Agricultural Commodity Protection by Phosphine Fumigation: Programmatic Environmental Assessment Tools Annex
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TR-499: Indium Phosphide (CASRN 22398-80-7) in F344/N Rats And
NTP TECHNICAL REPORT ON THE TOXICOLOGY AND CARCINOGENESIS STUDIES OF INDIUM PHOSPHIDE (CAS NO. 22398-80-7) IN F344/N RATS AND B6C3F1 MICE (INHALATION STUDIES) NATIONAL TOXICOLOGY PROGRAM P.O. Box 12233 Research Triangle Park, NC 27709 July 2001 NTP TR 499 NIH Publication No. 01-4433 U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES Public Health Service National Institutes of Health FOREWORD The National Toxicology Program (NTP) is made up of four charter agencies of the U.S. Department of Health and Human Services (DHHS): the National Cancer Institute (NCI), National Institutes of Health; the National Institute of Environmental Health Sciences (NIEHS), National Institutes of Health; the National Center for Toxicological Research (NCTR), Food and Drug Administration; and the National Institute for Occupational Safety and Health (NIOSH), Centers for Disease Control and Prevention. In July 1981, the Carcinogenesis Bioassay Testing Program, NCI, was transferred to the NIEHS. The NTP coordinates the relevant programs, staff, and resources from these Public Health Service agencies relating to basic and applied research and to biological assay development and validation. The NTP develops, evaluates, and disseminates scientific information about potentially toxic and hazardous chemicals. This knowledge is used for protecting the health of the American people and for the primary prevention of disease. The studies described in this Technical Report were performed under the direction of the NIEHS and were conducted in compliance with NTP laboratory health and safety requirements and must meet or exceed all applicable federal, state, and local health and safety regulations. Animal care and use were in accordance with the Public Health Service Policy on Humane Care and Use of Animals. -
Transition Metal Phosphides for the Catalytic Hydrodeoxygenation of Waste Oils Into Green Diesel
catalysts Review Transition Metal Phosphides for the Catalytic Hydrodeoxygenation of Waste Oils into Green Diesel M. Consuelo Alvarez-Galvan * , Jose M. Campos-Martin * and Jose L. G. Fierro * Energy and Sustainable Chemistry Group (EQS), Instituto de Catálisis y Petroleoquímica, CSIC, c/Marie Curie, 2 Cantoblanco, 28049 Madrid, Spain * Correspondence: [email protected] (M.C.A.-G.); [email protected] (J.M.C.-M.); jlgfi[email protected] (J.L.G.F.) Received: 28 February 2019; Accepted: 15 March 2019; Published: 22 March 2019 Abstract: Recently, catalysts based on transition metal phosphides (TMPs) have attracted increasing interest for their use in hydrodeoxygenation (HDO) processes destined to synthesize biofuels (green or renewable diesel) from waste vegetable oils and fats (known as hydrotreated vegetable oils (HVO)), or from bio-oils. This fossil-free diesel product is produced completely from renewable raw materials with exceptional quality. These efficient HDO catalysts present electronic properties similar to noble metals, are cost-efficient, and are more stable and resistant to the presence of water than other classical catalytic formulations used for hydrotreatment reactions based on transition metal sulfides, but they do not require the continuous supply of a sulfide source. TMPs develop a bifunctional character (metallic and acidic) and present tunable catalytic properties related to the metal type, phosphorous-metal ratio, support nature, texture properties, and so on. Here, the recent progress in TMP-based catalysts for HDO of waste oils is reviewed. First, the use of TMPs in catalysis is addressed; then, the general aspects of green diesel (from bio-oils or from waste vegetable oils and fats) production by HDO of nonedible oil compounds are presented; and, finally, we attempt to describe the main advances in the development of catalysts based on TMPs for HDO, with an emphasis on the influence of the nature of active phases and effects of phosphorous, promoters, and preparation methods on reactivity. -
Features & Benefits
Click Here To Purchase Features & Benefits: • TAURUS SC is a water-based suspension concentrate of 9.1% Fipronil for Pre and Post-construction termite applications, and to control perimeter pests • Apply at a rate of 4 gallons of dilution per 10 linear feet per foot of depth for termites • TAURUS SC is labeled for barrier applications targeting listed occasional invaders around structures • Now with EP/LI applications PRECAUTIONARY STATEMENTS ® Hazards to Humans and Domestic Animals Caution TAURUS SC Harmful if swallowed, absorbed through skin or inhaled. Do not get in eyes, on skin Termiticide / Insecticide or on clothing. Do not breathe spray mist. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, or using tobacco. Remove and It is a violation of federal law to use this product in a manner inconsistent wash contaminated clothing before reuse. with its labeling. Personal Protective Equipment (PPE): • For sale to, use and storage only by individuals/firms licensed or registered All pesticide handlers (mixers, loaders, and applicators) must wear long-sleeved by the state to apply termiticide and/or general pest control products. shirt and long pants, socks, shoes, and chemical-resistant gloves. All pesticide • DO NOT use this product for termite or other pest control indoors, except for handlers must wear a dust/mist filtering respirator (MSHA/NIOSH approval number label-specified applications for termite control and foam applications to wall prefix TC-21C), or a NIOSH approved respirator with any N, R, P or HE filter, when voids for control of other listed pests. working in a non-ventilated space, including but not limited to crawl-spaces and • DO NOT use on golf course turf. -
Historical Use of Lead Arsenate and Survey of Soil Residues in Former Apple Orchards in Virginia
HISTORICAL USE OF LEAD ARSENATE AND SURVEY OF SOIL RESIDUES IN FORMER APPLE ORCHARDS IN VIRGINIA by Therese Nowak Schooley Thesis submitted to the faculty of the Virginia Polytechnic Institute and State University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE IN LIFE SCIENCES in Entomology Michael J. Weaver, Chair Donald E. Mullins, Co-Chair Matthew J. Eick May 4, 2006 Blacksburg, Virginia Keywords: arsenic, lead, lead arsenate, orchards, soil residues, historical pesticides HISTORICAL USE OF LEAD ARSENATE AND SURVEY OF SOIL RESIDUES IN FORMER APPLE ORCHARDS IN VIRGINIA Therese Nowak Schooley Abstract Inorganic pesticides including natural chemicals such as arsenic, copper, lead, and sulfur have been used extensively to control pests in agriculture. Lead arsenate (PbHAsO4) was first used in apple orchards in the late 1890’s to combat the codling moth, Cydia pomonella (Linnaeus). The affordable and persistent pesticide was applied in ever increasing amounts for the next half century. The persistence in the environment in addition to the heavy applications during the early 1900’s may have led to many of the current and former orchards in this country being contaminated. In this study, soil samples were taken from several apple orchards across the state, ranging from Southwest to Northern Virginia and were analyzed for arsenic and lead. Based on naturally occurring background levels and standards set by other states, two orchards sampled in this study were found to have very high levels of arsenic and lead in the soil, Snead Farm and Mint Spring Recreational Park. Average arsenic levels at Mint Spring Recreational Park and Snead Farm were found to be 65.2 ppm and 107.6 ppm, respectively. -
Safe Pest Control
SAFE PEST CONTROL U.S. Department of Housing and Urban Development • Office of Healthy Homes and Lead Hazard Control “For years, cockroaches have defeated our best efforts to get rid of them. We sprayed and sprayed, but they always came back. Now we under- stand there are better methods and products that really work” Environmental Health Watch Did you know...? ■ Many pesticides for home use are toxic? ■ There are alternative pest management methods that limit the use of toxic substances? ■ Mice, cockroaches, and cockroach "dust” can trigger asthma attack? What is it? Integrated pest management (IPM) is a way to remove pests, like cock- roaches, mice, and rats from a home. IPM is a common sense approach that: ■ Denies pests food, water, shelter and a way to enter the home. ■ Uses baits and powders, such as gel baits, traps and borate powder. Why use IPM? ■ IPM is safer. IPM does not use as many harmful pesticides as traditional pest control. - Avoiding pesticides is especially important in homes. Pesticides can contain long lasting, toxic chemicals or lung irritants that cause asthma attacks. Children are among those most vulnerable to exposure. IPM strategies apply pesticides only as needed and use the least hazardous pesticides to control pests. continued on back www.hud.gov/offices/lead U.S. Department of Housing and Urban Development SAFE PEST CONTROL Office of Healthy Homes and Lead Hazard Control Non-toxic traps can be part of an IPM strategy. If needed, call a pest control professional who uses IPM practices. If you have taken all the steps described above and still have a pest problem, you may need a professional to help. -
4-Cyano-3-Benzoylamino-N
(19) TZZ _T (11) EP 2 427 427 B1 (12) EUROPEAN PATENT SPECIFICATION (45) Date of publication and mention (51) Int Cl.: of the grant of the patent: C07C 255/60 (2006.01) 25.12.2013 Bulletin 2013/52 (86) International application number: (21) Application number: 10713937.0 PCT/EP2010/054862 (22) Date of filing: 14.04.2010 (87) International publication number: WO 2010/127926 (11.11.2010 Gazette 2010/45) (54) 4-CYANO-3-BENZOYLAMINO-N-PHENYL-BENZAMIDES FOR USE IN PEST CONTROL 4-CYANO-3-BENZOYLAMINO-N-PHENYL-BENZAMIDE ZUR VERWENDUNG IN DER SCHÄDLINGSBEKÄMPFUNG 4-CYANO-3-BENZOYLAMINO-N-PHÉNYL-BENZAMIDES DESTINÉS À ÊTRE UTILISÉS DANS LA LUTTE ANTIPARASITAIRE (84) Designated Contracting States: • HUETER, Ottmar Franz AT BE BG CH CY CZ DE DK EE ES FI FR GB GR CH-4332 Stein (CH) HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL • MAIENFISCH, Peter PT RO SE SI SK SM TR CH-4332 Stein (CH) (30) Priority: 06.05.2009 GB 0907822 (74) Representative: Herrmann, Jörg et al 18.12.2009 GB 0922234 Syngenta Crop Protection Münchwilen AG (43) Date of publication of application: Intellectual Property Department 14.03.2012 Bulletin 2012/11 Schaffhauserstrasse CH-4332 Stein (CH) (73) Proprietor: Syngenta Participations AG 4058 Basel (CH) (56) References cited: EP-A1- 1 714 958 WO-A1-2008/000438 (72) Inventors: WO-A1-2008/074427 • JUNG, Pierre Joseph Marcel CH-4332 Stein (CH) Remarks: • GODFREY, Christopher Richard Ayles Thefile contains technical information submitted after CH-4332 Stein (CH) the application was filed and not included in this specification Note: Within nine months of the publication of the mention of the grant of the European patent in the European Patent Bulletin, any person may give notice to the European Patent Office of opposition to that patent, in accordance with the Implementing Regulations. -
Who Needs Chlorpyrifos and Why (By Crop)?
1 WHO NEEDS CHLORPYRIFOS AND WHY (BY CROP)? EXCERPTS OF COMMENTS SUBMITTED TO EPA AT EPA-HQ-OPP-2015-0653 GENERAL “Consumers I have visited with that do not have any ag background are easily swayed into the belief that farmers are polluting the environment and recklessly applying chemicals. Truth is our farmers are professionals and with today’s pricing cannot afford to be over- or misapplying inputs that affect their bottom lines…. I strongly suggest that you…allow producers of the world’s food source to continue using the product chlorpyrifos.” – North Dakota farmer. “Many food crop industries in the Pacific Northwest are concerned about the impacts to pest management based on EPA’s proposed tolerance revocation of chlorpyrifos, including several minor crop groups with limited pesticide options. These industries include processed vegetables, strawberry, grass seed, mint, and cranberry. For many of these industries, chlorpyrifos has unique properties that make it an essential part of their Integrated Pest Management program. It is also an important tool for resistance management. Several of these industries have conducted research to identify effective alternatives to chlorpyrifos, but currently there aren’t viable alternatives that match the efficacy and low risk of this product for managing a number of critical pests…. A revocation of all chlorpyrifos tolerances would eliminate a number of low-risk, critical uses in cases where few alternatives exist at present, and in many cases those alternatives (neonicotinoids, pyrethroids) would be less efficacious, more expensive and have greater impacts on nontarget species including pollinators and beneficial insects. Further, the economic impacts based on resulting crop damage would be substantial.” – Oregon State University Agronomist. -
Chlorpyrifos, Part 1: Toxicology
JOURNAL OF PESTICIDE REFORM/ WINTER 1994 • VOL.14, NO. 4 ■ INSECTICIDE FACTSHEET CHLORPYRIFOS, PART 1: TOXICOLOGY The broad spectrum organophosphate insecticide chlorpyrifos is the most widely used insecticide in the U.S. Total use is estimated at almost 30 million pounds per year. Like all organophosphate insecticides, chlorpyrifos affects the nervous system by inhibiting an enzyme that is important in the transmission of nerve impulses. Symptoms of acute poisoning include headache, nausea, muscle twitching, and convulsions. Chlorpyrifos poisonings are reported to state and federal agencies more often than poisonings of almost every other insecticide. In both laboratory animals and humans, chlorpyrifos can also cause delayed effects on the nervous system. Some effects have been measured years after exposure. Human birth defects have been associated with exposure to chlorpyrifos products. In pregnant laboratory animals, chlorpyrifos exposure caused fetal death. Pups that did survive were smaller pups and did not survive as well as pups from unexposed mothers. Chlorpyrifos also affects the male reproductive system; exposure to a chlorpyrifos product has caused death of cells in male rat testes and a decrease in sperm production in cattle. Chlorpyrifos has caused genetic damage in human blood and lymph cells, mice spleen cells, and hamster bone marrow cells. Immune system abnormalities have been reported from patients exposed to chlorpyrifos. Many individuals report developing sensitivities to a broad array of substances following chlorpyrifos exposure. The second part of this factsheet will discuss human exposure to chlorpyrifos and the ecological effects of chlorpyrifos. BY CAROLINE COX mary agricultural uses are for oranges, al- plications are made annually. -
Binary and Ternary Transition-Metal Phosphides As Hydrodenitrogenation Catalysts
Research Collection Doctoral Thesis Binary and ternary transition-metal phosphides as hydrodenitrogenation catalysts Author(s): Stinner, Christoph Publication Date: 2001 Permanent Link: https://doi.org/10.3929/ethz-a-004378279 Rights / License: In Copyright - Non-Commercial Use Permitted This page was generated automatically upon download from the ETH Zurich Research Collection. For more information please consult the Terms of use. ETH Library Diss. ETH No. 14422 Binary and Ternary Transition-Metal Phosphides as Hydrodenitrogenation Catalysts A dissertation submitted to the Swiss Federal Institute of Technology Zurich for the degree of Doctor of Natural Sciences Presented by Christoph Stinner Dipl.-Chem. University of Bonn born February 27, 1969 in Troisdorf (NRW), Germany Accepted on the recommendation of Prof. Dr. Roel Prins, examiner Prof. Dr. Reinhard Nesper, co-examiner Dr. Thomas Weber, co-examiner Zurich 2001 I Contents Zusammenfassung V Abstract IX 1 Introduction 1 1.1 Motivation 1 1.2 Phosphides 4 1.2.1 General 4 1.2.2 Classification 4 1.2.3 Preparation 5 1.2.4 Properties 12 1.2.5 Applications and Uses 13 1.3 Scope of the Thesis 14 1.4 References 16 2 Characterization Methods 1 2.1 FT Raman Spectroscopy 21 2.2 Thermogravimetric Analysis 24 2.3 Temperature-Programmed Reduction 25 2.4 X-Ray Powder Diffractometry 26 2.5 Nitrogen Adsorption 28 2.6 Solid State Nuclear Magnetic Resonance Spectroscopy 28 2.7 Catalytic Test 33 2.8 References 36 3 Formation, Structure, and HDN Activity of Unsupported Molybdenum Phosphide 37 3.1 Introduction -
Chemical Vapor Deposition of Heteroepitaxial Boron Phosphide Thin Films
University of Tennessee, Knoxville TRACE: Tennessee Research and Creative Exchange Doctoral Dissertations Graduate School 12-2013 Chemical Vapor Deposition of Heteroepitaxial Boron Phosphide Thin Films John Daniel Brasfield University of Tennessee - Knoxville, [email protected] Follow this and additional works at: https://trace.tennessee.edu/utk_graddiss Part of the Semiconductor and Optical Materials Commons Recommended Citation Brasfield, John Daniel, "Chemical aporV Deposition of Heteroepitaxial Boron Phosphide Thin Films. " PhD diss., University of Tennessee, 2013. https://trace.tennessee.edu/utk_graddiss/2558 This Dissertation is brought to you for free and open access by the Graduate School at TRACE: Tennessee Research and Creative Exchange. It has been accepted for inclusion in Doctoral Dissertations by an authorized administrator of TRACE: Tennessee Research and Creative Exchange. For more information, please contact [email protected]. To the Graduate Council: I am submitting herewith a dissertation written by John Daniel Brasfield entitled "Chemical Vapor Deposition of Heteroepitaxial Boron Phosphide Thin Films." I have examined the final electronic copy of this dissertation for form and content and recommend that it be accepted in partial fulfillment of the equirr ements for the degree of Doctor of Philosophy, with a major in Chemistry. Charles S. Feigerle, Major Professor We have read this dissertation and recommend its acceptance: Laurence Miller, Frank Vogt, Ziling Xue Accepted for the Council: Carolyn R. Hodges Vice Provost and Dean of the Graduate School (Original signatures are on file with official studentecor r ds.) Chemical Vapor Deposition of Heteroepitaxial Boron Phosphide Thin Films A Dissertation Presented for the Doctor of Philosophy Degree The University of Tennessee, Knoxville John Daniel Brasfield December 2013 Copyright © 2013 by John Daniel Brasfield All rights reserved. -
Contracting for Pest Control Service in Public Buildings ______A
Contracting for Pest Control Service in Public Buildings _____________________________________________________ A. Greene Regional Entomologist U. S. General Services Administration Three Core Principles of Public Sector Contracting ______________________________________________________ Contracting is Law The Principle of Fairness Competition must be maximized No bidder can be unfairly excluded The Principle of Frugality Minimum requirements only The goal should be greatest value The Six Principal Components of Service Contracting ______________________________________________________ Program management Type of contract Estimating cost Method of award Statement of work Quality assurance 1. Program Management ______________________________________________________ Who will be the Integrated Pest MANAGER? IPM = Integrated Procurement Mission 2. Type of Contract ________________________________________________________ Janitorial service or separate contract? How will the work be ordered & paid for? Firm-Fixed Price Indefinite Delivery __________________________________________________________The Firm-Fixed-Price Contract Advantages: Minimum administrative burden Easiest type of contract to budget for Disadvantages: Highly inflated prices if bidders feel there are high cost risks, e.g.: Excessive monitoring/recordkeeping requirements High-cost, indeterminate specialty work included (e.g. termites, bird deterrence, wildlife trapping) __________________________________________________________The Firm-Fixed-Price Contract Needless (& Expensive) -
Subject Index
SUBJECT INDEX Vol. 1: 1–698, Vol. 2: 699–1395, Vol. 3: 1397–2111, Vol. 4: 2113–2798, Vol. 5: 2799–3440. Page numbers suffixed by t and f refer to Tables and Figures respectively. Absorption spectra in aqueous solution, 752–770 of americium, 1364–1368 compounds of, 721–752 americium (III), 1364–1365, 1365f coordination complexes in solution, americium (IV), 1365 771–782 americium (V), 1366, 1367f history of, 699–700 americium (VI), 1366, 1367f isotope production, 702–703 americium (VII), 1367–1368, 1368f metallic state of, 717–721 of liquid plutonium, 963 in nature, 703–704 of neptunium, 763–766, 763f, 786–787 nuclear properties of, 700–702 neptunium (VII) ternary oxides, 729 separation and purification, 704–717 of plutonium plutonium hexafluoride, 1088, 1089f atomic properties of, 857–862 ions, 1113–1117, 1116t compounds of, 987–1108 plutonium (IV), 849 metal and intermetallic compounds of, polymerization, 1151, 1151f 862–987 tetrachloride, 1093–1094, 1094f natural occurrence of, 822–824 tribromide, 1099t, 1100 nuclear properties of, 815–822 trichloride, 1099, 1099t separation and purification of, 826–857 Accelerator mass spectrometry (AMS), of solution chemistry of, 1108–1203 neptunium, 790 Actinide elements Acetates atomic volumes of, 922–923, 923f of americium, 1322, 1323t extraction of of plutonium, 1177, 1180 DIDPA, 1276 Acetone, derived compounds, of americium, HDEHP, 1275 1322, 1323t, 1324 organophosphorus and Acids carbamoylphosphonate reagents, for Purex process, 711 1276–1278 for solvent extraction, 839 stripping of, 1280–1281 Actinide