Methane on Mars: new insights into the sensitivity of CH4 with the NOMAD/ExoMars spectrometer through its first in-flight calibration Giuliano Liuzzia,b, Geronimo L. Villanuevaa, Michael J. Mummaa, Michael D. Smitha, Frank Daerdenc, Bojan Risticc, Ian Thomasc, Ann Carine Vandaelec, Manish R. Pateld,e, José-Juan Lopez-Morenof, Giancarlo Belluccig, and the NOMAD team a NASA Goddard Space Flight Center, 8800 Greenbelt Rd., Greenbelt, 20771 MD, USA b Dep. of Physics, American University, 4400 Massachusetts Av., Washington, 20016 DC, USA c Belgian Institute for Space Aeronomy, BIRA-IASB, Ringlaan 3, 1180 Brussels, Belgium d School of Physical Sciences, The Open University, Milton Keynes, MK7 6AA, UK e SSTD, STFC Rutherford Appleton Laboratory, Chilton, Oxfordshire OX11 0QX, UK f Instituto de Astrofisica de Andalucia, IAA-CSIC, Glorieta de la Astronomia, 18008 Granada, Spain g Istituto di Astrofisica e Planetologia Spaziali, IAPS-INAF, Via del Fosso del Cavaliere 100, 00133 Rome, Italy Corresponding author: Giuliano Liuzzi, e-mail:
[email protected] Abstract The Nadir and Occultation for MArs Discovery instrument (NOMAD), onboard the ExoMars Trace Gas Orbiter (TGO) spacecraft was conceived to observe Mars in solar occultation, nadir, and limb geometries, and will be able to produce an outstanding amount of diverse data, mostly focused on properties of the atmosphere. The infrared channels of the instrument operate by combining an echelle grating spectrometer with an Acousto-Optical Tunable Filter (AOTF). Using in-flight data, we characterized the instrument performance and parameterized its calibration. In particular: an accurate frequency calibration was achieved, together with its variability due to thermal effects on the grating.