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HASA OXIDIZER Safety Data Sheet (SDS No

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HASA OXIDIZER Safety Data Sheet (SDS No Safety Data Sheet (SDS No. 214) HASA OXIDIZER HASA OXIDIZER Safety Data Sheet Emergency 24 Hour Telephone: CHEMTREC 800.424.9300 Corporate Headquarters: Hasa Inc. P. O. Box 802736 Santa Clarita, CA 91355 Telephone 661.259.5848 Fax 661.259.1538 SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 1.1 Product Identification : 1.1.1 Product Name : Hasa Oxidizer 1.1.2 CAS # : (Chemical Abstracts This product is a mixture of Oxone® and other Service) ingredients. The active ingredient of Oxone® is potassium peroxymonosulfate, KHSO 5 [CAS 10058-23- 8], commonly known as potassium monopersulfate, which is present as a component of a triple salt with the formula 2KHSO 5·KHSO 4·K 2SO 4 (potassium hydrogen peroxymonsulfate sulfate (5:3:2:2), [CAS 70693-62-8]). 1.1.3 RTECS : (Registry of Toxic Not available. Effects of Chemical Substances) 1.1.4 EINECS : (European Inventory Not available. of Existing Chemical Substances) 1.1.5 Synonym : Oxone® (DuPont™), Potassium Monopersulfate (MPS), Potassium Peroxymonosulfate. 1.1.6 Chemical Name : Potassium Peroxymonosulfate Sulfate 1.1.7 Chemical Formula : 2KHSO 5·KHSO 4·K 2SO 4 1.2 Recommended Use : Pool and spa shock oxidizer. 1.3 Company Identification : Hasa Inc. P. O. Box 802736 Santa Clarita, CA 91355 1.4 Emergency Telephone Number : CHEMTREC : 1-800-424-9300 (24 hour) 1.5 Non -Emer gency Assistance : 661-259-5848 (8 AM – 5 PM PST / PDT) Revision Date: 06/01/2015 (Supersedes previous revisions) Page 1 of 10 SECTION 2: HAZARD(S) IDENTIFICATION Safety Data Sheet (SDS No. 214) HASA Health Hazard Skin Corrosion/Irritation Category 1 Acute Toxicity (oral) Category 4 Symbol OXIDIZER Signal Word WARNING Causes severe skin burn and eye damage. Hazard Statements Harmful if swallowed. Precautionary Prevention Statements Do not breathe dusts or mists. Wash hands thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Do not eat, drink or smoke when using this product. Response IF SWALLOWED : Rinse mouth. Do NOT induce vomiting. Call a Poison Center or doctor if you feel unwell. IF ON SKIN (OR HAIR) : Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. IF INHALED : Remove person to fresh air and keep comfortable for breathing. Immediately call a Poison Center or doctor. IF IN EYES : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Storage Store locked up. Disposal Dispose of contents/container in accordance with local / regional / national / international regulations. SECTION 3: COMPOSITION INFORMATION ON INGREDIENTS Ingredient Formula CAS No. Weight % 3.1 Potassium Peroxymonosulfate KHSO 5 10058-23-8 43.0 3.2 Potassium Bisulfate KHSO 4 7646-93-7 23.0 3.3 Potassium Sulfate K2SO 4 7778-80-5 29.0 3.4 Potassium Peroxydisulfate K2S2O8 7727-21-1 3.0 3.5 Magnesium Carbonate MgCO 3 546-93-0 2.0 Revision Date: 06/01/2015 (Supersedes previous revisions) Page 2 of 10 SECTION 4: FIRST AID MEASURES Safety Data Sheet (SDS No. 214) HASA 4.1 IF IN EYES • Hold eye open and rinse slowly and gently with water for 15-20 minutes. • Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. • Call a poison control center or doctor for treatment advice. OXIDIZER 4.2 IF ON SKIN OR • Take off contaminated clothing. CLOTHING • Rinse skin immediately with plenty of water for 15-20 minutes. • Call a poison control center or doctor for treatment advice. 4.3 IF INHALED • Move person to fresh air. • If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. • Call a poison control center or doctor for further treatment advice. 4.4 IF SWALLOWED • Call a poison control center or doctor immediately for treatment advice. • Have person sip a glass of water if able to swallow. • Do not induce vomiting unless told to do so by a poison control center or doctor. • Do not give anything by mouth to an unconscious person. HOT LINE NUMBER Have the product container or label with you when calling a poison control center or doctor, or going for treatment. You may also contact 1-800-424-9300 for emergency medical treatment information. NOTE TO PHYSICIAN Probable mucosal damage may contraindicate the use of gastric lavage. SECTION 5: FIRE FIGHTING MEASURES 5.1 Flammable Limits: Nonflammable and noncombustible. 5.2 Flash Point: Will not flash. 5.3 Fire & Explosio n Improper storage of large masses of Oxone® can trap heat and Hazards: lead to ignition of combustibles (See section on "Handling and Storage"). Grinding or intensive mixing may cause decomposition with liberation of heat and oxygen; ignition of oxidizable material if present may occur. 5.4 Extinguishing Media: Water. DO NOT use carbon dioxide or other gas containing extinguishers. 5.5 Products of Combustion: Oxygen. 5.6 Fire Fighting Will release oxygen when heated, intensifying a fire. Acidic mist Instructions: may be present; self contained breathing apparatus should be used. 5.7 Fire and Explosion Improper storage of large masses of this product can trap heat Hazards: and lead to ignition of combustibles (See section on "Handling and Storage"). Grinding or intensive mixing may cause decomposition with liberation of heat and oxygen; ignition of oxidizable material if present may occur. Revision Date: 06/01/2015 (Supersedes previous revisions) Page 3 of 10 SECTION 6: ACCIDENTAL RELEASE MEASURES Safety Data Sheet (SDS No. 214) HASA 6.1 Safeguards Review FIRE FIGHTING MEASURES (Section 5) and HANDLING (Personnel): AND STORAGE (Section 7.1) before proceeding with clean-up. Use appropriate Personal Protective Equipment during clean-up. 6.2 Spills: Sweep up. Place in plastic bag for disposal. Flush area with low OXIDIZER pressure water. If necessary, neutralize with soda ash. 6.3 Prec autions: Will release oxygen when heated, intensifying a fire. Acidic mist may be present; self contained breathing apparatus should be used. 6.4 Disposal: See Section 13. SECTION 7: HANDLING AND STORAGE 7.1 Handling: Do not inhale. Do not get in eyes, on skin or clothing. Wash thoroughly after handling. Wash clothing after use. 7.2 Storage: This product should be stored in cool, dry areas, away from combustible materials, incompatible chemicals (Section 10.4), and sources of heat such as space heaters and light fixtures. Prolonged storage at ambient temperatures greater than 32°C (90°F) should be avoided. Oxone® decomposition will be accelerated on contact with moisture. Product packaging includes a water-resistant liner, but storage conditions should also include provisions for prevention of contact with water, including high airborne humidity. Pallets of 25 kg bags can be stacked. Leave open space on all sides of each pallet to provide ventilation. See local fire codes for allowable limits. Bulk bags should be stored on pallets. If stacked use pyramid style, no more than 2 pallets high. Closely stacked bags should not exceed a 4 ft. (1.2 m) cube. Keep packages dry. Revision Date: 06/01/2015 (Supersedes previous revisions) Page 4 of 10 SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION Safety Data Sheet (SDS No. 214) HASA 8.1 Engineering Controls: Use sufficient ventilation to keep employee exposure below recommended limits. 8.2 Personal Protection: OXIDIZER 8.2.1 Eye / Face : Wear safety glasses or coverall chemical splash goggles. 8.2.2 Inhalation: A NIOSH approved air-purifying respirator with an appropriate particulate cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air-purifying respirators is limited. Use a positive pressure air-supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying respirators may not provide adequate protection. 8.2.3 Skin: Where there is potential for skin contact, wear impervious clothing such as gloves, apron, boots or whole bodysuit. 8.3 Exposure Guidelines : Ingredient OSHA PEL ACGIH (American Conference (Permissible Exposure Limit) of Governmental and Industrial Hygienists) TLV (Threshold Limit Value) 8.3.1 Oxone® PNOR (Particulates Not Otherwise None Established. Monopersulfate Regulated): Compound: 15 mg/m³, 8 hr, TWA, Total Dust 5 mg/m³, 8 hr, TWA, Respirable Dust 8.3.2 Potassium PNOR : None Established. Sulfate: 15 mg/m³, Total Dust, 8 hr, TWA 5 mg/m³, Respirable Dust, 8 hr, TWA 8.3.3 Potassium PNOR : 0.1 mg/m³, 8 hr, TWA Peroxydisulfate: 15 mg/m³, Total Dust, 8 hr, TWA 5 mg/m³, Respirable Dust, 8 hr, TWA 8.3.4 Magnesium PNOR : 10 mg/m³, Total Dust, 8 hr, TWA Carbonate: 15 mg/m³, Total Dust, 8 hr, TWA 5 mg/m³, Respirable Dust, 8 hr, TWA Revision Date: 06/01/2015 (Supersedes previous revisions) Page 5 of 10 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Safety Data Sheet (SDS No. 214) HASA 9.1 Appearance : White, free flowing granules. 9.2 Odor: Odorless. 9.3 Odor Threshold: Odorless. 9.4 pH: 2.3 (1% of unblended "OXONE®” solution) OXIDIZER 9.5 Melting Point: Decomposes. 9.6 Freezing point : Not pertinent. 9.7 Boiling Point & Boiling Range : Not pertinent. 9.8 Flash Point : No information available. 9.9 Evaporation Rate: No information available. 9.10 Flammability (solid, gas) : Not flammable. 9.11 Upper / Lower Flammability or No information available. Explosive Limits: 9.12 Vapor Pressure : Not pertinent. 9.13 Vapor Density: Not volatile. 3 3 9.14 Bulk Density: 1100 – 1400 kg/m (69 – 87 lb/ft ). 9.15 Specific Gravity: (H 2O=1) Not pertinent. 9.16 Solubility in Water: 25.6 g /100 mL water @ 20 OC (68 OF) (for unblended "OXONE®”) 9.17 Partition Coefficient: (n-octanol / log Pow: <0.3 at 20°C water): 9.18 Auto -ignition Temperature : No information available.
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