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Eur. J. Mineral., 32, 449–455, 2020 https://doi.org/10.5194/ejm-32-449-2020 © Author(s) 2020. This work is distributed under the Creative Commons Attribution 4.0 License. Luxembourgite, AgCuPbBi4Se8, a new mineral species from Bivels, Grand Duchy of Luxembourg Simon Philippo1, Frédéric Hatert2, Yannick Bruni2, Pietro Vignola3, and Jiríˇ Sejkora4 1Laboratoire de Minéralogie, Musée National d’Histoire Naturelle, Rue Münster 25, 2160 Luxembourg, Luxembourg 2Laboratoire de Minéralogie, Université de Liège B18, 4000 Liège, Belgium 3CNR-Istituto di Geologia Ambientale e Geoingegneria, via Mario Bianco 9, 20131 Milan, Italy 4Department of Mineralogy and Petrology, National Museum, Cirkusová 1740, 193 00 9, Prague, Czech Republic Correspondence: Frédéric Hatert ([email protected]) Received: 24 March 2020 – Revised: 30 June 2020 – Accepted: 15 July 2020 – Published: 12 August 2020 Abstract. Luxembourgite, ideally AgCuPbBi4Se8, is a new selenide discovered at Bivels, Grand Duchy of Lux- embourg. The mineral forms tiny fibres reaching 200 µm in length and 5 µm in diameter, which are deposited on dolomite crystals. Luxembourgite is grey, with a metallic lustre and without cleavage planes; its Mohs hard- ness is 3 and its calculated density is 8.00 g cm−3. Electron-microprobe analyses indicate an empirical formula Ag1:00.Cu0:82Ag0:20Fe0:01/61:03Pb1:13Bi4:11.Se7:72S0:01/67:73, calculated on the basis of 15 atoms per formula unit. A single-crystal structure refinement was performed to R1 D 0:0476, in the P 21=m space group, with 3 a D 13:002.1/, b D 4:1543.3/, c D 15:312.2/Å, β D 108:92.1/◦, V D 782:4.2/Å , Z D 2. -
A New Sulfide Mineral (Mncr2s4) from the Social Circle IVA Iron Meteorite
American Mineralogist, Volume 101, pages 1217–1221, 2016 Joegoldsteinite: A new sulfide mineral (MnCr2S4) from the Social Circle IVA iron meteorite Junko Isa1,*, Chi Ma2,*, and Alan E. Rubin1,3 1Department of Earth, Planetary, and Space Sciences, University of California, Los Angeles, California 90095, U.S.A. 2Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, U.S.A. 3Institute of Geophysics and Planetary Physics, University of California, Los Angeles, California 90095, U.S.A. Abstract Joegoldsteinite, a new sulfide mineral of end-member formula MnCr2S4, was discovered in the 2+ Social Circle IVA iron meteorite. It is a thiospinel, the Mn analog of daubréelite (Fe Cr2S4), and a new member of the linnaeite group. Tiny grains of joegoldsteinite were also identified in the Indarch EH4 enstatite chondrite. The chemical composition of the Social Circle sample determined by electron microprobe is (wt%) S 44.3, Cr 36.2, Mn 15.8, Fe 4.5, Ni 0.09, Cu 0.08, total 101.0, giving rise to an empirical formula of (Mn0.82Fe0.23)Cr1.99S3.95. The crystal structure, determined by electron backscattered diffraction, is aFd 3m spinel-type structure with a = 10.11 Å, V = 1033.4 Å3, and Z = 8. Keywords: Joegoldsteinite, MnCr2S4, new sulfide mineral, thiospinel, Social Circle IVA iron meteorite, Indarch EH4 enstatite chondrite Introduction new mineral by the International Mineralogical Association (IMA 2015-049) in August 2015. It was named in honor of Thiospinels have a general formula of AB2X4 where A is a divalent metal, B is a trivalent metal, and X is a –2 anion, Joseph (Joe) I. -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Fe,Mg)S, the IRON-DOMINANT ANALOGUE of NININGERITE
1687 The Canadian Mineralogist Vol. 40, pp. 1687-1692 (2002) THE NEW MINERAL SPECIES KEILITE, (Fe,Mg)S, THE IRON-DOMINANT ANALOGUE OF NININGERITE MASAAKI SHIMIZU§ Department of Earth Sciences, Faculty of Science, Toyama University, 3190 Gofuku, Toyama 930-8555, Japan § HIDETO YOSHIDA Department of Earth and Planetary Science, Graduate School of Science, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan § JOSEPH A. MANDARINO 94 Moore Avenue, Toronto, Ontario M4T 1V3, and Earth Sciences Division, Royal Ontario Museum, 100 Queens’s Park, Toronto, Ontario M5S 2C6, Canada ABSTRACT Keilite, (Fe,Mg)S, is a new mineral species that occurs in several meteorites. The original description of niningerite by Keil & Snetsinger (1967) gave chemical analytical data for “niningerite” in six enstatite chondrites. In three of those six meteorites, namely Abee and Adhi-Kot type EH4 and Saint-Sauveur type EH5, the atomic ratio Fe:Mg has Fe > Mg. Thus this mineral actually represents the iron-dominant analogue of niningerite. By analogy with synthetic MgS and niningerite, keilite is cubic, with space group Fm3m, a 5.20 Å, V 140.6 Å3, Z = 4. Keilite and niningerite occur as grains up to several hundred m across. Because of the small grain-size, most of the usual physical properties could not be determined. Keilite is metallic and opaque; in reflected light, it is isotropic and gray. Point-count analyses of samples of the three meteorites by Keil (1968) gave the following amounts of keilite (in vol.%): Abee 11.2, Adhi-Kot 0.95 and Saint-Sauveur 3.4. -
Magmatic Sulfides in the Porphyritic Chondrules of EH Enstatite Chondrites
Published in Geochimica et Cosmochimica Acta, Accepted September 2016. http://dx.doi.org/10.1016/j.gca.2016.09.010 Magmatic sulfides in the porphyritic chondrules of EH enstatite chondrites. Laurette Piani1,2*, Yves Marrocchi2, Guy Libourel3 and Laurent Tissandier2 1 Department of Natural History Sciences, Faculty of Science, Hokkaido University, Sapporo, 060-0810, Japan 2 CRPG, UMR 7358, CNRS - Université de Lorraine, 54500 Vandoeuvre-lès-Nancy, France 3 Laboratoire Lagrange, UMR7293, Université de la Côte d’Azur, CNRS, Observatoire de la Côte d’Azur,F-06304 Nice Cedex 4, France *Corresponding author: Laurette Piani ([email protected]) Abstract The nature and distribution of sulfides within 17 porphyritic chondrules of the Sahara 97096 EH3 enstatite chondrite have been studied by backscattered electron microscopy and electron microprobe in order to investigate the role of gas-melt interactions in the chondrule sulfide formation. Troilite (FeS) is systematically present and is the most abundant sulfide within the EH3 chondrite chondrules. It is found either poikilitically enclosed in low-Ca pyroxenes or scattered within the glassy mesostasis. Oldhamite (CaS) and niningerite [(Mg,Fe,Mn)S] are present in ! 60 % of the chondrules studied. While oldhamite is preferentially present in the mesostasis, niningerite associated with silica is generally observed in contact with troilite and low-Ca pyroxene. The Sahara 97096 chondrule mesostases contain high abundances of alkali and volatile elements (average Na2O = 8.7 wt.%, K2O = 0.8 wt.%, Cl = 7000 ppm and S = 3700 ppm) as well as silica (average SiO2 = 63.1 wt.%). Our data suggest that most of the sulfides found in EH3 chondrite chondrules are magmatic minerals that formed after the dissolution of S from a volatile-rich gaseous environment into the molten chondrules. -
Moon Minerals a Visual Guide
Moon Minerals a visual guide A.G. Tindle and M. Anand Preliminaries Section 1 Preface Virtual microscope work at the Open University began in 1993 meteorites, Martian meteorites and most recently over 500 virtual and has culminated in the on-line collection of over 1000 microscopes of Apollo samples. samples available via the virtual microscope website (here). Early days were spent using LEGO robots to automate a rotating microscope stage thanks to the efforts of our colleague Peter Whalley (now deceased). This automation speeded up image capture and allowed us to take the thousands of photographs needed to make sizeable (Earth-based) virtual microscope collections. Virtual microscope methods are ideal for bringing rare and often unique samples to a wide audience so we were not surprised when 10 years ago we were approached by the UK Science and Technology Facilities Council who asked us to prepare a virtual collection of the 12 Moon rocks they loaned out to schools and universities. This would turn out to be one of many collections built using extra-terrestrial material. The major part of our extra-terrestrial work is web-based and we The authors - Mahesh Anand (left) and Andy Tindle (middle) with colleague have build collections of Europlanet meteorites, UK and Irish Peter Whalley (right). Thank you Peter for your pioneering contribution to the Virtual Microscope project. We could not have produced this book without your earlier efforts. 2 Moon Minerals is our latest output. We see it as a companion volume to Moon Rocks. Members of staff -
Sulfides in Enstate Chondrites
Sulfides in Enstatite Chondrites: Indicators of Impact History Kristyn Hill1,2, Emma Bullock2, Cari Corrigan2, and Timothy McCoy2 1Lock Haven University of Pennsylvania, Lock Haven, PA 17745, USA 2National Museum of Natural History, Department of Mineral Sciences, Washington D.C. 20013, USA Introductton Results Discussion Enstatite chondrites are a class of meteorites. They are Determining the history of the parent body of a referred to as chondrites because of the spherical Impact Melt, Slowly Cooled chondritic meteorite often includes distinguishing whether chondrules found in the matrix of the meteorites. Enstatite aa bb cc d d or not the meteorite was impact melted, and the cooling chondrites are the most highly reduced meteorites and rate. contain iron-nickel metal and sulfide bearing minerals. The Impact melts are distinguishable by the texture of the matrix is made up of silicates, enstatite in particular. There metal and sulfide assemblages. A meteorite that was are usually no oxides found, which supports the idea that impact melted will contain a texture of euhedral to these formed in very oxygen poor environments. The subhedral silicates, like enstatite, protruding into the metal enstatite chondrites in this study are type 3, meaning they or sulfides (figure 2). Some textures will look shattered are unmetamorphosed and not affected by fluids. (figure 2b). Meteorites that contain the mineral keilite are Studying enstatite chondrites will help us determine the PCA 91125 ALHA 77156 PCA 91444 PCA 91085 also an indicator of impact melts (figure 3). Keilite only evolution of their parent bodies which formed at the occurs in enstatite chondrite impact-melt rocks that cooled beginning of our solar system. -
Thermal History of the Enstatite Chondrites from Silica Polymorphs
Meteoritics & Planetary Science 40, Nr 6, 855–868 (2005) Abstract available online at http://meteoritics.org Thermal history of the enstatite chondrites from silica polymorphs M. KIMURA1*, M. K. WEISBERG2, Y. LIN3, A. SUZUKI4, E. OHTANI4, and R. OKAZAKI5 1Faculty of Science, Ibaraki University, Mito 310-8512, Japan 2Department of Physical Sciences, Kingsborough College of the City University of New York, Brooklyn, New York 11235, and Department of Earth and Planetary Sciences, American Museum of Natural History, New York, New York 10024, USA 3State Key Laboratory of Lithosphere Tectonic Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China 4Institute of Mineralogy, Petrology, and Economic Geology, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan 5Department of Earth and Planetary Sciences, Faculty of Sciences, Kyushu University, Fukuoka 812-8581, Japan *Corresponding author. E-mail: [email protected] (Received 18 January 2005; revision accepted 14 April 2005) Abstract–Here we report the results of our petrologic and mineralogical study of enstatite (E) chondrites in order to explore their thermal histories. We studied silica phases in 20 E chondrites by laser micro Raman spectroscopy to determine the silica polymorphs they contain. Silica phases are commonly present in E chondrites and their polymorphs reflect the physical conditions of formation. The samples studied here include EH3–5, EL3–6, E chondrite melt rocks, and an anomalous E chondrite. We identified quartz, tridymite, cristobalite, and silica glass in the samples studied. EH4– 5 and EH melt rocks are divided into high and low temperature classes based on niningerite- alabandite solid solutions. -
Buseckite, (Fe,Zn,Mn)S, a New Mineral from the Zakłodzie Meteorite
American Mineralogist, Volume 97, pages 1226–1233, 2012 Buseckite, (Fe,Zn,Mn)S, a new mineral from the Zakłodzie meteorite CHI MA,* JOHN R. BECKETT, AND GEORGE R. ROSSMAN Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, U.S.A. ABSTRACT Buseckite (IMA 2011-070), (Fe,Zn,Mn)S, is the Fe-dominant analog of wurtzite, a new member of the wurtzite group discovered in Zakłodzie, and an ungrouped enstatite-rich achondrite. The type material occurs as single-crystal grains (4–20 µm in size) in contact with two or more of enstatite, plagioclase, troilite, tridymite, quartz, and sinoite. Low-Ni iron, martensitic iron, schreibersite, keilite, cristobalite, and graphite, which are also present in the type sample, are not observed to be in contact with buseckite. Buseckite is black under diffuse illumination and nearly opaque grayish brown in transmitted light. The mean chemical composition of buseckite, as determined by electron micro- probe analysis of the type material, is (wt%) S 35.84, Fe 28.68, Zn 23.54, Mn 10.04, Mg 1.18, sum 99.28, leading to an empirical formula calculated on the basis of 2 atoms of (Fe0.46Zn0.32Mn0.16Mg0.04 )∑0.99S1.01. Electron backscatter diffraction patterns of buseckite are a good match to that of synthetic 3 (Zn0.558Fe0.442)S with the P63mc structure, showing a = 3.8357, c = 6.3002 Å, V = 80.27 Å , and Z = 2. Buseckite is likely derived from the breakdown of high-temperature pyrrhotite to form troilite and buseckite following the solidification of sulfide-rich liquids produced during impact melting of an enstatite-rich rock. -
By Michael Fleischer and Constance M. Schafer Open-File Report 81
U.S. DEPARTMENT OF THE INTERIOR GEOLOGICAL SURVEY THE FORD-FLEISCHER FILE OF MINERALOGICAL REFERENCES, 1978-1980 INCLUSIVE by Michael Fleischer and Constance M. Schafer Open-File Report 81-1174 This report is preliminary and has not been reviewed for conformity with U.S. Geological Survey editorial standards 1981 The Ford-Fleischer File of Mineralogical References 1978-1980 Inclusive by Michael Fleischer and Constance M. Schafer In 1916, Prof. W.E. Ford of Yale University, having just published the third Appendix to Dana's System of Mineralogy, 6th Edition, began to plan for the 7th Edition. He decided to create a file, with a separate folder for each mineral (or for each mineral group) into which he would place a citation to any paper that seemed to contain data that should be considered in the revision of the 6th Edition. He maintained the file in duplicate, with one copy going to Harvard University, when it was agreed in the early 1930's that Palache, Berman, and Fronde! there would have the main burden of the revision. A number of assistants were hired for the project, including C.W. Wolfe and M.A. Peacock to gather crystallographic data at Harvard, and Michael Fleischer to collect and evaluate chemical data at Yale. After Prof. Ford's death in March 1939, the second set of his files came to the U.S. Geological Survey and the literature has been covered since then by Michael Fleischer. Copies are now at the U.S. Geological Survey at Reston, Va., Denver, Colo., and Menlo Park, Cal., and at the U.S. -
Alphabetical List
LIST L - MINERALS - ALPHABETICAL LIST Specific mineral Group name Specific mineral Group name acanthite sulfides asbolite oxides accessory minerals astrophyllite chain silicates actinolite clinoamphibole atacamite chlorides adamite arsenates augite clinopyroxene adularia alkali feldspar austinite arsenates aegirine clinopyroxene autunite phosphates aegirine-augite clinopyroxene awaruite alloys aenigmatite aenigmatite group axinite group sorosilicates aeschynite niobates azurite carbonates agate silica minerals babingtonite rhodonite group aikinite sulfides baddeleyite oxides akaganeite oxides barbosalite phosphates akermanite melilite group barite sulfates alabandite sulfides barium feldspar feldspar group alabaster barium silicates silicates albite plagioclase barylite sorosilicates alexandrite oxides bassanite sulfates allanite epidote group bastnaesite carbonates and fluorides alloclasite sulfides bavenite chain silicates allophane clay minerals bayerite oxides almandine garnet group beidellite clay minerals alpha quartz silica minerals beraunite phosphates alstonite carbonates berndtite sulfides altaite tellurides berryite sulfosalts alum sulfates berthierine serpentine group aluminum hydroxides oxides bertrandite sorosilicates aluminum oxides oxides beryl ring silicates alumohydrocalcite carbonates betafite niobates and tantalates alunite sulfates betekhtinite sulfides amazonite alkali feldspar beudantite arsenates and sulfates amber organic minerals bideauxite chlorides and fluorides amblygonite phosphates biotite mica group amethyst -
Volatization of Extraterrestrial Materials As Determined by Zinc Isotopic Analysis Randal Christopher Paniello Washington University in St
Washington University in St. Louis Washington University Open Scholarship All Theses and Dissertations (ETDs) 12-27-2013 Volatization of Extraterrestrial Materials as Determined by Zinc Isotopic Analysis Randal Christopher Paniello Washington University in St. Louis Follow this and additional works at: https://openscholarship.wustl.edu/etd Part of the Earth Sciences Commons Recommended Citation Paniello, Randal Christopher, "Volatization of Extraterrestrial Materials as Determined by Zinc Isotopic Analysis" (2013). All Theses and Dissertations (ETDs). 1188. https://openscholarship.wustl.edu/etd/1188 This Dissertation is brought to you for free and open access by Washington University Open Scholarship. It has been accepted for inclusion in All Theses and Dissertations (ETDs) by an authorized administrator of Washington University Open Scholarship. For more information, please contact [email protected]. WASHINGTON UNIVERSITY IN ST. LOUIS Department of Earth and Planetary Sciences Dissertation Examination Committee: Frederic Moynier, Chair Alex Bradley Jeffrey G. Catalano Bruce Fegley Christine Floss Brad Joliff Ernst Zinner Volitization of Extraterrestrial Materials as Determined by Zinc Isotopic Analysis by Randal C Paniello A dissertation presented to the Graduate School of Arts and Sciences of Washington University in partial fulfillment of the requirements for the degree of Doctor of Philosophy December 2013 St. Louis, Missouri © 2013 Randal C. Paniello ii TABLE OF CONTENTS List of Figures………………………………………………………………………….. v List of Tables…………………………………………………………………………… vii Acknowledgements…………………………………………………………………….. ix Statement on Role of Candidate in Coauthored Work………………………………….. x 1. Introduction……………………………………………………………………………. 1 a. References…………………………………………………………………….... 9 2. Methodology……………………………………………………………………………. 11 3. Martian Meteorites and Lunar Materials a. Introduction……………………………………………………………………. 15 b. Manuscript: “Zinc isotopic evidence for the origin of the Moon”……………… 17 c.