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Safety Data Sheet Propionaldehyde

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Safety Data Sheet Propionaldehyde Safety data sheet Issue Date 14-Nov-2019 Revision Date 14-Nov-2019 Version 3 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product Name Propionaldehyde Chemical Name CAS No EC No REACH Registration Number Propionaldehyde 123-38-6 204-623-0 01-2119456625-33-0001 Pure substance/mixture Substance 1.2. Relevant identified uses of the substance or mixture and uses advised against Application Use: as an intermediate, strictly controlled conditions applies (exposure scenarios not required) Uses advised against Not identified. 1.3. Details of the supplier of the safety data sheet Manufacturer Perstorp Oxo AB SE-444 84 Stenungsund Sweden Tel. +46 303 728600 Fax. +46 303 728607 www.perstorp.com E-mail address [email protected] 1.4. Emergency telephone number Europe (+)1 760 476 3961 (contract no: 334101) United Kingdom (+)44 8 08 189 0979 (contract no: 334101) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute toxicity - Oral Category 4 - (H302) Acute toxicity - Inhalation (Vapours) Category 4 - (H332) Skin corrosion/irritation Category 2 - (H315) Serious eye damage/eye irritation Category 2 - (H319)* Specific target organ toxicity (single exposure) Category 3 - (H335) Flammable liquids Category 2 - (H225) 2.2. Label elements Symbols/Pictograms Signal word ___________________________________________________________________________________________ Page 1 / 10 EUGB - BE Propionaldehyde Revision Date 14-Nov-2019 ___________________________________________________________________________________________ Danger Hazard statements H225 - Highly flammable liquid and vapour H332 - Harmful if inhaled H302 - Harmful if swallowed H319 - Causes serious eye irritation H315 - Causes skin irritation H335 - May cause respiratory irritation Precautionary Statements P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P241 - Use explosion-proof electrical/ ventilating/ lighting/ equipment P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P312 - Call a POISON CENTER or doctor if you feel unwell P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337 + P313 - If eye irritation persists: Get medical advice/attention Contains: Propionaldehyde 2.3. Other hazards * The substance has a harmonised EU classification with Eye Irritation Cat 2. Test data have however shown that the damages were not reversible within 21 days which means that the substance should be regarded as a substance classified with Eye Irritation Cat 1. SECTION 3: Composition/information on ingredients 3.1 Substances Chemical Name EC No CAS No REACH Registration Weight-% Classification according to Number Regulation (EC) No. 1272/2008 [CLP] Propionaldehyde 204-623-0 123-38-6 01-2119456625-33-0001 100 Flam. Liq. 2 (H225) Acute Tox. 4 (H302) Acute Tox. 4 (H332) Skin Irrit. 2 (H315) Eye Irrit. 2 (H319) STOT SE 3 (H335) Full text of H- and EUH-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures General advice Remove contaminated clothing and shoes. First aid personnel should pay attention to their own safety. Inhalation Remove to fresh air. If breathing is irregular or stopped, administer artificial respiration. Keep victim warm and quiet. Seek immediate medical attention/advice. Skin contact Immediately flush skin with water and rinse skin with soap and water for at least 5-10 minutes. Use lukewarm water if possible. Remove contaminated clothing and shoes. Get medical attention if redness does not disappear. Eye contact Important! Immediately rinse cautiously with tempered water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention. Ingestion Clean mouth with water and drink plenty of water afterwards. Do NOT induce vomiting. Seek immediate medical attention/advice. 4.2. Most important symptoms and effects, both acute and delayed Inhalation: May cause irritation of the upper respiratory tract. Excessive inhalation of high concentrations may cause nausea, ___________________________________________________________________________________________ Page 2 / 10 EUGB - BE Propionaldehyde Revision Date 14-Nov-2019 ___________________________________________________________________________________________ vomiting, headache, and dizziness. Skin contact: May cause redness and swelling of the skin. Absorption of harmful amounts is not likely. Eye contact: Causes severe irritation with flood of tears and pain and strong redness and swelling of the eye. Risk of damage to the conjunctiva and cornea. Ingestion: May cause irritation of the mouth, throat, esophagus, and stomach including severe pain. Nausea, vomiting, diarrhea, dizziness or drowsiness, and headache may as well occur. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Alcohol resistant foam. Carbon dioxide (CO2). Extinguishing powder. Unsuitable extinguishing media High volume water jet. Do not use a solid water stream as it may scatter and spread fire. 5.2. Special hazards arising from the substance or mixture The substance is a flammable liquid and may form explosive air/vapour mixtures. Vapour is heavier than air and may accumulate in low areas and travel a considerable distance up to the source of ignition. When flames are extinguished, explosive re-ignition may occur. Hazardous combustion products Carbon dioxide (CO2), Carbon monoxide (CO). 5.3. Advice for firefighters Wear self-contained breathing apparatus and protective suit. Additional information Prevent fire extinguishing water from contaminating surface water or the ground water system. Cool containers with flooding quantities of water until well after fire is out. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures The substance/product is registered with strictly controlled conditions as defined in Article 18(4) of Regulation (EC) No. 1907/2006 (REACH Regulation) and must therefore be handled as such. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep unprotected persons away. In case of major spill contact the rescue services. For emergency responders: Wear fully protective suit. Wear full face mask with filter for organic substances. 6.2. Environmental precautions Do not allow into any sewer, on the ground or into any body of water. Local authorities should be advised if significant spillages cannot be contained. See Section 12 for additional ecological information. 6.3. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Small spill Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large spill Pump up the product into a spare container suitably labelled. Ground container and fittings. Methods for cleaning up Clean contaminated surface thoroughly. Use clean non-sparking tools to collect absorbed material. 6.4. Reference to other sections See Section 7,8,13 for more information. SECTION 7: Handling and storage 7.1. Precautions for safe handling Handle only under strictly controlled conditions in accordance with Regulation (EC) No. 1907/2006, Art. 18 (4). Comply with ___________________________________________________________________________________________ Page 3 / 10 EUGB - BE Propionaldehyde Revision Date 14-Nov-2019 ___________________________________________________________________________________________ 2014/34/EU concerning equipment and protective systems intended for use in potentially explosive atmospheres and, Directive 1999/92/EC regarding minimum requirements for improving the safety and health protection of workers potentially at risk from explosive atmospheres. Keep away from sources of ignition - No smoking. Take action to prevent static discharges. General Hygiene Considerations Not applicable. No exposure expected. 7.2. Conditions for safe storage, including any incompatibilities Store under inert atmosphere, e.g. nitrogen pad. Keep in a cool place. 7.3. Specific end use(s) Not applicable. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure Limits Keep personal exposure levels below Derived No Effect Level (DNEL) and national exposure limit values (if existing). Derived No Effect Level (DNEL) - worker No DNEL values have been calculated since the product is an intermediate which must be handled according to strictly controlled conditions. Derived No Effect Level (DNEL) - Consumer No DNEL values have been calculated since the product is an intermediate which must be handled according to strictly controlled conditions. Predicted No Effect Concentration (PNEC) No PNEC values have been calculated since the product is an intermediate which must be handled according to strictly controlled conditions. 8.2. Exposure controls Appropriate engineering controls Comply with 2014/34/EU concerning equipment and protective systems intended for use in potentially explosive atmospheres and, Directive 1999/92/EC regarding minimum requirements for improving the safety and health protection of workers potentially at risk from explosive atmospheres. Individual protection
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