A Bibliography of Experimental Saturation Properties of the Cryogenic Fluids1
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Chapter 5 Measures of Humidity Phases of Water
Chapter 5 Atmospheric Moisture Measures of Humidity 1. Absolute humidity 2. Specific humidity 3. Actual vapor pressure 4. Saturation vapor pressure 5. Relative humidity 6. Dew point Phases of Water Water Vapor n o su ti b ra li o n m p io d a a at ep t v s o io e en s n d it n io o n c freezing Liquid Water Ice melting 1 Coexistence of Water & Vapor • Even below the boiling point, some water molecules leave the liquid (evaporation). • Similarly, some water molecules from the air enter the liquid (condense). • The behavior happens over ice too (sublimation and condensation). Saturation • If we cap the air over the water, then more and more water molecules will enter the air until saturation is reached. • At saturation there is a balance between the number of water molecules leaving the liquid and entering it. • Saturation can occur over ice too. Hydrologic Cycle 2 Air Parcel • Enclose a volume of air in an imaginary thin elastic container, which we will call an air parcel. • It contains oxygen, nitrogen, water vapor, and other molecules in the air. 1. Absolute Humidity Mass of water vapor Absolute humidity = Volume of air The absolute humidity changes with the volume of the parcel, which can change with temperature or pressure. 2. Specific Humidity Mass of water vapor Specific humidity = Total mass of air The specific humidity does not change with parcel volume. 3 Specific Humidity vs. Latitude • The highest specific humidities are observed in the tropics and the lowest values in the polar regions. -
Physics, Chapter 17: the Phases of Matter
University of Nebraska - Lincoln DigitalCommons@University of Nebraska - Lincoln Robert Katz Publications Research Papers in Physics and Astronomy 1-1958 Physics, Chapter 17: The Phases of Matter Henry Semat City College of New York Robert Katz University of Nebraska-Lincoln, [email protected] Follow this and additional works at: https://digitalcommons.unl.edu/physicskatz Part of the Physics Commons Semat, Henry and Katz, Robert, "Physics, Chapter 17: The Phases of Matter" (1958). Robert Katz Publications. 165. https://digitalcommons.unl.edu/physicskatz/165 This Article is brought to you for free and open access by the Research Papers in Physics and Astronomy at DigitalCommons@University of Nebraska - Lincoln. It has been accepted for inclusion in Robert Katz Publications by an authorized administrator of DigitalCommons@University of Nebraska - Lincoln. 17 The Phases of Matter 17-1 Phases of a Substance A substance which has a definite chemical composition can exist in one or more phases, such as the vapor phase, the liquid phase, or the solid phase. When two or more such phases are in equilibrium at any given temperature and pressure, there are always surfaces of separation between the two phases. In the solid phase a pure substance generally exhibits a well-defined crystal structure in which the atoms or molecules of the substance are arranged in a repetitive lattice. Many substances are known to exist in several different solid phases at different conditions of temperature and pressure. These solid phases differ in their crystal structure. Thus ice is known to have six different solid phases, while sulphur has four different solid phases. -
Demonstration of a Persistent Current in Superfluid Atomic Gas
Demonstration of a persistent current in superfluid atomic gas One of the most remarkable properties of macroscopic quantum systems is the phenomenon of persistent flow. Current in a loop of superconducting wire will flow essentially forever. In a neutral superfluid, like liquid helium below the lambda point, persistent flow is observed as frictionless circulation in a hollow toroidal container. A Bose-Einstein condensate (BEC) of an atomic gas also exhibits superfluid behavior. While a number of experiments have confirmed superfluidity in an atomic gas BEC, persistent flow, which is regarded as the “gold standard” of superfluidity, had not been observed. The main reason for this is that persistent flow is most easily observed in a topology such as a ring or toroid, while past BEC experiments were primarily performed in spheroidal traps. Using a combination of magnetic and optical fields, we were able to create an atomic BEC in a toriodal trap, with the condensate filling the entire ring. Once the BEC was formed in the toroidal trap, we coherently transferred orbital angular momentum of light to the atoms (using a technique we had previously demonstrated) to get them to circulate in the trap. We observed the flow of atoms to persist for a time more than twenty times what was observed for the atoms confined in a spheroidal trap. The flow was observed to persist even when there was a large (80%) thermal fraction present in the toroidal trap. These experiments open the possibility of investigations of the fundamental role of flow in superfluidity and of realizing the atomic equivalent of superconducting circuits and devices such as SQUIDs. -
Pressure Vs Temperature (Boiling Point)
Boiling Points and Vapor Pressure Background Boiling Points and Vapor Pressure Background: Definitions Vapor Pressure: The equilibrium pressure of a vapor above its liquid; the pressure of the vapor resulting from the evaporation of a liquid above a sample of the liquid in a closed container. Boiling Point: The temperature at which the vapor pressure of a liquid is equal to the atmospheric (or applied) pressure. As the temperature of the liquid increases, the vapor pressure will increase, as seen below: https://www.chem.purdue.edu/gchelp/liquids/vpress.html Vapor pressure is interpreted in terms of molecules of liquid converting to the gaseous phase and escaping into the empty space above the liquid. In order for the molecules to escape, the intermolecular forces (Van der Waals, dipole- dipole, and hydrogen bonding) have to be overcome, which requires energy. This energy can come in the form of heat, aka increase in temperature. Due to this relationship between vapor pressure and temperature, the boiling point of a liquid decreases as the atmospheric pressure decreases since there is more room above the liquid for molecules to escape into at lower pressure. The graph below illustrates this relationship using common solvents and some terpenes: Pressure vs Temperature (boiling point) Ethanol Heptane Isopropyl Alcohol B-myrcene 290.0 B-caryophyllene d-Limonene Linalool Pulegone 270.0 250.0 1,8-cineole (eucalyptol) a-pinene a-terpineol terpineol-4-ol 230.0 p-cymene 210.0 190.0 170.0 150.0 130.0 110.0 90.0 Temperature (˚C) Temperature 70.0 50.0 30.0 10 20 30 40 50 60 70 80 90 100 200 300 400 500 600 760 10.0 -10.0 -30.0 Pressure (torr) 1 Boiling Points and Vapor Pressure Background As a very general rule of thumb, the boiling point of many liquids will drop about 0.5˚C for a 10mmHg decrease in pressure when operating in the region of 760 mmHg (atmospheric pressure). -
ESSENTIALS of METEOROLOGY (7Th Ed.) GLOSSARY
ESSENTIALS OF METEOROLOGY (7th ed.) GLOSSARY Chapter 1 Aerosols Tiny suspended solid particles (dust, smoke, etc.) or liquid droplets that enter the atmosphere from either natural or human (anthropogenic) sources, such as the burning of fossil fuels. Sulfur-containing fossil fuels, such as coal, produce sulfate aerosols. Air density The ratio of the mass of a substance to the volume occupied by it. Air density is usually expressed as g/cm3 or kg/m3. Also See Density. Air pressure The pressure exerted by the mass of air above a given point, usually expressed in millibars (mb), inches of (atmospheric mercury (Hg) or in hectopascals (hPa). pressure) Atmosphere The envelope of gases that surround a planet and are held to it by the planet's gravitational attraction. The earth's atmosphere is mainly nitrogen and oxygen. Carbon dioxide (CO2) A colorless, odorless gas whose concentration is about 0.039 percent (390 ppm) in a volume of air near sea level. It is a selective absorber of infrared radiation and, consequently, it is important in the earth's atmospheric greenhouse effect. Solid CO2 is called dry ice. Climate The accumulation of daily and seasonal weather events over a long period of time. Front The transition zone between two distinct air masses. Hurricane A tropical cyclone having winds in excess of 64 knots (74 mi/hr). Ionosphere An electrified region of the upper atmosphere where fairly large concentrations of ions and free electrons exist. Lapse rate The rate at which an atmospheric variable (usually temperature) decreases with height. (See Environmental lapse rate.) Mesosphere The atmospheric layer between the stratosphere and the thermosphere. -
Contents 1 Classification of Phase Transitions
PHY304 - Statistical Mechanics Spring Semester 2021 Dr. Anosh Joseph, IISER Mohali LECTURE 35 Monday, April 5, 2021 (Note: This is an online lecture due to COVID-19 interruption.) Contents 1 Classification of Phase Transitions 1 1.1 Order Parameter . .2 2 Critical Exponents 5 1 Classification of Phase Transitions The physics of phase transitions is a young research field of statistical physics. Let us summarize the knowledge we gained from thermodynamics regarding phases. The Gibbs’ phase rule is F = K + 2 − P; (1) with F denoting the number of intensive variables, K the number of particle species (chemical components), and P the number of phases. Consider a closed pot containing a vapor. With K = 1 we need 3 (= K + 2) extensive variables say, S; V; N for a complete description of the system. One of these say, V determines only size of the system. The intensive properties are completely described by F = 1 + 2 − 1 = 2 (2) intensive variables. For instance, by pressure and temperature. (We could also choose temperature and chemical potential.) The third intensive variable is given by the Gibbs’-Duhem relation X S dT − V dp + Ni dµi = 0: (3) i This relation tells us that the intensive variables PHY304 - Statistical Mechanics Spring Semester 2021 T; p; µ1; ··· ; µK , which are conjugate to the extensive variables S; V; N1; ··· ;NK are not at all independent of each other. In the above relation S; V; N1; ··· ;NK are now functions of the variables T; p; µ1; ··· ; µK , and the Gibbs’-Duhem relation provides the possibility to eliminate one of these variables. -
Problem Set #10 Assigned November 8, 2013 – Due Friday, November 15, 2013 Please Show All Work for Credit
Problem Set #10 Assigned November 8, 2013 – Due Friday, November 15, 2013 Please show all work for credit To Hand in 1. 1 2. –1 A least squares fit of ln P versus 1/T gives the result Hvaporization = 25.28 kJ mol . 3. Assuming constant pressure and temperature, and that the surface area of the protein is reduced by 25% due to the hydrophobic interaction: 2 G 0.25 N A 4 r Convert to per mole, ↓determine size per molecule 4 r 3 V M N 0.73mL/ g 60000g / mol (6.02 1023) 3 2 2 A r 2.52 109 m 2 23 9 2 G 0.25 N A 4 r 0.0720N / m 0.25 6.02 10 / mol (4 ) (2.52 10 m) 865kJ / mol We think this is a reasonable approach, but the value seems high 2 4. The vapor pressure of an unknown solid is approximately given by ln(P/Torr) = 22.413 – 2035(K/T), and the vapor pressure of the liquid phase of the same substance is approximately given by ln(P/Torr) = 18.352 – 1736(K/T). a. Calculate Hvaporization and Hsublimation. b. Calculate Hfusion. c. Calculate the triple point temperature and pressure. a) Calculate Hvaporization and Hsublimation. From Equation (8.16) dPln H sublimation dT RT 2 dln P d ln P dT d ln P H T 2 sublimation 11 dT dT R dd TT For this specific case H sublimation 2035 H 16.92 103 J mol –1 R sublimation Following the same proedure as above, H vaporization 1736 H 14.43 103 J mol –1 R vaporization b. -
Chapter Two Properties of Ammonia
Chapter Two Properties of Ammonia Physical Properties General Anhydrous ammonia exists as either a colorless gas, colorless liquid, or white solid, depending on its pressure and temperature. In nearly all commonly encountered situations, it exists as either a liquid or a gas. The gas is less dense than air and the liquid is less dense than water at standard conditions. Ammonia gas (vapor) diffuses readily in air and the liquid is highly soluble in water with an accompanying release of heat. Ammonia exhibits classical saturation relationships whereby pressure and temperature are directly related so long as both the vapor and liquid phase are present. It does have a critical pressure and temperature. At atmospheric pressure, a closed container of ammonia vapor and liquid will be in equilibrium at a temperature of –28°F [–33°C]. It should be noted however that if liquid ammonia is spilled or released to the atmosphere at normal temperatures, the resultant pool of boiling liquid will be significantly colder than –28°F due to the law of partial pressures (the partial pressure of the ammonia vapor in the air near the liquid surface will be less than atmospheric pressure). The following table provides some of the important physical properties of ammonia. TABLE 2-1 Physical Properties of Ammonia Property Condition Value (IP) Value (SI) Molecular Weight 17.03 17.03 Color None None Physical State Room Temp Gas Gas Freezing Point P=1 atm –108°F –78°C Boiling Point P=1 atm –28.1°F –33.3°C Critical Pressure 1657 psia 11,410 kPa Critical Temp 271°F -
Phase Transition a Phase Transition Is the Alteration in State of Matter Among the Four Basic Recognized Aggregative States:Solid, Liquid, Gaseous and Plasma
Phase transition A phase transition is the alteration in state of matter among the four basic recognized aggregative states:solid, liquid, gaseous and plasma. In some cases two or more states of matter can co-exist in equilibrium under a given set of temperature and pressure conditions, as well as external force fields (electromagnetic, gravitational, acoustic). Introduction Matter is known four aggregative states: solid, liquid, and gaseous and plasma, which are sharply different in their properties and characteristics. Physicists have agreed to refer to a both physically and chemically homogeneous finite body as a phase. Or, using Gybbs’s definition, one can call a homogeneous part of heterogeneous system: a phase. The reason behind the existence of different phases lies in the balance between the kinetic (heat) energy of the molecules and their energy of interaction. Simplified, the mechanism of phase transitions can be described as follows. When heating a solid body, the kinetic energy of the molecules grows, distance between them increases, and in accordance with the Coulomb law the interaction between them weakens. When the temperature reaches a certain point for the given substance (mineral, mixture, or system) critical value, melting takes place. A new phase, liquid, is formed, and a phase transition takes place. When further heating the liquid thus formed to the next critical temperature the liquid (melt) changes to gas; and so on. All said phase transitions are reversible; that is, with the temperature being lowered, the system would repeat the complete transition from one state to another in reverse order. The important thing is the possibility of co- existence of phases and their reciprocal transition at any temperature. -
ABSTRACT for CWS 2002, Chemogolovka, Russia Ulf Israelsson
ABSTRACT for CWS 2002, Chemogolovka, Russia Ulf Israelsson Use of the International Space Station for Fundamental Physics Research Ulf E. Israelsson"-and Mark C. Leeb "Jet Propulsion Laboratory, 4800 Oak Grove Drive, Pasadena, CA 9 1 109, USA bNational Aeronautics and Space Administration, Code UG, Washington D.C., USA NASA's research plans aboard the International Space Station (ISS) are discussed. Experiments in low temperature physics and atomic physics are planned to commence in late 2005. Experiments in gravitational physics are planned to begin in 2007. A low temperature microgravity physics facility is under development for the low temperature and gravitation experiments. The facility provides a 2 K environment for two instruments and an operational lifetime of 4.5 months. Each instrument will be capable of accomplishing a primary investigation and one or more guest investigations. Experiments on the first flight will study non-equilibrium phenomena near the superfluid 4He transition and measure scaling parameters near the 3He critical point. Experiments on the second flight will investigate boundary effects near the superfluid 4He transition and perform a red-shift test of Einstein's theory of general relativity. Follow-on flights of the facility will occur at 16 to 22-month intervals. The first couple of atomic physics experiments will take advantage of the free-fall environment to operate laser cooled atomic fountain clocks with 10 to 100 times better performance than any Earth based clock. These clocks will be used for experimental studies in General and Special Relativity. Flight defiiiiiiori experirneni siudies are underway by investigators studying Bose Einstein Condensates and use of atom interferometers as potential future flight candidates. -
Thermophysical Properties of Helium-4 from 2 to 1500 K with Pressures to 1000 Atmospheres
DATE DUE llbriZl<L. - ' :_ Demco, Inc. 38-293 National Bureau of Standards A UNITED STATES H1 DEPARTMENT OF v+ *^r COMMERCE NBS TECHNICAL NOTE 631 National Bureau of Standards PUBLICATION APR 2 1973 Library, E-Ol Admin. Bldg. OCT 6 1981 191103 Thermophysical Properties of Helium-4 from 2 to 1500 K with Pressures qc to 1000 Atmospheres joo U57Q lV-O/ U.S. >EPARTMENT OF COMMERCE National Bureau of Standards NATIONAL BUREAU OF STANDARDS 1 The National Bureau of Standards was established by an act of Congress March 3, 1901. The Bureau's overall goal is to strengthen and advance the Nation's science and technology and facilitate their effective application for public benefit. To this end, the Bureau conducts research and provides: (1) a basis for the Nation's physical measure- ment system, (2) scientific and technological services for industry and government, (3) a technical basis for equity in trade, and (4) technical services to promote public safety. The Bureau consists of the Institute for Basic Standards, the Institute for Materials Research, the Institute for Applied Technology, the Center for Computer Sciences and Technology, and the Office for Information Programs. THE INSTITUTE FOR BASIC STANDARDS provides the central basis within the United States of a complete and consistent system of physical measurement; coordinates that system with measurement systems of other nations; and furnishes essential services leading to accurate and uniform physical measurements throughout the Nation's scien- tific community, industry, and commerce. The Institute consists of a Center for Radia- tion Research, an Office of Measurement Services and the following divisions: Applied Mathematics—Electricity—Heat—Mechanics—Optical Physics—Linac Radiation 2—Nuclear Radiation 2—Applied Radiation 2 —Quantum Electronics3— Electromagnetics 3—Time and Frequency 3 —Laboratory Astrophysics 3—Cryo- 3 genics . -
The Thermodynamic Properties of Nitrogen from 64 to 300* K Between
Lonal Bureau of btaudaj a.^ Lilarary, M.W. Bldg JUIV 6 1962 PB 161630 ^ecknlcciL ^^ote 129 THE THERMODYNAMIC PROPERTIES OF NITROGEN FROM 64 TO 300^ K BETWEEN 0.1 AND 200 ATMOSPHERES THOMAS R. STROBRIDGE U. S. DEPARTMENT OF COMMERCE NATIONAL BUREAU OF STANDARDS THE NATIONAL BUREAU OF STANDARDS Functions and Activities The functions of the National Bureau of Standards are set forth in the Act of Congress, March 3, 1901, as amended by Congress in Public Law 619, 1950. These include the development and maintenance of the na- tional standards of measurement and the provision of means and methods for making measurements consistent with these standards; the determination of physical constants and properties of materials; the development of methods and instruments for testing materials,- devices, and structures; advisory services to government agen- cies on scientific and technical problems; invention and development of devices to serve special needs of the Government; and the development of standard practices, codes, and specifications. The work includes basic and applied research, development, engineering, instrumentation, testing, evaluation, calibration services, and various consultation and information services. Reseeirch projects are also performed for other government agencies when the work relates to and supplements the basic program of the Bureau or when the Bureau's unique competence is required. The scope of activities is suggested by the listing of divisions and sections on the inside of the back cover. Publications The results of the Bureau's research are published either in the Bureau's own series of publications or in the journals of professional and scientific societies.