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Xrd and Tem Studies on Nanophase Manganese
Clays and Clay Minerals, Vol. 64, No. 5, 488–501, 2016. 1 1 2 2 3 XRD AND TEM STUDIES ON NANOPHASE MANGANESE OXIDES IN 3 4 FRESHWATER FERROMANGANESE NODULES FROM GREEN BAY, 4 5 5 6 LAKE MICHIGAN 6 7 7 8 8 S EUNGYEOL L EE AND H UIFANG X U* 9 9 NASA Astrobiology Institute, Department of Geoscience, University of Wisconsin Madison, Madison, 10 À 10 1215 West Dayton Street, A352 Weeks Hall, Wisconsin 53706 11 11 12 12 13 Abstract—Freshwater ferromanganese nodules (FFN) from Green Bay, Lake Michigan have been 13 14 investigated by X-ray powder diffraction (XRD), micro X-ray fluorescence (XRF), scanning electron 14 microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), and scanning 15 transmission electron microscopy (STEM). The samples can be divided into three types: Mn-rich 15 16 nodules, Fe-Mn nodules, and Fe-rich nodules. The manganese-bearing phases are todorokite, birnessite, 16 17 and buserite. The iron-bearing phases are feroxyhyte, goethite, 2-line ferrihydrite, and proto-goethite 17 18 (intermediate phase between feroxyhyte and goethite). The XRD patterns from a nodule cross section 18 19 suggest the transformation of birnessite to todorokite. The TEM-EDS spectra show that todorokite is 19 associated with Ba, Co, Ni, and Zn; birnessite is associated with Ca and Na; and buserite is associated with 20 2+ +2 3+ 20 Ca. The todorokite has an average chemical formula of Ba0.28(Zn0.14Co0.05 21 2+ 4+ 3+ 3+ 3+ 2+ 21 Ni0.02)(Mn4.99Mn0.82Fe0.12Co0.05Ni0.02)O12·nH2O. -
Redalyc.Mineralogical Study of the La Hueca Cretaceous Iron-Manganese
Revista Mexicana de Ciencias Geológicas ISSN: 1026-8774 [email protected] Universidad Nacional Autónoma de México México Corona Esquivel, Rodolfo; Ortega Gutiérrez, Fernando; Reyes Salas, Margarita; Lozano Santacruz, Rufino; Miranda Gasca, Miguel Angel Mineralogical study of the La Hueca Cretaceous Iron-Manganese deposit, Michoacán, south-western Mexico Revista Mexicana de Ciencias Geológicas, vol. 17, núm. 2, 2000, pp. 142-151 Universidad Nacional Autónoma de México Querétaro, México Available in: http://www.redalyc.org/articulo.oa?id=57217206 How to cite Complete issue Scientific Information System More information about this article Network of Scientific Journals from Latin America, the Caribbean, Spain and Portugal Journal's homepage in redalyc.org Non-profit academic project, developed under the open access initiative Revista Mexicana de Ciencias Geológicas, volumen 17, número 2, 143 2000, p. 143- 153 Universidad Nacional Autónoma de México, Instituto de Geología, México, D.F MINERALOGICAL STUDY OF THE LA HUECA CRETACEOUS IRON- MANGANESE DEPOSIT, MICHOACÁN, SOUTHWESTERN MEXICO Rodolfo Corona-Esquivel1, Fernando Ortega-Gutiérrez1, Margarita Reyes-Salas1, Rufino Lozano-Santacruz1, and Miguel Angel Miranda-Gasca2 ABSTRACT In this work we describe for the first time the mineralogy and very briefly the possible origin of a banded Fe-Mn deposit associated with a Cretaceous volcanosedimentary sequence of the southern Guerrero terrane, near the sulfide massive volcanogenic deposit of La Minita. The deposit is confined within a felsic tuff unit; about 10 meters thick where sampled for chemical analysis. Using XRF, EDS and XRD techniques, we found besides todorokite, cryptomelane, quartz, romanechite (psilomelane), birnessite, illite-muscovite, cristobalite, chlorite, barite, halloysite, woodruffite, nacrite or kaolinite, and possibly hollandite-ferrian, as well as an amorphous material and two unknown manganese phases. -
Metamorphism of Sedimentary Manganese Deposits
Acta Mineralogica-Petrographica, Szeged, XX/2, 325—336, 1972. METAMORPHISM OF SEDIMENTARY MANGANESE DEPOSITS SUPRIYA ROY ABSTRACT: Metamorphosed sedimentary deposits of manganese occur extensively in India, Brazil, U. S. A., Australia, New Zealand, U. S. S. R., West and South West Africa, Madagascar and Japan. Different mineral-assemblages have been recorded from these deposits which may be classi- fied into oxide, carbonate, silicate and silicate-carbonate formations. The oxide formations are represented by lower oxides (braunite, bixbyite, hollandite, hausmannite, jacobsite, vredenburgite •etc.), the carbonate formations by rhodochrosite, kutnahorite, manganoan calcite etc., the silicate formations by spessartite, rhodonite, manganiferous amphiboles and pyroxenes, manganophyllite, piedmontite etc. and the silicate-carbonate formations by rhodochrosite, rhodonite, tephroite, spessartite etc. Pétrographie and phase-equilibia data indicate that the original bulk composition in the sediments, the reactions during metamorphism (contact and regional and the variations and effect of 02, C02, etc. with rise of temperature, control the mineralogy of the metamorphosed manga- nese formations. The general trend of formation and transformation of mineral phases in oxide, carbonate, silicate and silicate-carbonate formations during regional and contact metamorphism has, thus, been established. Sedimentary manganese formations, later modified by regional or contact metamorphism, have been reported from different parts of the world. The most important among such deposits occur in India, Brazil, U.S.A., U.S.S.R., Ghana, South and South West Africa, Madagascar, Australia, New Zealand, Great Britain, Japan etc. An attempt will be made to summarize the pertinent data on these metamorphosed sedimentary formations so as to establish the role of original bulk composition of the sediments, transformation and reaction of phases at ele- vated temperature and varying oxygen and carbon dioxide fugacities in determin- ing the mineral assemblages in these deposits. -
Washington State Minerals Checklist
Division of Geology and Earth Resources MS 47007; Olympia, WA 98504-7007 Washington State 360-902-1450; 360-902-1785 fax E-mail: [email protected] Website: http://www.dnr.wa.gov/geology Minerals Checklist Note: Mineral names in parentheses are the preferred species names. Compiled by Raymond Lasmanis o Acanthite o Arsenopalladinite o Bustamite o Clinohumite o Enstatite o Harmotome o Actinolite o Arsenopyrite o Bytownite o Clinoptilolite o Epidesmine (Stilbite) o Hastingsite o Adularia o Arsenosulvanite (Plagioclase) o Clinozoisite o Epidote o Hausmannite (Orthoclase) o Arsenpolybasite o Cairngorm (Quartz) o Cobaltite o Epistilbite o Hedenbergite o Aegirine o Astrophyllite o Calamine o Cochromite o Epsomite o Hedleyite o Aenigmatite o Atacamite (Hemimorphite) o Coffinite o Erionite o Hematite o Aeschynite o Atokite o Calaverite o Columbite o Erythrite o Hemimorphite o Agardite-Y o Augite o Calciohilairite (Ferrocolumbite) o Euchroite o Hercynite o Agate (Quartz) o Aurostibite o Calcite, see also o Conichalcite o Euxenite o Hessite o Aguilarite o Austinite Manganocalcite o Connellite o Euxenite-Y o Heulandite o Aktashite o Onyx o Copiapite o o Autunite o Fairchildite Hexahydrite o Alabandite o Caledonite o Copper o o Awaruite o Famatinite Hibschite o Albite o Cancrinite o Copper-zinc o o Axinite group o Fayalite Hillebrandite o Algodonite o Carnelian (Quartz) o Coquandite o o Azurite o Feldspar group Hisingerite o Allanite o Cassiterite o Cordierite o o Barite o Ferberite Hongshiite o Allanite-Ce o Catapleiite o Corrensite o o Bastnäsite -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Geology and Ore Deposits of the Central York Mountains, Western Seward Peninsula, Alaska
Geology and Ore Deposits of p50 the Central York Mountains, I Western Seward Peninsula, S3 Alaska GEOLOGICAL SURVEY BULLETIN 1287 O GC oc O es ^ HI » <=; HI i i QC GO eea 00 Geology and Ore Deposits of the Central York Mountains, Western Seward Peninsula, Alaska By C. L. SAINSBURY GEOLOGICAL SURVEY BULLETIN 1287 Description of the geologic structure, stratigraphy, petrology, and ore deposits of an area containing tin deposits and a new type of beryllium deposit UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1969 UNITED STATES DEPARTMENT OF THE INTERIOR WALTER J. HICKEL, Secretary GEOLOGICAL SURVEY William T. Pecora, Director Library, of Congress catalog-card No, 78-602244 For sale by the Superintendent of Documents, U.S. Government Printing Office Washington, D.C. 20402 - Price $3.00 (paper cover) CONTENTS Page Abstract_ _______________________________________________________ l Introduction__________-__-_-______--__---------____________--_--__ 2 Location_ ___________________________________________________ 2 Purpose and scope of report_._--___-----_--____-________-_-_-_ 3 Methods of study__________-_---___--_--_-_.________._----___ 4 Acknowledgments __________-_-__----___---_______l______--____ 4 Previous work_____-__-__-----_-________--___________---____- 5 Sedimentary rocks._________-____-_-_____-___-_-___________----_-__ 6 Pre-Ordovician rocks___________________________________________ 7 Slate of the York region-____________________________________ 7 Argillaceous and dolomitic limestone.___--___-_______-----___ 9 Undifferentiated limestone and argillaceous and dolomitic lime stone_ ________________________________________________ 10 Summary of pre-Ordovician rocks_______-_-__________------_ 11 Lower Ordovician rocks.____-___-_--_____---__________-___--_-_ 12 Argillaceous limestone and limestone (shallow-water facies) _ _ _. -
Study of the Structure Model of Todorokite
Title Study of the Structure Model of Todorokite Author(s) Miura, Hiroyuki Citation 北海道大学理学部紀要, 23(1), 41-51 Issue Date 1991-07 Doc URL http://hdl.handle.net/2115/36772 Type bulletin (article) File Information 23-1_p41-51.pdf Instructions for use Hokkaido University Collection of Scholarly and Academic Papers : HUSCAP Jour. Fac. Sci., Hokkaido Univ., Ser. IV, vol. 23, no. 1, July., 1991, pp. 41 -51 STUDY OF THE STRUCTURE MODEL OF TODOROKITE by Hiroyuki Miura (with 5 text-figures and 3 tables) Abstract The X - ray diffraction study of todorokite from Japan was carried out and appropriate struc tural model was calculated by Rietveld method. The calculation of the theoretical diffraction pattern was done for a layer structural model and the calculated results show that the layer model can explain the observed diffraction data. Some of the properties of todorokite such as superstructure or shrinkage of c-axis on heating can be explained by the layer model which con tains random H 20 between the [MnOs] layers. Introduction Todorokite is a manganese oxide mineral having H 20 in its structure. It was reported first from the Todoroki gold mine, Hokkaido, Japan (Yoshimura, 1934) . This mineral occurs as aggregate of fine acicular crystals. It also contains H20, Ca, Ba and Mg. The X -ray powder diffraction data of todorokite clearly show diffraction peaks of 9.6, 4.8, 3.2, 2.45 and 1.42 A. Since 1934 there has been many reports of todorokite like minerals from all over the world (Frondel, 1953; Frondel et aI. , 1960; Ljunggren, 1960; Straczek et aI., 1960; Faulring, 1961 ; Larson, 1962; Radtke et aI., 1967; Lawrence et aI., 1968; Harada, 1982; Siegel and Turner, 1983) . -
Todorokite and Pyrolusite from Vermlands Taberg
NOTES AND NEWS THE AMERICAN MINERALOGIST, VOL. 45, JANUARY_FEBRUARY, 1960 TODOROKITE AND PYROLUSITEFROM VERMLANDS TABERG, SWEDEN Poxrus L;uNccnnN, Unioersity oJ Lund,, Lund., Swed.en During the courseof an examination of the soft iron ore of Vermlands Taberg in western Sweden (P. Ljunggren, 1958) manganesemineraliza- tion was found to have taken place both in the goethitized iron ore and in the argillized wall-rock. The manganeseoxides are found as veins in the soft iron ore, as impregnations in the argillized wall-rock and in secondary calcite veins. A formation of dendrites of manganeseoxides is also very common. This rnanganesemineralization is mainly concen- trated to the border zone between the soft iron ore and the argillized skarn and leptite rocks. The width of the manganiferous veins hitherto found, often less than ten centimetres, is too small to allow any pro- fitable mining of manganeseore. The quite predominating manganeseoxide mineral in these veins is pyrolusite. In a secondary calcite vein cutting the soft iron ore another manganese oxide mineral was found and identified as todorokite (T. Yoshimura, 1934; C. Frondel, 1953).An examination of the pyrolusite and the todorokite is given in the present paper. Tooonoxtrs The todorokite is found as black aggregatesin a 5 cm. wide secondary calcite vein in the soft iron ore. The aggregatesconsist of small needle- shapedcrystals (maximum size0.2X0.01 mm.) arrangedspherulitically or dendritically in the calcite vein. The mineral was found upon ,-ray examination to be identical with todorokite (Mn, Ba, Ca, Mg) MnaOz.HsO, as describedby C. Frondel in 1953 and T. Yoshimura in 1934. -
Cr-Hollandite: Breaking Tradition with Todorokite-Type Manganese Oxides Stanton Ching Connecticut College, [email protected]
Connecticut College Digital Commons @ Connecticut College Chemistry Faculty Publications Chemistry Department 8-2012 Cr-Hollandite: Breaking Tradition with Todorokite-type Manganese Oxides Stanton Ching Connecticut College, [email protected] Jonathan P. Franklin Carley M. Spencer Follow this and additional works at: http://digitalcommons.conncoll.edu/chemfacpub Part of the Chemistry Commons Recommended Citation Ching, S. S., Franklin, J. P., & Spencer, C. M. Cr-hollandite: Breaking tradition with todorokite-type manganese oxides. Polyhedron, 2012, doi:10.1016/j.poly.2012.07.099 This Article is brought to you for free and open access by the Chemistry Department at Digital Commons @ Connecticut College. It has been accepted for inclusion in Chemistry Faculty Publications by an authorized administrator of Digital Commons @ Connecticut College. For more information, please contact [email protected]. The views expressed in this paper are solely those of the author. Elsevier Editorial System(tm) for Polyhedron Manuscript Draft Manuscript Number: POLY-D-12-00837R1 Title: Cr-Hollandite: Breaking Tradition with Todorokite-type Manganese Oxides Article Type: Michelle Millar Issue Keywords: manganese oxide chromium hollandite hydrothermal synthesis Corresponding Author: Dr. Stanton Ching, Corresponding Author's Institution: Connecticut College First Author: Stanton Ching Order of Authors: Stanton Ching; Jonathan P Franklin; Carley M Spencer Manuscript Region of Origin: USA Graphical Abstract (synopsis) (for review) Click here to download high resolution image *Manuscript Click here to view linked References Cr-Hollandite: Breaking Tradition with Todorokite-type Manganese Oxides Stanton Ching,* Jonathan P. Franklin, and Carley M. Spencer Department of Chemistry, Connecticut College, New London, CT 06320, USA * Corresponding author. Tel.: 860-439-2753; fax 860-439-2477; E-mail address: [email protected] This contribution is dedicated to the memory of Michelle M. -
A Specific Gravity Index for Minerats
A SPECIFICGRAVITY INDEX FOR MINERATS c. A. MURSKyI ern R. M. THOMPSON, Un'fuersityof Bri.ti,sh Col,umb,in,Voncouver, Canad,a This work was undertaken in order to provide a practical, and as far as possible,a complete list of specific gravities of minerals. An accurate speciflc cravity determination can usually be made quickly and this information when combined with other physical properties commonly leads to rapid mineral identification. Early complete but now outdated specific gravity lists are those of Miers given in his mineralogy textbook (1902),and Spencer(M,i,n. Mag.,2!, pp. 382-865,I}ZZ). A more recent list by Hurlbut (Dana's Manuatr of M,i,neral,ogy,LgE2) is incomplete and others are limited to rock forming minerals,Trdger (Tabel,l,enntr-optischen Best'i,mmungd,er geste,i,nsb.ildend,en M,ineral,e, 1952) and Morey (Encycto- ped,iaof Cherni,cal,Technol,ogy, Vol. 12, 19b4). In his mineral identification tables, smith (rd,entifi,cati,onand. qual,itatioe cherai,cal,anal,ys'i,s of mineral,s,second edition, New york, 19bB) groups minerals on the basis of specificgravity but in each of the twelve groups the minerals are listed in order of decreasinghardness. The present work should not be regarded as an index of all known minerals as the specificgravities of many minerals are unknown or known only approximately and are omitted from the current list. The list, in order of increasing specific gravity, includes all minerals without regard to other physical properties or to chemical composition. The designation I or II after the name indicates that the mineral falls in the classesof minerals describedin Dana Systemof M'ineralogyEdition 7, volume I (Native elements, sulphides, oxides, etc.) or II (Halides, carbonates, etc.) (L944 and 1951). -
Petrogenesis of Ferromanganese Nodules from East of the Chagos Archipelago, Central Indian Basin, Indian Ocean
ELSEVIER Marine Geology 157 (1999) 145±158 Petrogenesis of ferromanganese nodules from east of the Chagos Archipelago, Central Indian Basin, Indian Ocean Ranadip Banerjee a,Ł, Supriya Roy b, Somnath Dasgupta b, Subir Mukhopadhyay b, Hiroyuki Miura c a Geological Oceanography Division, National Institute of Oceanography, Dona Paula, Goa 403004, India b Department of Geological Sciences, Jadavpur University, Calcutta, 700032, India c Department of Geology and Mineralogy, Faculty of Science, Hokkaido University, Sapporo, 060, Japan Received 28 May 1997; accepted 24 July 1998 Abstract Deep-sea ferromanganese nodules occur over a large area and on many different sediment types of the Central Indian Basin, Indian Ocean. Selected samples were studied to determine their chemical and mineralogical compositions and microstructural features. Repeated laminations of variable thickness, alternately dominated by todorokite and vernadite, are characteristic of these nodules. These laminae show, on electron microprobe line scans, corresponding interlaminar partitioning of Mn±Cu±Ni and Fe±Co. The bulk chemical compositions of these nodules plot in both the hydrogenetic and early diagenetic ®elds on the Fe±Mn±(Ni C Cu C Co) ð10 ternary diagram. The binary diagram depicting the covariation of Mn C Ni C Cu against Fe C Co shows two distinct parallel regression lines, one delineated by nodules from terrigenous, siliceous ooze and siliceous ooze±terrigenous sediments and the other by nodules from red clay, siliceous ooze±red clay and calcareous ooze±red clay. An increasing diagenetic in¯uence in the nodules with the nature of the host sediment types was observed in the sequence: terrigenous ! siliceous ooze and red clay ! siliceous=calcareous ooze±red clay. -
Nucleation and Growth of Todorokite from Birnessite: Implications for Trace-Metal Cycling in Marine Sediments
This is a repository copy of Nucleation and growth of todorokite from birnessite: Implications for trace-metal cycling in marine sediments. White Rose Research Online URL for this paper: http://eprints.whiterose.ac.uk/81100/ Version: Accepted Version Article: Atkins, AL, Shaw, S and Peacock, CL (2014) Nucleation and growth of todorokite from birnessite: Implications for trace-metal cycling in marine sediments. Geochimica et Cosmochimica Acta, 144. 109 - 125. ISSN 0016-7037 https://doi.org/10.1016/j.gca.2014.08.014 Reuse Unless indicated otherwise, fulltext items are protected by copyright with all rights reserved. The copyright exception in section 29 of the Copyright, Designs and Patents Act 1988 allows the making of a single copy solely for the purpose of non-commercial research or private study within the limits of fair dealing. The publisher or other rights-holder may allow further reproduction and re-use of this version - refer to the White Rose Research Online record for this item. Where records identify the publisher as the copyright holder, users can verify any specific terms of use on the publisher’s website. Takedown If you consider content in White Rose Research Online to be in breach of UK law, please notify us by emailing [email protected] including the URL of the record and the reason for the withdrawal request. [email protected] https://eprints.whiterose.ac.uk/ 1 Nucleation and growth of todorokite from birnessite: Implications for trace- 2 metal cycling in marine sediments 3 4 Amy L. Atkins1, Samuel Shaw2 and Caroline L. Peacock1* 5 6 1University of Leeds, School of Earth and Environment, Leeds, LS2 9JT, UK.