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United States Patent (19) 11) Patent Number: 4,634,789 Teller Et Al

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United States Patent (19) 11) Patent Number: 4,634,789 Teller Et Al United States Patent (19) 11) Patent Number: 4,634,789 Teller et al. 45 Date of Patent: "Jan. 6, 1987 54 CONVERSION OF ACETONTRILE TO 56) References Cited GLYCOLONTRILE AND/OR U.S. PATENT DOCUMENTS GLYCOLAMDE 3,516,789 6/1970 Sennewald et al. ......... 260/465.3 X (75) Inventors: Raymond G. Teller, Aurora; James F. 4,515,732 5/1985 Brazdil et al. .................... 260/465.6 Brazdil, Mayfield Village; Linda C. Glaeser, Middleburg Heights, all of OTHER PUBLICATIONS Ohio Deutsch et al.; J. Prabst. Chemie, 321 (1), (1979), pp. (73) Assignee: The Standard Oil Company, 137-40, Cleveland, Ohio Primary Examiner-Joseph Paul Brust * Notice: The portion of the term of this patent Attorney, Agent, or Firm-Charles S. Lynch; John E. subsequent to May 7, 2002 has been Miller; Larry W. Evans disclaimed. 21) Appl. No.: 643,207 57 ABSTRACT 22 Filed: Aug. 22, 1984 The vapor phase oxidation of acetonitrile with molecu lar oxygen in the presence or absence of water vapor to 51) Int. Cl. .................. C07C 121/34; CO7C 121/36; produce glycolonitrile or glycolamide in the presence CO7C 102/08 of a vanadium oxide based catalyst. 52 U.S. Cl. ..................................... 558/451; 558/457 58 Field of Search ..................... 260/465.6; 564/130; 558/451 10 Claims, No Drawings 4,634,789 1. 2 port being 5-95, usually 10-90 weight percent of the CONVERSION OF ACETONTRLE TO catalyst composition. GLYCOLONTRILE AND/OR GLYCOLAM DE Especially useful catalysts are where A is K, a is 0.005-0.05, b is zero and c is 2; and where B is Fe, a is This invention relates to a novel catalytic method of 5 zero, b is 0.05-0.5 and c is 2. making glycolonitrile and/or glycolamide from aceto It should be understood that the valence state of the nitrile. vanadium or other metals in the active catalyst during The conventional method to prepare glycolonitrile the catalytic reaction is not known. has been by the reaction of formaldehyde with either The overall reaction going from acetonitrile to hydrocyanic acid or with a mixture of water and so O glycolonitrile or glycolamide (or both) requires one half dium cyanide. Glycolonitrile can be hydrolyzed to mole of molecular oxygen gas. However, according to glycolamide. Because of the relatively dangerous nature the invention it is contemplated that a deficiency of of inorganic cyanides, it is desirable to avoid such start oxygen can be employed, as little as, for instance, one ing material reactants. Moreover, acetonitrile is a prod tenth mole per mole of acetonitrile, with unreacted uct which is available in fairly large quantities as a by 15 product from other processes and it is of rather low acetonitrile being available for recycle. Usually no more value, and is thus an inexpensive starting material. than two moles of molecular oxygen are employed for It is an object of the present invention to provide a each mole of acetonitrile, although higher ratios can be new catalytic method for making glycolonitrile and/or employed. glycolamide that does not utilize inorganic cyanides. The reaction is effected attemperatures between 200 It is a further object of the present invention to pro 20 and 700° C., usually between 250 and 550 C. The vide a catalytic process for making glycolonitrile and gaseous molecular oxygen can of course be diluted with /or glycolamide from acetonitrile. a nonreactive gas such as nitrogen; in this connection, Other objects, as well as aspects and advantages, of air can of course be used. The reaction is effected by the invention will become aparent from a study of the contacting the reactants with the solid heterogeneous specification and claims. 25 Vanadium oxidation catalyst, and can be carried out in a The foregoing objectives are realized by the present fixed bed, fluid bed, transfer line or a gravitating mov invention according to which there is provided a cata ing bed reactor. Reactor pressures are not critical and lytic process for making glycolonitrile or glycolamide can be well below or well above atmospheric, but abso which comprises the vapor phase oxidatin of acetoni o lute pressures of 10 to 20 psi are usually empoyed. trile with molecular oxygen in the presence or absence It is a feature of the invention that one or both of of water vapor and in the presence of a solid vanadium fumaronitrile or maleonitrile are sometimes co-pro oxide based catalyst having the elements and the pro duced with the glycolonitrile and these useful products portions indicated by the following empirical formula: can be recovered and sold as such or converted to the corresponding diacids. AaBtVOx 35 The following specific examples are illustrative only where and demonstrate (1) the preparation of specific catalysts A is one or more of K, Na, Rb, Cs, Tl, Mg, Ca, Li; useful in the claimed process as well as (2) representa B is one or more of Ti, Cr, Mn, Fe, Co, Ni, Cu, Ag, tive examples of the catalytic oxidation process of the Zn, Au, Zr, Nb, Mo, Ta, W, Th,La Ce, Pr, Nd, Sm, 40 present invention. Eu, Sb, Te, and Sn EXAMPLE 1. a=0-2, usually 0-1, b=0-3, usually 0-1, At low heat, ammonium metavanadate was dissolved c=2-15, in about 600 ml. of water. The temperature was raised c2(a-b) and 45 to drive off water while stirring. It was dried at 120° C. X is determined by the oxidaton state of the other overnight. It was then denitrified at 290 C. for 3 hours elements present. and then 425 C. for 3 hours. It was slurried in 300 ml. When effected in the presence of water either or both of water and placed in a 120° C. oven over the weekend. of glycolamide and glycolonitrile is formed in a single THe resulting dark blue V2O5 catalyst was ground to step. SO 20-35 mesh and then calcined at 550 C. for 3 hours In the foregoing process an especially useful group of prior to use. catalysts are vanadium oxide based catalysts having the elements and the proportions indicated by the following EXAMPLE 2. empirical formula: NHVO3 (116.99 g) was stirred in about 300 ml of 55 distilled water with low heat. Silica sol (69.27 g. 40% AaBBVOx SiO2) was added. Cupric nitrate (Cu(NO3)2.(2.5 H2O, 58.15 g) was then added. The resulting slurry was where heated and stirred to remove part of the water. It was A is one or more of K, Cs, and Mg; then heated at 120° C. overnight to dry the solids. The B is one or more of Ti, Cr, Fe and Cu; dried material was then denitrified by heating at 290 C. a=0-2, usually 0-1; for 3 hours, followed by 425 C. for 3 hours. It was b=0-3, usually 0-1; ground to 20-35 mesh particle size. The catalyst was c=2-15; 80% CuosV2O, on 20 percent SiO2 support. c2(a-b) and x is determined by the oxidation state of the other 65 EXAMPLE 3 elements present. NHVO3 (116.99g.) was dissolved in about 600 ml of The catalysts can be on an inorganic oxide support distilled water. Silica sol (56.84 g. 40% SiO2) was such as alumina, silica, silica-alumina, etc. with the sup added. The resulting slurry was then heated and stirred 4,634,789 3 4 to remove part of the water. It was dried by heating without departing from the spirit and scope of the dis overnight at about 120° C. The catalyst was then deni- closure or from the scope of the claims. trified and ground as in Example 2. This catalyst was We claim: 80% V2O5 on 20% SiO2 support. 1. The production of glycolonitrile or glycolamide by 5 the vapor phase oxidation of acetonitrile with molecular EXAMPLE 4 oxygen in the absence or presence of water vapor and in NHAVO3 (116.99g.) was stirred in about 300 ml of the presence of a vanadium oxide based catalyst having distilled water with low heat. Silica sol (59.33 g. 40% the elements and the proportions indicated by the fol SiO2) was added. Ferric nitrate (Fe(NO3)39 H2O, 20.2 lowing empirical formula: g). was then added. The resulting slurry heated and 10 stirred to remove part of the water. It was then heated AgBtVOx at 120° C. overnight to dry the solids. The dried mate rial was then denitrified by heating at 290' C. for 3 where hours, followed by 425 C. for 3 hours. It was ground to A is one or more of K, Na, Rb, Cs, Tl, Mg, Ca, Li; 20-35 mesh particle size. This catalyst was 80% Feo.1. 15 B is one or more of Ti, Cr, Mn, Fe, Co, Ni, Cu, Ag, V2Ox on 20 percent SiO2 support. Zn, Au, Zr, Nb, Mo, Ta, W, Th, La Ce, Pr, Nd, Sm, Eu, Sb, Te, and Sn EXAMPLE 5 as 0-2 NH4VO3 (116.99 g) was stirred in about 300 ml of b=0-3 distilled water with low heat. Silica sol (56.94 g. 40% 20 c2-15, SiO2) was added. Potassium nitrate (KNO3) was then c2(a+b) and added. The resulting slurry heated and stirred to re- x is determined by the oxidation state of the other move part of the water. It was then heated at 120° C. elements present, wherein glycolamide is produced overnight to dry the solids. The dried material was then only when water is present.
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