Hydrogen, Nuclear, Ammonia Another (Blue Sky) Way

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Hydrogen, Nuclear, Ammonia Another (Blue Sky) Way Department of Department of Mechanical Mechanical Engineering Engineering Powertrain & Vehicle PowertrainLow & Vehicle-Carbon Aviation – How can this be achieved? Research Centre Research Centre Dr James Turner Professor of Engines and Energy Systems University of Bath, UK Niels Bohr “Prediction is very difficult, especially if it's about the future.” Overview of Presentation Downsized engines . The historical link between aviation and automotive Our need to change . The growth in transportation energy The need for high energy density fuel in aviation . Pure hydrocarbons and the problem with everything else Some options for decarbonizing fuel in aviation . Hydrogen, nuclear, ammonia Another (blue sky) way . ZELTA Carbon-neutral liquid fuels . Decarbonizing practical fuels Concluding remarks Downsized, Boosted Engines – the Link Aviation pursued engine boosting to maintain power at altitude and then to increase specific output significantly Many of the engine technologies now employed in road vehicle engines effectively came from aviation via racing . Twin-spark ignition 1923 Halford . Double overhead cams (DOHC) Special Engine . Four valves per cylinder (4vpc) 4vpc, DOHC 6-cylinder The first turbocharged . Supercharging (then turbocharging) car engine . High octane fuels . Direct injection (DI) . Water injection (‘ADI’) Major Frank Halford designed all of de Havilland’s Major Halford was engines and all of the Napier H-engines, as well as being President of the fundamental in the successful development of the gas RAeS in 1951 turbine (with ‘straight-through’ combustion chambers) Automotive Engines are Architecturally-Frozen Aero Engines… It could be argued that the template for the modern automotive engine was actually laid down by Napier in 1916 with the Lion . 4vpc, DOHC, narrow valve angle and a single cam cover . 101 years old Then general automotive engineering followed aero engine technology after a 10-20 year delay… However, in the 1940s/50s the gas turbine comprehensively broke this delayed take-up link . …And the automotive industry never adopted the sleeve valve as a result Consequently the modern automotive engine shares Napier Lion much in common with the Rolls-Royce Merlin, Daimler- Benz 601 and Allison V-1710 . Effectively it’s architecturally frozen at 85 years old Potential Transfer of Automotive Technology Back to Aviation It has been attempted to use an automotive engine in light aviation before – the Porsche Flugmotor PFM 3200 . Development started in 1981 . 212-241 bhp Modern downsized, boosted, DI automotive engines are light, reliable and fuel efficient, and their control systems may well be more reliable than current light aircraft avionics . Due to on-board diagnostics requirements There are now several all-aluminium 2.0 litre DI engines which deliver 200-350 bhp . Is this an option worth persuing? This would be going full circle on engines… UK Transport Energy Consumption by Mode, 1970-2014 Air transport represents a particular problem: How do you fully decarbonize an aircraft? Air Water Road Rail Taken from: Energy Consumption in the UK (2015), DECC Change in UK Transport Energy Consumption, 1970-2014 Long-range aircraft present a significant problem Even hybrid aircraft propulsion systems can only Air reduce CO2 while there is fossil carbon in the fuel % Water Road Air: +320 Air: Rail Taken from: Energy Consumption in the UK (2015), DECC UK Road Transport Energy by Type of Vehicle, 1970-2014 2008: Beginning of Simple: let’s just electrify the private road transportation fleet EU CO2 legislation Consumption of road transport is ‘only’ 40 Mtoe… Cars 1 Mtoe = 41.87 PJ (41.87 x 1015 J)… This is a continuous output of 1.33 GW over a year – more than a good-sized nuclear power station (~ 1 GW) HGVs LGVs Buses Motorcycles Taken from: Energy Consumption in the UK (2015), DECC UK Transport Energy Consumption by Mode, 2014 53 x 1 GW nuclear The total design power of the two power stations Hinkley Point C reactors is 3.2 GW 16.5 Hinkley Point Cs For perspective, in 2014 the average UK electrical power demand was 34.4 GW (or only half the total transport demand) Peak demand in 2015 was 52.7 GW To date, the only practical energy 5.3 Hinkley Point Cs system for transport has been fossil oil 17 x 1 GW nuclear power stations Which, because we have developed fuel supply together with transportation, has developed symbiotically with it By my reckoning, we pump oil at a rate of 7.4% of the flow of Niagara Falls… Taken from: Energy Consumption in the UK (2015), DECC Long-Range Aircraft Battery Sizing Calculation At take-off, a Boeing 787-9 has 50.7 tonnes of fuel on board for a 9000 km flight . This is 605 MWh of energy (2.18 x 106 MJ) To convert to electric propulsion, we should allow an approximate factor of two to allow for increased electric machine efficiency versus thermal engines . Implies energy at take-off for the electric version is 302.5 MWh (1.09 x 106 MJ) • Or 3000 Tesla Model S P100D batteries (which are 700 kg each…) Using 150-250 Wh/kg as a cell energy density, this gives a battery mass of 1210-2017 tonnes (cell level) Calculation courtesy of Current 787-9 fully-laden take-off Dr Richard Pearson, BP weight is 253 tonnes . Battery will be 5-8 times heavier At 1.4 MW it would take 216 hours (9 days) to fully charge it… Plainly, this isn’t going to work! On-Board Energy Density: Batteries v Everything… HTA 30 aviation Diesel/Kerosene really 25 Road Gasoline needs to transport be here Rider: at 20 could E85 automotive happily scale Densities: live here M85 15 Ethanol Liquid (cryogenic) H2 = 70.8 kg/m3 H is hardly 2 Kerosene (jet fuel) = better than Methanol 10 840 kg/m3 batteries Liquid H2 (or 11.8 times greater) 5 700 bar H2 200 bar Methane This makes them really expensive and heavy Net volumetric energy density / [MJ/l] / density energy volumetric Net 0 Compared to liquid fuels batteries don’t really get off the origin… Batteries 0 5 10 15 20 25 30 35 40 Net gravimetric energy density / [MJ/kg] Courtesy Lotus Engineering How do you Decarbonize Aviation? General Electric Ammonia (NH3) and X211 turbojet: Hydrazine (N2H4) have also nuclear core (!) been researched, as has… Hydrogen Uranium Oxide Requirement to carry significant energy makes liquid hydrogen viable here NERVA Nuclear Rocket Engine Carbon-Neutral Ammonia Battlefield Mobile Compact 82% of power to Reactor electrolysis What could possibly go wrong? 32.7% efficient in terms of HHV Allison PD-81 Ammonia Taken from RRHT Allison Branch Research Engine Newsletter, November 2011 Can Hydrogen Work? (1) Liquid hydrogen has historically been investgated by the Lockheed Skunk Works and Pratt & Whitney – Project ‘Suntan’ . Hydrogen was considered attractive because of its high lower heating value and the fact that a lot of energy would have to be carried Suntan performed preliminary design work and P&W built a liquid H2 engine . The 304 . But the idea was dropped because of the problem of difficulties in hydrogen storage The concept was rescoped and became the SR-71 Pratt & Whitney 304 ‘Suntan’ engine Taken from: “Advanced Engine Development at Pratt & Whitney” by Mulready, R.C. Can Hydrogen Work? (2) Recently the EU-funded ‘Cryoplane’ project investigated the use of liquid hydrogen to fuel long-range passenger aircraft . Combustion tests using hydrogen were conducted to establish engine control limits Investigations into global warming potential were conducted . H2 was found to significantly better than kerosene . Water is a greenhouse gas too, but if the hydrogen cycle is closed then this is not an issue – as long as ‘green’ hydrogen from e.g. electrolysis is used Unfortunately the requirement for a Note impact of large particular shape of tank – torospherical – torospherical tanks meant that the concept was not viable There is also the need to derive lift from the fuel energy in heavier-than-air aircraft 6 For the 787-9: 2.18 x 10 MJ = 18 tonnes of H2 Which occupies 254.2 m3 c.f. 60.4 m3 of kerosene – 4.2 times greater Cryoplane ZELTA – Zero Emission Lighter-Than-Air If the requirement for high-speed aerodynamic efficiency and the need to carry the energy to generate lift can be removed, an interesting possibility arises… A preliminary design study has been conducted at the University of Bath . Suggests that a 100-tonne payload, 100 knot airship with sufficient range to fly from Cardington to San Francisco could be built and fuelled using liquid hydrogen Note: helium would be the lifting gas, not hydrogen! . Exhaust ballast recovery and fuel cells to generate electricity and supply potable water would also be incorporated LH2 Tank ZELTA Richardson, A., ‘Study of design factors for rigid airships for long- range, high-payload operation with zero in use carbon emissions’ Returning to the Actual Problem… The real problem with transport is that we operate the vehicles on fossil fuels . Economically-affordable engines do not have to use such fuels: both Diesel and Ford made their engines run on biofuels – we then made them run on fossil fuels instead But there is no shortage of carbon-free energy . We just need to find a means to convert it to a form usable in existing vehicles Solving the Problem… A pragmatic solution would be to use renewable energy to synthesize drop-in alternatives to the fuels we use now These are known as ‘Carbon-Neutral Liquid Fuels’, ‘Electrofuels’ or ‘Synthetic Fuels’ Solving the Problem: the Sustainable Methanol-Based Cycle Feed stocks are water, air Energy in Hydrogen from and renewable energy electrolysis of water: 1 H O H + O 2 2 2 2 The price of these feed stocks is free and a high- value product is made Carbon out Methanol synthesis: Provides the economic Synthetic CO 2 + 3H2 C H3 OH + H2 O hydrocarbons From Lackner, K.,‘Options for and products driver to decarbonize and Capturing Carbon Dioxide CO2 consumption from the Air’, May 2008 a valuable buffer for Fuel use: renewable energy 3 CH OH + O Direct air 3 2 2 capture of CO2 CO 2 + 2H2 O Carbon in CO2 from fossil fuel burning Atmospheric CO 2 power plants Gasoline, diesel and kerosene CO2 emission can also be synthesized from AdaptedAdapted from Olah fromet al., The Olah Methanol et Economy al., these feed stocks – with an ‘The Methanol Economy’ energy penalty (c.
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