Erwin Schrödinger: a Compreensão Do Mundo Infinitesimal Através De Uma Realidade Ondulatória

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Erwin Schrödinger: a Compreensão Do Mundo Infinitesimal Através De Uma Realidade Ondulatória Douglas Guilherme Schmidt Erwin Schrödinger: a compreensão do mundo infinitesimal através de uma realidade ondulatória Mestrado em História da Ciência Pontifícia Universidade Católica de São Paulo São Paulo 2008 Douglas Guilherme Schmidt Erwin Schrödinger: a compreensão do mundo infinitesimal através de uma realidade ondulatória MESTRADO EM HISTÓRIA DA CIÊNCIA Dissertação apresentada à Banca Examinadora como exigência parcial para obtenção do título de Mestre em História da Ciência pela Pontifícia Universidade Católica de São Paulo, sob a orientação da Profa. Doutora Lilian Al-Chueyr Pereira Martins. Pontifícia Universidade Católica de São Paulo São Paulo 2008 SCHMIDT, Douglas Guilherme. “Erwin Schrödinger: a compreensão do mundo infinitesimal através de uma realidade ondulatória” São Paulo, 2008. Dissertação (Mestrado) – PUC-SP Programa: História da Ciência Orientadora: Profa. Dra. Lilian Al-Chueyr Pereira Martins Folha de aprovação Banca Examinadora _________________________________ _________________________________ _________________________________ Autorizo, exclusivamente para fins acadêmicos e científicos, a reprodução total ou parcial desta dissertação por processos fotocopiadores ou eletrônicos. Ass.: _____________________________________________________ Local e data: _______________________________________________ [email protected] A minha mãe Eliana, a minha esposa Maria Ângela e à memória de meu pai Guilherme. Agradecimentos À Professora e orientadora Lilian Al-Chueyr Pereira Martins por seu apoio e objetividade, elevando minha auto-estima e segurança na realização deste trabalho. Pela orientação do Professor Roberto de Andrade Martins que sabiamente me auxiliou durante a elaboração deste trabalho e que me autorizou a utilizar sua análise inédita dos trabalhos de Schrödinger de 1926. Aos Professores José Luiz Goldfarb e Roberto de Andrade Martins, que fizeram parte da minha banca de qualificação, dando sugestões importantes para melhoria desta dissertação. Pela orientação das Professoras Ana Maria Alfonso-Goldfarb e Maria Elice Brzezinski Prestes que me auxiliaram na elaboração do projeto de mestrado durante os primeiros passos do curso. Aos professores do programa pelo convívio, empenho e dedicação que tiveram neste breve espaço de tempo. Ao núcleo do programa bolsa-mestrado e oficina pedagógica da diretoria centro-sul da Secretaria da Educação do estado de São Paulo, pela dedicação e auxílio com relação à bolsa de estudos. A minha família, em especial, a minha esposa Maria Ângela que teve paciência e compreensão quando estive ausente. RESUMO O presente trabalho histórico investiga a fase inicial da construção da mecânica ondulatória formulada pelo físico austríaco Erwin Schrödinger (1887- 1961), dando especial atenção aos trabalhos por ele realizados de dezembro de 1925 até fevereiro de 1926. Nesse período, Schrödinger concebeu as bases de sua teoria quântica e redigiu os dois primeiros artigos sobre o assunto, publicados na revista Annalen der Physik. Esta dissertação analisa esses dois artigos, bem como alguns de seus precedentes e repercussões. É analisada em especial a influência da teoria de ondas de matéria do físico francês Louis de Broglie (1892- 1987) no desenvolvimento da teoria de Schrödinger, bem como outros trabalhos e circunstâncias importantes que contribuíram para a elaboração da mecânica ondulatória. Discute-se também a interpretação que o próprio Schrödinger deu à sua teoria, comparando-a com o enfoque adotado por outros físicos da época. Palavras chaves: Erwin Schrödinger, mecânica ondulatória, equação de onda de Schrödinger, quantização, função de onda, física quântica, mecânica quântica. ABSTRACT This historical research analyses the initial period of construction of wave mechanics, as propounded by the Austrian physicist Erwin Schrödinger (1887- 1961), emphasizing his work from December 1925 to February 1926. During these months Schrödinger created the basis of his quantum theory and wrote his two earlier papers on this subject. They were published in the Annalen der Physik. The present dissertation analyses those two papers, and some of their precedents and immediate consequences. Special attention is given to the influence of the theory of matter waves of the French physicist Louis de Broglie (1892-1987) upon the development of Schrödinger’s theory, as well as other works and relevant circumstances that contributed to the creation of wave mechanics. The dissertation also discusses the interpretation given by Schrödinger to his own theory, comparing it to the approach of other physicists of that time. Keywords: Erwin Schrödinger, wave mechanics, Schrödinger wave equation, quantization, wave function, quantum physics, quantum mechanics. SUMÁRIO INTRODUÇÃO – TEMÁTICA GERAL....................................................................................................... 1 CAPÍTULO 1 – A FÍSICA QUÂNTICA ANTES DA CONSTRUÇÃO DA MECÂNICA ONDULATÓRIA............................................................................................................................................. 6 1.1 PLANCK E A QUANTIZAÇÃO DA ENERGIA.......................................................................................... 6 1.2 ALBERT EINSTEIN E O QUANTUM DE LUZ .......................................................................................... 9 1.3 A TEORIA DOS CALORES ESPECÍFICOS DE EINSTEIN E O CONGRESSO SOLVAY................................ 12 1.4 O ÁTOMO QUANTIZADO DE NIELS BOHR........................................................................................ 14 1.5 A TEORIA RELATIVÍSTICA DE SOMMERFELD................................................................................... 16 1.6 O DESENVOLVIMENTO DA MECÂNICA MATRICIAL ........................................................................ 19 1.7 LOUIS DE BROGLIE E A NATUREZA DA LUZ..................................................................................... 21 1.8 AS ONDAS ASSOCIADAS ÀS PARTÍCULAS ........................................................................................ 22 1.9 EXPLICAÇÃO DA QUANTIZAÇÃO DO ÁTOMO, POR LOUIS DE BROGLIE.............................................. 24 1.10 LOUIS DE BROGLIE E A RELAÇÃO ENTRE ÓPTICA E MECÂNICA ..................................................... 27 1.11 A TEORIA FINAL DE LOUIS DE BROGLIE ....................................................................................... 29 CAPÍTULO 2 – SCHRÖDINGER E A TEORIA QUÂNTICA................................................................. 31 2.1 EINSTEIN E A TEORIA DE LOUIS DE BROGLIE.................................................................................. 32 2.2 SCHRÖDINGER E A ESTATÍSTICA DOS GASES................................................................................... 34 2.3 SCHRÖDINGER E A TESE DE LOUIS DE BROGLIE.............................................................................. 36 2.4 A BUSCA DE UMA EQUAÇÃO DE ONDA RELATIVÍSTICA ................................................................... 39 2.5 AS FÉRIAS DE SCHRÖDINGER NO NATAL DE 1925........................................................................... 43 2.6 O CADERNO DE ANOTAÇÕES DE SCHRÖDINGER ............................................................................. 47 2.7 O RETORNO A ZURICH E OS ARTIGOS DE 1926................................................................................ 48 CAPÍTULO 3. ANÁLISE DOS DOIS PRIMEIROS ARTIGOS DE SCHRÖDINGER DE 1926.......... 55 3.1 “QUANTIZAÇÃO COMO UM PROBLEMA DE AUTOVALOR. PRIMEIRA MEMÓRIA” .............................. 55 3.1.1 A estratégia de Schrödinger .................................................................................................. 55 3.1.2 Introdução da equação de onda ............................................................................................ 57 3.1.3 O átomo de hidrogênio.......................................................................................................... 59 3.1.4 As vibrações atômicas ........................................................................................................... 62 3.1.5 Energia e freqüência ............................................................................................................. 63 3.1.6 Batimentos e a condição de freqüência de Bohr ................................................................... 65 3.1.7 O adendo: outra apresentação da equação de onda............................................................. 66 3.2 “QUANTIZAÇÃO COMO UM PROBLEMA DE AUTOVALOR. SEGUNDA MEMÓRIA”.............................. 67 3.2.1 Justificativa da equação de onda .......................................................................................... 67 3.2.2 Hamilton e a relação entre óptica e mecânica...................................................................... 68 3.2.3 Coordenadas generalizadas e geometria não-euclidiana ..................................................... 70 3.2.4 A passagem à idéia de frente de onda ................................................................................... 73 3.2.5 Relação entre os princípios de Fermat e de Maupertuis....................................................... 76 3.2.6 Justificativa de uma “mecânica ondulatória”....................................................................... 77 3.2.7 As propriedades da onda de fase........................................................................................... 78 3.2.8 Grupos de ondas...................................................................................................................
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