samples of the thorium peroxide were dried and ®red to ThO2 and aliquot of the thorium nitrate solution was evaporated to dryness and calcined to obtain the ThO22 . Both ThO have high purity (.99.5%). The content of total rare earth elements is very low (0.23% as oxide). Uranium was not detected. The great majority of the RE is precipitated and recovered from the ®ltrate by oxalic acid.
  • A Computer-Assisted Evaluation of the Thermochemical Data of the Compounds of Thorium

    A Computer-Assisted Evaluation of the Thermochemical Data of the Compounds of Thorium

    & TECH NATX INST. OF 5TAND NIST REFERENCE NBSIR 77-1300 A Computer-Assisted Evaluation of the Thermochemical Data of the Compounds of Thorium D. D. Wagman, R. H. Schumm and V. B. Parker Physical Chemistry Division Institute for Materials Research National Bureau of Standards Washington, D.C. 20234 August 1 977 r> ^rati for Qd, 3nal Atomic Energy Agency f Standard Reference Data, NBS /f77 NBSIR 77-1300 A COMPUTER-ASSISTED EVALUATION OF THE THERMOCHEMICAL DATA OF THE COMPOUNDS OF THORIUM D. D. Wagman, R. H. Schumm and V. B. Parker Physical Chemistry Division Institute for Materials Research National Bureau of Standards Washington, D.C. 20234 August 1977 Prepared for International Atomic Energy Agency and Office of Standard Reference Data, NBS U.S. DEPARTMENT OF COMMERCE, Juanita M. Kreps, Secretary Dr. Sidney Harman, Under Secretary Jordan J. Baruch, Assistant Secretary for Science and Technology NATIONAL BUREAU OF STANDARDS, Ernest Ambler, Acting Director TABLE OF CONTENTS I. General Description 1. Introduction 2 2. Explanation of the Contents of Tables 3 3. Unit of Energy and Fundamental Constants 8 4. Internal Consistency of the Tables 9 5. Arrangement of the Tables 11 II. Tables of Values for AHf% A3f° and S° at 298.15 K for the Compounds of Thorium and the Reaction Catalog III. Bibliography IV. Appendix: Thermal Functions for Thorium Compounds A-1 Th(c,l) A-6 Th(g) ' A-7 ThO(g) A-8 ThO^Cc) A-9 Th02(g) A-10 ThF(g) A-11 ThF^Cg) A-12 ThF^(g) A-13 ThF^(c,l) A- 14 ThF^(g) A-15 ThCl(g) A- 16 ThCl2(g) A-17 ThCl^Cg) A-18 ThCl^ (c,l) A-19 ThCl^(g) A-20 ThBr(g) A-21 ThBr2(g) A-22 ThBr^Cg) A-23 ThBr^(c,l) k-lu, ThBr^(g) A-25 Thl(g) ' \ A-26 Thl^Cg) A-27 ThIgCg) A-28 Thl^(c,l) A-29 A Computer-Assisted Evaluation of the Thermochemica 1 Data of the Compounds of Thorium by D.
  • Alkali Metal Actinide Complex Halides : Thermochemical and Structural Considerations J

    Alkali Metal Actinide Complex Halides : Thermochemical and Structural Considerations J

    Alkali metal actinide complex halides : thermochemical and structural considerations J. Fuger To cite this version: J. Fuger. Alkali metal actinide complex halides : thermochemical and structural considerations. Journal de Physique Colloques, 1979, 40 (C4), pp.C4-207-C4-213. 10.1051/jphyscol:1979465. jpa- 00218861 HAL Id: jpa-00218861 https://hal.archives-ouvertes.fr/jpa-00218861 Submitted on 1 Jan 1979 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. JOURNAL DE PHYSIQUE Colloque C4, supplément au n° 4, Tome 40, avril 1979, page C4-207 Alkali metal actinide complex halides: thermochemical and structural considerations J. Fuger Institute of Radiochemistry, University of Liege, Sart Tilman, B-4000 Liege, Belgium Résumé. — L'auteur passe en revue l'état actuel de nos connaissances dans le domaine de la thermodynamique des complexes halogènes d'actinides avec les ions alcalins, en portant une attention toute spéciale aux dérivés chlorés et bromes. Lorsque les données thermodynamiques et structurales sont accessibles, il tente de déduire l'évolution de l'énergie de la liaison actinide-halogène au sein d'une série de composés isomorphes ou analogues. Enfin, la variation énergétique au cours de la formation du complexe halogène à partir des halogénures binaires d'actinides et de métaux alcalins est prise pour base en vue de prévoir la stabilité de composés nouveaux, spécialement ceux pour lesquels l'halogénure binaire d'actinide n'a pas été préparé ou est de faible stabilité.
  • Selected Values of Chemical Thermodynamic Properties [Part 8]

    Selected Values of Chemical Thermodynamic Properties [Part 8]

    STAND 4 TEtH NATL INST. OF EFERENCE »"" "-r^JL -SOWS « J # W ^ 4t> * 11. % 00 NBS TECHNICAL NOTE 270"8 ^ <Vau of U.S. DEPARTMENT OF COMMERCE/National Bureau of Standards Selected Values of Chemical Thermodynamic Properties Compounds of Uranium, Protactinium, Thorium, Actinium, and the Alkali Metals -QC- lOu No. 270-8 1931 NATIONAL BUREAU OF STANDARDS The National Bureau of Standards' was established by an act ot Congress on March 3, 1901. The Bureau's overall goal is to strengthen and advance the Nation's science and technology and facilitate their effective application for public benefit. To this end, the Bureau conducts research provides: ( ) and I a basis for the Nation's physical measurement system, (2) scientilic and technological services for industry and government, (3) a technical basis tor equity in trade, and (4) technical services to promote public safety. The Bureau's technical work is per- formed by the National Measurement Laboratory, the National Engineering Laboratory, and the Institute for Computer Sciences and Technology. THE NATIONAL MEASUREMENT LABORATORY provides the national system ol physical and chemical and materials measurement; coordinates the system with measurement systems of other nations and furnishes essential services leading to accurate and uniform physical and chemical measurement throughout the Nation's scientilic community, industry, and commerce; conducts materials research leading to improved methods ol measurement, standards, and data on the properties of materials needed by industry, commerce, educational institutions, and Government; provides advisory and research services to other Government agencies; develops, produces, and distributes Standard Relerence Materials; and provides calibration services. The Laboratory consists ol the lollowmg centers: Absolute Physical Quantities — Radiation Research — Thermodynamics and Molecular Science — Analytical Chemistry — Materials Science.
  • ©2019 Marissa Ringgold ALL RIGHTS RESERVED

    ©2019 Marissa Ringgold ALL RIGHTS RESERVED

    ©2019 Marissa Ringgold ALL RIGHTS RESERVED ACTINIDE CHALCOGENIDO AND CHALCOGENOLATE COMPOUNDS By MARISSA RINGGOLD A dissertation submitted to the School of Graduate Studies Rutgers, the State University of New Jersey In partial fulfillment of the requirements for the degree of Doctor of Philosophy Graduate Program in Chemistry Written under the direction of John G. Brennan And approved by __________________________ __________________________ __________________________ __________________________ New Brunswick, New Jersey January, 2019 ABSTRACT OF THE DISSERTATION Actinide Chalcogenido and Chalcogenolate Compounds By MARISSA RINGGOLD Disseration Director: John G. Brennan Actinide chemistry, specifically thorium and uranium chalcogenolate and chalcogenido complexes are relatively unexplored. Traditionally in literature they contain sterically hindered environments or are synthesized under aqueous conditions. However, it has been discovered that thorium metal reductively inserts into the E-E bond of REER (R= Ph, C6F5; E = S, Se) to from stable chalcogenolate compounds whose size is determined by the identity of the neutral donor ligand or additional chalcogen in air-free, water-free conditions without the use of large bulky ligands. Thorium cubanes (py)8Th4(μ3-E′)4(μ2-EPh)4(η-EPh)4 (E, E′ = S, Se) were prepared from ligand-based redox reactions of elemental E′ with Th(EPh)4. Products with all four possible E/E′ combinations (E,E′ = S,S; Se,Se; S,Se; Se,S) were isolated and structurally characterized, ligand exchange reactions were explored, and the heterochalcogen compounds (py)8Th4(μ3-S)4(μ2-SePh)4(η-SePh)4 and (py)8Th4(μ3- Se)4(μ2-SPh)4(η-SPh)4 were heated to deliver solid solutions of ThSxSe2−x.
  • Actinide Research Quarterly

    Actinide Research Quarterly

    Targeted Radiation Therapy Seaborg postdocs developing actinide isotopes for cancer treatments Actinide Research Quarterly Preface In this quarter we continue from the previous issue and present research from another seven recent Seaborg postdoctoral fellows, many of whom have continued their work at Los Alamos National Laboratory (LANL) as scientists. Tis issue focuses on the chemistry of actinide elements relevant to a wide range of challenges, in particular: the separation of nuclear waste, the application of radionuclides in cancer treatments, and the aging of plutonium in the nation’s stockpile. One of the great challenges in actinide chemistry is understanding and predicting bonding in actinide molecules, which could pave the way for developing nuclear waste separation systems. Su (p11) has tackled these problems using advanced computational techniques to understand the nature of chemical bonding in Am3+ and Eu3+ salts, supported by experimental data, providing direct evidence for the frst time to explain behavior originally observed by our institute’s namesake Seaborg and his co-workers over 60 years ago. Te synthesis of the frst Np imido complex—an analog of the well-known neptunyl ion—is described by Brown (p17), a milestone achievement that also opens doors for theoretical studies which can improve our understanding of actinide bonding. Te coordination and catalytic chemistry of T and U has been explored by Browne (p23) and Erickson (p27), who used similar organo- metallic platforms to investigate high-nitrogen content molecules as nuclear fuel precursors and hydrogen-generating catalytic cycles, respectively. Te surface of metallic Pu is highly reactive and dynamic, which creates problems when trying to predict how the material will behave, especially in long-term storage (e.g., in the nation’s stockpile).
  • Toxicological Profile for Thorium

    Toxicological Profile for Thorium

    f Toxicological Profile for Thorium September 2019 ***DRAFT – DO NOT CITE OR QUOTE – August 29, 2019*** Version 4.0 THORIUM ii DISCLAIMER Use of trade names is for identification only and does not imply endorsement by the Agency for Toxic Substances and Disease Registry, the Public Health Service, or the U.S. Department of Health and Human Services. THORIUM iii FOREWORD This toxicological profile is prepared in accordance with guidelines* developed by the Agency for Toxic Substances and Disease Registry (ATSDR) and the Environmental Protection Agency (EPA). The original guidelines were published in the Federal Register on April 17, 1987. Each profile will be revised and republished as necessary. The ATSDR toxicological profile succinctly characterizes the toxicologic and adverse health effects information for these toxic substances described therein. Each peer-reviewed profile identifies and reviews the key literature that describes a substance's toxicologic properties. Other pertinent literature is also presented, but is described in less detail than the key studies. The profile is not intended to be an exhaustive document; however, more comprehensive sources of specialty information are referenced. The focus of the profiles is on health and toxicologic information; therefore, each toxicological profile begins with a relevance to public health discussion which would allow a public health professional to make a real-time determination of whether the presence of a particular substance in the environment poses a potential threat to human health. The adequacy of information to determine a substance's health effects is described in a health effects summary. Data needs that are of significance to the protection of public health are identified by ATSDR.
  • A Thesis on the Constitution of Alloys of Thorium with Certain Transition Metals. , by J.R. Thomson Submitted for the Degree Of

    A Thesis on the Constitution of Alloys of Thorium with Certain Transition Metals. , by J.R. Thomson Submitted for the Degree Of

    A thesis on The constitution of alloys of thorium with certain transition metals. , by J.R. Thomson submitted for the degree of Doctor of Philosophy in the University of London. Department of Metallurgy, Imperial College of Science August, 1963. and Technology, Prince Consort Road, London, S.W.7. 1. SUMMARY The behaviour of the transition series of elements has long been of interest and the position of thorium in group 4A of the periodic table near to the beginning of a possible 'actinide' series of elements has made a know- ledge of its properties and alloying behaviour of especial interest from the theoretical point of view. In the present work, the physical properties and electron theory of the transition metals and their alloys have been reviewed. Factors affecting the formation of intermetallic compounds have also been reviewed and their applications to some specific types of crystal structure discussed. The phase diagrams of six binary alloy systems of thorium with the metals ruthenium, rhodium, palladium, osmium, iridium and platinum have been investigated in the temperature range 1000°C - 1500°C, mainly by x-ray and metallographic methods. Solid solubility of thorium in palladium has been observed and intermetallic compounds occur in each system. The crystal structures of 15 of these compounds, embracing 7 structure types, have been determined while the structures of 5 other compounds have been confirmed. In several cases additional information about the latter compounds has been obtained. 2. In general, the results are in agreement with alloy theory although the solubility of thorium in palladium would not be predicted by current theories.