Appendix I Glossary of Mining and Related Terms Relevant to Mine Water
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Clay Minerals Soils to Engineering Technology to Cat Litter
Clay Minerals Soils to Engineering Technology to Cat Litter USC Mineralogy Geol 215a (Anderson) Clay Minerals Clay minerals likely are the most utilized minerals … not just as the soils that grow plants for foods and garment, but a great range of applications, including oil absorbants, iron casting, animal feeds, pottery, china, pharmaceuticals, drilling fluids, waste water treatment, food preparation, paint, and … yes, cat litter! Bentonite workings, WY Clay Minerals There are three main groups of clay minerals: Kaolinite - also includes dickite and nacrite; formed by the decomposition of orthoclase feldspar (e.g. in granite); kaolin is the principal constituent in china clay. Illite - also includes glauconite (a green clay sand) and are the commonest clay minerals; formed by the decomposition of some micas and feldspars; predominant in marine clays and shales. Smectites or montmorillonites - also includes bentonite and vermiculite; formed by the alteration of mafic igneous rocks rich in Ca and Mg; weak linkage by cations (e.g. Na+, Ca++) results in high swelling/shrinking potential Clay Minerals are Phyllosilicates All have layers of Si tetrahedra SEM view of clay and layers of Al, Fe, Mg octahedra, similar to gibbsite or brucite Clay Minerals The kaolinite clays are 1:1 phyllosilicates The montmorillonite and illite clays are 2:1 phyllosilicates 1:1 and 2:1 Clay Minerals Marine Clays Clays mostly form on land but are often transported to the oceans, covering vast regions. Kaolinite Al2Si2O5(OH)2 Kaolinite clays have long been used in the ceramic industry, especially in fine porcelains, because they can be easily molded, have a fine texture, and are white when fired. -
Removal of Iron-Bearing Minerals from Gibbsitic Bauxite by Direct Froth Flotation
a Original Article http://dx.doi.org/10.4322/2176-1523.0924 REMOVAL OF IRON-BEARING MINERALS FROM GIBBSITIC BAUXITE BY DIRECT FROTH FLOTATION Felipe de Melo Barbosa 1 Maurício Guimarães Bergerman 2 Daniela Gomes Horta 3 Abstract The refractory bauxite needs to present less than 2.5% of Fe2O3 to be applied in the ceramics industry. The depletion of high Al2O3 grade deposits has stimulated the improvement of bauxite concentration methods in order to remove iron-bearing minerals. The objective of this study was to evaluate the influence of collector dosage, pH and milling time on the gibbsite flotation performance. Firstly, the sample mineralogical composition was determined by means of X-ray diffraction (XRD) and binocular loupe analysis. X-ray fluorescence (XRF) analysis was used to determine the sample chemical composition. Flotation was then accomplished by using hydroxamate as gibbsite collector, sodium silicate as silicate depressant and starch as iron-bearing minerals depressant. The bauxite Fe2O3 content was reduced from 7.66% to 4.81-5.03%. In addition, the flotation performance decreased by diminishing the pH from 9.5 to 8.5 or increasing the pH to 10.5. The milling time influence on the flotation indicates that the presence of slime can significantly affect the gibbsite concentration. Keywords: Bauxite; Gibbsite; Direct flotation; Hydroxamate. REMOÇÃO DE MINERAIS PORTADORES DE FERRO DE BAUXITA GIBSÍTICA POR FLOTAÇÃO DIRETA Resumo As bauxitas refratárias precisam apresentar teores de ferro menores que 2,5% para serem utilizadas na indústria de cerâmica. A exaustão dos depósitos com altos teores de Al2O3 tem estimulado a pesquisa por métodos de concentração de bauxita de forma a remover os minerais portadores de ferro. -
Part 629 – Glossary of Landform and Geologic Terms
Title 430 – National Soil Survey Handbook Part 629 – Glossary of Landform and Geologic Terms Subpart A – General Information 629.0 Definition and Purpose This glossary provides the NCSS soil survey program, soil scientists, and natural resource specialists with landform, geologic, and related terms and their definitions to— (1) Improve soil landscape description with a standard, single source landform and geologic glossary. (2) Enhance geomorphic content and clarity of soil map unit descriptions by use of accurate, defined terms. (3) Establish consistent geomorphic term usage in soil science and the National Cooperative Soil Survey (NCSS). (4) Provide standard geomorphic definitions for databases and soil survey technical publications. (5) Train soil scientists and related professionals in soils as landscape and geomorphic entities. 629.1 Responsibilities This glossary serves as the official NCSS reference for landform, geologic, and related terms. The staff of the National Soil Survey Center, located in Lincoln, NE, is responsible for maintaining and updating this glossary. Soil Science Division staff and NCSS participants are encouraged to propose additions and changes to the glossary for use in pedon descriptions, soil map unit descriptions, and soil survey publications. The Glossary of Geology (GG, 2005) serves as a major source for many glossary terms. The American Geologic Institute (AGI) granted the USDA Natural Resources Conservation Service (formerly the Soil Conservation Service) permission (in letters dated September 11, 1985, and September 22, 1993) to use existing definitions. Sources of, and modifications to, original definitions are explained immediately below. 629.2 Definitions A. Reference Codes Sources from which definitions were taken, whole or in part, are identified by a code (e.g., GG) following each definition. -
Somerset Geology-A Good Rock Guide
SOMERSET GEOLOGY-A GOOD ROCK GUIDE Hugh Prudden The great unconformity figured by De la Beche WELCOME TO SOMERSET Welcome to green fields, wild flower meadows, farm cider, Cheddar cheese, picturesque villages, wild moorland, peat moors, a spectacular coastline, quiet country lanes…… To which we can add a wealth of geological features. The gorge and caves at Cheddar are well-known. Further east near Frome there are Silurian volcanics, Carboniferous Limestone outcrops, Variscan thrust tectonics, Permo-Triassic conglomerates, sediment-filled fissures, a classic unconformity, Jurassic clays and limestones, Cretaceous Greensand and Chalk topped with Tertiary remnants including sarsen stones-a veritable geological park! Elsewhere in Mendip are reminders of coal and lead mining both in the field and museums. Today the Mendips are a major source of aggregates. The Mesozoic formations curve in an arc through southwest and southeast Somerset creating vales and escarpments that define the landscape and clearly have influenced the patterns of soils, land use and settlement as at Porlock. The church building stones mark the outcrops. Wilder country can be found in the Quantocks, Brendon Hills and Exmoor which are underlain by rocks of Devonian age and within which lie sunken blocks (half-grabens) containing Permo-Triassic sediments. The coastline contains exposures of Devonian sediments and tectonics west of Minehead adjoining the classic exposures of Mesozoic sediments and structural features which extend eastward to the Parrett estuary. The predominance of wave energy from the west and the large tidal range of the Bristol Channel has resulted in rapid cliff erosion and longshore drift to the east where there is a full suite of accretionary landforms: sandy beaches, storm ridges, salt marsh, and sand dunes popular with summer visitors. -
9/16 Weathering Notes
EAS 3030 9/16/08 LAD Weathering reactions We can consider many weathering reactions as acid-base reactions. Acidity in soils can be generated from several sources. The main ones are: • Hydration of CO2 (yields carbonic acid): CO2 + H2O H2CO3 • Organic decomposition to yield organic acids (R-COOH R-COO- + H+) • Sulfide oxidation to yield sulfuric acid (2FeS2+4H2O+7.5O2 4H2SO4+Fe2O3) • Atmospheric deposition of mineral acids such as H2SO4 and HNO3. The hydrogen ion released by these acids can react with carbonate minerals (e.g. CaCO3) or alumino-silicate minerals (feldspars, micas, clays ….). Carbonate and silicate weathering reactions can be considered separately: For carbonates, we can write: ++ - 1) CaCO3 + H2 CO3 Ca + 2HCO3 In this reaction carbonic acid (from CO2 and water) and calcium carbonate react to form bicarbonate ion and calcium ion. The net reaction yields no H+, so the carbonic acid has been neutralized by reaction with carbonate. It also yields no solid phases – the carbonate mineral undergoes complete dissolution. This sort of reaction is know as “congruent” dissolution. An example silicate reaction would be the reaction of potassium feldspar (a primary mineral) to form kaolinite, a secondary mineral . The reaction of a primary mineral to form a secondary mineral plus solutes is called “incongruent” dissolution. + + 2) 2KAlSi3O8(Kspar) + 2H + 9H2O Al2Si2O5(OH)4(kaol) + 4H4SiO4(aq) +2K If the source of acidity is CO2, we can write equivalently: + - 3) 2KAlSi3O8(Kspar) + 2CO2 + 11H2O Al2Si2O5(OH)4(kaol) + 4H4SiO4(aq) +2K + 2HCO3 In the breakdown of K-feldspar, acidity is consumed. We can see that H+ is used up and K+ is released to solution, a kind of “ion exchange” reaction. -
Boehmite and Gibbsite Nanoplates for the Synthesis of Advanced Alumina Products † ‡ † † § Xin Zhang,*, Patricia L
Article Cite This: ACS Appl. Nano Mater. 2018, 1, 7115−7128 www.acsanm.org Boehmite and Gibbsite Nanoplates for the Synthesis of Advanced Alumina Products † ‡ † † § Xin Zhang,*, Patricia L. Huestis, Carolyn I. Pearce, Jian Zhi Hu, Katharine Page, § ∥ † † Lawrence M. Anovitz, Alexandr B. Aleksandrov, Micah P. Prange, Sebastien Kerisit, † † † † ⊥ Mark E. Bowden, Wenwen Cui, Zheming Wang, Nicholas R. Jaegers, Trent R. Graham, † § § Mateusz Dembowski, Hsiu-Wen Wang, Jue Liu, Alpha T. N’Diaye,% Markus Bleuel,& ∥ † ‡ † # David F. R. Mildner,& Thomas M. Orlando, Greg A. Kimmel, Jay A. La Verne, Sue B. Clark, , † and Kevin M. Rosso*, † Pacific Northwest National Laboratory, Richland, Washington 99354, United States ‡ Radiation Laboratory and Department of Physics, University of Notre Dame, Notre Dame, Indiana 46556, United States § Oak Ridge National Laboratory, Oak Ridge, Tennessee 37830, United States ∥ School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332, United States ⊥ # The Voiland School of Chemical and Biological Engineering and Department of Chemistry, Washington State University, Pullman, Washington 45177, United States %Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States &National Institute of Standards and Technology, Gaithersburg, Maryland 20899, United States *S Supporting Information ABSTRACT: Boehmite (γ-AlOOH) and gibbsite (α-Al- (OH)3) are important archetype (oxy)hydroxides of alumi- num in nature that also play diverse roles across -
Treatment of Acid Mine Drainage 21
RESEARCH PAPER 99/10 Treatment of Acid Mine 2 FEBRUARY 1999 Drainage The problem of acid mine drainage (AMD) has been present since mining activity began thousands of years ago. Mining activity has disrupted the hydrology of mining areas so badly that it is extremely difficult to predict where water would eventually re-emerge. Individual mine closures have not resulted in massive AMD events as pumping continued so as to allow mining at nearby operational mines. It is now, when whole coalfields will finally close, that AMD will become the problem it has promised to be. AMD will be a chronic problem and one that will degrade local streams, rivers and other watercourses. Whilst, in some cases, drainage occurs that is not acidic, all mine drainage events pose the problem of introducing iron, and potentially other metals, to local watercourses. With the advent of major AMD events, as evidenced by Wheal Jane in Cornwall, it will become necessary to identify methods that will be used to treat AMD when coal fields close and the source of money to pay for them. The alternative is to prevent drainage occurring by continued pumping. Stephen McGinness SCIENCE AND ENVIRONMENT SECTION HOUSE OF COMMONS LIBRARY Recent Library Research Papers include: List of 15 most recent RPs 98/115 The Greater London Authority Bill: A Mayor and Assembly for London 11.12.98 Bill 7 of 1998-99 98/116 The Greater London Authority Bill: Transport Aspects Bill 7 of 1998-99 10.12.98 98/117 Water Industry Bill (revised edition) Bill 1 [1998/99] 10.12.98 98/118 The Greater London -
Compression Studies of Gibbsite and Its High-Pressure Polymorph
Phys Chem Minerals (1999) 26: 576±583 Ó Springer-Verlag 1999 ORIGINAL PAPER E. Huang á J.-F. Lin á J. Xu á T. Huang Y.-C. Jean á H.-S. Sheu Compression studies of gibbsite and its high-pressure polymorph Received: 28 September 1998 / Revised, accepted: 22 December 1998 Abstract Various X-ray diraction methods have been Introduction applied to study the compression behavior of gibbsite, Al(OH) , in diamond cells at room temperature. A phase 3 The water reservoir in the Earth's mantle may be do- transformation was found to take place above 3 GPa minately hosted in the hydrous minerals (e.g., Akimoto where gibbsite started to convert to its high-pressure and Akaogi 1984). Therefore, the study of hydrous polymorph. The high-pressure (HP) phase is quenchable minerals at high-pressure and temperature is crucial for and coexists with gibbsite at the ambient conditions after understanding the dynamic processes of water circula- being unloaded. This HP phase was identi®ed as nor- tion in the mantle. Examples such as triggering deep dstrandite based on the diraction patterns obtained at focus earthquakes (Kirby 1987; Meade and Jeanloz room pressure by angle dispersive and energy dispersive 1991) and regulating the water budget have been docu- methods. On the basis of this structural interpretation, mented in hydrous minerals under mantle environments. the bulk modulus of the two polymorphs, i.e., gibbsite In the past few years, some hydrous minerals with and nordstrandite, could be determined as 85 5 and trioctahedral layer structure such as brucite (Mg(OH) ) 70 5 GPa, respectively, by ®tting a Birch-Murnaghan 2 (e.g., Duy et al. -
Reaction of Aluminum with Water to Produce Hydrogen
Reaction of Aluminum with Water to Produce Hydrogen A Study of Issues Related to the Use of Aluminum for On-Board Vehicular Hydrogen Storage U.S. Department of Energy Version 2 - 2010 1 CONTENTS EXECUTIVE SUMMARY ……………………………………………………………….. 3 INTRODUCTION ………………………………………………………………………… 5 BACKGROUND ………………………………………………………………………….. 5 REACTION-PROMOTING APPROACHES ………………………………………….. 6 Hydroxide Promoters Oxide Promoters Salt Promoters Combined Oxide and Salt Promoters Aluminum Pretreatment Molten Aluminum Alloys PROPERTIES OF THE ALUMINUM-WATER REACTIONS RELATIVE ……….. 14 TO ON-BOARD SYSTEM PROPERTIES Hydrogen Capacities Kinetic Properties System Considerations REGENERATION OF ALUMINUM-WATER REACTION PRODUCTS …………. 17 SUMMARY ………………………………………………………………………………. 19 REFERENCES …………………………………………………………………………… 20 APPENDIX I – THERMODYNAMICS OF ALUMINUM-WATER REACTIONS … 23 APPENDIX II – ORGANIZATIONS PRESENTLY INVOLVED WITH ………….. 26 HYDROGEN GENERATION FROM ALUMINUM-WATER REACTIONS 2 Reaction of Aluminum with Water to Produce Hydrogen 1 2 John Petrovic and George Thomas Consultants to the DOE Hydrogen Program 1 Los Alamos National Laboratory (retired) 2 Sandia National Laboratories (retired) Executive Summary: The purpose of this White Paper is to describe and evaluate the potential of aluminum-water reactions for the production of hydrogen for on-board hydrogen-powered vehicle applications. Although the concept of reacting aluminum metal with water to produce hydrogen is not new, there have been a number of recent claims that such aluminum-water reactions might be employed to power fuel cell devices for portable applications such as emergency generators and laptop computers, and might even be considered for possible use as the hydrogen source for fuel cell-powered vehicles. In the vicinity of room temperature, the reaction between aluminum metal and water to form aluminum hydroxide and hydrogen is the following: 2Al + 6H2O = 2Al(OH)3 + 3H2. -
Minerals Found in Michigan Listed by County
Michigan Minerals Listed by Mineral Name Based on MI DEQ GSD Bulletin 6 “Mineralogy of Michigan” Actinolite, Dickinson, Gogebic, Gratiot, and Anthonyite, Houghton County Marquette counties Anthophyllite, Dickinson, and Marquette counties Aegirinaugite, Marquette County Antigorite, Dickinson, and Marquette counties Aegirine, Marquette County Apatite, Baraga, Dickinson, Houghton, Iron, Albite, Dickinson, Gratiot, Houghton, Keweenaw, Kalkaska, Keweenaw, Marquette, and Monroe and Marquette counties counties Algodonite, Baraga, Houghton, Keweenaw, and Aphrosiderite, Gogebic, Iron, and Marquette Ontonagon counties counties Allanite, Gogebic, Iron, and Marquette counties Apophyllite, Houghton, and Keweenaw counties Almandite, Dickinson, Keweenaw, and Marquette Aragonite, Gogebic, Iron, Jackson, Marquette, and counties Monroe counties Alunite, Iron County Arsenopyrite, Marquette, and Menominee counties Analcite, Houghton, Keweenaw, and Ontonagon counties Atacamite, Houghton, Keweenaw, and Ontonagon counties Anatase, Gratiot, Houghton, Keweenaw, Marquette, and Ontonagon counties Augite, Dickinson, Genesee, Gratiot, Houghton, Iron, Keweenaw, Marquette, and Ontonagon counties Andalusite, Iron, and Marquette counties Awarurite, Marquette County Andesine, Keweenaw County Axinite, Gogebic, and Marquette counties Andradite, Dickinson County Azurite, Dickinson, Keweenaw, Marquette, and Anglesite, Marquette County Ontonagon counties Anhydrite, Bay, Berrien, Gratiot, Houghton, Babingtonite, Keweenaw County Isabella, Kalamazoo, Kent, Keweenaw, Macomb, Manistee, -
For Sale Development Land with Outline Consent Land Off Woolley Colliery
FOR SALE DEVELOPMENT LAND WITH OUTLINE CONSENT LAND OFF WOOLLEY COLLIERY ROAD, WOOLLEY, SOUTH YORKSHIRE, S75 5JA 0.35 ha (0.87 acres) ▪ Development land on the boundary of Woolley Village with Darton near Barnsley ▪ Previously secured outline consent for part residential part commercial development ▪ Situated immediately adjacent large residential development and immediately available Location The site is broadly rectangular and benefits from immediate access off Woolley Colliery Road on the outskirts of Woolley Village on its boundary with Darton. The immediate area has been extensively developed with residential being easily accessible to the motorway network with junction 38 of the M1 being less than 3 miles. Description The subject site comprises a broadly rectangular development site with an access already created off Woolley Colliery Road. Interested parties should satisfy themselves with regard to all planning matters direct with the Local Authority, Wakefield Council 01924 306090. Services We understand all main services are connected to Woolley Colliery Road although no tests have been carried out on any services connected to the site boundary and therefore were unable to comment as to the condition or capacity. Developers/purchaser must rely upon their own enquiries. Price The vendors will consider either unconditional or Total Site Area 0.35 ha (0.87 acres) conditional offers for the site. Planning VAT The site secured in April 2016 an outline planning consent All prices are quoted exclusive of VAT. from Wakefield Council for development of 12 one bed apartments; 3 A1 retail units and 1,400m² of B1 office use Legal Costs with associated parking (application number 15/02643/OUT). -
Coalbed Methane Exploration in Somerset. the Chew
ABSTRACT This report draws on public information on coalbed methane (CBM) exploration in Somerset to highlight the extensive nature of the resource and identify which communities might be impacted by its development. Ninety percent of the current Petroleum Exploration and Development License area was evaluated and reported on by a previous licence holder in 2000. The content of that evaluation is not widely known but is still valid and may have been a motivating factor in the current holder procuring the licences. GeoMet UK’s licence relinquishment report is available as a PDF file from the UK Onshore Geophysical Library but without its maps and overlays. This report reproduces those maps from GeoMet’s original data and compares them with local administrative units and designations. Frack Free Chew Valley COALBED METHANE 30 June 2014 EXPLORATION IN SOMERSET. THE CHEW VALLEY, KEYNSHAM & THE MENDIP HILLS 0 GeoMet Relinquishment Report to DECC, PEDL 074, Somerset The intention of this report is to draw attention to the possibility of exploration and development of coalbed methane in Somerset using publically available information. The work has been undertaken by Frack Free Chew Valley and is unfunded. Frack Free Chew Valley is a local community group which aims to raise awareness about unconventional gas exploration and development in the Chew Valley area and is a member of the Frack Free Somerset coalition but is not aligned with any political party or environmental group. Data presented in this report has come from the following sources: Goodwin, D., 2000, PEDL074 Somerset, Relinquishment report for GeoMet Operating Inc for GeoMet UK Ltd.