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Iseite, Mn2mo3o8, a New Mineral from Ise, Mie Prefecture, Japan
Journal of Mineralogical and PetrologicalIseite, a new Sciences, mineral Volume 108, page 37─ 41, 2013 37 LETTER Iseite, Mn2Mo3O8, a new mineral from Ise, Mie Prefecture, Japan * ** ** *** Daisuke NISHIO-HAMANE , Norimitsu TOMITA , Tetsuo MINAKAWA and Sachio INABA * The institute for Solid State Physics, University of Tokyo, Kashiwa, Chiba 277-8581, Japan ** Department of Earth Science, Faculty of Science, Ehime University, Matsuyama, Ehime 790-8577, Japan *** Inaba-Shinju Corporation, Minamiise, Mie 516-0109, Japan Iseite, Mn2Mo3O8, a new mineral that is a Mn-dominant analogue of kamiokite, is found in the stratiform ferro- manganese deposit, Shobu area, Ise City, Mie Prefecture, Japan. It is the first mineral species that includes both Mn and Mo as essential constituents. Iseite is iron-black in color and has a submetallic luster. It occurs as ag- gregates up to about 1 mm in size made of minute crystals (<20 μm). Iseite has a zoned structure closely associ- ated with undetermined Mn-Fe-Mo oxide minerals with hexagonal forms, and it occasionally coexists with 3 small amounts of powellite. Its Mohs hardness is 4-5, and its calculated density is 5.85 g/cm . The empirical formula of iseite is (Mn1.787Fe0.193)Σ1.980Mo3.010O8. Its simplified ideal formula is written as Mn2Mo3O8. The min- eral is isostructural with kamiokite (hexagonal, P63mc). The unit cell parameters are a = 5.8052 (3) Å, c = 10.2277 (8) Å, V = 298.50 (4) Å3, and Z = 2. The Rietveld refinement using synchrotron radiation (λ = 0.413 Å) powder XRD data converges to Rwp = 3.11%, and confirms two independent Mn sites—tetrahedral and octahe- IV VI dral—in the crystal structure of iseite, indicating the structure formula Mn Mn Mo3O8. -
Washington State Minerals Checklist
Division of Geology and Earth Resources MS 47007; Olympia, WA 98504-7007 Washington State 360-902-1450; 360-902-1785 fax E-mail: [email protected] Website: http://www.dnr.wa.gov/geology Minerals Checklist Note: Mineral names in parentheses are the preferred species names. Compiled by Raymond Lasmanis o Acanthite o Arsenopalladinite o Bustamite o Clinohumite o Enstatite o Harmotome o Actinolite o Arsenopyrite o Bytownite o Clinoptilolite o Epidesmine (Stilbite) o Hastingsite o Adularia o Arsenosulvanite (Plagioclase) o Clinozoisite o Epidote o Hausmannite (Orthoclase) o Arsenpolybasite o Cairngorm (Quartz) o Cobaltite o Epistilbite o Hedenbergite o Aegirine o Astrophyllite o Calamine o Cochromite o Epsomite o Hedleyite o Aenigmatite o Atacamite (Hemimorphite) o Coffinite o Erionite o Hematite o Aeschynite o Atokite o Calaverite o Columbite o Erythrite o Hemimorphite o Agardite-Y o Augite o Calciohilairite (Ferrocolumbite) o Euchroite o Hercynite o Agate (Quartz) o Aurostibite o Calcite, see also o Conichalcite o Euxenite o Hessite o Aguilarite o Austinite Manganocalcite o Connellite o Euxenite-Y o Heulandite o Aktashite o Onyx o Copiapite o o Autunite o Fairchildite Hexahydrite o Alabandite o Caledonite o Copper o o Awaruite o Famatinite Hibschite o Albite o Cancrinite o Copper-zinc o o Axinite group o Fayalite Hillebrandite o Algodonite o Carnelian (Quartz) o Coquandite o o Azurite o Feldspar group Hisingerite o Allanite o Cassiterite o Cordierite o o Barite o Ferberite Hongshiite o Allanite-Ce o Catapleiite o Corrensite o o Bastnäsite -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Extraterrestrial Mineral Harder Than Diamonds Discovered in Israel Jan 15, 2019 Helen Flatley
Extraterrestrial Mineral Harder than Diamonds Discovered in Israel Jan 15, 2019 Helen Flatley A new discovery in the mountains of northern Israel has caused significant excitement for geologists around the world. While working in the Zevulun Valley, close to Mount Carmel, Israeli mining company Shefa Yamim found a new mineral never before discovered on earth. The International Mineralogical Association regularly approves new minerals for its official list, with up to 100 new substances added to the register each year. However, this latest discovery was hailed as a significant event, as it was previously believed that this type of mineral was only found on extraterrestrial material. The new mineral loosely resembles allendeite, a mineral previously seen on the Allende meteorite that fell to earth in February of 1969. However, this is the first time that such a substance has been found to naturally occur in rock on Earth itself. The CEO of Shefa Yamim, Abraham Taub, told Haaretz that the mineral had been named carmeltazite, after the place of its discovery and the minerals contained within its structure: titanium, aluminum and zirconium. While the majority of the new minerals approved by the International Mineralogical Association are unspectacular in appearance, carmeltazite offers considerable commercial opportunities, as it resembles other gemstones used in the making of jewelry. The crystal structure of carmeltazite. Photo by MDPI CC BY-SA 4.0 This strange new mineral was found embedded in cracks within sapphire, the second hardest mineral (after diamonds) found to occur naturally on earth. Carmeltazite closely resembles sapphire and ruby in its chemical composition, and is found in black, blue-green, or orange-brown colors, with a metallic hue. -
Mineralogical and Oxygen Isotopic Study of a New Ultrarefractory Inclusion in the Northwest Africa 3118 CV3 Chondrite
Meteoritics & Planetary Science 55, Nr 10, 2184–2205 (2020) doi: 10.1111/maps.13575 Mineralogical and oxygen isotopic study of a new ultrarefractory inclusion in the Northwest Africa 3118 CV3 chondrite Yong XIONG1, Ai-Cheng ZHANG *1,2, Noriyuki KAWASAKI3, Chi MA 4, Naoya SAKAMOTO5, Jia-Ni CHEN1, Li-Xin GU6, and Hisayoshi YURIMOTO3,5 1State Key Laboratory for Mineral Deposits Research, School of Earth Sciences and Engineering, Nanjing University, Nanjing 210023, China 2CAS Center for Excellence in Comparative Planetology,Hefei, China 3Department of Natural History Sciences, Hokkaido University, Sapporo 060-0810, Japan 4Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, USA 5Isotope Imaging Laboratory, Creative Research Institution Sousei, Hokkaido University, Sapporo 001-0021, Japan 6Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China *Corresponding author. E-mail: [email protected] (Received 27 March 2020; revision accepted 09 September 2020) Abstract–Calcium-aluminum-rich inclusions (CAIs) are the first solid materials formed in the solar nebula. Among them, ultrarefractory inclusions are very rare. In this study, we report on the mineralogical features and oxygen isotopic compositions of minerals in a new ultrarefractory inclusion CAI 007 from the CV3 chondrite Northwest Africa (NWA) 3118. The CAI 007 inclusion is porous and has a layered (core–mantle–rim) texture. The core is dominant in area and mainly consists of Y-rich perovskite and Zr-rich davisite, with minor refractory metal nuggets, Zr,Sc-rich oxide minerals (calzirtite and tazheranite), and Fe-rich spinel. The calzirtite and tazheranite are closely intergrown, probably derived from a precursor phase due to thermal metamorphism on the parent body. -
RINMANITE, Zn2sb2mg2fe4o14(OH)2, a NEW MINERAL SPECIES with a NOLANITE-TYPE STRUCTURE from the GARPENBERG NORRA MINE, DALARNA, SWEDEN
1675 The Canadian Mineralogist Vol. 39, pp. 1675-1683 (2001) RINMANITE, Zn2Sb2Mg2Fe4O14(OH)2, A NEW MINERAL SPECIES WITH A NOLANITE-TYPE STRUCTURE FROM THE GARPENBERG NORRA MINE, DALARNA, SWEDEN DAN HOLTSTAM§ Department of Mineralogy, Research Division, Swedish Museum of Natural History, Box 50007, SE-104 05 Stockholm, Sweden KJELL GATEDAL School of Mines and Metallurgy, Box 173, SE-682 24 Filipstad, Sweden KARIN SÖDERBERG AND ROLF NORRESTAM Department of Structural Chemistry, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden ABSTRACT Rinmanite, ideally Zn2Sb2Mg2Fe4O14(OH)2, is a new mineral species from the Garpenberg Norra Zn–Pb mine, Hedemora, Dalarna, in south-central Sweden, where it occurs in a skarn assemblage associated with tremolite, manganocummingtonite, talc, franklinite, barite and svabite. Rinmanite crystals are prismatic, up to 0.5 mm in length, with good {100} cleavage. The VHN100 –3 is in the range 841–907. Dcalc = 5.13(1) g•cm . The mineral is black (translucent dark red in thin splinters) with a submetallic luster. The mineral is moderately anisotropic and optically uniaxial (–). Reflectance values measured in air are 13.5–12.1% ( = 470 nm), 12.9–11.8% (546 nm), 12.6–11.7 (589 nm) and 12.2–11.3% (650 nm). Electron-microprobe analyses of rinmanite (wt.%) gave MgO 8.97, Al2O3 0.82, MnO 2.47, Fe2O3 34.33, ZnO 14.24, Sb2O5 36.31, H2O 1.99 (calculated), sum 99.13, yielding the empirical formula (Zn1.58Mn0.31Mg0.06)⌺1.95Sb2.03[Mg1.95Fe3.88Al0.15]⌺5.98O14.01(OH)1.99. Rinmanite is hexagonal, space group 3 P63mc, with a 5.9889(4), c 9.353(1) Å, V 290.53(5) Å and Z = 1. -
On the Nature and Significance of Rarity in Mineralogy
1 1 REVISION #2—American Mineralogist—January 12, 2016 2 3 On the nature and significance of rarity in mineralogy 4 5 Robert M. Hazen1* and Jesse H. Ausubel2 6 1Geophysical Laboratory, Carnegie Institution, 5251 Broad Branch Road NW, Washington, D. C. 20015, USA. 7 2Program for the Human Environment, Rockefeller University, 1230 York Ave., New York, New York 10021, USA. 8 9 ABSTRACT 10 More than half of the >5000 approved mineral species are known from 5 or fewer localities 11 and thus are rare. Mineralogical rarity arises from different circumstances, but all rare mineral 12 species conform to one or more of 4 criteria: (1) P-T-X range: minerals that form only under 13 highly restricted conditions in pressure-temperature-composition space; (2) Planetary constraints: 14 minerals that incorporate essential elements that are rare or that form at extreme conditions that 15 seldom occur in Earth’s near-surface environment; (3) Ephemeral phases: minerals that rapidly 16 break down under ambient conditions; and (4) Collection biases: phases that are difficult to 17 recognize because they lack crystal faces or are microscopic, or minerals that arise in lithological 18 contexts that are difficult to access. Minerals that conform to criterion (1), (2), or (3) are 19 inherently rare, whereas those matching criterion (4) may be much more common than 20 represented by reported occurences. 21 Rare minerals, though playing minimal roles in Earth’s bulk properties and dynamics, are 22 nevertheless of significance for varied reasons. Uncommon minerals are key to understanding 23 the diversity and disparity of Earth’s mineralogical environments, for example in the prediction 24 of as yet undescribed minerals. -
A Review of the Structural Architecture of Tellurium Oxycompounds
Mineralogical Magazine, May 2016, Vol. 80(3), pp. 415–545 REVIEW OPEN ACCESS A review of the structural architecture of tellurium oxycompounds 1 2,* 3 A. G. CHRISTY ,S.J.MILLS AND A. R. KAMPF 1 Research School of Earth Sciences and Department of Applied Mathematics, Research School of Physics and Engineering, Australian National University, Canberra, ACT 2601, Australia 2 Geosciences, Museum Victoria, GPO Box 666, Melbourne, Victoria 3001, Australia 3 Mineral Sciences Department, Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA 90007, USA [Received 24 November 2015; Accepted 23 February 2016; Associate Editor: Mark Welch] ABSTRACT Relative to its extremely low abundance in the Earth’s crust, tellurium is the most mineralogically diverse chemical element, with over 160 mineral species known that contain essential Te, many of them with unique crystal structures. We review the crystal structures of 703 tellurium oxysalts for which good refinements exist, including 55 that are known to occur as minerals. The dataset is restricted to compounds where oxygen is the only ligand that is strongly bound to Te, but most of the Periodic Table is represented in the compounds that are reviewed. The dataset contains 375 structures that contain only Te4+ cations and 302 with only Te6+, with 26 of the compounds containing Te in both valence states. Te6+ was almost exclusively in rather regular octahedral coordination by oxygen ligands, with only two instances each of 4- and 5-coordination. Conversely, the lone-pair cation Te4+ displayed irregular coordination, with a broad range of coordination numbers and bond distances. -
Sc,Ti,Al,Zr,Mg,Ca,□)2O3, a NEW ULTRA-REFRACTORY MINERAL in ALLENDE Chi Ma1*, Oliver Tschauner1,2, John R
75th Annual Meteoritical Society Meeting (2012) 5004.pdf DISCOVERY OF KANGITE, (Sc,Ti,Al,Zr,Mg,Ca,□)2O3, A NEW ULTRA-REFRACTORY MINERAL IN ALLENDE Chi Ma1*, Oliver Tschauner1,2, John R. Beckett1, George R. Rossman1, Wenjun Liu3. 1Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125, USA; 2High Pressure Science and Engineering Center and Department of Geoscience, University of Nevada, Las Vegas, NV 89154, USA; 3Advanced Photon Source, Argonne National Laboratory, Argonne, IL 60439, USA. *[email protected] Introduction: During a nano-mineralogy investigation of the Allende CV3 carbonaceous chondrite, we identified a new scan- dia mineral named “kangite” in an irregular ultra-refractory in- clusion. It has a cubic Ia3 bixbyite-type structure and a formula unit (Sc,Ti,Al,Zr,Mg,Ca,□)2O3. Field-emission SEM with EDS and electron back-scatter diffraction, electron microprobe and synchrotron micro-Laue diffraction were used to characterize the composition and structure. We report here the first occurrence of kangite in nature, as a new ultra-refractory oxide among the ear- liest solids formed in the solar nebula, and discuss its origin and significance for nebular processes. The mineral and the mineral name (kangite) have been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association (IMA 2011-092). Occurrence, Chemistry, and Crystallography: Kangite (26.6 wt% Sc2O3) appears as four irregular to subhedral grains, 1 to 4 μm in size, alone or in contact with REE-rich perovskite and MgAl-spinel in type davisite (up to 17.7 wt% Sc2O3) [1]. -
Design Rules for Discovering 2D Materials from 3D Crystals
Design Rules for Discovering 2D Materials from 3D Crystals by Eleanor Lyons Brightbill Collaborators: Tyler W. Farnsworth, Adam H. Woomer, Patrick C. O'Brien, Kaci L. Kuntz Senior Honors Thesis Chemistry University of North Carolina at Chapel Hill April 7th, 2016 Approved: ___________________________ Dr Scott Warren, Thesis Advisor Dr Wei You, Reader Dr. Todd Austell, Reader Abstract Two-dimensional (2D) materials are championed as potential components for novel technologies due to the extreme change in properties that often accompanies a transition from the bulk to a quantum-confined state. While the incredible properties of existing 2D materials have been investigated for numerous applications, the current library of stable 2D materials is limited to a relatively small number of material systems, and attempts to identify novel 2D materials have found only a small subset of potential 2D material precursors. Here I present a rigorous, yet simple, set of criteria to identify 3D crystals that may be exfoliated into stable 2D sheets and apply these criteria to a database of naturally occurring layered minerals. These design rules harness two fundamental properties of crystals—Mohs hardness and melting point—to enable a rapid and effective approach to identify candidates for exfoliation. It is shown that, in layered systems, Mohs hardness is a predictor of inter-layer (out-of-plane) bond strength while melting point is a measure of intra-layer (in-plane) bond strength. This concept is demonstrated by using liquid exfoliation to produce novel 2D materials from layered minerals that have a Mohs hardness less than 3, with relative success of exfoliation (such as yield and flake size) dependent on melting point. -
Minerals Found in Michigan Listed by County
Michigan Minerals Listed by Mineral Name Based on MI DEQ GSD Bulletin 6 “Mineralogy of Michigan” Actinolite, Dickinson, Gogebic, Gratiot, and Anthonyite, Houghton County Marquette counties Anthophyllite, Dickinson, and Marquette counties Aegirinaugite, Marquette County Antigorite, Dickinson, and Marquette counties Aegirine, Marquette County Apatite, Baraga, Dickinson, Houghton, Iron, Albite, Dickinson, Gratiot, Houghton, Keweenaw, Kalkaska, Keweenaw, Marquette, and Monroe and Marquette counties counties Algodonite, Baraga, Houghton, Keweenaw, and Aphrosiderite, Gogebic, Iron, and Marquette Ontonagon counties counties Allanite, Gogebic, Iron, and Marquette counties Apophyllite, Houghton, and Keweenaw counties Almandite, Dickinson, Keweenaw, and Marquette Aragonite, Gogebic, Iron, Jackson, Marquette, and counties Monroe counties Alunite, Iron County Arsenopyrite, Marquette, and Menominee counties Analcite, Houghton, Keweenaw, and Ontonagon counties Atacamite, Houghton, Keweenaw, and Ontonagon counties Anatase, Gratiot, Houghton, Keweenaw, Marquette, and Ontonagon counties Augite, Dickinson, Genesee, Gratiot, Houghton, Iron, Keweenaw, Marquette, and Ontonagon counties Andalusite, Iron, and Marquette counties Awarurite, Marquette County Andesine, Keweenaw County Axinite, Gogebic, and Marquette counties Andradite, Dickinson County Azurite, Dickinson, Keweenaw, Marquette, and Anglesite, Marquette County Ontonagon counties Anhydrite, Bay, Berrien, Gratiot, Houghton, Babingtonite, Keweenaw County Isabella, Kalamazoo, Kent, Keweenaw, Macomb, Manistee, -
New Mineral Names*,†
American Mineralogist, Volume 106, pages 1186–1191, 2021 New Mineral Names*,† Dmitriy I. Belakovskiy1 and Yulia Uvarova2 1Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18 korp. 2, Moscow 119071, Russia 2CSIRO Mineral Resources, ARRC, 26 Dick Perry Avenue, Kensington, Western Australia 6151, Australia In this issue This New Mineral Names has entries for 10 new species, including huenite, laverovite, pandoraite-Ba, pandoraite- Ca, and six new species of pyrochlore supergroup: cesiokenomicrolite, hydrokenopyrochlore, hydroxyplumbo- pyrochlore, kenoplumbomicrolite, oxybismutomicrolite, and oxycalciomicrolite. Huenite* hkl)]: 6.786 (25; 100), 5.372 (25, 101), 3.810 (51; 110), 2.974 (100; 112), P. Vignola, N. Rotiroti, G.D. Gatta, A. Risplendente, F. Hatert, D. Bersani, 2.702 (41; 202), 2.497 (38; 210), 2.203 (24; 300), 1.712 (60; 312), 1.450 (37; 314). The crystal structure was solved by direct methods and refined and V. Mattioli (2019) Huenite, Cu4Mo3O12(OH)2, a new copper- molybdenum oxy-hydroxide mineral from the San Samuel Mine, to R1 = 3.4% using the synchrotron light source. Huenite is trigonal, 3 Carrera Pinto, Cachiyuyo de Llampos district, Copiapó Province, P31/c, a = 7.653(5), c = 9.411(6) Å, V = 477.4 Å , Z = 2. The structure Atacama Region, Chile. Canadian Mineralogist, 57(4), 467–474. is based on clusters of Mo3O12(OH) and Cu4O16(OH)2 units. Three edge- sharing Mo octahedra form the Mo3O12(OH) unit, and four edge-sharing Cu-octahedra form the Cu4O16(OH)2 units of a “U” shape, which are in Huenite (IMA 2015-122), ideally Cu4Mo3O12(OH)2, trigonal, is a new mineral discovered on lindgrenite specimens from the San Samuel turn share edges to form a sheet of Cu octahedra parallel to (001).