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The Layered Mafic-Ultramafic Complexes of the Tocantins State, Central : Recently Discovered Large Proterozoic Intrusions with Favorable Potential to Host PGE Deposits

Cesar F. Ferreira Filho1, Humberto A. F. Lima1, Elton L. Dantas1, Walid El K. Daoud2 and Jade Salomão Neto2 1Instituto de Geociências, Universidade de Brasília, Brasília, DF, 70910-900, Brazil. 2Verena Minerals Corporation, SCS, Ed. Central, sala 207, Brasília, DF, 70304-900. e-mail: [email protected]

Introduction Neoproterozoic tectonized granites (Quaresma and Magmatic Ni-Cu-PGE deposits can be Kotschoubey, 2001) indicate the importance of the grouped into two major types (Naldrett et al., 1989; Brasiliano magmatic-tectonic-metamorphic event in 1999), those that are mined primarily because of the region. Geochronological data for the layered their contained Ni and Cu, and those mined complexes are so far restricted to Pb-Pb zircon primarily because of their PGE content. While the dating of the Carreira Comprida Anorthosite first group encompasses several deposits formed at (Gorayeb and Moura, 2001), suggesting a 2,071 ± 4 distinct environments, including volcanic- My age for the magmatism. associated deposits, deposits located at the base or The geochronology and tectonic setting of the at feeder conduits of layered intrusions, and mafic and mafic-ultramafic layered intrusions are deposits associated to extra-terrestrial impact; still poorly constrained. The overall tectonic world-class PGE deposits are restricted to large scenario of large metamorphosed and tectonized Archean to Paleoproterozoic layered intrusions layered intrusions within the Brasiliano belt closely emplaced into stable tectonic terranes (Bushveld, resembles what is described for the large layered Great Dyke, Stillwater). Large layered intrusions complexes in central Brazil, the Niquelândia, Barro and/or areas where clusters of several layered Alto and Canabrava complexes located 500 km to intrusions occur represent thus prospective targets the South (Ferreira Filho, 1998; Ferreira Filho and for PGE deposits. This paper describes for the first Pimentel, 2000; Pimentel et al., 2000). However, time the geology of several large Proterozoic any attempt to correlate these two groups of layered layered intrusions in the Tocantins State, central complexes is hampered by the lack of geo- Brazil (Fig. 1). chronological and petrological data for the layered complexes of the Tocantins State. Regional Geology The studied layered mafic and mafic- The Layered Intrusions ultramafic intrusions are located at the Tocantins The layered mafic and mafic-ultramafic Province, which represents a large Brasiliano intrusions of the Tocantins State are assigned to (Neoproterozoic) orogen formed between the São three groups on the basis of rock types, assemblage Francisco and Amazonian cratons (Fig. 1). The of cumulus minerals, geophysical anomalies and layered intrusions occur at the northern part of the regional field association (Table 1). Brasília belt (Pimentel et al., 2000), an area of The Carreira Comprida Anorthosite (Fig. poorly exposed Precambrian terranes which are 1) includes a large area (Table 1) of predominantly partially covered by Phanerozoic sediments. Mafic plagioclase and ilmenite-magnetite cumulate rocks. and mafic-ultramafic intrusions were discovered The structure and magmatic stratigraphy of the and delineated during an exploration program Carreira Comprida Anorthosite are unconstrained developed by Verena Minerals Corporation, due to poor exposition. Coarse-grained anorthosite, including airborne geophysics and drilling. They a plagioclase and magnetite-ilmenite cumulate with consist of elongated bodies oriented parallel to the postcumulus Ca-rich clinopyroxene and quartz, is NE regional trend, forming a 120 km-long array the most frequent rock type. Interlayered which disappears under the Paleozoic-Mesozoic gabbronorite, olivine norite, leucotroctolite and Parnaíba Basin (Fig. 1). The metamorphosed and anorthosite occur at the Crixás river section of the tectonized layered intrusions are mainly hosted by layered body. Accessory phases, including cumulus metamorphic volcanic-sedimentary sequences to apatite and intercumulus quartz, indicate extensive the West and by high-grade terranes of the Porto fractionation of the mafic magma. Olivine Nacional Complex to the East. Several compositions range from moderately forsteritic (up to Fo 69) for the olivine + plagioclase cumulates, to foliation and pervasive metamorphic recrystal- highly fayalitic (Fo 11) for olivine + plagioclase + lization. Metamorphic assemblages indicate that pigeonite + apatite cumulates. The primary peak metamorphism reached the granulite facies of cumulates are variably transformed into metamorphism. metamorphic equivalents characterized by tectonic

Figure 1. Geology of the region, Tocantins State.

Table 1. Mafic and mafic-ultramafic intrusions of the Tocantins State.

Intrusion/Group Areal Extent Major Rock Types Cumulate Assemblage Olivine (for each intrusion) (for the whole Group) (for the whole Group)

Group 1 Carreira Comprida 85 x 10 km Anothosite, Gabbro, Pl; Pl+Ol,; Pl+Ol+Pig Fo = 11-69 Leuco-troctolite, Pl + Ol + Pig + Ap Ni = < 850 ppm Gabbronorite

Group 2 VE3 10 x 0.8 km Wherlite; Gabbro Ol+Cpx±Chr; Fo = 84-86 7.5 x 2.5 km Clinopyroxenite; Cpx ; Cpx+Pl Ni = 600-1300 ppm São Domingos 26 x 3 km

Group 3 Intrusion A 14 x 3.5 km Metabasites No magmatic silicates Intrusion B 5 x 1.8 km preserved. Pl = plagioclase; Ol = olivine; Pig = pigeonite; Ap = apatite; Chr = chromite.

The VE3, Monte do Carmo and São significant ultramafic componenent, are mainly Domingos mafic-ultramafic complexes (Fig. 1 and contemplated for the layered complexes at the Table 1) consist of a high proportion of ultramafic Tocantins State. This discovery provides an to mafic rocks. These intrusions are poorly exposed additional target for PGE exploration in Brazil. but well delineated by significant geophysical anomalies. Drilling at the southern part of the VE3 References body intercepted several hundred meters of Ferreira Filho, C.F., 1998, Geology and petrology interlayered wherlite (olivine + clinopyroxene ± of the large layered intrusions of central chromite cumulates), clinopyroxenite (cpx Brazil, implications for PGE cumulates) and gabbro (cpx + plagioclase mineralizations, In: 8th International cumulates). Olivine compositions are quite Platinum Symposium, The Geological forsteritic (up to Fo 86) for olivine + clinopyroxene Society of South Africa, Extended cumulates drilled at the VE3 body. Similar rock Abstracts Volume, p. 107-110. types outcrop at the Monte do Carmo complex. The Ferreira Filho, C.F., and Pimentel, M. M., 2000, rocks are variably transformed into foliated Sm-Nd isotope systematics and REE data metamorphic equivalents (talc-tremolite serpent- of troctolites and their metamorphic tinite, talc-serpentine tremolitite, hornblendite, equivalents of the Niquelândia Complex, amphibolite) characterized by pervasive central Brazil: further constraints for the metamorphic recrystallization at the amphibolite timing of magmatism and metamorphism: facies of metamorphism. Journal of South American Earth Sciences, Poorly exposed gabbroic intrusions v. 13, p. 647-659. (Intrusions A and B of Fig. 1 and Table 1) occur at Gorayeb, P.S.S. and Moura, C.A.V., 2001, the eastern part of the NE trend of layered Aspectos geológicos e geocronológicos do complexes. These intrrusions consist mainly of anortosito Carreira Comprida, região de recrystallized mafic rocks and have distinct Porto Nacional, TO: In: 7th Simpósio de geophysical features when compared to the mafic- Geologia da Amazônia, Belém-PA, ultramafic complexes. Resumos Expandidos, CD-ROM. Naldrett, A.J., 1989, Magmatic Sulfide Deposits: Conclusions Oxford University Press, New York, 186 The mafic and mafic-ultramafic layered p. complexes of Tocantins represent one of the most Naldrett, A.J., 1999, World-class Ni-Cu-PGE extensive igneous association of their type in deposits: key factors in their genesis: Brazil. Broad generalizations about layered Mineralium Deposita, v. 34, p. 227-240. intrusions hosting significant PGE deposits, such as Pimentel, M.M., Fuck, R.A., Jost, H., Ferreira Archean or Paleoproterozoic age, emplacement into Filho, C.F., and Araujo, S.M., 2000, The stable tectonic terranes, large areal extent and Basement of the Brasília Fold Belt and the Goiás Magmatic Arc: In: Tectonic Quaresma, E.C., and Kotschoubey, B., 2001, Evolution of South America, H.G. Granito Arueira, região de Porto Nacional, Cordani, Milani, E.J., Thomaz Filho, A. & TO: testemunho de granitogênese Campos, D.A. (eds.), , 31st brasiliana: In: 7th Simpósio de Geologia da International Geological Congress, p. 195- Amazônia, Belém-PA, Resumos 229. Expandidos, CD-ROM.