Femtochemistry and Femtobiology
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Near-Infrared Optical Modulation for Ultrashort Pulse Generation Employing Indium Monosulfide (Ins) Two-Dimensional Semiconductor Nanocrystals
nanomaterials Article Near-Infrared Optical Modulation for Ultrashort Pulse Generation Employing Indium Monosulfide (InS) Two-Dimensional Semiconductor Nanocrystals Tao Wang, Jin Wang, Jian Wu *, Pengfei Ma, Rongtao Su, Yanxing Ma and Pu Zhou * College of Advanced Interdisciplinary Studies, National University of Defense Technology, Changsha 410073, China; [email protected] (T.W.); [email protected] (J.W.); [email protected] (P.M.); [email protected] (R.S.); [email protected] (Y.M.) * Correspondence: [email protected] (J.W.); [email protected] (P.Z.) Received: 14 May 2019; Accepted: 3 June 2019; Published: 7 June 2019 Abstract: In recent years, metal chalcogenide nanomaterials have received much attention in the field of ultrafast lasers due to their unique band-gap characteristic and excellent optical properties. In this work, two-dimensional (2D) indium monosulfide (InS) nanosheets were synthesized through a modified liquid-phase exfoliation method. In addition, a film-type InS-polyvinyl alcohol (PVA) saturable absorber (SA) was prepared as an optical modulator to generate ultrashort pulses. The nonlinear properties of the InS-PVA SA were systematically investigated. The modulation depth and saturation intensity of the InS-SA were 5.7% and 6.79 MW/cm2, respectively. By employing this InS-PVA SA, a stable, passively mode-locked Yb-doped fiber laser was demonstrated. At the fundamental frequency, the laser operated at 1.02 MHz, with a pulse width of 486.7 ps, and the maximum output power was 1.91 mW. By adjusting the polarization states in the cavity, harmonic mode-locked phenomena were also observed. To our knowledge, this is the first time an ultrashort pulse output based on InS has been achieved. -
Pulse Shaping and Ultrashort Laser Pulse Filamentation for Applications in Extreme Nonlinear Optics Antonio Lotti
Pulse shaping and ultrashort laser pulse filamentation for applications in extreme nonlinear optics Antonio Lotti To cite this version: Antonio Lotti. Pulse shaping and ultrashort laser pulse filamentation for applications in extreme nonlinear optics. Optics [physics.optics]. Ecole Polytechnique X, 2012. English. pastel-00665670 HAL Id: pastel-00665670 https://pastel.archives-ouvertes.fr/pastel-00665670 Submitted on 2 Feb 2012 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. UNIVERSITA` DEGLI STUDI DELL’INSUBRIA ECOLE´ POLYTECHNIQUE THESIS SUBMITTED IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF PHILOSOPHIÆ DOCTOR IN PHYSICS Pulse shaping and ultrashort laser pulse filamentation for applications in extreme nonlinear optics. Antonio Lotti Date of defense: February 1, 2012 Examining committee: ∗ Advisor Daniele FACCIO Assistant Prof. at University of Insubria Advisor Arnaud COUAIRON Senior Researcher at CNRS Reviewer John DUDLEY Prof. at University of Franche-Comte´ Reviewer Danilo GIULIETTI Prof. at University of Pisa President Antonello DE MARTINO Senior Researcher at CNRS Paolo DI TRAPANI Associate Prof. at University of Insubria Alberto PAROLA Prof. at University of Insubria Luca TARTARA Assistant Prof. at University of Pavia ∗ current position: Reader in Physics at Heriot-Watt University, Edinburgh Abstract English abstract This thesis deals with numerical studies of the properties and applications of spatio-temporally coupled pulses, conical wavepackets and laser filaments, in strongly nonlinear processes, such as harmonic generation and pulse reshap- ing. -
Autocorrelation and Frequency-Resolved Optical Gating Measurements Based on the Third Harmonic Generation in a Gaseous Medium
Appl. Sci. 2015, 5, 136-144; doi:10.3390/app5020136 OPEN ACCESS applied sciences ISSN 2076-3417 www.mdpi.com/journal/applsci Article Autocorrelation and Frequency-Resolved Optical Gating Measurements Based on the Third Harmonic Generation in a Gaseous Medium Yoshinari Takao 1,†, Tomoko Imasaka 2,†, Yuichiro Kida 1,† and Totaro Imasaka 1,3,* 1 Department of Applied Chemistry, Graduate School of Engineering, Kyushu University, 744, Motooka, Nishi-ku, Fukuoka 819-0395, Japan; E-Mails: [email protected] (Y.T.); [email protected] (Y.K.) 2 Laboratory of Chemistry, Graduate School of Design, Kyushu University, 4-9-1, Shiobaru, Minami-ku, Fukuoka 815-8540, Japan; E-Mail: [email protected] 3 Division of Optoelectronics and Photonics, Center for Future Chemistry, Kyushu University, 744, Motooka, Nishi-ku, Fukuoka 819-0395, Japan † These authors contributed equally to this work. * Author to whom correspondence should be addressed; E-Mail: [email protected]; Tel.: +81-92-802-2883; Fax: +81-92-802-2888. Academic Editor: Takayoshi Kobayashi Received: 7 April 2015 / Accepted: 3 June 2015 / Published: 9 June 2015 Abstract: A gas was utilized in producing the third harmonic emission as a nonlinear optical medium for autocorrelation and frequency-resolved optical gating measurements to evaluate the pulse width and chirp of a Ti:sapphire laser. Due to a wide frequency domain available for a gas, this approach has potential for use in measuring the pulse width in the optical (ultraviolet/visible) region beyond one octave and thus for measuring an optical pulse width less than 1 fs. -
Basic Keyword List
NOTICE TO AUTHORS 2008 Basic Keyword list A Antibodies Bismuth Chalcogens Ab initio calculations Antifungal agents Block copolymers Chaperone proteins Absorption Antigens Bond energy Charge carrier injection Acidity Antimony Bond theory Charge transfer Actinides Antisense agents Boranes Chelates Acylation Antitumor agents Borates Chemical vapor deposition Addition to alkenes Antiviral agents Boron Chemical vapor transport Addition to carbonyl com- Aqueous-phase catalysis Bridging ligands Chemisorption pounds Arene ligands Bromine Chemoenzymatic synthesis Adsorption Arenes Brønsted acids Chemoselectivity Aerobic oxidation Argon Chiral auxiliaries Aggregation Aromatic substitution C Chiral pool Agostic interactions Aromaticity C-C activation Chiral resolution Alanes Arsenic C-C bond formation Chirality Alcohols Arylation C-C coupling Chlorine Aldehydes Aryl halides C-Cl bond activation Chromates Aldol reaction Arynes C-Glycosides Chromium Alkali metals As ligands C-H activation Chromophores Alkaline earth metals Asymmetric amplification C1 building blocks Circular dichroism Alkaloids Asymmetric catalysis Cadmium Clathrates Alkanes Asymmetric synthesis Cage compounds Clays Alkene ligands Atmospheric chemistry Calcium Cleavage reactions Alkenes Atom economy Calixarenes Cluster compounds Alkylation Atropisomerism Calorimetry Cobalamines Alkyne ligands Aurophilicity Carbanions Cobalt Alkynes Autocatalysis Carbene homologues Cofactors Alkynylation Automerization Carbene ligands Colloids Allenes Autoxidation Carbenes Combinatorial chemistry Allosterism -
Photochemistry of Highly Excited States R
COMMENTARY COMMENTARY Photochemistry of highly excited states R. D. Levinea,b,c,1 These days on earth we are photochemically reasonably A forceful illustration of the benefits of the synergy of well shielded. The far UV radiation is filtered by the ozone experiment and theory in understanding the detailed and other components of the atmosphere. In the iono- electronic and nuclear dynamics in highly excited states is sphere and beyond there is much challenging chemistry provided by the very recent work reported by Peters et al. induced by such higher-energy photons. The shielding by (8). Methyl azide is pumped by an 8-eV vacuum UV (VUV) the atmosphere also makes demands on such experi- pulse of 10-fs duration and probed by a second 1.6-eV in- ments in the laboratory. There is, however, recent interest frared (IR) pulse that ionizes the molecule. The experiment largely driven by technology that makes higher resolution as seen through the eyes of a theorist is shown in Fig. 1. The possible. The experimental technology is advanced light pump pulse prepares a single excited electronic state, la- sources that offer far higher intensities, sharper wave- beled as S8, that theory shows has a mixed valence and length definition or, complementarily, short-duration Rydberg character. It is unusual that a single excited state pulses. The two alternatives make a whole because of is accessed at such a high energy. The high-level computa- the quantum mechanical time–energy uncertainty princi- tions reported by Peters et al. are quite clear that the ple that makes short pulses necessarily broad in energy. -
The Science and Applications of Ultrafast, Ultraintense Lasers
THE SCIENCE AND APPLICATIONS OF ULTRAFAST, ULTRAINTENSE LASERS: Opportunities in science and technology using the brightest light known to man A report on the SAUUL workshop held, June 17-19, 2002 THE SCIENCE AND APPLICATIONS OF ULTRAFAST, ULTRAINTENSE LASERS (SAUUL) A report on the SAUUL workshop, held in Washington DC, June 17-19, 2002 Workshop steering committee: Philip Bucksbaum (University of Michigan) Todd Ditmire (University of Texas) Louis DiMauro (Brookhaven National Laboratory) Joseph Eberly (University of Rochester) Richard Freeman (University of California, Davis) Michael Key (Lawrence Livermore National Laboratory) Wim Leemans (Lawrence Berkeley National Laboratory) David Meyerhofer (LLE, University of Rochester) Gerard Mourou (CUOS, University of Michigan) Martin Richardson (CREOL, University of Central Florida) 2 Table of Contents Table of Contents . 3 Executive Summary . 5 1. Introduction . 7 1.1 Overview . 7 1.2 Summary . 8 1.3 Scientific Impact Areas . 9 1.4 The Technology of UULs and its impact. .13 1.5 Grand Challenges. .15 2. Scientific Opportunities Presented by Research with Ultrafast, Ultraintense Lasers . .17 2.1 Basic High-Field Science . .18 2.2 Ultrafast X-ray Generation and Applications . .23 2.3 High Energy Density Science and Lab Astrophysics . .29 2.4 Fusion Energy and Fast Ignition. .34 2.5 Advanced Particle Acceleration and Ultrafast Nuclear Science . .40 3. Advanced UUL Technology . .47 3.1 Overview . .47 3.2 Important Research Areas in UUL Development. .48 3.3 New Architectures for Short Pulse Laser Amplification . .51 4. Present State of UUL Research Worldwide . .53 5. Conclusions and Findings . .61 Appendix A: A Plan for Organizing the UUL Community in the United States . -
Laboratory Astrophysics: from Observations to Interpretation
April 14th – 19th 2019 Jesus College Cambridge UK IAU Symposium 350 Laboratory Astrophysics: From Observations to Interpretation Poster design by: D. Benoit, A. Dawes, E. Sciamma-O’Brien & H. Fraser Scientific Organizing Committee: Local Organizing Committee: Farid Salama (Chair) ★ P. Barklem ★ H. Fraser ★ T. Henning H. Fraser (Chair) ★ D. Benoit ★ R Coster ★ A. Dawes ★ S. Gärtner ★ C. Joblin ★ S. Kwok ★ H. Linnartz ★ L. Mashonkina ★ T. Millar ★ D. Heard ★ S. Ioppolo ★ N. Mason ★ A. Meijer★ P. Rimmer ★ ★ O. Shalabiea★ G. Vidali ★ F. Wa n g ★ G. Del-Zanna E. Sciamma-O’Brien ★ F. Salama ★ C. Wa lsh ★ G. Del-Zanna For more information and to contact us: www.astrochemistry.org.uk/IAU_S350 [email protected] @iaus350labastro 2 Abstract Book Scheduley Sunday 14th April . Pg. 2 Monday 15th April . Pg. 3 Tuesday 16th April . Pg. 4 Wednesday 17th April . Pg. 5 Thursday 18th April . Pg. 6 Friday 19th April . Pg. 7 List of Posters . .Pg. 8 Abstracts of Talks . .Pg. 12 Abstracts of Posters . Pg. 83 yPlenary talks (40') are indicated with `P', review talks (30') with `R', and invited talks (15') with `I'. Schedule Sunday 14th April 14:00 - 17:00 REGISTRATION 18:00 - 19:00 WELCOME RECEPTION 19:30 DINNER BAR OPEN UNTIL 23:00 Back to Table of Contents 2 Monday 15th April 09:00 { 10:00 REGISTRATION 09:00 WELCOME by F. Salama (Chair of SOC) SESSION 1 CHAIR: F. Salama 09:15 E. van Dishoeck (P) Laboratory astrophysics: key to understanding the Universe From Diffuse Clouds to Protostars: Outstanding Questions about the Evolution of 10:00 A. -
14. Measuring Ultrashort Laser Pulses I: Autocorrelation the Dilemma the Goal: Measuring the Intensity and Phase Vs
14. Measuring Ultrashort Laser Pulses I: Autocorrelation The dilemma The goal: measuring the intensity and phase vs. time (or frequency) Why? The Spectrometer and Michelson Interferometer 1D Phase Retrieval Autocorrelation 1D Phase Retrieval E(t) Single-shot autocorrelation E(t–) The Autocorrelation and Spectrum Ambiguities Third-order Autocorrelation Interferometric Autocorrelation 1 The Dilemma In order to measure an event in time, you need a shorter one. To study this event, you need a strobe light pulse that’s shorter. Photograph taken by Harold Edgerton, MIT But then, to measure the strobe light pulse, you need a detector whose response time is even shorter. And so on… So, now, how do you measure the shortest event? 2 Ultrashort laser pulses are the shortest technological events ever created by humans. It’s routine to generate pulses shorter than 10-13 seconds in duration, and researchers have generated pulses only a few fs (10-15 s) long. Such a pulse is to one second as 5 cents is to the US national debt. Such pulses have many applications in physics, chemistry, biology, and engineering. You can measure any event—as long as you’ve got a pulse that’s shorter. So how do you measure the pulse itself? You must use the pulse to measure itself. But that isn’t good enough. It’s only as short as the pulse. It’s not shorter. Techniques based on using the pulse to measure itself are subtle. 3 Why measure an ultrashort laser pulse? To determine the temporal resolution of an experiment using it. To determine whether it can be made even shorter. -
Femtosecond Pulse Generation
Femto-UP 2020-21 School Femtosecond Pulse Generation Adeline Bonvalet Laboratoire d’Optique et Biosciences CNRS, INSERM, Ecole Polytechnique, Institut Polytechnique de Paris, 91128, Palaiseau, France 1 Definitions Electric field of a 10-fs 800-nm pulse nano 10-9 sec pico 10-12 femto 10-15 2,7 fs atto 10-18 10 fs time 2 Many properties Electric field of a 10-fs 800-nm pulse High peaki power (Energy /Duration) Ultrashorti Duration Spectral Properties i (Frequency Comb) time 3 Time-resolved spectroscopy Electric field of a 10-fs 800-nm pulse Ultrashorti Duration Time-resolved spectroscopy Direct observation of ultrafast motions time Ahmed Zewail, Nobel Prize in chemistry 1999, femtochemistry 4 Imaging Electric field of a 10-fs 800-nm pulse High peaki power (Energy /Duration) Nonlinear microscopy time 5 Material processing Electric field of a 10-fs 800-nm pulse High peaki power (Energy /Duration) Laser matter interaction Drilling, cutting, etching,… time Areas of applications : aeronautics, electronics, medical,6 optics… Light matter interaction Electric field of a 10-fs 800-nm pulse High peaki power (Energy /Duration) Ability to reach extreme conditions (amplified system) Applications : Sources of intense particles beams, X-rays, high energy density science, laboratory astroprophysics … time 7 Metrology Electric field of a 10-fs 800-nm pulse Spectral Properties i (Frequency Comb) Nobel Prize 2005 "for their contributions to the development of laser-based time precision spectroscopy, including the optical frequency comb technique." 8 Outline -
Infrared and UV-Visible Time-Resolved Techniques for the Study of Tetrapyrrole-Based Proteins
Infrared and UV-visible time-resolved techniques for the study of tetrapyrrole-based proteins A thesis submitted to The University of Manchester for the degree of Doctor of Philosophy (PhD) in the Faculty of Life Sciences 2013 Henry John Russell Contents List of Tables .......................................................................................................................................................................... 5 List of Figures ........................................................................................................................................................................ 6 Abstract ...................................................................................................................................................................................10 Declaration ............................................................................................................................................................................11 Copyright Statement ........................................................................................................................................................11 Acknowledgements ..........................................................................................................................................................12 Abbreviations and Symbols ..........................................................................................................................................13 Preface and Thesis Structure .......................................................................................................................................16 -
Ultrashort Laser Pulses I
Ultrashort Laser Pulses I Description of pulses Intensity and phase The instantaneous frequency and group delay Zero th and first-order phase Prof. Rick Trebino Georgia Tech The linearly chirped Gaussian pulse www.frog.gatech.edu An ultrashort laser ) t I( t ) ( pulse has an intensity X and phase vs. time. Neglecting the spatial dependence for field Electric now, the pulse electric field is given by: Time [fs] X ∝1 ω −φ + (t )2 I( t ) exp{ it [0 (t) ]} cc. Intensity Carrier Phase frequency A sharply peaked function for the intensity yields an ultrashort pulse. The phase tells us the color evolution of the pulse in time. The real and complex ) t I( t ) pulse amplitudes ( X X Removing the 1/2, the c.c., and the exponential factor with the carrier frequency yields the complex amplitude, E(t), of the pulse: field Electric E(t )∝I( t ) exp{ − i φ(t ) } Time [fs] This removes the rapidly varying part of the pulse electric field and yields a complex quantity, which is actually easier to calculate with. I( t ) is often called the real amplitude, A(t), of the pulse. The Gaussian pulse For almost all calculations, a good first approximation for any ultrashort pulse is the Gaussian pulse (with zero phase). = − τ 2 EtE( )0 exp ( t /HW 1/ e ) = − τ 2 E0 exp 2ln 2( t /FWHM ) = − τ 2 E0 exp 1.38( t /FWHM ) τ τ where HW1/e is the field half-width-half-maximum, and FWHM is the intensity full-width-half-maximum. 2 The intensity is: ∝ − τ 2 ItE()0 exp 4ln2(/ t FWHM ) ∝2 − τ 2 E0 exp 2.76( t /FWHM ) Intensity vs. -
Angwcheminted, 2000, 39, 2587-2631.Pdf
REVIEWS Femtochemistry: Atomic-Scale Dynamics of the Chemical Bond Using Ultrafast Lasers (Nobel Lecture)** Ahmed H. Zewail* Over many millennia, humankind has biological changes. For molecular dy- condensed phases, as well as in bio- thought to explore phenomena on an namics, achieving this atomic-scale res- logical systems such as proteins and ever shorter time scale. In this race olution using ultrafast lasers as strobes DNA structures. It also offers new against time, femtosecond resolution is a triumph, just as X-ray and electron possibilities for the control of reactivity (1fs 10À15 s) is the ultimate achieve- diffraction, and, more recently, STM and for structural femtochemistry and ment for studies of the fundamental and NMR spectroscopy, provided that femtobiology. This anthology gives an dynamics of the chemical bond. Ob- resolution for static molecular struc- overview of the development of the servation of the very act that brings tures. On the femtosecond time scale, field from a personal perspective, en- about chemistryÐthe making and matter wave packets (particle-type) compassing our research at Caltech breaking of bonds on their actual time can be created and their coherent and focusing on the evolution of tech- and length scalesÐis the wellspring of evolution as a single-molecule trajec- niques, concepts, and new discoveries. the field of femtochemistry, which is tory can be observed. The field began the study of molecular motions in the with simple systems of a few atoms and Keywords: femtobiology ´ femto- hitherto unobserved ephemeral transi- has reached the realm of the very chemistry ´ Nobel lecture ´ physical tion states of physical, chemical, and complex in isolated, mesoscopic, and chemistry ´ transition states 1.