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FLAMMABLES Ignitable Waste (Flammables) - The waste code is D001 It is a liquid and has flash point less than 140 °F (60° C) Below are examples of flammable liquids that would be D001 Hazardous Waste Class IA Flash point below 73 F, boiling point below 100 F acetaldehyde, ethyl chloride, petroleum ether collodion, methyl ethyl ether, propylene oxide ethyl ether, pentane Class IB Flash point below 73 F, boiling point at or above 100 F acetone, ethyl acetate, methyl alcohol benzene, ethyl alcohol, methylcyclohexane butyl alcohol, gasoline, toluene Class IC Flash point at or above 73 F and below 100 F amyl acetate, isopropanol , turpentine amyl alcohol, methyl alcohol dibutyl ether, xylene, styrene Class II Flash point at or above 100 F and below 140 F acetic acid, fuel oil no. 44, mineral spirits camphor oil, methyl lactate, varsol cyclohexane, hydrazine, kerosene KEY - H - Health, F - Flammability, R - Reactivity, SH - Special Hazard See NFPA tab for ratings number definition Compound CAS H F R SH 1-(2-Aminoethyl)piperazine 000140-31-8 2 2 0 1-Amino-2-propanol 000078-96-6 2 2 0 1-Butanethiol 000109-79-5 2 3 0 FLAMMABLES 1-Butene 000106-98-9 1 4 0 1-Chloro-1-nitroethane 000600-25-9 - 2 3 1-Chloro-1-nitropropane 000600-25-9 - 2 3 1-Chloro-2-propanol 000127-00-4 2 2 0 1-Chlorohexane -- - 3 0 1-Chloropropylene 000590-21-6 2 4 2 1-Crotyl bromide 004784-77-4 2 3 2 1-Crotyl chloride 000591-97-9 2 3 2 1-Decene -- 0 2 0 1-Hexene 000592-41-6 1 3 0 1-Methyl piperazine 075079-26-4 2 2 0 1-Methyl-3,5-diethyl-benzene 002050-24-0 0 2 0 1-Methylnaphthalene 000090-12-0 2 2 0 1-Nitropropane 000108-03-2 1 3 2 1-Octanethiol 2 2 0 1-Octene 000111-66-0 1 3 0 1-Pentene (n-amylene) 000109-67-1 1 4 0 1-Pentyne 000627-19-0 - 3 3 1-Phenyl-2-butene 001560-06-1 - 2 0 1,1-Dichloro-1-nitro ethane 2 2 3 1,1-Dichloro-1-nitro propane 000595-44-8 2 2 3 1,1-Dichloroethene 2 4 2 1,1-Dimethylhydrazine 000057-14-7 4 3 1 1,1-Ethylidene dichloride 000075-34-3 2 3 0 1,1,2-Trichloroethane 000079-00-5 1,1,3,3-Tetramethoxypropane 022288-43-3 0 2 0 1,2-Butanediol 000584-03-2 1 2 0 1,2-Butylene oxide 000106-88-7 2 3 2 1,2-Dichlorobutane 000616-21-7 2 2 0 1,2-Dichloroethylene 2 3 2 1,2-Dicholoroethyl ether 3 2 1 1,2-Dimethylcyclohexane 000583-57-3 0 - 0 1,2-Dinitrobenzene 000528-29-0 1,2-Ethanediol diformate 000629-15-2 1 2 0 1,2-Ethylidene dichloride 000107-06-2 2 3 0 FLAMMABLES 1,2,3-Trichloropropane 000096-18-4 3 2 0 1,2,3-Trimethylbenzene 000526-73-8 0 2 0 1,2,3-Trimethylbenzene 90.5% 000526-73-8 0 2 0 1,2,3,4-Tetramethylbenzene 95% 000488-23-3 0 2 0 1,2,3,4,5-Pentamethyl benzene 95% -- - 2 0 1,2,3,5-Tetramethylbenzene 85.5% 000527-53-7 0 2 0 1,2,3,6-Tetrahydrobenzaldehyde 2 2 0 1,2,4-Triethylbenzene -- - 2 0 1,2,4-Trimethylbenzene 000095-63-6 0 2 0 1,2,4,5-Tetramethylbenzene 95% 000527-53-7 0 2 0 1,3-Butadiene 000106-99-0 2 4 2 1,3-Butanediamine 000590-88-5 3 2 0 1,3-Dichloro-2-butene 000926-57-8 3 3 2 1,3-Dichloro-2,4-hexadiene -- - 2 0 1,3-Dichlorobutene-2 -- 2 3 0 1,3-Dichloropropene 000542-75-6 2 3 0 1,3-Dicholoro-2-butene 3 3 2 1,3-Dicholoro-2-propanol 2 2 0 1,3-Dicholoro-2,4-hexadiene - 2 0 1,3-Dimethylbutyl acetate 000108-84-9 1 2 0 1,3-Dimethylbutylamine 000108-09-8 2 3 0 1,3-Dimethylcyclohexane 000591-21-9 0 3 0 1,3-Dimethylcyclohexane-cis 0 3 0 1,3-Dimethylcyclohexane-trans 0 3 0 1,3-Pentadiene (cis and trans mix) 000504-60-9 0 4 2 1,3-Propanediamine 000104-78-9 2 3 0 1,3,5-Trimethylbenzene 000108-67-8 0 2 0 1,3,5-Trimethylcyclohexane 001839-63-0 0 - 0 1,4-Dichlorobutane 3 2 0 1,4-Dimethylcyclohexane 000589-90-2 1 3 0 1,4-Dimethylcyclohexane-cis 000589-90-2 0 3 0 1,4-Dimethylcyclohexane-trans 000589-90-2 0 3 0 1,4-Hexadiene 000592-45-0 0 3 0 1,4-Thioxane 2 2 0 1,5-Cyclooctadiene 000111-78-4 - 3 0 FLAMMABLES 1,5-Dichloropentane 000628-76-2 2 3 0 1,5-Dicholoropentane 2 3 0 1,5,9-Cyclododecatriene 004904-61-4 - 2 0 2-(Diethylamino) ethanol 2 2 0 2-(Diethylamino) ethyl acrylate 002426-54-2 2 2 1 2-(Dimethylamino) ethanol 000108-01-0 2 2 0 2-(Dimethylamino) ethyl methacrylate 002867-47-2 2 2 0 2-Amino-1-butanol 000096-20-8 2 2 0 2-Amino-2-methyl-1-propanol 000124-68-5 2 2 0 2-Butanethiol 000513-53-1 2 3 0 2-Butene-cis 000590-18-1 1 4 0 2-Butene-trans 000624-64-6 1 4 0 2-Butyne 000503-17-3 - 4 - 2-Chloro propylene 000557-98-2 2 4 0 2-Chloro-1-propanol 000078-89-7 2 2 0 2-Chloro-1,3-butadiene 000126-99-8 2 3 0 2-Chloro-2-nitropropane 000594-71-8 - 2 3 2-Chlorobutene-2 004461-41-0 2 3 0 2-Chloroethanol 000107-07-3 4 2 0 2-Chloroethyl acetate 000542-58-5 2 2 0 2-Ethoxy-3,4-dihydro-2-pyran 000103-75-3 2 2 1 2-Ethoxyethyl acetate 000111-15-9 2 2 0 2-Ethyl butyl glycol -- 0 2 0 2-Ethyl-1-butene 000760-21-4 0 3 0 2-Ethyl-3-propylacrolein 000645-62-5 2 2 1 2-Ethylbutyl acetate 1 2 0 2-Ethylbutyl acrylate 003953-10-4 2 2 0 2-Ethylbutyl alcohol 000097-95-0 1 2 0 2-Ethylbutyraldehyde 000097-96-1 2 3 1 2-Ethylhexanal 000123-05-7 2 2 1 2-Ethylhexanol 000104-76-7 2 2 0 2-Ethylhexyl acetate 000103-09-3 2 2 0 2-Ethylhexyl acrylate 000103-11-7 2 2 2 2-Ethylhexyl chloride 000123-04-6 2 2 0 2-Ethylhexylamine 000104-75-6 2 2 0 FLAMMABLES 2-Ethylisohexanol 000106-67-2 1 2 - 2-Heptanol 000543-49-7 0 2 0 2-Hexene-cis 007688-21-3 0 3 0 2-Mercaptoethanol 000060-24-2 2 2 - 2-Methoxybutanol 1 2 0 2-Methoxybutyl acetate 1 2 0 2-Methoxybutyraldehyde 0 2 0 2-Methoxyethyl acrylate 0 2 0 2-Methyl butynol 2 3 0 2-Methyl-1-butanol 000137-32-6 2 2 0 2-Methyl-1-butene (technical grade) 000563-46-2 2 4 0 2-Methyl-1-pentanol 000105-30-6 0 2 0 2-Methyl-1-pentene 000763-29-1 1 3 0 2-Methyl-1,3-pentadiene 001118-58-7 0 3 0 2-Methyl-2-butanol 000075-85-4 1 3 0 2-Methyl-2-butene 000513-35-9 2 3 0 2-Methyl-2-ethyl-1,3-dioxolane -- 2 3 0 2-Methyl-2-pentene 000625-27-4 1 3 0 2-Methyl-2-propanethiol 000075-66-1 2 3 0 2-Methyl-3-ethylpentane 000609-26-7 0 3 0 2-Methyl-4-ethylhexane 003074-75-7 0 3 0 2-Methyl-5-ethyl-piperidine 000104-89-2 2 2 0 2-Methyl-5-ethylpyridine 000104-90-5 3 2 0 2-Methylbiphenyl 000643-58-3 2 - 0 2-Methylbutyraldehyde 000096-17-3 2 3 0 2-Methylcyclohexanol 000583-59-5 - 2 0 2-Methyldecane 006975-98-0 0 2 0 2-Methylfuran 000534-22-5 2 3 1 2-Methylhexane 000591-76-4 0 3 0 2-Methylpentane 000107-83-5 1 3 0 2-Methylpropenal 000078-85-3 3 3 2 2-Methylpropene 000115-11-7 1 4 0 2-Methylpyrazine 000109-08-0 2 2 0 2-Methyltetrahydrofuran 000096-47-9 2 3 0 2-Methylvaleraldehyde 000123-15-9 1 3 0 FLAMMABLES 2-Nitropropane 000079-46-9 1 3 2 2-Octanol 000123-96-6 1 2 0 2-Octene (mixed cis and trans isomers) -- 1 3 0 2-Picoline 000109-06-8 2 2 0 2-Vinyl-5-ethylpyridine 005408-74-2 2 2 2 2, Beta-butoxyethoxyethyl chloride 2 2 0 2,2-Dichloro isopropyl ether 039638-32-9 2 2 0 2,2-Dichloroethyl ether 3 2 1 2,2-Dimethylbutane 000075-83-2 1 3 0 2,2-Dimethylpropane 000463-82-1 0 4 0 2,2,3-Trimethylbutane 000464-06-2 0 3 0 2,2,3-Trimethylpentane 000564-02-3 0 3 0 2,2,3,3-Tetramethyl pentane -- 0 3 0 2,2,3,4-Tetramethylpentane 001186-53-4 0 3 0 2,2,4-Trimethylpentane - 3 0 2,2,5-Trimethylhexane -- 2 3 0 2,2'-Dichloroethyl ether 000111-44-4 3 2 1 2,3-Butanedione 000431-03-8 1 3 0 2,3-Butylene oxide 2 3 2 2,3-Dichlorobutadiene-1,3 001653-19-6 3 3 2 2,3-Dichlorobutane 007581-97-7 2 2 0 2,3-Dichloropropene 000078-88-6 3 3 0 2,3-Dimethyl-1-butene 000563-78-0 0 3 0 2,3-Dimethyl-2-butene 000563-79-1 0 3 0 2,3-Dimethylbutane 000079-29-8 1 3 0 2,3-Dimethylhexane 000584-94-1 0 3 0 2,3-Dimethyloctane 007146-60-3 0 2 0 2,3-Dimethylpentaldehyde -- 2 3 0 2,3-Dimethylpentane 000565-59-3 0 3 0 2,3,3-Trimethyl-1-butene 000594-56-9 0 3 0 2,3,3-Trimethylpentane 000560-21-4 0 3 0 2,3,4-Trimethyl-1-pentene 000565-76-4 0 3 0 2,4-Dimethyl-3-ethylpentane -- 0 3 0 2,4-Dimethyl-3-pentanol -- 0 2 0 2,4-Dimethylhexane 000589-43-5 0 3 0 FLAMMABLES 2,4-Dimethylpentane 000108-08-7 0 3 0 2,4-Hexadienal 080466-34-8 2 2 0 2,4-Pentanedione 2 2 0 2,4,4-Trimethyl-2-pentene 000107-40-4 2 3 0 2,4,8-Trimethyl-6-nonanol 000123-17-1 0 2 0 2,5-Dimethylfuran 000625-86-5 2 3 0 2,5-Dimethylpyrazine 000123-32-0 - 2 0 2,5-Dinitrotoluene 000619-15-8 2,5-Norbornadiene 000121-46-0 - 3 1 2,5,5-Trimethylheptane -- 0 2 0 2,6-Dimethylmorpholine 000141-91-3 2 2 0 2,6-Dinitrotoluene 000606-20-2 2,6,8-Trimethyl-4-nonanol 000123-17-1 2 2 0 2,6,8-Trimethyl-4-nonanone 000123-18-2 2 2 0 2,beta-Butoxyethoxyethyl chloride 001120-23-6 2 2 0 3-(Diethylamino)-propylamine 000104-78-9 2 2 0 3-(Dimethylamino)-propionitrile - 2 1 3-(Dimethylamino)-propylamine 3 2 0 3-Aminopropanol 000156-87-6 3 2 0 3-Chloropropionitrile 000542-76-7 - 2 1 3-Ethoxypropanal 002806-85-1 2 2 0 3-Ethoxypropionaldehyde 002806-85-1 2 3 0 3-Ethyloctane 005881-17-4 0 2 0 3-Heptanol 000589-82-2 0 2 0 3-Heptene (mixed cis and trans) -- 0 3 0 3-Hexanone 000589-38-8 1 3 0 3-Hexenol-cis 000928-96-1 1 2 0 3-Isopropoxypropionitrile -- 1 2 1 3-Methoxybutanol 002517-43-3 1 2 0 3-Methoxybutyraldehyde 005281-76-5 0 2 0 3-Methoxypropionitrile 000110-67-8 4 2 1 3-Methoxypropylamine 005332-73-0 2 3 0 3-Methyl butynol 000115-19-5 2 3 0 3-Methyl-1-butene 000563-45-1 2 4 0 3-Methyl-1-pentynol 000077-75-8 1 2 0 FLAMMABLES 3-Methyl-2-butanethiol 002084-18-6 2 3 0 3-Methyl-4-ethylhexane 003074-77-9 0 3 0 3-Methylcyclohexanol 000591-23-1 0 2 0 3-Methylhexane 000589-34-4 0 3 0 3-Methylpentane 000096-14-0 1 3 0 3-Pentanol 000584-02-1 1 2 0 3,3-Diethylpentane 001067-20-5 0 3 0 3,3-Dimethylheptane 004032-86-4 0 3 0 3,3,5-Trimethyl-1-cyclohexanol 000116-02-9 2 2 0 3,4-Dichlorobutene-1 064037-54-3 3 2 1 3,4-Dimethyloctane -- 0 2 0 3,4,4-Trimethyl-2-pentene 000598-96-9 0 3 0 3,5,5-Trimethylhexanol 003452-97-9 2 2 0 4-(2-Aminoethyl)-morpholine 002038-03-1 2 2 0 4-Ethylmorpholine 000100-74-3 2 3 0 4-Ethyloctane 015869-86-1 0 2
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    Pt. 770 15 CFR Ch. VII (1–1–21 Edition) in the item that qualitatively affect the per- roller bearings and parts). This applies formance of the U.S. and foreign items; to separate shipments of anti-friction (vi) Evidence of the interchangeability of bearings or bearing systems and anti- U.S. and foreign items; friction bearings or bearing systems (vii) Patent descriptions for the U.S. and foreign items; shipped with machinery or equipment (viii) Evidence that the U.S. and foreign for which they are intended to be used items meet a published industry, national, or as spares or replacement parts. international standard; (2) An anti-friction bearing or bear- (ix) A report or eyewitness account, by ing system physically incorporated in a deposition or otherwise, of the foreign item’s segment of a machine or in a complete operation; machine prior to shipment loses its (x) Evidence concerning the foreign manu- identity as a bearing. In this scenario, facturers’ corporate reputation; (xi) Comparison of the U.S. and foreign end the machine or segment of machinery item(s) made from a specific commodity, containing the bearing is the item sub- tool(s), device(s), or technical data; or ject to export control requirements. (xii) Evidence of the reputation of the for- (3) An anti-friction bearing or bear- eign item including, if possible, information ing system not incorporated in a seg- on maintenance, repair, performance, and ment of a machine prior to shipment, other pertinent factors. but shipped as a component of a com- plete unassembled (knocked-down) ma- SUPPLEMENT NO.
  • Chapter 2: Alkanes Alkanes from Carbon and Hydrogen

    Chapter 2: Alkanes Alkanes from Carbon and Hydrogen

    Chapter 2: Alkanes Alkanes from Carbon and Hydrogen •Alkanes are carbon compounds that contain only single bonds. •The simplest alkanes are hydrocarbons – compounds that contain only carbon and hydrogen. •Hydrocarbons are used mainly as fuels, solvents and lubricants: H H H H H H H H H H H H C H C C H C C C C H H C C C C C H H H C C H H H H H H CH2 H CH3 H H H H CH3 # of carbons boiling point range Use 1-4 <20 °C fuel (gasses such as methane, propane, butane) 5-6 30-60 solvents (petroleum ether) 6-7 60-90 solvents (ligroin) 6-12 85-200 fuel (gasoline) 12-15 200-300 fuel (kerosene) 15-18 300-400 fuel (heating oil) 16-24 >400 lubricating oil, asphalt Hydrocarbons Formula Prefix Suffix Name Structure H CH4 meth- -ane methane H C H H C H eth- -ane ethane 2 6 H3C CH3 C3H8 prop- -ane propane C4H10 but- -ane butane C5H12 pent- -ane pentane C6H14 hex- -ane hexane C7H16 hept- -ane heptane C8H18 oct- -ane octane C9H20 non- -ane nonane C10H22 dec- -ane decane Hydrocarbons Formula Prefix Suffix Name Structure H CH4 meth- -ane methane H C H H H H C2H6 eth- -ane ethane H C C H H H H C H prop- -ane propane 3 8 H3C C CH3 or H H H C H 4 10 but- -ane butane H3C C C CH3 or H H H C H 4 10 but- -ane butane? H3C C CH3 or CH3 HydHrydorcocaarrbobnos ns Formula Prefix Suffix Name Structure H CH4 meth- -ane methane H C H H H H C2H6 eth- -ane ethane H C C H H H H C3H8 prop- -ane propane H3C C CH3 or H H H C H 4 10 but- -ane butane H3C C C CH3 or H H H C H 4 10 but- -ane iso-butane H3C C CH3 or CH3 HydHrydoroccarbrobnsons Formula Prefix Suffix Name Structure H H
  • Benzene MSDS

    Benzene MSDS

    He a lt h 2 3 Fire 3 2 0 Re a c t iv it y 0 Pe rs o n a l Pro t e c t io n H Material Safety Data Sheet Benzene MSDS Section 1: Chemical Product and Company Identification Product Name: Benzene Contact Information: Catalog Codes: SLB1564, SLB3055, SLB2881 Sciencelab.com, Inc. 14025 Smith Rd. CAS#: 71-43-2 Houston, Texas 77396 RTECS: CY1400000 US Sales: 1-800-901-7247 International Sales: 1-281-441-4400 TSCA: TSCA 8(b) inventory: Benzene Order Online: ScienceLab.com CI#: Not available. CHEMTREC (24HR Emergency Telephone), call: Synonym: Benzol; Benzine 1-800-424-9300 Chemical Name: Benzene International CHEMTREC, call: 1-703-527-3887 Chemical Formula: C6-H6 For non-emergency assistance, call: 1-281-441-4400 Section 2: Composition and Information on Ingredients Composition: Name CAS # % by Weight Benzene 71-43-2 100 Toxicological Data on Ingredients: Benzene: ORAL (LD50): Acute: 930 mg/kg [Rat]. 4700 mg/kg [Mouse]. DERMAL (LD50): Acute: &gt;9400 mg/kg [Rabbit]. VAPOR (LC50): Acute: 10000 ppm 7 hours [Rat]. Section 3: Hazards Identification Potential Acute Health Effects: Very hazardous in case of eye contact (irritant), of inhalation. Hazardous in case of skin contact (irritant, permeator), of ingestion. Inflammation of the eye is characterized by redness, watering, and itching. Potential Chronic Health Effects: CARCINOGENIC EFFECTS: Classified A1 (Confirmed for human.) by ACGIH, 1 (Proven for human.) by IARC. MUTAGENIC EFFECTS: Classified POSSIBLE for human. Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female [POSSIBLE].
  • Alkanes-1 [Compatibility Mode]

    Alkanes-1 [Compatibility Mode]

    10/17/2011 Alkanes ALKANES (a “family” of hydrocarbons) CnH2n+2 CH 4 C2H6 C3H8 C4H10 etc. C2H6 ethane H H H—C—C—H H H sp 3, bond angles = 109.5 o H H σ-bonds (sigma) C C HH HH rotation about C--C (conformations) representation: “andiron” or “sawhorse” 1 10/17/2011 H H H H H H H H H H H H “staggered” “eclipsed” torsional strain: deviation from staggered. Newman projections: H H H H H H H H H H H H y g r e n e l a 3 Kcal i t n e t o p rotation about C-C The barrier to rotation about the carbon-carbon bond in ethane is 3 Kcal/mole. The rotation is ~ “free.” C3H8 propane H H H HC C C H projection formula H H H CH3CH2CH3 partially condensed formula 2 10/17/2011 CH3 H CH3 H H H H H H H H H staggered eclipsed y g r e n e l a 3.4 Kcal i t n e t o p rotation about C-C C H butane(s) 4 10 H H C H H H H H H H HC C C C H HC C C H projection H H H H H H H CH 3 partially condensed CH3CH2CH2CH3 CH3CHCH3 stick formulas Two isomers of butane C 4H10 : CH 3CH 2CH 2CH 3 n-butane bp 0 oC mp –138 oC d 0.622 g/cc CH 3 CH 3CHCH 3 isobutane bp -12 oC mp -159 oC d 0.604 g/cc 3 10/17/2011 Conformations about C2-C3 in n-butane: CH3 H CH3 H H H H H H H H C CH3 3 anti CH3/H eclipsed CH3 H3C CH3 H3C H H H H H H H H gauche CH3/CH3 eclipsed conformations about C2-C3 in n-butane: H3CCH3 CH3 H3C 4.4-6.1 Kcal y g r e n 3.4 Kcal e l 0.8 Kcal a i t CH3 n H C e 3 t CH3 o p CH3 gauche anti rotation C5H12 pentane(s) CH3CH2CH2CH2CH3 n-pentane CH3 CH3CHCH2CH3 isopentane CH3 CH3CCH3 neopentane CH3 these are common, or trivial, names where a prefix is used to idicate the structure.