A&A 432, 515–529 (2005) Astronomy DOI: 10.1051/0004-6361:20040331 & c ESO 2005 Astrophysics PAH charge state distribution and DIB carriers: Implications from the line of sight toward HD 147889, R. Ruiterkamp1,N.L.J.Cox2,M.Spaans3, L. Kaper2,B.H.Foing4,F.Salama5, and P. Ehrenfreund2 1 Leiden Observatory, PO Box 9513, 2300 RA Leiden, The Netherlands e-mail:
[email protected] 2 Institute Anton Pannekoek, Kruislaan 403, 1098 SJ Amsterdam, The Netherlands 3 Kapteyn Astronomical Institute, PO Box 800, 9700 AV Groningen, The Netherlands 4 ESA Research and Scientific Support Department, PO Box 299, 2200 AG Noordwijk, The Netherlands 5 Space Science Division, NASA Ames Research Center, Mail Stop 245-6, Moffett Field, California 94035, USA Received 25 February 2004 / Accepted 29 September 2004 Abstract. We have computed physical parameters such as density, degree of ionization and temperature, constrained by a large observational data set on atomic and molecular species, for the line of sight toward the single cloud HD 147889. Diffuse interstellar bands (DIBs) produced along this line of sight are well documented and can be used to test the PAH hypothesis. To this effect, the charge state fractions of different polycyclic aromatic hydrocarbons (PAHs) are calculated in HD 147889 as a function of depth for the derived density, electron abundance and temperature profile. As input for the construction of these charge state distributions, the microscopic properties of the PAHs, e.g., ionization potential and electron affinity, are determined for a series of symmetry groups. The combination of a physical model for the chemical and thermal balance of the gas toward HD 147889 with a detailed treatment of the PAH charge state distribution, and laboratory and theoretical data on specific PAHs, allow us to compute electronic spectra of gas phase PAH molecules and to draw conclusions about the required properties of PAHs as DIB carriers.