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Mathematical modeling of thin layer drying characteristics of dika ( gabonensis) nuts and kernels

O.A. Aregbesolaa, B.S Ogunsinaa,n, A.E. Sofolahana, N.N. Chimeb

aDepartment of Agricultural and Environmental Engineering, Obafemi Awolowo University, Ile Ife, bDepartment of Agricultural and Bioresource Engineering, University of Nigeria, Nsukka, Nigeria

Abstract

The thin layer drying characteristics of dika kernels and nuts were investigated at four drying temperatures of 50, 60, 70 and 80 1C and the data was fitted to drying models. Non-linear regression analysis was used to determine model parameters, while coefficient of determination (R2) and standard error of estimate (SEE) formed the basis for determining the model of best fit. The Modified Henderson–Pabis drying model gave the best fit for the dika kernels while the two term model was best for the dika nuts. Effective moisture diffusivity ranged from 2.84 1010 m2/s to 5.06 10 11 m2/s for the kernels and from 1.22 10 10 m2/s to 2.03 10 10 m2/s for the nuts. The activation energies of dika kernels and nuts were 16.747 kJ/mol and 37.019 kJ/mol respectively.

& 2015 Association of Vice-Chancellors of Nigerian Universitie. Production and hosting by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

Keywords: Moisture content; Temperature; Moisture ratio; Activation energy; Moisture diffusivity

1. Introduction et al., 1996). As trade in dika kernels is on the increase, product quality standard and value addition are becoming The of lesser known indigenous for prime criteria for setting price for farmers and traders. There is subsistence agriculture is playing a major role in enhancing therefore the need to understand unit operations involved in rural livelihoods, mitigating deforestation and environmental dika fruit processing. degradation in sub-Sahara (Leakey et al., 2005). The The need to preserve more food during peak harvest period, dika (Irvingia gabonensis) has high utility value; the reduce post-harvest losses and equalize availability in-between , the fruits, the bark, the hardwood and the roots have seasons make artificial drying inevitable in bulk handling several medicinal, food and industrial applications (Ndoye of modern food products (Doymaz et al., 2006). Artificial et al., 1997; Ayuk et al., 1999). Apart from the common use of dryers are rapid and provide uniform, hygienic dried product the kernels as a soup thickener in West Africa, the kernel oil and reduce losses (Karathanos and Belessiotis, 1997; Goyal and meal are potential base materials for pharmaceutical et al., 2007). binders, confectionery, edible , soap and cosmetics Thin layer drying studies provide the basis for understanding the (Ogunsina et al., 2012). Dika fruit processing involves unique drying characteristics of any particular food material. The fermentation of the fresh fruits in heaped piles for few days results of such studies have been widely used to simulate dryers and washing the rotten pulp to obtain the nuts. Afterwards, the under deep-bed drying conditions and for quantifying parameters nuts are sun-dried and cracked to obtain the kernels (Ladipo for the design of specialized drying equipment. In thin layer drying, the moisture content of a bio-material exposed to a stream of

n drying air of known relative humidity, velocity and temperature Corresponding author. is monitored over a period of time. A number of mathematical E-mail address: [email protected] (B. Ogunsina). Peer review under responsibility of Association of Vice-Chancellors of models have been developed to simulate moisture movement and Nigerian Universities. mass transfer during the drying of many agricultural products. http://dx.doi.org/10.1016/j.nifoj.2015.04.012 0189-7241/& 2015 Association of Vice-Chancellors of Nigerian Universitie. Production and hosting by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

Please cite this article as: Aregbesola, O.A., et al., Mathematical modeling of thin layer drying characteristics of dika (Irvingia gabonensis) nuts and kernels. Nigerian Food Journal (2015), http://dx.doi.org/10.1016/j.nifoj.2015.04.012 2 O.A. Aregbesola et al. / Nigerian Food Journal ] (]]]]) ]]]–]]]

Table 1 Thin-layer drying models used for the study.

Name Model Reference

Newton MR¼exp(kt) Ayensu (1997) Page MR ¼ expðÞktn Diamante and Munro (1993) Modified page MR ¼ expðÞðÞkt n White et al. (1981) Henderson and Pabis MR ¼ a expðÞkt Akpinar et al. (2003) Logarithmic MR ¼ a expðÞþkt c Yagcioglu et al. (1999) Two term MR ¼ a expðk0tÞþ b expðk1tÞ Togrul and Pehlivan (2004) Diffusion MR ¼ a expðÞþkt ðÞ1a expðÞkbt Yaldiz and Erdekin (2001) Modified Henderson and Pabis MR ¼ a expðÞþkt b expðÞþgt c expðÞht Karathanos and Belessiotis (1999)

1.2 0.8

0.7 1

50 C 0.6

0.8 60 C 0.5 50 C 70 C 60 C 0.4 0.6 80 C 70 C

0.3 80 C 0.4 Moisture Ratio

Moisture Content 0.2

0.2 0.1

0 0 0 1000 1500 2000 2500 0 500 0 500 1000 1500 2000 2500 -0.1 Time(min) Time(min) -0.2

0.8 1.2

0.7 1 50 C 0.6 60 C 70 C 0.8 50 C 0.5 80 C 60 C 0.6 70 C 0.4 80 C

0.4 0.3 Moisture Ratio Moisture Content 0.2 0.2

0.1 0 0 200 400 600 800 1000 1200 1400 1600 1800 Time(min) 0 0 500 1000 1500 2000 Fig. 2. Moisture ratio versus time. (a) and (b) kernel. -0.1 Time(min)

Fig. 1. Moisture content versus time. (a) Nut and (b) kernel. Although drying is a major unit operation in dika fruits These have been found very useful in understanding drying processing from nuts to kernels, the literature regarding the kinetics and optimization of drying conditions (Vega et al., 2007; drying characteristics of dika nuts and kernels are rarely Doymaz et al., 2006; Mwithiga and Ochieng-Olwal, 2005). available. Therefore, the objective of this work is to investigate

Please cite this article as: Aregbesola, O.A., et al., Mathematical modeling of thin layer drying characteristics of dika (Irvingia gabonensis) nuts and kernels. Nigerian Food Journal (2015), http://dx.doi.org/10.1016/j.nifoj.2015.04.012 O.A. Aregbesola et al. / Nigerian Food Journal ] (]]]]) ]]]–]]] 3 the thin layer drying characteristics of dika nuts and kernels, fit content of sample (% db), t the drying time (min), and k is the the drying data into eight thin layer models and determine their drying constant (min1). effective diffusivities and activation energies. Other thin layer drying models which are commonly used for agricultural products include Page, Diffusion, Henderson and Pabis, Modified Henderson–Pabis, modified Page, Lewis, 2. Theoretical background for modeling of drying data Midilli and Kucuk, Logarithmic, Two Term, Two Term exponential, Thompson, Wang and Singh amongst others The simplest model for describing thin layer drying char- (Özdemir and Devres, 1999; Kashaninejad et al., 2007; acteristics of agricultural products is in the form of the Hassan-Beygi et al., 2009). exponential model (Eq. (1)). It assumes negligible resistance to moisture movement to the surface of the material and that the resistance to moisture movement is concentrated on the 3. Effective diffusivity and activation energy surface of the material and is referred to as ‘simple lumped’ model (which is analogous to Newton's law of cooling) The effective diffusivity of a product can be estimated by (Temple and Boxtel, 1999) Fick's second diffusion law for slab geometry (Taheri- Garavand et al., 2011; Adabi et al., 2013) as follows: M Me MR ¼ ¼ expðÞkt ð1Þ Mi Me Mi Me MR ¼ Mo Me where MR is the moisture ratio, M the moisture content at any 1 8 X 1 ð2nþ1Þπ2D t time ‘t’ (% db), M the equilibrium moisture content (emc) at ¼ exp eff ð2Þ e π2 2 2 ðÞ2nþ1 4H the conditions of the drying air (% db), Mi the initial moisture n 1

Table 2 Coefficients of thin layer drying models and goodness of fit for dika nuts.

S/N Model Temp (1C) Parameters R2 SEE

1 Newton 50 K¼0.0051 0.9913 0.0316 60 K¼0.0053 0.9734 0.0520 70 K¼0.0066 0.9860 0.0385 80 K¼0.0061 0.9858 0.0384

2 Page 50 K¼0.0100, n¼0.8677 0.9954 0.0234 60 K¼0.0192, n¼0.7475 0.9965 0.0193 70 K¼0.0152, n¼0.8286 0.9937 0.0262 80 K¼0.0152, n¼0.8162 0.9973 0.0169 3 Modified page 50 K¼0.0050, n¼0.8677 0.9954 0.0234 60 K¼0.0050, n¼0.7475 0.9965 0.0193 70 K¼0.0064, n¼0.8286 0.9937 0.0262 80 K¼0.0059, n¼0.8162 0.9973 0.0169

4 Henderson and Pabis 50 K¼0.0050, a¼0.9799 0.9917 0.0312 60 K¼0.0045, a¼0.9145 0.9837 0.0415 70 K¼0.0063, a¼0.9676 0.9872 0.0375 80 K¼0.0055, a¼0.9414 0.9907 0.0317

5 Logarithmic 50 K¼0.0054, a¼0.9616, c¼0.0296 0.9941 0.0270 60 K¼0.0049, a¼0.8986, c¼0.0267 0.9854 0.0400 70 K¼0.0070, a¼0.9470, c¼0.0368 0.9911 0.0319 80 K¼0.0058, a¼0.9302, c¼0.0178 0.9914 0.0312

6 Two term 50 K0 ¼0.0095, k1 ¼0.0025, a¼0.5981, b¼0.4278 0.9989 0.0118 60 K0 ¼0.0216, k1 ¼0.0031, a¼0.3465, b¼0.6705 0.9987 0.0120 70 K0 ¼0.0126, k1 ¼0.0028, a¼0.6221, b¼0.4047 0.9988 0.0121 80 K0 ¼0.0238, k1 ¼0.0042, a¼0.2780, b¼0.7377 0.9988 0.0118 7 Diffusion 50 K¼0.0083, a¼0.6206, b¼0.2801 0.9984 0.0141 60 K¼0.0198, a¼0.3381, b¼0.1535 0.9986 0.0125 70 K¼0.0113, a¼0.6288, b¼0.2382 0.9982 0.0143 80 K¼0.0218, a¼0.2687, b¼0.1917 0.9987 0.0123 8 Modified Henderson and Pabisa 50 k¼0.0025, g¼0.0025, h¼0.0095, a¼0.2139, b¼0.2139, c¼0.5981 0.9989 0.0123 60 k¼0.0031, g¼0.0031, h¼0.0216, a¼0.3352, b¼0.3352, c¼0.3465 0.9987 0.0125 70 k¼0.0028, g¼0.0028, h¼0.0126, a¼0.2024, b¼0.2024, c¼0.6221 0.9988 0.0127 80 k¼0.0042, g¼0.0042, h¼0.0238, a¼0.3689, b¼0.3689, c¼0.2780 0.9988 0.0124

aH–P: Henderson–Pabis.

Please cite this article as: Aregbesola, O.A., et al., Mathematical modeling of thin layer drying characteristics of dika (Irvingia gabonensis) nuts and kernels. Nigerian Food Journal (2015), http://dx.doi.org/10.1016/j.nifoj.2015.04.012 4 O.A. Aregbesola et al. / Nigerian Food Journal ] (]]]]) ]]]–]]]

This assumes that moisture migration is due to diffusion, Akpinar et al. (2003) described the temperature dependence negligible shrinkage, constant diffusion coefficients and tem- of effective diffusivity by the Arrhenius relationship: perature. For long drying periods, Eq. (2) may be further E simplified to only the first term of the series and the moisture D ¼ D exp a ð5Þ eff o RT ratio (MR) can be reduced to Mi/Mo since Me will be relatively small compared to Mi and Mo. The logarithmic form of Eq. (2) where Do is the pre-exponential factor of the Arrhenius therefore is equation (m2/s); E the activation energy (kJ/mol); R the a π2 universal gas constant (kJ/mol K) and T is the absolute air ¼ Mi ¼ 8 Deff t ð Þ ln MR ln ln 2 2 3 temperature (K). Mo π 4H where MR is the dimensionless moisture ratio, M the moisture i 4. Materials and methods content at any time, Me the emc and Mo the initial moisture content (kg of H O/kg of dry matter), H the half-thickness of 2 5 kg of freshly harvested dika fruits was obtained from a the slab/slices in sample (m), n a positive integer, D the eff farm in Ibadan, Oyo State The fresh fruits were left in a heap effective diffusivity (m2/s) and t is the drying time (min). for 5 days when the fleshy pulp was totally rotten. The rotten From Eq. (3), effective diffusivity can be calculated by fruits were depulped manually and washed in water to extract plotting ln(MR) against drying time (t); this gives a straight the dika nuts (Ohaeri and Ohaeri, 2014), weighing about 2 kg line, the slope of which may be expressed as (wet weight). Half of the nuts were cracked manually using a π2D fl Slope ¼ eff ð4Þ hammer against a at stone to obtain the dika kernels while the 4H2 other half was retained as uncracked nuts for the study. The

Table 3 Coefficients of thin layer drying models and goodness of fit for dika kernels.

S/N Model Temp (1C) Parameters R2 SEE

1 Newton 50 K¼0.0102 0.9731 0.0481 60 K¼0.0114 0.9918 0.0274 70 K¼0.0152 0.9972 0.0158 80 K¼0.0162 0.9911 0.0279

2 Page 50 K¼0.0359, n¼0.7220 0.9982 0.0129 60 K¼0.0249, n¼0.8259 0.9997 0.0057 70 K¼0.0222, n¼0.9090 0.9990 0.0098 80 K¼0.0313, n¼0.8398 0.9975 0.0151 3 Modified page 50 K¼0.0100, n¼0.7220 0.9982 0.0129 60 K¼0.0114, n¼0.8259 0.9997 0.0057 70 K¼0.0152, n¼0.9090 0.9990 0.0098 80 K¼0.0162, n¼0.8398 0.9975 0.0151

4 Henderson–Pabis 50 K¼0.0087, a¼0.9069 0.9826 0.0395 60 K¼0.0105, a¼0.9417 0.9953 0.0211 70 K¼0.0148, a¼0.9805 0.9976 0.0151 80 K¼0.0154, a¼0.9640 0.9924 0.0264

5 Logarithmic 50 K¼0.0098, a¼0.8928, c¼0.0309 0.9867 0.0353 60 K¼0.0110, a¼0.9338, c¼0.0144 0.9962 0.0194 70 K¼0.0154, a¼0.9738, c¼0.0124 0.9984 0.0127 80 K¼0.0169, a¼0.9515, c¼0.0266 0.9956 0.0207

6 Two term 50 K0¼0.0247, k1 ¼0.0046, a¼0.5122, b¼0.4860 0.9999 0.0030 60 K0¼0.0355, k1 ¼0.0082, a¼0.2647, b¼0.7308 0.9995 0.0075 70 K0¼0.0204, k1 ¼0.0076, a¼0.7235, b¼0.2810 0.9996 0.0065 80 K0¼0.0245, k1 ¼0.0065, a¼0.7156, b¼0.2907 0.9998 0.0040 7 Diffusion 50 K¼0.0249, a¼0.5122, b¼0.1831 0.9999 0.0029 60 K¼0.0387, a¼0.2518, b¼0.2164 0.9995 0.0074 70 K¼0.0197, a¼0.7545, b¼0.3612 0.9996 0.0064 80 K¼0.0239, a¼0.7210, b¼0.2676 0.9998 0.0042 8 Modified Henderson–Pabis 50 k¼0.0046, g¼0.0046, h¼0.0247, a¼0.2430, b¼0.2430, c¼0.5122 0.9999 0.0031 60 k¼0.0126, g¼0.0050, h¼0.0825, a¼0.6669, b¼0.2267, c¼0.1078 0.9998 0.0048 70 k¼0.0032, g¼0.0130, h¼0.0279, a¼0.0435, b¼0.6456, c¼0.3174 0.9996 0.0064 80 k¼0.0065, g¼0.0065, h¼0.0245, a¼0.1456, b¼0.1451, c¼0.7156 0.9998 0.0042

*H–P: Henderson–Pabis.

Please cite this article as: Aregbesola, O.A., et al., Mathematical modeling of thin layer drying characteristics of dika (Irvingia gabonensis) nuts and kernels. Nigerian Food Journal (2015), http://dx.doi.org/10.1016/j.nifoj.2015.04.012 O.A. Aregbesola et al. / Nigerian Food Journal ] (]]]]) ]]]–]]] 5 initial moisture content of the kernels and nuts was determined The plot of moisture ratio versus time for the nuts and kernels by oven drying method following AOAC standards (2000). are presented in Fig. 2. From the plots it was noticed that Approximately, 10 g of the nuts and the kernels were oven drying occurred predominately during the falling rate period dried at 130 1C until the mass did not change significantly for the nuts and kernels; hence it may be inferred that the between two weighing succession. The drying experiment dominant physical mechanism governing the moisture move- involved one hundred grams (100 g) of each of the nuts and ment in dika nuts and kernels was diffusion along the moisture kernels, dried simultaneously in a Gallenkemp drying cabinet concentration gradient as obtained for most agricultural (OVL 220 010W, made in England) at four different tempera- products (Karathanos and Belessiotis, 1999). tures 50, 60, 70 and 80 1C. The weight of the samples were Tables 2 and 3 show the results of non-linear analysis of the taken using an electronic balance (mettler toledo pb 153; fitting of eight semi-theoretical models to the thin layer drying sensitivity 70.001 g; made in USA) at 30 min interval until data for the dika kernels and nuts at the different drying the weight was constant (samples attained equilibrium with the temperatures considered. These tables show that the drying drying air conditions). The weight of the samples was taken constant (k) increased as drying temperature increased for most quickly to avoid interference with the drying process. After- of the models; whereas, the values of other model parameters wards, the final moisture content of the samples was deter- did not show a definite trend. From the evaluation criteria (R2 mined by the oven drying method, and the value obtained was and SEE), all models gave a good description of the thin layer taken as the equilibrium moisture content of the sample (at the drying characteristics of dika nuts and kernels with R240.97. drying air conditions). Moisture ratio, MR was obtained for the kernels and nuts using Eq. (1). Based on the foregoing, a graph of moisture ln MR versus Time for Dika Nuts ratio (MR) against time (t) at the different drying temperatures Time(min) 0 was plotted. Drying data of the dika nuts and kernels were 0 500 1000 1500 2000 2500 fitted to eight thin drying models (Table 1) and the data subsets were fitted by multiple non-linear regression technique. -2 50 C

Regression analyses were performed using Wolfram Mathe- 60 C matica 6.0 (Wolfram, 2007). Coefficient of determination (R2) -4 70 C and standard error of estimate (SEE) were chosen as criteria to 80 C determine the equation of best fit. The values of R2 and SEE -6

were obtained from Eqs. (6) and (7) respectively: ln MR P P n n ðMRi MRpre;iÞ ðMRi MRexp;iÞ R2 ¼ P i 1 Pi 1 ð6Þ -8 n ð Þ2 n ð Þ2 i 1 MRi MRpre;i i 1 MRi MRexp;i P n 2 -10 ðMR ; MR ; Þ SEE ¼ i 1 exp i pre i ð7Þ df -12 where MRexp,i is the ith experimental moisture ratio, Mpre,i is In MR versus Time for Dika Kernels the ith predicted moisture ratio, n the number of observations, Time(min) and df is the number of degrees of freedom of regression 0 model. 0 500 1000 1500 2000

The effective diffusivities of the nuts and kernels were -2 estimated using the simplified Fick's second diffusion model 50 (Eq. (4)) and activation energy was obtained from Eq. (5). -4 60

70 5. Results and discussion -6 80

Fig. 1 shows thin layer drying curves of dika nuts and -8 kernels at the different drying temperatures considered. The ln MR total drying times for the dika kernels to reach emcs were 600, -10 720, 840 and 960 min at drying temperatures of 80, 70, 60 and 1 50 C respectively. Dika nuts required total drying times of -12 840, 960, 1080 and 1440 min for the nuts to reach emc at drying temperatures of 80, 70, 60 and 50 1C respectively. This -14 implies that more time was required to dry the dika nuts compared to the kernels. Shorter total drying times have also been reported by some researchers for some edible kernels -16 compared to nuts (Azzouz et al., 2002; Krokida et al., 2003). Fig. 3. Plot of ln(MR) versus time for dika fruits. (a) Nuts and (b) kernels.

Please cite this article as: Aregbesola, O.A., et al., Mathematical modeling of thin layer drying characteristics of dika (Irvingia gabonensis) nuts and kernels. Nigerian Food Journal (2015), http://dx.doi.org/10.1016/j.nifoj.2015.04.012 6 O.A. Aregbesola et al. / Nigerian Food Journal ] (]]]]) ]]]–]]]

Table 4 Effective diffusivities of dika kernels and nuts at different drying temperatures.

Temp (1C) Nuts Equation of fit R2 Kernels Equation of fit R2

50 1.22E10 y¼0.0035x0.1883 0.9897 5.06E11 y¼0.0052x0.3969 0.9806 60 1.22E10 y¼0.0037x0.172 0.9891 2.84E10 y¼0.0077x0.2747 0.9883 70 1.62E10 y¼0.0042x0.2291 0.9734 3.24E10 y¼0.0085x0.51 0.9286 80 2.03E10 y¼0.0054x0.0426 0.9676 3.65E10 y¼0.009x0.4225 0.9691

ln Deff versus 1/Temp(K) Rostagi, 2001) nuts, respectively and within an acceptable 1/Temp(K-1) range of 12.87–58.15 kJ/mol documented by Senadeera et al. -21 (2003) for most food crops. 0.0028 0.00285 0.0029 0.00295 0.003 0.00305 0.0031 0.00315

-21.5 6. Conclusions

Kernels Nuts Thin layer drying characteristics of dika nut and kernels was -22 investigated at four drying temperatures in an air oven. The data obtained was fitted into eight semi-empirical models.

-22.5 From the investigation, the following conclusions were drawn: Deff

ln i) Thin layer drying of dika nuts and kernels predominately -23 occurred in the falling rate period; hence, the drying process for dika nuts and kernels could be said to be dominantly

-23.5 driven by diffusion. ii) The Modified Henderson–Pabis model gave the best fit (with R2 value of 0.9998 and SEE value of 0.0046) for dika -24 kernels, while the two term model was best for dika nuts 2 Fig. 4. Plot of ln(Deff) versus 1/T for dika nuts and kernels. (with R value of 0.9988 and SEE value of 0.0094). Effective moisture diffusivity ranged between 5.06 However, based on the highest R2 values and lowest SEE 10 11 and 2.84 10 10 m2/s for kernels; and between values the most suitable models for describing the thin layer 1.22 10 10 m2/s and 2.03 10 10 m2/s for nuts, drying characteristics of dika kernels and nuts are the Modified whereas, the activation energy of dika kernels and nuts Henderson–Pabis and the two term respectively. In a similar were 16.747 kJ/mol and 37.019 kJ/mol respectively. study by Palipane and Driscoll (1994) the two term model was also found suitable for describing the thin layer drying References characteristics of nuts-in-shell and kernels. The effective moisture diffusivities were obtained from the plots of Ayensu, A., 1997. Dehydration of food crops using a solar dryer with ln (MR) versus drying time (t)inFig. 3. From Table 4, the convective heat flow. Solar Energy 59, 121–126. results showed an increase in effective moisture diffusivity Adabi, M.E., Minaei, S., Motavalli, A., Taghizadeh, A., Azadbakht, M., 2013. Energy consumption, effective moisture diffusion and activation energy in for dika nuts and kernels as drying temperature increased. drying of thyme leaves (Part II). Int. J. Agron. Prod. 4 (9), 11 The values for moisture diffusivity ranged from 5.06 10 2404–2412. to 2.84 10 10 m2/s, for dika kernels and from 1.22 AOAC, 2000. 17th edn. In: Cunnif, P. (Ed.), Official Methods of Analysis 1010 m2/s to 2.03 1010 m2/s for dika nuts. These values Association of Official Analytical Chemists, vol. II. Arlington, VA, USA, – fell within the range of 0.8 1013 to 64.6 1010 m2/s pp. 1 37. Akpinar, E.K., Bicer, Y., Yildiz, C., 2003. Thin layer drying of red pepper. J. considered suitable for most fruits and vegetables (Sobukola Food Eng. 59 (1), 99–104. and Dairo, 2007). However, the corresponding expressions in Ayuk, E.T., Duguma, B., Franzel, S., Kenge, J., Mollet, M.T., Zenteng, P., Table 4 show that the best fit for each drying temperature is 1999. Uses, management and economic potential of Irvingia gabonensis in given by a linear relationship (R240.96). the humid lowlands of Cameroon. For. Ecol. Manag. 113 (1), 1–9. From the plot of ln(D ) versus 1/T (Fig. 4), it was noticed Azzouz, S., Guizani, A., Jomaa, W., Belghith, A., 2002. Moisture diffusivity eff drying kinetic equation of convective drying of grapes. J. Food Eng. 55, that the activation energy of dika nuts (37.019 kJ/mol) was 323–330. more than twice that of the kernels (16.747 kJ/mol). This may Diamante, L.M., Munro, P.A., 1993. Mathematical modeling of the thin layer be attributed to the fact that more energy is required to cause solar drying of sweet potato slices. Solar Energy 51, 271–276. moisture removal from the inner cavity of the shell to through Doymaz, I., Tugrul, N., Pala, M., 2006. Drying characteristics of dill and – the shell to the drying air. The activation energy of the dika nut parsley leaves. J. Food Eng. 77 (3), 559 565. Goyal, R.K., Kingsley, A.R.P., Manikantan, M.R., Ilyas, S.M., 2007. was close to values of 33.3 and 28.7 kJ/mol reported for Mathematical modelling of thin layer drying kinetics of plum in a tunnel (Tavakolipour, 2011) and (Hebbar and dryer. J. Food Eng. 79 (1), 176–180.

Please cite this article as: Aregbesola, O.A., et al., Mathematical modeling of thin layer drying characteristics of dika (Irvingia gabonensis) nuts and kernels. Nigerian Food Journal (2015), http://dx.doi.org/10.1016/j.nifoj.2015.04.012 O.A. Aregbesola et al. / Nigerian Food Journal ] (]]]]) ]]]–]]] 7

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Please cite this article as: Aregbesola, O.A., et al., Mathematical modeling of thin layer drying characteristics of dika (Irvingia gabonensis) nuts and kernels. Nigerian Food Journal (2015), http://dx.doi.org/10.1016/j.nifoj.2015.04.012