II. QC SUMMARY E.P.A. CASE NO. __i
A. Surroaate % Recovery Summary • D, DFTPP Performance Summary B. Reagent BlanK Summary • E. BFB Performance Summary C. Matrix Spike Duplicate/ Recovery Summary
013247 A. Surrogate % Recovery Summary Surrogate compounds are added to each sample prior to extraction and analysis ol Its various fractions, Trie recovery ot surrogates la a measure ol extraction efficiency ol classes ol compounds, II surrogate recoveries are outside acceptance criteria, the logic applied Is described In I-D, Decision Tree Process,
013243 HP WII Bs* li
PP-rii iW-^i'^*S?§*^^^S?'?^>?*ni F-i^^.rt-'jti"*.*-*^ i r r i> r r rr i1 ri;,'•*"*i i i* FI»I i« i* J——N Tpf i IA$,1^ vjrf US r >j '•«**! 311 • i ! *«« iM^M ssI'ls ifiq ?»!Sl!»i_ WF K nWte ii «4*v "" •••-•* *g '* M<
4> q
sir
** > iiil VS
v> ' VI \ in , !l|P / ?«'»
^
r «-, F-
013252
ss SB ' »!•» = ? * Sr a' ~ • i™ K 3
i i i to •*
.,=> CTBJ«£i £.IT - ? ?«i* :"B (2 ;,|, I I -:,-;!: I . * :" 1 I 1 o II
3 S 11 x »3i r=n •0•2 (8
IPS m
0132157
C. Matrix Spike Duplicate/Recovery Summary Representative compounds lor each traction are spiked Into allquots ol samples selected lor spiking. The recoveries and precision lor these spiked compounds are calculated and reported on the EPA-deslgnated form, Corrections are made for dilutions and for non- standard sample sizes, An additional column has been added to the iiPA form to Include concentrations ol spike compounds In original, unsplked, samples; these are subtracted Irom the concentrations detected In the spiked samples, Associated samples are listed lor each spiked set ot sample fractions; these represent samples processed with the spiked set, at the frequency of one set for each fraction per case, or at least per 20 samples. II acceptable recoveries or precision are not achieved for spiked samples, the actions taken correspond to those described In I -D, II there Is not sufficient sample remaining to repeat the extraction, other samples may be used, or original data reported,
013260
D. DFTPP Performance Summary Copies of the DFTPP Performance Forms are Included, This form la filled out for the tune generated for each Instrument at the beginning of each 8-hour shift to document that the Instrument has been properlyoallbrated, It la signed by the analyst's supervisor to docu- ment Its review and approval, Since no samples are analyzed until the tuning criteria are met, a form with deviations recorded Is superfluous; therefore, the form entitled Form VII, "Instrument Tune and Performance Summary," Exhibit B, page 28 ot 42 of the contract, la not Included In this report. / I OFTPP F1H CM: ait.: &//o/$v Shift: _
MlM Ion Miun3inci Crlttrli M .nn to M.nn i nf MM m «« tk.B JJML » w im H tiiiif 2;00lof Bits jo.oo io-W.'
k. IPbtrettrt g.on to 9.0 iafl aBBiS" ^:iJ»FofiHi2fei2
.13 «3j l7.00;.t«_23JfflS-QtJBBsaJ42_ ' ,nd IfB F"ianMnet Kiium;:.;... crltirl*. - " ' Inltim "*" '•• Riqulrid Obiiryed HI.
. ,v.-, ..••.,.-oi...... * * • ••• • li-.v.'-r-'T.^"^, ^' • -iSViJfjJjf1 . • • ••____ •- ' ' •„_ ' *—^T'.T.-'^;-HiT...'"' '*''* ".''.iTi«l"-.;,• • '" i•*•"**!*• *' •«.;J :taa Revision Date 1/31W, 0( *9 V? mn.l«L*TlLE l»<™i*HT TUNE MB DFTPP m, BfTPP Ion Abundance Crlttrli f Kt1it1»t Uundinee 30,00 to. 60.00 1 of MH ion M \ftt thun 3.Of) 1 of Mil 69 ...... r*lit1vc ibundinci less, thin 2.00X of MIS 69 •40.00 1 60.00 1 of nut lest thin 1.001 nf mm 1M bite peik. 100 fttrcent 1 60.00 44j(Jt«^o"25Jlia*JrfJWM-*^-^ one? inn BFB HtrTonunct uttuitt; p,rf.r«nc, rnriti «rtrta- and M t. * «M. tt. Mtt '"" toqulnd Otoierved a MttwM^..ii.s.^^.^p:.L^^? ^*^[^Sfl!%"^fflii^ '-±- _ (Coimti « 119 Mn MhriCMw B1.Mutyl Pnthilrti Situritwl RevlslpnO.tel/31/OA, VMM t»»l ' SEMI-VCIATILE USTRUKNT TUNE AND PERFORMANCE CASE HO, ______COWRACTW Htid 'canouChem CONTRACT HO, 68.QM%2.68-01-6866 LOH LEVEL—————— HEP. LEVEl—— HIW LMIL . ______SOlL/SEt, / / DRPP File NMC: 2tfVto?JS Cl? Dite BFTPP Kail Ion Aburidihce Criteria t »t1it1« Abundinee SI 30 00 to 60 00 1 nf mitt 1QR 77*7 ,?-*£ .. ' T-,.;. •. .'• ••:•" :••• '>".•;•.••. . {,';.'! IfM thin ?.f|n J| of PMS M "'** -£° ••11 C9 itlstlvt ihundincv &.9K ' '. -70 lest thin 2.00X of miss 69 40.00 to 60.00 t of mass 198 •.•5.;.""5«?sr '•"i*i!';T|§7 J«is than LOO* nf IMM 199 —— -^.'^-•••- *•• •- •' -'.^w*1 198 /^ 199 g.on to 9.on i «f M« iflft : -•'•• ^^ •-Z0. W -.; 365 ijniiirjthan i.oox of wyjaa— *W^"'*43f" ifiSMfc^Z^fe..;^- ' • .^rf»- •• , .vi'ti'- '. ly,:, •vA- 1*4 * ' U? i? .no togs. not of ™« M •••**',/« inmtu ..„.....,—r.~..,. ™r-sr-^irtpr«' -^^Sz-—-Am 1U— X £^£*Hu £ •|y-1 /| A^g leflildlneDetectible Pfet Quo ; ^ Area (Counti) 40 * DirAnthricm • 3^f^^ Dl-fclutyl FDthalite Uturitri Q Yet y QfHo '» Figure In { . )1s»ofmttM 013265 2 Figure In ( , )1i»ofnni H Ofl^r^P r>* 3 Figure 1n t , ) U I of «M *4Z 'r Ivlilon Date • ....._... ._.. fifflJli ga SEHMUUUU IHiilKUntni lum KM CASE HO. _____ CONTRACTOR Htid CcfipuChitn CONTRACT HO. 66-01.6762,68-01-6666 ,«...„.-. HEP. LEVEt HIGH LEVEL MIWSED. JZZZIIIZII OTHER (Specify) DFTPP File tone: Pite; ?.'>V.IV Shin; ft- Anilyst! DFTPP Km Ion AburiJSnce Criteria I Relit lye Abundance SI 30.110 to 60. nn t, nf mtK 19ft fir fas tfiin ''9 nr o ££ nii W Ktiitive ihundance less -than 2.00J of mass 69 '''$'& 40.00 to 60.00 1 of MSS 198 . , ,, IMS than l.OM of niss 19B 198 bin peik, 100 percent 199 _5,00 to 9.00 1 of mi« *9 "7 preient but lets MII thin "".«! Miter thtn*4d'.OMi of ' 413 17.00 tO-M.On« of rnisi Uf . ""5l >s ina BFg-TeFtcrMnce neiuitirTTT The DFTPP pcrforiince rttulti were reftexid and found to be within the speclflc-ti ••criteria, inlttm . ,^ . Dite I I 'Deviation!-' ''vf •'' ...Wl,;,.i\, .,.,. Required Obierved mte/Tlnie/lnttruiiient File Htmber Conpound '• 'B/I Abimdinee Abundinct Area (Counts) 40 ng DllTAnthricrn^ • ajr?/ ^ DI-H-lutyl fhthilate Saturated QVes ^JjHo '» Figure In { . ) It S of MIS 69 JE^Si.,,,,. ' ' 013263 2 Figure In (<*, } Is I of MIS •? 3F1«ur,1n( , )1,|of«,.M2 E. BFB Performance Summary Copies at the BFB Performance Forma are Included, This form Is filled out for the tune generated for each Instrument at the beginning ol each 8-hour shift to document that the Instrument has been properly calibrated, It Is signed by the analyst's supervisor to docu- ment Ita review and approval, Since no samples are analyzed until the tuning criteria are met, a form with deviations recorded Is superfluous; therefore, the form entitled Form VII, "InatrumentTWe anil" Performance Summary," Exhibit B, page 28 of 42 of the contract, la not Included in tfila report. 013267 IW.R54 VOLATILE INSTRUMENT TUNE AND PERFQRHJNCE CASE NO. ______CONTRACTOR Head CompuChem . .CONTRACT NO. 66-01-6762,6B-01-68fS LOH LEVEL —— MED. LEVEL —— HIGH LEVEL """ HATER " ~""" S01L/SED. ' ' OTHER (Specify) , , BFB File Ntme: ______Date: _aUlm Shift: • ft KnalyTt: BFB Hiss Ion Abundance Criteria % Relative Abundance IS. 00 to AO.Oa* of mass, 95 : 75 30.00 to 60.00 X of mass 95 • . r- •.«' : • *. •• ,h,. base peak. Jfl0.oercent'"1*v "'• ws*i**1' 96' 5.00..to-a.OO~X-of ma'ss 95 . .. . less than-hOO % of mass 95 ...... - 174 greater-tharSO.OO S of mass 95 1-75 5.0(rto-9700-T of mass 174 grea.tec-tban-.95. 00 X, but less *thafi 101,00 t; of tnass':'i7r: :-:" rS'.dO to.g.QOl-of mass 176 .12 )2 iyBJ'ecfoniianceJBtui.ti; The .BFtiper-formnce results were reviewed and fowd^kf; be Mitfilrfl'he specified was ^rtttertii——— . Date Deviations ••-, Required Observed •- ——PiteyTlme/ln5trum_ent File Number Compound 'n/z Abundance Abundance '•'*'• Date ' 1 Value 'in ( . ) 1s * of 'iuss'174 '!::'1^1'?'.^:?'!1 •'' 2Vi1ue1n( , ) 1s % of Mass 176 w "^ Qt3963 ,3Va!ue1n( . )^1s % of mass 174 FORM Vll ". '£".'". PEH VOLATILE INSTRUMENT TUNE AND PERFORMANCE CASE NO. ______CONTRACTOR Mead CompuChem CONTRACT NO. 68-01-6762.68-01-6866 LOW LEVEL —— MED. LEVEL " ' ——" HIGH LEVEL HATER ______SOIL/SED. ' OTHER (Specify) '" ' / / , BFB File Name: Pft.fr'fraoVl/*_____ Date: »/6/*Y Shift: A ffijaTyst: BFB Hasi Ion Abun'Uari'co Criteria t Relative Abundance S. 00-tOh'4fliOai.Vof mass 95 30.00 to 60.00 % of mass 95 '•"'... -95- loo 95 5ltlese (••"•••tlR'c.iitiw"'s then r.'OO'' 't •' o•••f .mas ' •r^H1'-"^s 95 . • •'•• • . 174 grea1er'tfi«"ri~50.00 % of mass 95 ^JKSBlSl'VuVt-bf muss 174 erthair95.rQO X, but less .. 177 "s'!oi»4»4.0a-»-o' f mass 176 ( 7 .02.12 •••+••;•,>••• '«" i»Ut;. The BFB~perfdrnance results were reviewed and found to btMlthln the specified :cr1terta;—r^?.., . initials \" Date Deviations Required Observed 'Pate/Time/Instrument File Number Compound n/i Abundance Abundance 'ate omnents: ...; 013^63 2Vaiue1n( , ) h » of mass 176 , 3V,lue1nf. kki • VOLATILE. INSTRUMENT TUNE MID PERFORMANCE CASE NO. CONTRACTOR Mead CcmuChem CONTRACT NO. 68-01-6762 ,68-01-686 LOW IEVEL \S> MED. LEVEL HIGH LEVEL 4* wro ~ SOIL/SED. ' "'i- OTHER (Specify) , , BFB File Name: tPm&jc/g 11ite: aJ-JblfCY Shin: o_ Analyst: "JrV BFB Mass Ion Abundance Criteria 1 Relative Abundance 50- 15.00 to 40.00' 1 of mass 95 r,«.< •75 30.00 to 60.00 X of mass 95 •• ^ •*;•>?*•••• • 95 base peak. 100 percent """••••'*-> .•..^JHSN»*^fl,,-v«**.. / *?..:. '• ...... 96 5.00 to 9.00 X of mass 95 -jcfj ,,. . ...;.. 173 less than 1.00 X of mass'95 . ...^^^^P^''. ' '"" ' 174 greater than 50.00 X of mass 95 ?«/ Y? 175 "57bb to 9. W'X 'of mass 174 ^•^ .. ,,^.>., *^r^.,5)i '•^m. greater, than 95.00 X.^but less ^ ^i^*^^*^- - ••-^;iQ3 . .... iriari'iOl',00 X, of mass' 174 M,l£j4J$&g9ARj*; !r&flft'to..9.QQ X of mass 176 . ,";SaS!^«^™,^: • ..... ,.<*k;to)2 -itVTfS*?." ' .: ...;..• ' ^WaWSfv .•.- : '$t>>H'.'' BFB Perfonn»nce>n»sults: • ••• •"» J Thi BFB performance "res ultsNiiiere''t!^1ewi!'dII'an^'lSrto''''be'^mh1n the specified psi^rlterla, • •• -^a'W'WjJRfl*liiii'^Siife'm " "• '•'•••• • al^1i / / inwiMs..,,,.^,, Bate "| Deviations .». Required Observed d Dite/Ti'rne/ Instrument File Number Compound mil Abundance Abundance *r sw^-. • •''•' ••••'•••• • •••• •*M--V ^ ft'^ r^' "'''' ^^W^I:^^K '^"~° nTT 'initlilt ,- ••••» Date lOBinents : . . „;•„., -.71.,. •;•- ., .•••.,•- ••••...•- •••:••• 'W-: • c- •. .•.•.'.ii7Aii.:e»«- .««'.•>!>• ... .,••'."•.••**..' .• " .... .•>• n-r-i«< r.' •'. -••• ..i.*Mt,';;,"i:%«(H'.)l»*x,'jV-'-W-?*'"'*.«WtV' •" "•' •'" '••' • INT." >• . i- V:. ••, . '."I,*,!. • M '-ft 'I,1-. 1C. -"'. Sff.WS j"W-' •'• " " • ' •.« V*.ltf* ••'••" / ...i . 1 .;'.•> • •«..-.: 11 Value 1n ( . ) Is X of mass 174 ••.:-• •':,.,,„'-tvit !"('/*•' . ' ' • i '.'/^I'l'f'V, V'" 2 Value 1n ( . } Is X of mass 176 -;. ' v-^fer: 013270 -; 3 Vllue 1n ( . X 1S » of mass ,74 FORMjj, ,. ^^ ^ ^^ PEM VOLATILE INSTRUMENT TUNE AND PERFORMANCE CASE NO. ______CONTRACTOR Held CoeauChem CONTACT «. 68.01-676? .6B-Ql-6Bf- LOW UVEL u<> "* MED. LEVEL" WISH LEVEL ______WER ^mHZ WHVSED. u ^- OTHER (Specify 1 •'""" i i IFB File Mane: feFtWajocit*____ tote: pJ '. .'SI jJL^^?^'^T-fHHttiS'?l^'yT^yffr^^ ^M^^ttrff^ltf tf areater-thtn 50.00 X of mass 95 5.00. tO-ftkOO * of mass 174 greater than 95.00 X, but lew JOiiPfrof mass -174 --* 176 nsultt »ere',rev1ewed>nd found.itoj^ within the.ip»ci|t«t; . il.--'«>>.;.i.tr^aS li.'. •""••..<.•",«;**? _. Deviations ' ' " ""' -r ' -^j."";""" '"" 'Required Obsemti _ PiteTTime/Instrument File Number Compound n/z Abundance Abundance ^-i-~:.(»'.' •••••:i.i"«;*. 174 ,..,-. r. )ii»of;imt 176 . ..^p- ;T^ • '.013271 3 value in ( ., ) liWU lM;;,!S?Sl":"* .. J^. „„„,« «,- . . * - VOLATILE INSTRUMENT TUNE AND PERFORMANCE CASE NO.. ______CONTRACTOR KndJEBBSaL. CWKA^IO. .M.Q1.6762 ,68.01-6866 ION LEVEL _____ NED.. ICVEl______• " S5..«« TT-T MATER MlL/ffl). - OTHER (Specify) 30.00 to 60 JO I of matt 95 . •• 174 greater than 50.00 E'of'iMM 95 •''•*''w"'1ff^ 175 5.00 to 9.00 X of Bats 174 flreiterthen 95.00,X, .but less ,. -tffff )' f^...~^^iJAZ3JjSS&llKiL~.\.'l(£fM*,-.i> •afH.a"." j-v^ions .slleqiired Obiervici TOeTSlnttrument file Nurnber Ce^md •/! Abundance Of MSI Value In ( , ) U * of •» Vtlue 1n SAMPLE DATA PACKET E.P.A, CASE NO. ^33S E.P.A. Sample No. = CompuChem No. • A, HSL Results- 'Organic Analysis *E, TCDD Chromatogram(s)/ Data Sheets Quantltatlon Report B, TentatlvSyldenflflecrCompounds • EICP's Ust . __ ___ 'F. Pesticide Chromalogram(s)/ "C. VOA Chromatoflram(s)/ Quantltallon Report Quantltatlon Report • Mass Spectra of GC/MS • D.uaLMass.3pectra.ot HSL Confirmation II Required 'Compounds -Q, Worksheets • Ubwy.sewl.jpiolni . ^J'worHsheets "D, Semi-volatile Cnromatoaram(s)/ • Extraction Worksheets Quantltatlon Report • Compound Usts • Dual Mass Spectra of HSL ' • Miscellaneous Calculation Compounds • Sheets • Library Search Spectra 'Sequence repeated as required ~Q 013273 Oft''..SB 0 <« A. HSL Results - Organic Analysis Data Sheets Results are reported on the specified forma for each fraction ot each sample, Detection limits are CompuChem's, determined as described In IV-Q, Differences In sample sizes or dilutions require application ot correction factors, noted In appropriate boxes to be checked, Dry weights have been determined for solid samples, and the values on the Organic Analysis-Data-sheets represent dry weight concentrations, % moisture figures are also noted for each sample, Where footnotes are applicable, they have been noted with dala^unlltoa ai described In I-D, 013274 t» U.S. 'ENVIRONMEIffAL'l>ROTECTION AGENCY-CI.P Sample Management Office .P.O. Bex BIB, Alexandria, VA 22313 - 705/J57-2490 fa ORGANICS ANALYSIS DATA SHEET Laboratory Ham: Mood CompuChem Cose Number: Lab Sample ID No.; JtS'S? "' ' ' '' OC Report No.! '_ Sample Matrix! Solid ______| Contract No.: ~ Onto Rolono Authorized By: X/S/ Date Sampie Received: A-jl 7- SEMI VOLATILE CdfOVNOS CONCENTRATION: ((SkoiUM HIGH (circle one) ""DATE EXTRACTED/PHePABTOi'' /,'. DATE ANALYZED! *„., Hgltlpll/Detection llmlti^y 1 Qor I00or_ _ (Check Box for Appropriate SSL WSI PPI (circle out) (2IA) 88-06-2 2,4r6-tFfcbTorof!tienol IOU (22A) 59-50-7 p-cMore-i«-er»iol 20U (24A) 95-57-8 2-ehlorophenol • IOU (31A) 12Z-B3-2 2,4-dlchlorophenol ...R1JW'*"''"Via/ ' <34M 105-87-9;••2,4-4lMttlVlp(liM|i."'i"< .»•opnwl)ettier 20U <43B) 111-91-1 t)li-<2-chfijroathoxy)i«ettian« . 20U July, 1983 29 / • , U.S. ENVIROWENTAL PROTECTION AGENCY - CLP Sample Management Office P.O. Bex 818, Alexandria, Virginia 22313 - 703/357-2490 I «*W ORGANICS ANALYSIS DATA SHEET Laboratory Name: CnrouChem______Cam Number Lab Sample ID Noi WgfTS' ______00 Report No. Sample Matrix: Solid______Contract No.! Dnti Releate Author I»ed Bvi V/ Dato Soaple Rtctlvwl: ..... , . ... 7 ...w,; -• • •' •V '\VOLATIUS .•«... .Uv.,,i«,..- _• PESTICIDES CONCENTRATION! (5i)HEDIUM HIGH (circle) ' „„_,, .CONCENTRATIONS C^)MEDIUM HIGH (clrcl* one) niir.iirmiLArcnAicD.crn.'"",'. i^ t . r-_y J i. " ••""• • '.. MTE EXTRACTED/PREPARED I ' flOtf PERCENT MOISTURE: /. If ,^™. =• iM______" ' PERC£Nt'l«ISTW)Es Multiply Detection ll«lt» by 1 \\or |*-f""/• / Multiply Dtttctlon llnlti by I J^crjII l.tf , (Check Box for Appropriate Factor) «.,. •.-.. (Check Box for Appropriate Factor) .vSUU- ug/l • • ••" ug/L PP* CAS> optsSTKa) PPI CAM . ___ (clrJTTorie) - •••.«• • •-,. . • v^.'."-.i;*!'- v (clrcTfwie) ( 2V) 107-02-8 (clrcTToTie) 2,3,7,8-tetrach lorodl PBIUO- (I29B) 1746-01-6 p-dloxln______O.I6U Jlll«F 1983 29 C. VOA Chromatogram(s)/Quantltatlon Report dual mass spectra are provided. These spectra are labeled with the CASI and the CompuChem compound number associated, and can also be Identified with reference to the scan number and base Ion noted on the automatic quantltatlon report. The spectra for non-HSL compounds present at greater than 25% of the response of the nearest Internal standard are also Included, These are obtained from a library search of the EPA/NIH spectral data base, These spectra were generated via a limited-library search against standards run at the beginning of lr» contract, wort, on each Instrument. 013279 T'1"" ''ti&tiif&afty'!."'• .•sK'-vsa PROCEDURE: RK DIAGNOSTIC REPORT g/03/84 10:08:80 DATA FILE: 08019558AiB REFERENCE: V23B 0| METHOD: V238 INITIALIZATION OPTION: 2 PROCESSING OPTION: 3 ^ REPORT: V238S1 < "••—- STANDARDS ——— X —— PLUSi UNKNOWNS —— X - LIST NAMES - > PROC USED POSS RMS PROC USED POSS RMS STANDARD/UNKNOWN 3 2 1 0 44 B 1 77 V23BS1/V23BU1 1 44 COMPOUNDS PROCESSED. 8 FOUND i NO LIB ENTRY REF PRED SEL DELTA PEAKS FJCT PEAKS. M/E TOP DELTA PEAKS 1 PS 1 -230- 230 230 , V"'I ,961 130- •WWST. -1 1 ; s P6 v ••'»$,! -412 411 -A. . . •••!»:•-•. .79" 410 •t, . 1 3 -491. 490 490 ! ••<,;'. 993 "•' .'"" 53, 490. .... 1 4 '" P*K $*|t"'2 -34 53 . w'.".. •.. ••.-•^•a^' • i-Aski?W:,V.i . ..30 ( ' '• . s pa'k|> ' '3 -87 88 "' " • ' 94 ..JV ( 6 i$»»... 4 -106 106 , , . . •"•«'•'? .^te1 •-f'VA*i('• 7 P5 5 -130 130 « . . « 64 t ( , B PS 6 -171 171 172 1 1 ' 971 84 171 -1 X 9 PS 7 -182 182 183 1 1 984 • . 38 183 .1 10 PS 8 -182 . 182 . , , • 56 , . , 11 PS 9 -194. 194 . , • •' •' v . - 53 , , ' , IB PS 10" -211 211 , , '"'•"" '';"" 101 211 i. 13 PS 11 -202 202 lit. 76 203 1 •«-14 PS, 12. .-223r.•j-,223 vflw. ;..v". ., 96 -. , ( — ->VM m • - .v ^ , •'is "' , * — ~-z^' f«a*48 ; ."sss^i,'.:;' _• j •^V*(83 ':,-•""•'"•'" ;.-.,; •:" ' ..7 P5 .VA,*' in'mm ^•1 *^»4lT^^ 9A.U •J- wijjj • .. .„ , . B--I ••..-,«. ^71 PS'" -270 270 '"" , •'->83 "270" i 1 i. IB ''PS 16 -283- :-'2BS ''*'**'•' . 62 , * 19 PS 17 -284 284 284 . . 1 983 .72 283 -i i 26 PS 18 -313f • 313 ... • ' 97 t ( ( -21 PS 19 -320: 320 i . i * . Xif , , , t 22 P6 2 -321- - 321 . . . i 43 , , , 23 P6 3 -327- 327 i i . i 127 , , , 24 P6 4 -357.- 357 t t i • 65 , 25 P6 5 -361 361 > i i i " , 73 26 P6 6 -372" 372 i i i i 130 ( ( 27 P6 7 -384 384 i i . « , V 78 , 28 P6 a -3BS. 385 . . i « 97 , -386 386 lit* ( ( 29 P6 ..... 9 ,., »• .n..)>!rtlJZSi.. * ( 30 P6. >-10 '•-383 383 ;'"* '*•*** v. "'*";"" '127' t f> 31 P6 11 --408 408 V'i "I'^Jrt-i .... . tar- , f'...« .-•"•^•. ' 32 P6 12 -436 436 i « i i • . 173 , , , > 33 P6 13 -448 448 . i . • *,:- . 58 t ( ( : 34 P7 ,,2 -479 „ 479 ' " ' • • ' •• ' ''"' fa . : ' 58-'• 478 2 . ;«l'b • ' ''l^.'.V P7 ''•'.'/•"is -483 .483 i • . . *c/^n(Mi(*W * /** .1. or'ftlJVZJK'^mfQ'i* ."'• '•«'' *HW . . V« 35 -ABB «!4aa •' -rfw..--.;..;,. ., . •;B.'*»;:*!'!K"s*w*iig«i1 36 T1B3 $.Wa • : :•..;•,-...64j.fet,-KM.;>:!|fc.ffS'. ' • i**Wlw 37 P71;* 's -316 -'313 , , "•W&ljA."" f *„, , . -.-flS? *'''•' / 1 30 PUT 6 -346 545 . a. «..* .. ' .. ' . 112 345 ,»A 1 39 P7 7 -609 60S .' , . , 106 , 40 P7 a -748 747 ,... , , , •,.4104 , , , 4J P7 9 -793 792 . "'106 48 P8 2 -284 284 283 -i. i, 987 65 283 013291 pa 3 -512 .512 511 -1 1 981 100 511 'i V . .*t. -1 4 P8 4 -692 '691 692 1 1 988 176 692 1 Ofl/tRRfl . j QUANTITATION REPORT FILE: ! ' DATA: GH0i955SAia, TI , PV03/84 9:28:00 I briMPLE: 10 CM OF SAMPLE #19538 + H UL 10941*10936 ON tUB SUBMITTED BY: #18 ANALYST: 633 f •' AMOUNT=AREA * REF, AMNT/IREF. AREA)* RESP. FACT) RESP, FAC. FROM LIBRARY ENTRY NO NAME •' ' ' 1 * BROMOCHLOROMETHANE 29 i NO RET(L) RATIO RRT (L) RATIO AUNT AMNT(L) R, FAC R. FAC(L) RATIO 11 10:16 1,00 0,878 1.01 0,47 60.00 0,022 2.819 0,01 | ||| 11: 20 0. 970 60. 00 0. 70S *J 12:36 1,078 60,00 0.311 14 13:16 1,135 60,00 0,780 IE! 13: 43 1. 00 1, 174 1. 00 0. 21 60. 00 0, 005 1. 519 0. 00 16 14:29 1,239 60.00 0.996 , 17 14: 26 1, 00 1. 235 1. 00 6, 27 449. 98 0. 001 0. 095 0. 01 IB 15:55 1.361 60.00 . . 1.241 19-16:16 -t.391 ... ,-,^V.:,,,. 60,00 ••> .X" V:#.««r> #;•« 2Ei 20: 57 1. 00 1. 000 1, 00 10. 00 10, 00 1, 000 ' " 1, 000 1. 00 21 16: 19 1, 396 60. 00 1. 025 28 16:37 1.422' "'.,::;:.',.,,. 60. 00.^,. • • .CS319JL '. 23 18:' 09 1,552 60. 00 ' 0.211 24 18:21,: • •«. 1.370 . =;; 60. 00' ^ ."" 1. 404 . K .;f . 25 18:-5S a7,-4B 1, 00 -TK374 " 'l.'OO •*—. 0. OS 60.'0« " ' 0, 'Wjt -? ,,U«: 37 2. 648 . ... . ,.»«.. 60, 00 . .- 1. 109 40-;''''3iB! 01 • 3.23fc " " ' 60.00 2.323 41 40: 19 - 3, 448 . 60. 00 1, 437 42 14: 26 1. 00 1. 233 1. 00 7. 10 10. 00 0, 796 1, 120 0. 71 43 26:02 1.00 a 226 1.00 11.47 "iOO 1. 799 1.369 1.15 44 35: 11 1, 00 3, 009 1. 00 11, 88 10. 00 2. 339 1, 969 1. 19 fr ':'"^^fw''-'-,*\£$l:sr'"' • ' ';r N *'"' •:"• ""•'•"•• I!i'|r : - "•'•' ' '-"•: 013284 ior '•>'; u, «H S Ufcr* •..SfciSML—..,nfijs, «1 • 1 ••^•4-":;:!?lf- ••:.»-fe"';: o 8 i a *s CS » M. tO Ul *i1 00 g ^ 81 ' •""-- " ?°- 013^5 1 iI CO • m i/to r* .:.';!.' j ,M,. ,; •sv liiei m •• 00 •< .,.,..-...- ^.'.'.,A ;*- ||l «us*& . g»8 vKr^,>- ^l* _ ..,..; ,:. ..,.j,«, . If) _ ...v»*CU> Ml ** 1 s5 1 + m •'•••• • oi w. - F •1 • •* • »•»s •m g W»*<*^'-- . ..-*»' • o .•"•.. . . .( | ' .p •••" " ''"• ^"••'W; 5« ?§ a- h* : •,. • ...... „. J..;^*- ! '....';•• ' § '••"•Vf '-\f.'- ".•<• ' ^-;.1SnV-' -. ii.j' '.•'-,'."• ... "•~,V.-.. sogj a tf*«^^^i'^dj.'..- ••• •'•'• ''"*? -^••;W gS,, f\j ^ tnc•J Jo^ g1\ — m®" £^ ? 88 f>1 « 9 j__, . , I , , ,. ...__| *i CQ D 8- W s s ' . . I • 'W ' • •>•• ' _t>7i- . ;„ I*M 8 013S -i——r-i——i——|——i——r—i——i——| ' j- Pi' OJU (\ 4S 5 P1 I*N f P^r-nn gg 'r •"•'•' P isg | HE P . -M*. (3. Mt> »O O>>-oocBio.5.oiwi> «>MU1O. Jtw5p 8 " TO "C S « , ,.... B, w*-SH 5»CT«»^itoi1 ? •*- ,21 s.1 .. -d elw S?^ <^ " ^. 3 aft«',;(.r H';.- 0. Semi-Volatile Chr6matogram(s)/Quant!tatlon Report For those compounds detected at greater than '/i the detection limits on the HSL listing, dual mass spectra are provided, These spectra are labeled with the CASI and the CompuChem compound number associated, and can also be Identified with reference to non-MSL compounds present at greater than 26% of the response of the nearest Internal standard are also Included. These are obtained from a library search of the EPA/NIH spectral data base, These spectra were generated via a limited-library search against standards run at the beginning of the contract worK, on each Instrument, 'D13230 D (\OAR73 -a S ..8s M 10 -6 N -:-•='.. - u, g i §31 88 g a|4; •i?:', » « 01339 90 PROCEDURE; RK DIAGNOSTIC REPORT 2/IQ/Q4 8:10:37 DATA PILE: QHQ1955BC1» . , . REFERENCE: FSCC7 METHOD: FSCC7 INITIALIZATION OPTION: 8 PROCESSING OPTION; 3 A REPORT: FSCC7S1 *^^^ . '. . • »! i i < —— STANDARDS ——— X —— PLUS. UNKNOWNS -i- X .- LIST NAMES - > PRQC USED P08S RMS PROC USED,' POSS RMS STANDARD/UNKNOWN . • 6 6 I 108 34' 6'" l< 103 F8CC7S1/FSCC7U1 -6 . 6 • •! • 103 34 • .10 *..».».. • 84 '• FSCC7Sa/f!!8CC7US i SS COMPOUNDS PROCESSED. 10 FOUND ... , :. '^ I ,..„-. , ..'>•?,„,. i ...-. -.;•.,• fli'Xrtst«K»''Wil' fp < COMPOUND X ——*••——K---- SEARCH '• Jm-*ift*!H--. x' SAT' X •"!••;»">" -CHRO ——"—- 5 'NO LIB .GENTRY 'ReF • :-.PRBQ- -SB-'DEttfA ffiAHB" iftfcBBAKB' •• WE^'vTOP DELTA- PEWS -77AC-.M776 776 -9B8'.,, .988 9B8 -1896 1896 -2033 2032 -2334 2332 8 -362 363 3 -736 736 4 -733 733 -749 749 6 -749 749 7 -769 769 B -778 778 -1084 ,,1024 i12s -109-mi 9 1099 14-1191 36 , 37 C9''''^a;rll99 1199 38 C3 "n 3 -1229 1229 39 C3 4 -1263 1863 40 C3 8-1268 1268 41 C3 • 6 -1274 1874 42 C3 7 -1893 1893 C3 B -1301 1301 C3 9-1319^1319 49 C3 10 -1332 1338 46 . C3 11 -1329 1329 47 03 12 -1341 1341 48 C3 13 -1387 1386 49 C3 14 -1393 1398 9U UU IS -1390 1389 ..... 166 91 C3 16 -1402 1401 . . . . , ,. 138 98 G3 17 -1412 1411 . . . . .198 93 C3 18 -1416 1418 ..... 169 94 C3 19 -1420 1419 ..... 77 99 C4 8 -1477 1476 ..... S4B C4 3 -1900 1499 ..... 2B4 G4 4 -1834 1933 ..... 266 58 C4 5 -1958 1597 ..... 178 89 C4 6 -1566 1868 . . . .,176 60 C4 7 -1678 1674 ..... 149 61 C4 8 -1770 1769 ..... 802 68 C9 2 -1B10 1B09 . . • . . ,• ,208 64 C9 "' "•"4;'-i'943':''l948-":" ! ' " ' '*' - )•'"'*"*•;., v •';'•"'149 AnvX^s 9 • ' 232 66 C3 .,- -6--8030'" 8089 ! ! :-».'•! .dfev , .'' '888 ST C3 7 -8068 ••8061 . " . 'r*-'.sfW*W&:'i, . ,149 68 J»^.,.B r8Q38 ''8037...,. . ,.., • .... .- >;..i. ,,^,i;;" . '-BW. ,9 -S 71'"ei"' .3 -2861 '8860 . ' " ", J""" ... 898 78 C6' 4-8348'2341 . . . ».f'-^' . 898 73 C6 '9 -8784 8788 . . . . 876 74 C6 6 -2806 2804 . . . , . 278 73 C6 7 -2909 * '8907 . . , , 876 .V 76 C7 2 -988 988 988 . 1 990 ,118 988 ''• 77 .C7 ,.'."7SK3..:#739 739 . • . wsLfts;-..1 •;,';..«•':••• W 739 7B""C7"'"": •"4r*3&78' 872 878 . lv"-.'?fWB^aa ' •_ ' gg B72 79 C7 9 -1181 1181 1181 . 1 993 . 178 1181 >,-.iBO C7'..v^A...rli*3* ' H3A;Vf.'-. . .•;".• .•'•.;•;-. .,..• 330 .1437 OIMR82 t (JUANTITATIQN REPORT FILE: OH019338C18 • DATA: OH019558C1S. TI 1 AMPLE02/10/8: 4IU 7:33:0L 195530 t SUL is (109551 \ "BMITTED BY: is ANALYST: 794 J AMOUNT-AREA * REF.AUNT/(REF, AREA)* RESP,FACT) . RESP. FAC. FROM LIBRARY ENTRY f » NO NAME f 1 »D4-li4-DICHLQRQBENZENE (13) • ., ... v .•....•. «...... c i 8 441 rHHTROBODmeTHYAniNE " ' r- ••••'•; • i 3 610 PHENOL t 4 473 ANILINE .w-•- . «••»«. I 9 411 BISU-CHLQROETHYDETHGR "'•"*" — .».>.? 6 601 8-CHLOROPHENOL -,^6;:'?•««:•: *;.:«,.... ••• 7 481 1.3-DICHLQROBENZENE . . . ' ''.'"•*SSS.; 98 ^asr^^-DICHLOROBENZEN474 'BENZYL ALCOHOL E """'' . •^•i?-"' '—' 10 480 1.8-DICHLOROBENZENE II 680 8-METHYLPHENOL •v ' ' 18 418 BIS(8-CHLOROISOPROPYL)ETHER 13 622 4-METHYLPHENOL 14 448 N-NITRQSO-DI-N-PROPYLAMINE ,,.19 436 HEXACHLOROETMANE ^,:;;,,. 16 440 NITROBENZENE " 17 #460 DB-NAPHTHALENE (IS) .18 438 i -ft- " *l t-UUIBMIU;nM!Uk.yj..!^>li>'" ' B IS (2-CHU1RQETHOXY)METHANE •2?-,;683 BENZQIC ACID 23 608 8.4-DICHLOROPHENOL 84 446 1,2,4-TRICHLORDBENZENE 89 439 NAPHTHALENE 86 479 4-CHLQRQANILINE .27 434 HEXACHLOROBUTADIENE 28 60S P-CHLORO-M-CRESOL 89 477 8-METHYLNAPHTHALENE 30 439 HEXACHLORQCYCLQPENTADIENE 31 611 8.4.6-TRICHLQROPHENQL 3-2 626 2,4,5-TRICHLQRQPHENOL 33 *D10-ACENAPHTHENE (IS) 34 416 2-CHLQRONAPHTHALENE •.••.•• 39 479 3-NITROANILINE ;'-."' 36 489 DIMETHYLPHTHALATE 37 402 ACENAPHTHYLENE 38 488 8.6-DINITROTOLUENE 39 478 2-NITROANILINE 40 401 ACENAPHTHENE • • •41 609 a. 4-DINITRQPHENOL 42 607 4-NITROPHENOL 43 476 DIBENZOFURAN 44 427 8.4-DINITROTOLUENE ,.., ...... (\1 qofl-S '49 484 DIETHYLPHTHALATE ' " " ' '""" UlJft^iJ 46 417 4-CHLOROPHENYL PHENYL ETHER NO NAME 47 438 FLUORENE 48 480 4-NITROANILINE 604 4, 6-DINITRO-O-CRESQL 443 DIPHENYLAMINE (N-NITROSO) 91 430 1,2-DIPHENYLHYDRAZINE (AZOBENZENE) 98 #467 D10-PHENANTHRENE (IS) 93 414 4-BRQMOPHENYL PHENYL ETHER 94 433 HEXACHLOROBENZENE 99 609 PENTACHLORQPHENOL | 36 444 PHENANTHRENE ! 97 403 ANTHRACENE * "" ""•' 98 486 DI-N-BUTYLPHTHALATE 99 431 FLUORANTHENE 60 *437 M8-CHRYSENE (IS) ', 61 443 PYRENE .„ «, ._ ' 68 TO* BENZIDENE""" '"' 63 419raUTYLBENZYLPHTHALATE ), i 64 4iSa'3,3'-DlCHLORQBENZIDINE ; 69 408-.BENZO( A) ANTHRACENE 66 413 BI9<8-ETHYLHEXYL)PHTHALATE | 67 418 CHRYSENE , 68 429'DI-N-QCTYLPHTHALATE 69 *D18-BENZO(A)PYRENE (IS) I 70 407 BENZD(B)FLUORANTHENE "i-~7t 409 BENZO(H)FLUORANTHENE 78 406 BENZOtA>PVRENE 73 437 INQENp(Uat»3-GLA)PyRENE 408 BENZQ(«,Hr I)PERYLENE ...^ :. ..,.'-',. *, : 619 2-FLUQRDPHENOL (SURROGATE) D9-PHENOL (SURROGATE) 78 447 D3-NITROBENZENE (SURROGATE) 77 448 8-FLUOROBIPHENYL (SURROGATE) ••.-*«•••• 80 TRIBROMOPHENOL (SURROGATE) •--'• ..^,.aw. •- 81 D10-PYRENE (SURROGATE) 88 ' D14-TERPHENYL (SURROGATE) ...... ,,,... NO M/E SCAN TIME REF RRT. METH AREA(H8HT) AMOUNT • XTQT 1 150 776 9:48 1 1.000 ABB 19606. 40.000 NO 6.32 8 NOT'FOUND 3 NOT FOUND 4 NOT FOUND . ...„.• 5 NOT FOUND • . •• ••t-ft'r-- '•;• '..;:•. . 6 NOT FOUND -, . , , ... , , ' ' " ' *'•'" •'*"'• • . 7 NOT FOUND r""';' : »>• :-... 8 NOT FOUND „,*.'.. 9 NOT .FOUND * . "-.*• ....,;.-. -.. 10 NOT FOUND „„,.. „ ,11 NOT FOUND^-.-\- -.'• ' 12 NOT FOUND " "" *' ' ; -Vir 13 NOT FOUND 14 'NOT FOUND 19 NOT FOUND ,16 NOT FOUND 17 136 988 12:21 17 1.000 A BV 43449, 40.000 NO 6.32 JB NOT FOUND . ' NO M/E SCAN TIME REF RRT METH AREA(HOHT) AMOUNT XTDT 19 NOT FOUND »NOT FOUND NOT FOUND 22 NOT FOUND 83 NOT FOUND 84 NOT FOUND 29 NOT FOUND 86 NOT FOUND 87 NOT FOUND 88 NOT FOUND 89 NOT FOUND 30 NOT FOUND 31 NOT FOUND 38 NOT FOUND' 33 164 1895 16: U. 33 1.000 ABB dKiStttt 40. 000 NO * 6.38 34 MOT^OUND ' 39 NOT-FOUND 36 NOT FOUND 37 NOT FOUND 38 NOT FOUND 39 NOT FOUND 40 NQT FOUND 41 NOT' .FOUND 48 NOT FOUND 43 NOT FOUND 44 NOT IWND 49 NOT FOUND 90 NOT FOUND .. 91 NOT FOUND • ;.. • • 92 188 1993 19:89 98 1.000 A BV 1|;:>i^|i3?13. W.'OOO NO 6.38 33 NOT FOUND 94 NOT FOUND 99 NOT FOUND 96 NOT FOUND 97 NOT FOUND 98 NOT FOUND 99 NOT FOUND . . . 60 840 2032 89:24 60 1.000 A BV »30B80, .,,*.. 40. 000 MB •'• •" 6.38 61 NBT-FOUND '.. ,...^tf£i? " " ' 68 NOT FOUND •*>*•'• '> .' ,:, 63 NOT FOUND 64 NOT FOUND 69 NOT, FOUND , ... 667 'NoiSfpuNNOT...FDUND ,,i... .•.. , . • ..- .68 NOT FOUND ' •' 69 ..864 2330 89; 0>. 69 1.000 ABB J. '.88791. 40. 000 NO 6.32 70 NOT FOUND 71 NOT FOUND -.a^jiV ,„„„ ..,., -~ 78 NOT FOUND ..,.»..„ ?,« 01329? •»3 NOT FOUND NOT FOUND NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT XTOT 78 NOT FOUND 76 112 388 7:81 1 0,798 A BV 16931, 98, 194 NG 8,24 99 739 9:11 17 0,744 A BV 19087. 38. 179 NG 6,03 88 878 10:54 17 0,683 A BV 31737. 94. 169 NG 8.58 79 178 1181 14:46 17 1.199 A BV 5B269. 72.819 NG 11.90 BO 330 1437 17:58 33 1. 110 ABB 3736, 80. 137 NO 3. IB Si SIS 1806 22:34 60 0, B89 A BB 89723. 84.716 NG 13.35 82 S44 1844 S3:03 52 1. 1B7 A BV 66779, 71.643 NG 11.31 RET(L9:'4a ) RATIi; ooO RRT(Li.ooo) RATI1,0O0 -40.0AMNT0 AMNT(L4o;o)o R.FAtfobCo R.FAC(Li.ooo) RATIi.oO o 0.466 90.00 0.449 0.94B .... 90.00 '..•-.1.876 - 0.949 "wflO.00- " .1.183 0.960 . iw* • . • ., ..^JJOirOQ , .. • „•'vl.OOi . .. . ^.r- wrao^^yt' •,-.... 90,00 90.00- 0.339'1'- 90.00 0,871 -90,00 0.778 90.00 0,318 ' '•••'• 90,00 0.883 90.00 .:....„,..,. 0.169 "•" 30.001-'-""""™*'- 0.480 . 9O.OO 0.449 40,00.... 40..00..,,,,».000 o1.000,.. BBcr.w 1.00 !90,00 '——""0,390 90,00t 0.388-^' • ..,-.-'".... .;,aot«)830^00. • • - •. ,0,310.8042 18:. 16. 90;'00-..v 0,369 18:83 90,00 . 1.139 18:36 290, 00 0, 369 12:48 90, 00 0, 807 13:41 90.00 ,,; •. .... 0.479 13:93 90.00 0.318 14:83 30; 00 0.070 14:39 90, 00 0. 889 r6'si14:40 2 *40.oo 2940,ox»treood':.W!(;i.ooo/0 00 • 0. 822 . i.oo 14:36 30,00 ••'." ••?'!, 137, 13:19 S30;60 ' 0..49A...S. 19:47 WtW- 1.973 19:91 .,,...„ 90,.00.,,^.; . 1,697-,, 13: 39 ' '•^tS^^^'I*>•^•^'*al••^•• ^^Xl^^«*^^ 16:36 290, 00 . M*'071 '16:!39 189,00 " ' 0. 178 : 16:37 30,00 ,li.708 16:'46 90, 00 0, 916 17:80 90, 00 1, 671 17:89 90. 00 0, 999 47 17^9 IQ RRT•«« 5S 20:96 1.078 *goM 1699 39 88:07 1,139 •• .<**»•- «55" '. 1193 '' S? S:S llCO ll000 1'°° ^-°° ^"°« i-ooo tSo "i.oo 618 22:3788:48. ^ Ag0,890o ^. ,^^;,,.;''""3000 : ' ''•J! SJ*7 l ..; :.w. «.W6 •*;". ,. .»^W'SO.OO^.OiV*«1""'*.B76 ..' -V- • "T 1,004 • 30 00 o oat, 63 83:88 0.999 S^OO ?'£» 66 89:46 1.014 96 00 '319 67 83:28 1.008 90 00 1213 68 27:27 t.080 ' M 00 8 807 69 89:10 1.00 1.000 1.00 40.00 40.00 1.000 lioOO 1.00 ^,.88:6^^.0.969...... 100.00.^-,;^,. LlOa . 71 88:16 0.969 ... 100.00 1 102 78 89:16 1.003 "'='• MOO ;,,73 34:48 1...193 ..... :•'-»«;• 30 00 "•74 33r04w0 ....^808 ''''•• " ' •••'-""•*ffi<—<-gg 36:88 '•^V'Wfc.v,, . ' 76 7:81... 1.00 0.7ae_,lvOO 98.19 90; 00 0.6BB 77 9:11 1,00 0.744 1.00 38.18 90.00 0391 0460 78 10:94 1.00 0.883 1.00 94.17 loToO 0 984 £ N? 79.14:46 1.00 1.199 1.00 72.81 M. 00 1.073 0.737 m iZ'22 1<0° 1>108 *h<1°° 20'16 "'WOO ; 0.118 0.893 OMO 81 88:39 1,00 0.889 1.00 84.78 50,00 8.281 1 311 1 69 B2 23:03 1,00 1.187 1.00 71,64 50.00 1 Il6 o! 849 !'43 013293 •29 f3in BBwSSS-i: qgNft ' Ml 53\'SSaC 3i " 81 g a- S :4^ •013300 01 fcl E. TCDD Chromatogram(s)/Quantltatlon Report Instead of the QC chromatogram required In the contract, the TCDD extract la analyzed by GC/MS, and the RIG, EICP, and mass chrotnalogram Is Included, as well aa the automatic quantltatlon report, An Internal standard, carbon-13-labeled 2,3,7,8-TCDD, Is used for quanlltallon ol surrogate and any native which might be present. If the presence of an Interference Is detected, an external standard calculation la used, If the presence of native 2,3,7,8-TCDD Is detected, the Sample Management Office Is Informed so further analysis can be performed. 013301 UltO ^U CD PROCEDURE: RK DIAGNOSTIC REPORT 2/13/84 20:44' 4B DATA FILE: TC019358B84 REFERENCE: TC , A METHOD: TC INITIALIZATION OPTION: 8 PROCESSING OPTION: 3 W REPORT: TCS < —— STANDARDS ——— X ~r- PLUS UNKNOWNS —— X - LIST NAMES - > PROC USED POSS RMS PROC USED POSS RMS STANDARD/UNKNOWN 2 . g 3 SQ 7 4 1 0 TCS/TCU 7 COMPOUNDS PROCESSED. 4 FOUND - .^ NO LIB ENTRY REF PRED 8EL DELTA PEAKS '' ITT PEAKS M/E TOP DELTA PEAKS 1"TC 1 •"9W 912 911 -*"- 1.TB39 ,. . 332 911 . 1 2..TC 3 ' 87X BT7 .878 . "I*" • ;j;/*?i998"':' . SafSv.BTS '. 1 3.;fTC 3 ' B7t.rf 878 -'878 ••';••''. ^'l»v.998. . ,.;328 '.""878 . 1 4..W.TC ;.. r.,*'if'BTA'.'ir^^PT!i^...^i^»fj'-i1lJ«^p-\! . r " 8s7 ' B7B ..-. • 1 !'"6-:JitC- '" 6 987 "913' "". . ..iJ!'^ '. ;J' " r:r' 322 ' . "v*t"' | 7 TC 7 986 912 . " . . . '*,'.•. 237 918 '. 1 •.. «sjnw«'.-.... ., ...... • • .'" • • - 'SAif.wu 11" 013303 89 QUANTITATIQN REPORT FILE: TC019558B04 DATA: TC81955BB04. TI 9£/13/84 20:14: 00 IPPLE: 2/50 uL MIZZ 1935B (CH2333 - R3317 ) 8-2-84 OWA tt 04 SUBMITTED BY: 04 ANALYST:. 615 AMOUNT-AREA * REF. AMNT/(REF, AREA)* RESP. FACT) RESP, FAC. FROM LIBRARY ENTRY NO ', NAME 1! »13ClP.-2. 3.7. 8-TCDD(INTERNAL STANDARD) - • .',„ . ,;• . . . 2 1.2,3.4-TCDD " *."'"' 3. i, 2, 3i 4-TCDD 4 1* 2. 3i 4-TCDD ;:^ •"''^"*'fflj.'';'jw'?,v 5 2« 3. 7i B-TCDD '"'" ' ''ri''''..,•<•.,,.•;". -.. . 6«2y,3i7..B-TCDD. ..•> . , ••• .•''*"%; ..;,«.;.«•«• •.-••:,',•. iSST,-,,. 7 £*%?• 8-;ICDD . "'"i -i.. •»,,^j&/'-. -\ S^v;.^..^^ 'g.-.h^ss •••.-• «^; NO M/E . SCAN'''TIME REF RRT MET^H^'''';^^^^ ,;,' "TOT 1 332' '911 20:36 1 1.088 AW '4838310. ~ 288, 888 PG/UL 39.71 2 320 878 19: SI 1 0.964 A BV 900067. 38, 666 PG/UL 11,34 3 322 878 19: SI 1 8.964 A W 1231240. 41,920 PG/UL 12.40 4 257 878 19:81 1 0.964 A VB --403492. Si 960 PG/UL IS. 51 S 320 918 28:33 1 0. 999 A«BB 17173. ' 0. 742 PO/UL 0.22 ..Ai/NOT FOUND •;?#.„•... .: .r-r.^sw^' *7 237 910 20:33. 1 0.999 AW 21972. & 867 PC/UL 0.62 . „., . "-.ilf1"*' . .38.67#*ia!W^,.*lB*lB7- ' 8.967 8.19 3 19:42 1.01 0.962 1,00 ' 41.52 ..200" 99 ' 0," 253 1.221 8,21 4 19:42 1.01 0.962 1,08 91.96 208. §»> 8.083 0.328 8.26 3 28:31 1.08 1. 082 i. 88 8. 74 200.80 8.884 8.932 8. 80 6 28:29 i. 001 "T2fl«."tt *'" 1099 7 28:31' 1:08 1.882 1.88 & 87 288.00 0. 80S 8.438" 8.81 / /^ 013304 i _aJ- •MCW + " 23 iSaH R 1 «. S 01330^5 V ''^ F. Pesticide Chromatogram(s)/Quantitatlon Report Chromatograms from the packed and capillary column QC analyses of pesticide fractions are Included, Where the retention time Indicates Ihe presence ot a pesticide on the HSL list In the sample, It Is confirmed on an alternate column, If the concentration Is high enough, GC/MS confirmation Is provided and documented with a spectrum, as described In the contract, Exhibit D, page 6 of 70, sections 1,1 • 1,2, 013303 013307 K'eport. 6404. (HI Channel. 5 SaciplB, HI1 19lJiiU Injected at Ui24i5V UN l;iai 4, IVIJ'I fclSTD Method i fh'AU iieq. SEflUl Subsq/li'anp. 1/2:4 Btl i M Sl-wlrtth MV/Min Delay Min-Ar flunch .85(1 3.0(111 li.llfj Sup-Unk DwT II)-LM! KeMITW XilTW Mii-t 110 NO 0,11(1 0 .30 b.O 100.00 NU ••Actual run tine. 30.008 ninutes ._... .••/'„... •-•?'.-'•• . "^ ->• •-..•• Ended not on baseline ''•"'•• ,,^T raif*?. F«tor . ivfflP • • •" •« „„ — 20,38 .iOOQOE+01 130019. SH i3001B.,7SO "•S,r75 20.68 .iOOOOE+01 647278, :8H 647277.620 5.92 21.49 .100QOE+01 694952, SH 694951,070 6,06 21,99 lOOOOE+fll 94552BU, SH9'4SEii'Clb,000 6.42 23,31 '.lOOOOEtOl 35970, SH -35970,000 6.6624,17 .10000E+01 1124£!S, ST"1124S4,69II 7,0? 25.73 .100QQE+01 493436. "SH 493436,310 7. It) 26,06 .10000E+01 335U4'/, SH 33S&47.440 7332661 10000E+H '•••^SJi977s'i- SH^K/O^t 810 7.4V 27.21 ,inOOOE+01 S6S01. SH 56201.406 - --- .10000E+01 .161732.. 8^61^1.170 3S.'..33.79«...... lOOOOE+fll ..____. . _. ____._.. .57 34.75 -.10flOOE+fll, 'WT951W.' W 195406.120 7,87 35,84 .10UUUE+01 47U119, SV 478118,870 10:22 37,10 .10DOOE+01 30B50Q. 8H SOBiiUV.690 10,30 37.4U .10000E+01 196927,,8H .196926.590 10.4137,81 ;10000E+01 5P3f:16. 'Bff 52321A..OOO 10.7038.85 -.IDOOPE+Ul 609007, ST 609007.000 11.02 40 ,02 r, 10000E+01 1721B7V SV '172fB7";3lB" 11.0743.09 -. 100QOE+01 EJU2246, SV 882245.750 IS.11 43,98 ;.l«!!P.g+(!l 551363. SH -•-'- —— 18.8546.66:, t)'j * "10000E+01 390671. SV 3'?B67l.rJ00 13.43 4U.7S ..lOOOUE'lOl 1II6W3. SB 106BU3.060 14,1? 51.51 .lOOOUE+Ol 208726, SH 20B7SS.750 " 14,5552,88. Hi00ODE''Mil 364S4BBtl, SH364S4BB8.00 ,149954.41 ••,292771;.-07 .^33761. ST... ' ,. ,004. HEPrACHLDIt liPOXIDG 16.0350.21 .lOOOOt-XIl 1B64(I1. 3V 186400,750 17,41 63,22 .iOOOOtlHIl 1U3366, DV 123366,190 -.17.67 64,16 t,10flOOE+fll H5341, By.llS341.440 "18:0765.60 .lOOOOE+Oli..^;. 114367, SV.ti436&,97| y.:H tt:.66,13i *«RHtf-4l,"-Wtt.373i6E-07'A "l*'24£511 : ftn^ift lf:§65 66l:59s mm ?»-iv ?Lffl:33°o 19.55 70,99 .iOQOOE>01 164615, SV 164615,500 '7.65 71.34 .53672E-07 .i.29bfli8.v.8U.^.-. . .016 1 —74.2ion4 . .1QQOOM0.1 • • i?Z8Sg."-ffiL;i7?SSi-.itt'S 25 ,.04 90,90 TlOOOOE+01 163064, SV 1630&4.190 25.25 91,60 .lOOOOg+Ol . 116203, SV 116203 440 26,1, 0 94,7, 7 .IOOOOE+O. l S4V614,, SV 249614,37, 0 26.3595.68 .10000E+01 34U60, SV 534059.810 £6,51 96.27 . lOOOOfilll 506370, SV U06a69, BIO .. 26.9397,77 m .10000E+01 SOHA32. SV 508631,620 f~'"<1 27.54100.00 W ,11096E~OS 7714V1, SV ,8S6 28:05101.86 .10000E+IU 112447, SV 11244.7.060 2(J, 73104. 31 .lOIIOOC'llll 116U64. SB 116£63,Bia .29.36106,60 .lOIIOOKtUl 225873, SV 225872,670 89 Total Area = 63229760. Total AKIuA X « Efca Processed data filei r"jil!'4 Ran data file. R51S4 •'•' •:•«•!•!=•••: >lt,*- •j-. -.., M RUPLITUDE x.2S uV-s*)ConUs (Enlarged x 55.36) Report. 3H5B.OO Chsnnpl. 2 C*!?.333 R3517 Wfianple. OP 1955R Injected at S.81.11 ON FEB fi, 1984 EBTP Method. PAQKQ3 8eq. SEQ82 Subftq/Banp. 1/Sfl Bt).. ?B Si-width MV/Min Delay Min-Ar Bunch .500 .300 0,0(1 20 Auto Sufi-Unk ?VTo HH..J Raf-RJU ^ Httt^tt' Actual rwh"tifie. 35.008 nln'tittV "".. "'*'*"' ... .*,, ... . .•».„» ...... >«'«>> " .. •' ' RT^.ITM .. ...Factor Ar»« .•;.>,;u^i*.it»iUG/ML Hint -.43 2.02 .10000E+01 2B8B47. SB 2B2B47.310 162 2.96 .10000E+01 2M832, 8B270B31.940 .74 3.52 . .10QOOE+01 20000, SB 20000,500 .84 3,98 .lOOOOFI+Ot 324H1. SB 32480,812 1,06 5,05 lifOOOE+O) 4110S. SB 4U05.344 1.28 6,11 .10000E+01 3046. SB 3045,922 1,49 7,07 .13S55E-OS 143354, SB . 194 .ALPHA BHC 1.81 8.61 .IQOOOE+Qt 1363. SB 1363,26, 6 !.99,2&*44 .1QOOOE+0IOOOOE+O1I .18104%^1810. .. SBB 14515.53.1810.141 810 1411 lOQOOEtOl 10000E+01 B j ' \" 013311 G. Work Sheets Worksheets for each type of fraction are Included, There are extraction worksheets, describing which samples are processed In a batch, and listing the associated reagent blank, date, analyst, standards used, and conditions. Analysis worksheets are used at the Instrument station to denote condition of extracts, file names, standards used, dilutions, etc, Compound Hals are the wllhln-lab reporting forms used by the analysts to record hits and perform calculations to determine concentrations ot compounds, Data Is transferred from compound lists to ERA forms (Organic Analysis Data Sheets), When secondary Ion calculations or other adjustments are necessary, these calculations are performed on separate pages and Included with the associated worksheets to document the calculation, 013312 88 HP • •' • • 4 CASE f ^^33 DATE DUE ft VOA WORKSHEET cotDuCnwi /^5^ imttx/'Z ; . St^)1t Frtp CiMlc 111 , * Initnment Code 236 ComundLItt M LOW LEVEL SOLID ,-. • Dellverihlts Code 069 SUIT Std List 383 ' Int Std Llit 002 DwHelrttFictw /./f U. • .. ••."•'! • •• •'_ i-sir • OMAf IT Dlikl Itt '" GC/NSAnilMt 653 i OTLotf /0?4? Shift A" Dite ^ld/y > i 1 . OTFIle ftpffVoa.OSCiS SUndirdi.Fllt "'^r$P ^o aO§ C/f : ' Blink flit- .... ; ^ • - .... . «T1Jr«*,.^.. .• •ta.mr... 1. 10 Ptik Siireh Rcqulrtd: ./ 2. < of Puks Found / 3. EPA. sign ChronlcUs (Inltlilt) V Cements: t j % ... •'•• ,.| .i.'/. "'.';,.. ..,* • " * •-:«-*'• Chtckritor AiAJB Olteo^/T^ ffi^i^W'"''.'^^^;.. ' •••«••'.' *m^^mm • >./»>,* *' • ' " •"••• '•'••'•• '" " Inltlitor Date i»o/i.7n i « • SURROGATE: l^- 1 1 ———— j 1 ——P POSTED |C3313 FEB i' m • u"3 CASE » £*R DUE DATE I / / R_3 j|H DD < :1) ft SEM1-VOLAT1LES «-o-./fcsB «!Q'2aD!Dl !" GC'/Ms HdrtksHEET sample Fep Code IZB instrument code ^40 compound List 97 LOM LEVEL SOLID surrogate std. 3B2 Deliverable Code - 069 internal std. List D33 (added by ec/ns) . . • SAS " EPA » .2<$GY"~ Vnpy'Ui1ght Factor /. /^ Blank Associated with Cases ___ COMMENTS: . ,v:i;; . ~Z$F' Original" GC/HS Analysis: ' -' Utrict1on"DaU% V1al Analyzed ____ BN Vol /DO ul Add Vol / Second 6C/MS Analysis: "P Dilution { :1) p Relnjectlon Sample Vol. Injected ul Standard Lot t DFTPP Lot f Standard File D1sk) DFTP(P File D1sk( ) OHAf DlskV Analyst \ Data - ' l--»-»^» •^•^^^•1 ^HH-.^-^ " T "**P/"^*" \ ""•"• "...... wwv,;.;--.- .- • 1. n Peak Search Results \ • „ .I^'K^H. , W>» Xsurrogatos:^ J^U Q 2.h>#-of Ptaks Found 4/V " .. . \\ •n.i«?^fl,'«ii»l!5l,AJ?I TaT" •!T7"^» •••M FilTBIlI '• iWmb «"'wh*^1 _• ' • ''c!T3g!;P": /J -:'.^^i^^-^S Initial Review ^ " Date ^A/*7 Final Review // Date.// ; ' CASEI .gffl? DATE DUE TCDD COMPUCHEH I. WORKSHEET Sample Prep Code 713 Instrument Code ??? Compound List 63 . LW LEVEL SOLID • 1. Surrogite Std. • _._._ Deliverable Code - 069 Internal Std. List . sas .- ••-—-- EPA jg^g"7~ Ory Height Factor —L Blink *ssodatedw1th Case __!___ ———_. .——— ——— —:—— COWENTS: "'.,-" .' ' ' v.,.*"'~ ." "•••••:' •'« ^i'-ti;. .'•'••- 'Ills, . .'.iWV*-:i •»,. Analysis...,„«..i Instrumentation Code . Instrument f —______*"Jl]yst '_LL r^f.,,. .Cal1britl9fl.SW. Lot I. Pass 2 Log Reference ___ ——— Cements: Area Count TCDD Surrogate Standard.——————— units Area Count Surrogate 1n Sample ——————_— U.:* ' .' '•••««• Recovery •' i//„-...,,-* t. <• • 'Checked By 'J——II—_•••.--•?——_ 013315 ' PESTICIDES COMPUCHEM « /^^P ' A WORKSHEET Sample Preo Codf 7}^ , wi Instrument Code iis Compound List 94 LOH LEVEL SOLID Surrogate Std. 36B Deliverable Code • 069 • .SAS IPAf/<35/<7 Dry Height Factor , \ . 15 Blink', Associated with Case ___ 1 ——— • ' —— ; — ——— ——— COH1EHTS: ..._._«., Sample Voium • Sample Preo Code < • Reagent Set ... ——— Technician Date Fieri si 1 Complete Final Volume I. 11. III...... ;„.. .. — .. . . ———— "Analfift, 3 Extracts Instrumentation Code • •. •'**!5!!.. ...'. - ^ tattfl^idf.^KST ....f. * ...... CTbritlon Standard Lot 1 _/*&£. ^^ •• t-p-^u^yw'ft',,'.! . •; . • . Date ' " " l.'Z/t/fa aMv _ ConroentS! bg Reference ' inII.. Checked by Dite. 013316 00^704 :jT- VOLATILE PHEP MK9EET * WQ ""llOQ ASSIGNED TO LILrs-~^ DATE I f' Swplo So«pl«i Prip OC Sorole Irtlght (gl Onto Scrnani Typ« Original Volum (ml) Com. UO S L M Common ti fjd.fl I MM •'*•'..•*'•' '/,/ 300d MM w30.1*m1 fltjjp •i".C fv.M. ,. t/ . .,1 . A Suirostt* Na^'^'/ -f Sehtduti Riftrtnc*. M AMint /^ ASSIGNED TO 'I"*—'-——————I M — PATE. So»plo SwpU Cno M Snmolo Might (g) Data Orlqlnal Voluna Iml Cone. LIOl 51 I Coimnti Ms/ 30.$ m/L r-_i__iBiac_l I / & |Hajj£/_^___ . tcMiUIMTMei—————ii±———013313— r—•Surrosrt* /rfii ^."f tJJA-x——' /———— Mwuil Cwmtw. I tot. WUTILE m? WKSHEO ,„ V0 J4 A55I6H5D TO lt"OT —— - ______DATE SMpIt Pre? CMC OC Saw lo Might (g) Pate Scraans Cod* No. Type Original Volum (ml) Com. IIP 5 L M Carmen t» 1\\ IfcrV IHll /Q.M iff IfiT-'f VM- tt* .f? .31 Surrojit* No.. ______Selmtuli Rif«r«ne« / 013^1 Vj . . Amount ______Hmuil Counttr **"* Lot 00470? f ^09 O f It -1! I \ I Wl K 5 •I w, Qt s? K b! IH sr M% 1) it 3; I VJN ! , *T^ ST f COMPUCHEM NO. _____ DATE ,______1 of 2 COMPOUND LIST NC. ————— ——— IDENTIFIER VOLATILES - LOH LEVEL SOLID QUAKT. • COMPOUND REPORT CORRECTION RESULTS DETECT!OK NUMBER COMPOUNDS VALUE x FACTOR « (ug/fcol CHLOROMETHANE ...... BROMOMETHANE ...... 'VINYL CHLORIDE ...... •CHLOROETHANE...... METHYLENE CHLORIDE ...... ACETONE ..;..;:...... „. , ACROLEIN ...... vACRYLONITRILE':...... ' TRICHLOROFLUOROMETHANE ... - CARBON D1SULFIDE ...... 1,1-DICHLOROETHYLENE ..... 1,1-DICHLOROETHANE ...... TRANS-1.2-DICHLOROETHYLENE 'CHCOROFOR • K ...... - "(pi.,. . •..".. . ' ...... «W^V^g^(j^TRltHLOROETHANE .... N TETRACHLORIDE 2li!'V''r" 257 'VINYL ACETATE ...... 1^-' 22._7"""Z12 • BROMODICHLOROMETHANE ..... 23.' . 217 1,2-DICHLOROPROPANE ...... 24,.—. 250 TRANS-1,3-DICH'.OROPROPENE. 25. 229 TRICHLOROETHYLENE ...... i 26. 203 BENZENE ...... 27. 228 1,1,2-TRlCHLOROETHANE .... 1 ""28VJylll/ '.• 216 CIS-1,3, D1CHLOROPROPENE.. 29. 20B" DIBROHOCHLOROMETHANE ...i. 30. . 210 CHLOROETHYLYINYL ETHER.... 1U^:^'"|05 IROHOFORM ' - "^'^ .;,.(• t'AUr, ,1, . ... j^( ..»»«;" i' • , ——————— ""."" ...... - '"~'HQNE '.iyiivffirttllil'll.i -••.tvi.. ^''..™ -W5 .^2-HEXANONE ...... •.".'.....s:?.:,..——_^!j^ 35. 223 . 1,1,2,2-TETRACHLOROETHANE. ___ PLEASE COMPLETE CORRECTION FACTOR CALCULATIONS ON SECOND SHEET OF \ COMPOUND LIST ND. ___ BmCHBt N°' ————— WTE - ———— « •" IDENTIFIER VOLAT1LES - LOW LEVEL SOLID QUANT. MOUTH 'X?™3 i.n,»n,,un, REPORT CORRECTION RESULTS DETECTION COUNTER NUMaER COMPOUNDS VALUE X FACTOR • (ufl/kq) LlCiTluo/Ice H- 36. 224 TETRACHLOROETHENE...... ____ L7.l''*l BE"- 2.5. 37. 225 TOLUENE. "~~~~~" 2.'5 38.. ,.VY 207 . CHLOROBENZENE. 2.5J 39,"'"V"'2l9 ETHYLBENZENE . 2.5 4iJ. 251 STYRENE...... 2.5 41. 239 COMPOUND SURROGATE REPORT AMOUNT •• ' •, RECOVERY NUMBER COMPOUNDS______VALUE SPIKED RECOVERY HINDO'*' 256 D4-l,2,DICHLOROETHANE (SURR) *••• 7. /O""'""' 10.0 V (50-150)* 233 D£-TOLUENE (SURR)...... ••"______10.0 /if (81-120) 247 BROMO'FLUOROBENZENE (SURR).. Htttf 10.0 //q (57-137)* ^|...... si-• t f Rieovery '''OuiPt. Report V»1ue i „_,.. ' wnour.t spued x *00« -! CORRECTION FACTOR CALCULATION: Instrument Code 238 10 9 Ver'"Ht; of sample used * Dilution Fictor x Dry Wight Fictor ; ,r-J!U——— , ,,-^ • ££1* l',V. * • ''••-, t' t " (' • - *','•• ' " •. * •' •>»' . •*,,' ;•' . >• t '•?§'!!!* '. jtf19824 oo/t? 12 COMPUCHEM NO. _____ DATE ,____ 1 of 3 COMPOUND LIST NO. ___ ————— —————— ——— IDENTIFIER SEM1-VOLATILE5 - LOH LEVEL SOLID QUANT. COMPOUND REPORT CORRECTION RESULTS DET. LIK'.T COUNTER NUMBER COMPOUNDS_____ VALUE K FACTOR x " (ug/kgl 2 441 N-NITROSOD1METHYLAMINE ..... 3 610 PHENOL ...... 4 . 473 ANILINE ...... ' 5 411 ;',ilS(2-CHLOROETHYL)ETHER .... 6 601 2-CHLOROPHENOL 7 421 . ... 1,3-DICHLOROBENZENE ...... 422 1,4-DICHLOROBENZENE ...... 10... 420 1,2-DICHLOROBENZENE 11 • .620 2-MOHYLPHENOL 12 412 BIS(2-CHLOROISOPRQPYL1ETHER 13 622 4-METHYLPHENOL .,,14 442 N-NITROSO-DI-N-PROPYLAMIHE 15 ..,,,,-.436,,..,.,....HEXACHLOROETHANE v\W;:r»-i* ...... ffW 606 .^^-NmOPHENOL "'20 603 ' 2,MiKETHYLPHENOL ...... fl 410 'B1S(2-CHLOROETHOXY)HETHANE . 22 . 625 BENZOIC ACID ...... 23 602 2,4-DICHLOROPHENOL 24 446 1,2,4-TRICHLOROBENZENE 25 439 NAPHTHALENE ...... 26 475 4-CHLOROANILINE 27 •: 434 HEXACHLOROBUT.ADIEHE 28 <••'108 P-CHLOM-M-CffSOL,.. 29 477 2-HETHYLMAPTHALEHE ...... '.'.."'____; 30, 435 .. *«XACHLOROCYCLOPENTA01ENE .. ; 611 35 479 • 3-NITROANILINE 36 425 OIKETHYLPHTHALATE 37 402 ACENAPHTHYLENE 38 428 tt,6-DINITROTOLUENE PLEASE COMPLETE CORRECTION FACTOR CALCULATIONS ON THIRD SHEET OF THE COMPOUND LIST!!! •W.1-, 00 ''.71.3 • jjg COMPUCHEM NO. _____ BATE ______t ur ; COMPOUND LIST NO. ____ ————— ~———— ———— ' IDENTIFIER SEM1-VOIAT1LES .. IOU LEVEL SOLID QUANT. COMPOUND REPORT CORRECTION RESULTS DET LIMIT . COUNTER NUMBER COMPOUNDS____ VALUE x FACTOR x • _(ug/kg) (ug/kg) 39 476 2-N1TROAN1LINE 40 401 ACENAPHTHENE ..... 41 605 2,4-DINITROPKENOL 42 . 607 4-NITROPHENOL ..... ft*"" 476 OIBENZOFURAN ...... i44 427 2.4-D1N1TROTOLUENE. 45 424 DIETHYLPKTHALATE ...... ,..,„ m^ .., 417 4-CHLOROPKENYL PHENYL ETHER...V.. 4f'"" 432" -FLUORENE 48 480 4-NITROANIL1NE 49 604 4,6-DINITRO-O-CRESOL SO 443 DIPHENYLAMINE (N-NITROSO) .,...., 51 430 1,2-DIPKENYLHYDRAZlNE (AZOBENZENE) .. 53 41* 4-BROMOPHENYL PHENYL ETHER 54 433 HEXACKLOROBENZENE 65 '.609 PEtnrACKLOWPKttOL. 57 403' ANTHRACENE 58 .._426 , OI-N-BUTYLPHTHALATE 59 ... .431 FLUORANTHENE 61 __4J5 PYRENE ...... 62 _104 BENZIOINE 63 ....._415 BUTYLBENZYLPHTHALATE 64 423 3,3'-DICHLOROBEKZIDlNE £5 . .4Q5 BENZOf A)ANTHRACENE •'•66 413 BISd-ETWLKEXYDPHTHALATE...... 67 418 'CHRYSENE .'...'.....".'; 18 429 OI-N-OCTTLPHTHALATE ____ _ 70 , 407 KNZOIB1FUIORAHTHEHE .....'..^;1t«^*i_-.;:. *«. •::_.4S7 HOENO(1,2,3-C,0)PTKNE 74 419 DIBENZO(A.H)ANTHRACENE 75 408 BENZOIG.H.DPERYLENE (See cilculitlons i?ld turrogitcs en bick) COMPUCHEM NO. _____DATE ______3 of 3 COMPOUND LIST NO. ____ ————— —————— ' ———— IDENTIFIER 5EMMOLATILES - LOM LEVEL SOLID " QUANT. QUANT. REPORT COMPOUND SURROGATE REPORT AMOUNT I tt ACCEPTABLE NUMBER COMPOUNDS VALUE SPIKED x RECOVERY RANGE ,.819 Z-FLUOROPHENOL 62 125 i T~R\ 41. (26-116) ••'•••«2 'lyWCNOL •••- 3? 125 f . 30 (10-104) 447 D^NITROBENZENE ff+ 125 f ^ (19-115) .446 2.FUIOROBIPHENYL 73'S...: 125 » Jf (17-125) TRIBROMOPHENOL (32-124 )• 496 DM-TERPHENYL .;,,.,.. 7Z- _____ i .Recovery • ———Quint—. Repor Migunt Vilui e CORRECTION FACTOR CALCULATION; '...Tlnil txtrictlen voluBtQiiU 50 o jftfff ''[ ' " Dilution Height 1*1 for Mid, o.6mi for BN x Met Height Extricttd.(g) x Factor x Fictor x _I . 509 , ..,,,.... __ i.u mo u.s ni • * • - * • |/^ t" QUANT. REPORT AMOUNT SPIKED CONVERSION FACTOR! 250 ul ' ^"'- FlnilI Eiitriet>o1. (al) ...... Mount surrogits Aootd lui l * lul for Mid, 0.5*1 Tor IN JJ^fKtor • YW-«?:.»:•' "J' ""' I ..'.'^''vi^-.i' •For Advisory Purposes Only 013327 JRT 11/83 TCDD 069 Diagnostics FAiwiamt TC019558B04 ft Diagnostic VaJLut Paw/Fail 320/32S ratio; Surrogit* (0, 60 - 0. 94) 0. 81 Pass . (0. 67 - 8. 87) ' • ..•.. .. . An«lgt'« •ltrt«->;i|iiitthin 3 »can« at ... •can* from Xntirnal ilandard: Pa«» ' w;:".. ' 013328 fWlB. *9 ' ' TCDD Low Lsvsl Solid Filsnama: TC01955BB04 CompuChsm No, -££££._ Oats 02/13/B4 _Sampln: 2/50 uL MIZZ 19558 Compound Compound Quant Rsport * Correction - Result Detection Limit ~ No. Valus . Factor . (ug/kg) ;.*'.:: v (ugAg) •>,. -;. . .-:«., '. •*""" ..v*t' '**"••••<•. &,.. 469 S378-TCDD 0.74 0.0080 SOU' 1036 (0,160) , .., ...... »,. . . -tCDD••--• ) R«cov«r•• y • (Ant wMsuriid'/t tm'i' I 'ipihtd) * 109•X RBCQVWU • 19. SSX,;,^;.;^.',; vol (•WB/' 0. 1 ml) t (3a; g,,/ A«f iwtract«d) » 0. 060 Factor "9.9999 ' •'• " , ."jir»i»w»»w.sni.(:, . nuj*V«.'- ...*•.., " ''- " "' '':V-?<:- ' • NottirrT1iP4<-,.ttl*,-.'.K- 16•.0 dsttctio•. ... n limit is ths- opti«al (100% rscovsry. ) dstsction Limit. . ; ,.,.;, :Th«,Tr836. dsttction limit is th« rBCttysf.u-corrsciL» ( , l.ff>^-!fe,v>;1^^^^^ 013323 COMPUCHEH NO.______"DATE IDENTIFIER PESTICIDES (LOH LEVEL-SOLID) COMPOUND LIST . NO. ____ COMPUCHEM '••••• COMPOUND COUNTER JIJMBER COMPOUND NAME_____ RESULT DETECTION LIMIT (ugAg) 1. 0701 ALDRIN ...... —— 4.0 ? ALPHAvRHC 9. 0709 4,4'-DOD ————" 10. 0710 OIELORIN —— •——•—>., *«0 11. ":'b711 ALPHA-ENDOSllFAN -••••— 4.0 .:., t-ftiBriiTnr ••^•; '•niniiiiiiii '^•'•'•IN 0716 HEPTACHLOR..- . . ,..,.,,,. -.««,,-„. :.i.' .. COMPOUND SURROGATE I RECOVER?, '••- ,,AMOUNT * NUMBER COMPOUNDS .»-»-.•• RESULT SPIKED RECOVERY . . 0738 DIBUTYL CHLORENDATE (4U211* •Advliory L1»1t UC LABQKA10KY 'ase *.-&*3 en* , •"' EXTRACTION XNFQRflAnCW . .. Wt. OP vol. of sa/nple . SO "**^ "v ••-•• • •" i. ^..portion of wt. or voJl in p«st/harb '' '"' '- c»,rrgcT i on f ac TOP /- VOlUM* Of dilution factors for run pun ,<'OP pun # fOP PUP * 'n "'*